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Wyświetlanie 1-8 z 8
Tytuł:
Thermal Decomposition Kinetics of Hexanitrohexaazaisowurtzitane/Ammonium Perchlorate
Autorzy:
Zhu, Y.-L.
Wang, K.-K.
Shan, M.-X.
Zheng, X.-D.
Jiao, Q.-J.
Wang, J.-S.
Powiązania:
https://bibliotekanauki.pl/articles/358067.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
hexanitrohexaazaisowurtzitane
ammonium perchlorate
thermal analysis
thermal decomposition kinetics
Opis:
The thermal decomposition kinetics of hexanitrohexaazaisowurtzitane/ ammonium perchlorate (HNIW/AP) have been investigated by thermogravimetrydifferential scanning calorimetry-mass spectrometry (TG-DSC-MS) simultaneous analysis. TG showed that there were three weight loss processes for the thermal decomposition of the HNIW/AP mixture. The first was ascribed mainly to the thermal decomposition of HNIW, while the second and third were assigned to that of AP. The presence of AP has little effect on the thermal decomposition process of the HNIW component. The apparent activation energy of the thermal decomposition of the HNIW component, calculated by the Kissinger method, was little changed compared to that of neat HNIW. The addition of HNIW to AP caused the onset and end temperatures of the thermal decomposition to be decreased and the decomposition process to be shortened. The high-temperature and lowtemperature decomposition processes of AP became blurred in the presence of HNIW, and this was supported by the MS results.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 1; 149-159
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of the Thermal Behaviour of CL-20, Potassium Perchlorate, Lithium Perchlorate and Their Admixtures by DSC and TG
Autorzy:
Zhang, J.-J.
Guo, X.-J.
Jiao, Q.-J.
Zhang, H.-L.
Li, H.
Powiązania:
https://bibliotekanauki.pl/articles/358770.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
CL-20
potassium perchlorate
lithium perchlorate
thermal stability
phase transition
Opis:
The thermal decomposition characteristics of CL-20, potassium perchlorate (KP), lithium perchlorate (LP), a CL-20/KP mixture, and a CL-20/LP mixture were studied using thermogravimetry-differential scanning calorimetry (TG-DSC). The DSC curves for KP exhibited three endothermic peaks and one exothermic peak. The first two endothermic peaks correspond to the rhombic-cubic transition and the fusion of KP, respectively, the third indicates the fusion of KCl, while the exothermic peak is attributed to the decomposition of KP. The DSC curves obtained from LP showed four endothermic peaks and one exothermic peak. The first two endothermic peaks indicate the loss of adsorbed water and water of crystallization, while the third and fourth are associated with the fusion of LP and LiCl, respectively; the exothermic peak is due to the decomposition of LP. The presence of KP had little effect on the thermal decomposition of CL-20 while the addition of LP increased the temperature at which CL-20 exhibits an exothermic peak. In addition, the thermal decomposition of LP appeared to be catalyzed by the presence of CL-20.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 115-130
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication of Nano- and Micron- Sized Spheres of CL-20 by Electrospray
Autorzy:
Yan, S.
Li, M.
Sun, L.
Jiao, Q.
Huang, R.
Powiązania:
https://bibliotekanauki.pl/articles/358652.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
energetic materials
explosives
CL-20
electrospray
spherical particles
Opis:
The application of hexanitrohexaazaisowurtzitane (CL-20) in energetic materials will be expanded by its use as superfine particles. A method of fabricating nano- and micron-sized spheres of CL-20 by using electrospray is discussed. The effects of the precursor solution and the experimental conditions on the morphology and the crystal phase of the CL-20 particles are introduced. A variety of solvents was used to dissolve raw CL-20 for the preparation of the precursor solution with different CL-20 contents. The conductivity and viscosity of the precursor solutions were tested before the electrospray process. The electrostatic parameters were adjusted by changing the voltage and the distance between the nozzle and the plate. The morphology, crystal phase, mechanical sensitivity, density, and thermal stability of the raw CL-20 and the as-sprayed CL-20 samples were determined using scanning electron microscopy, X-ray diffraction, and differential scanning calorimetry (DSC). Furthermore, the density and the mechanical sensitivity were tested for the raw and the as-sprayed CL-20. DSC tests were conducted to compare the thermal stability and reactivity of the samples.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 4; 572-589
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on the Detonation Parameters of Aluminized Explosives Based on a Disequilibrium Multiphase Model
Autorzy:
Pei, H.
Nie, J.
Jiao, Q.
Powiązania:
https://bibliotekanauki.pl/articles/358535.pdf
Data publikacji:
2014
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
nonideal explosives
velocity of detonation
detonation pressure
relaxation timescale
Opis:
Detonation models are usually based on the classical Euler equations of gas dynamics under the assumption of thermodynamic equilibrium. However reported data show the Chapman-Jouguet (CJ) detonation parameters of nonideal explosives based on thermodynamic equilibrium codes are significantly different from experimental results. Based on the conventional CJ model, a new multiphase flow model, not in thermal equilibrium, was considered in this study. This approach was applied to compute the velocity of detonation for several aluminized explosives. The predictions are better than the CJ equilibrium model and are in excellent agreement with experimental data. All of the deviations for the velocity of detonation (VOD) are less than 4%.
Źródło:
Central European Journal of Energetic Materials; 2014, 11, 4; 491-500
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Bismuth Complex Catalysts on the Cure Reaction of Hydroxyl-terminated Polyether-based Polymer Bonded Explosives
Autorzy:
Ou, Y.
Jiao, Q.
Yan, S.
Zhu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/358587.pdf
Data publikacji:
2018
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
HTPE
bismuth complex catalyst
pot-life
manufacture time reduction
mechanical and thermal characteristics
Opis:
The kinetics of catalyzed urethane-forming reactions of hydroxyl-terminated polyether (HTPE) with toluene di-isocyanate (TDI) in the presence of bismuth complex catalysts was investigated by non-isothermal differential scanning calorimetry (DSC). Fourier transform infrared spectroscopy (FTIR) was employed to monitor the chemical interactions of relevant groups. The kinetic parameters, including the apparent activation energy (Ea) and reaction rate constants (k) at typical temperatures calculated by the Kissinger and Crane methods, were used to evaluate the catalytic activities of triphenylbismuth (TPB) and tris(3-ethoxyphenyl)bismuthine (TEPB). The variations of Ea were studied to obtain an insight into the consistency of catalytic mechanism for the bismuth complex catalysts. The viscosity build-up of HTPE-based polymer bonded explosive (PBX) slurry was then measured to verify the catalytic activity and the pot-life during an actual manufacturing process, which fitted with the kinetics of the catalyzed cure reaction. The cure process was evaluated by the hardness of the PBX grains maintained at a temperature below typical manufacturing conditions. The results showed that TEPB is an effective catalyst, reducing the Ea of the cure reaction and the manufacturing temperature and time with an acceptable pot-life. The mechanical, thermal characteristics and compatibility of the HTPE-based PBXs were also investigated. The results suggest that TEPB is compatible with HTPE-based PBXs and contributes to improving the mechanical properties and thermal safety.
Źródło:
Central European Journal of Energetic Materials; 2018, 15, 1; 131-149
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A method for tracing exogenous DNA uptake in live spermatozoa and embryos
Autorzy:
Mu, Y.
Wang, J.
Liu, Z.
Zhao, Y.
Zhang, X.
Jiao, M.
Lv, J.
Hao, J.
Kong, Q.
Powiązania:
https://bibliotekanauki.pl/articles/2087751.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spermatozoa
SMGT
exogenous DNA
IVF
Źródło:
Polish Journal of Veterinary Sciences; 2018, 21, 1; 193-202
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation and Characterization of Desensitized ?-HNIW in Solvent-Antisolvent Recrystallizations
Autorzy:
Jiang, X.
Guo, X.
Ren, H.
Jiao, Q.
Powiązania:
https://bibliotekanauki.pl/articles/358201.pdf
Data publikacji:
2012
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ε -HNIW
supersaturation
crystal morphology
thermal decomposition
reduced sensitivity
Opis:
The solubility of hexanitrohexaazaisowurtzitane (HNIW) in solvent and solvent-antisolvent mixtures, and the temperature at which the HNIW's polymorph transforms were studied. The solubility of HNIW in solvent-antisolvent mixtures was measured at 30 C and these data were fitted to a generalized solubility curve. Recrystallization experiments were conducted at 30 C in the case of saturation with the volume ratio of ethyl acetate to petroleum ether (chloroform) ranging from 0:1 to 4:1. Desensitized HNIW was obtained by ethyl acetate and petroleum ether crystallization and characterized by Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), High Performance Liquid Chromatography (HPLC) and Scanning Electron Microscopy (SEM). The FTIR and XRD spectra confirmed the structural features of ε-HNIW. The blocklike ε-HNIW grains had an average particle size of 160 ?m and high purity (98.52%). The decomposition of ε-HNIW was observed in the temperature range of 225-246 C by Differential Scanning Calorimetry (DSC). Furthermore, the impact and friction sensitivity tests suggested that the desensitized ε-HNIW was less sensitive than raw HNIW. Small scale gap tests with desensitized ε-HNIW showed that these crystals are less sensitive to shock initiation.
Źródło:
Central European Journal of Energetic Materials; 2012, 9, 3; 219-236
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on the Mechanism and Kinetics of Polymorphic Transitions of ε CL-20 in Composite Systems
Autorzy:
Guo, X.-Y.
Zhang, P.
Xu, J.-J.
Wang, Z.-H.
Jiao, Q.-J.
Powiązania:
https://bibliotekanauki.pl/articles/358032.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
polymorphic transition
kinetics
activation energy
transition temperature
Opis:
In order to explore the polymorphic transition law for ε-CL-20 in composite systems, the polymorphic transition process of pure ε-CL-20 crystals stimulated by heat was investigated by the X-ray Diffraction (XRD) method, and the kinetic parameters of the polymorphic transition process were calculated (including the apparent activation energy Ea and the pre-exponential factor lnA). Meanwhile the effects of different additives on the polymorphic transition process and kinetics of ε-CL-20 were explored in detail. The experimental results showed that the ε-form tends to transform into the γ- form on heating and that the Ea and lnA for the transition process were 209.97 kJ/mol and 57.47, respectively. The first group of additives clearly promoted the polymorphic transition of ε-CL-20 and lowered the initial transition temperature and the activation energy. The second and third groups of additives inhibited the polymorphic transition of ε-CL-20 and raised the initial transition temperature and the activation energy.
Źródło:
Central European Journal of Energetic Materials; 2015, 12, 4; 689-702
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-8 z 8

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