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    Wyświetlanie 1-4 z 4
    Tytuł:
    Application of Pyrolox sorbent for vanadium(V) ions removal
    Autorzy:
    Wójcik, Grzegorz
    Hubicki, Zbigniew
    Powiązania:
    https://bibliotekanauki.pl/articles/2146947.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    vanadium(V)
    kinetics
    removal
    sorption
    Pyrolox
    Opis:
    The sorption of vanadium(V) ions from acidic solutions using the Pyrolox sorbent was studied at varying ions concentrations, pH, contact time and temperature. The investigated ions were determined by means of graphite-furnace atomic absorption spectrometry (GF-AAS). The sorption capacity of vanadium(V) ions was examined in the pH range 2-10. The adsorption capacities of vanadium(V) ions depend on the pH values. Therefore, the initial pH 2 of vanadium(V) results in the highest adsorption capacities. The sorption vanadium(V) kinetics was investigated. The experimental data were analyzed using the pseudo-first-order, pseudo-second-order forms, Elovich, and intra-particle diffusion models. The kinetics of vanadium(V) sorption is described by the pseudo-first-order in the best way. The results indicate the endothermic process of V(V) ions sorption. The presented results of vanadium ions recovery from the solutions obtained as a result of spent catalysts leaching indicate the possibility of vanadium recovery.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 2; art. no. 147974
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Removal of acid, direct and reactive dyes on thepolyacrylic anion exchanger
    Autorzy:
    Polska-Adach, Ewelina
    Wawrzkiewicz, Monika
    Hubicki, Zbigniew
    Powiązania:
    https://bibliotekanauki.pl/articles/110859.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    dye removal
    polyacrylic anion exchanger
    reactive dye
    direct dye
    acidic dye
    Opis:
    In the present studythe polyacrylic anion exchanger Amberlite IRA 478 (IRA 478) was used forremoval of textile dyes such as C.I. Acid Red 18 (AR18), C.I. Reactive Blue 21 (RB21) and C.I. Direct Yellow 142 (DY142) from aqueous solutions. Sorption of the above-mentioned dyes was carried out by the static and dynamic methods. The obtained results were analyzed by determining the adsorption isothermparameters using the Langmuir and Freundlichmodels. Kinetic parameters of dyessorption were calculated from the pseudo-first order, pseudo-second order and intraparticle diffusion models. The monolayer sorption capacities of IRA 478 determined from the Langmuir isotherm were found to be 1098.5 mg/g for AR18 (R2=0.994), 46.8 mg/g for DY142 (R2=0.820) and 23.5 mg/g for RB21 (R2=0.987).Kinetic studies revealed that effectiveness of AR18, DY142 and RB21 uptakeincreases with increasing phase contact time and initial dyesconcentration.The kinetics of the dyessorption process on the anion exchanger is best described by the pseudo-second order model (PSO) due to the high values of the determination coefficients R2 (linearity condition of the plot t/qt vs.t). The rate constantsof the pseudo-second order kinetics k2are reduced from 0.1001 to 0.0008 g/mg·min for AR18, from 0.0147 to 0.0112 g/mg·min for DY142 and 0.0489 to 0.0072 g/mg·min for RB21 with an increase of initial concentration of dyes.The presence of salts and surfactants had an impact on the retention of direct and reactive dyes.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 6; 1496-1508
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Chlorates(VII) removal on Dowex™PSR-2 resin
    Autorzy:
    Kołodyńska, Dorota
    Łyko, Aleksandra
    Gęca, Marzena
    Hubicki, Zbigniew
    Powiązania:
    https://bibliotekanauki.pl/articles/764134.pdf
    Data publikacji:
    2016
    Wydawca:
    Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
    Tematy:
    chlorates
    removal
    ion exchange
    Dowex™PSR-2
    Opis:
    Lately there has been observed the increased presence of chlorates(VII) in the natural environment which can affect human health negatively. Therefore the removal of chlorate(VII) ions using the gel type resin functionalized with the tri-n-butyl ammonium (Dowex™PSR-2) from waters was studied. The main aim was to evaluate the effects of experimental conditions including contact time, initial solution concentration, pH and temperature on chlorate(VII) ions removal as well as the anion exchanger properties on chlorate(VII) ions sorption. It was found that only the pseudo second order model described the experimental data well and the intraparticle diffusion was not the rate-limiting step. According to the Freundlich model, the qe value was to be 69.26 mg/g at optimum conditions (pH 7.0 at 25 oC).
    Źródło:
    Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2016, 71, 1
    2083-358X
    Pojawia się w:
    Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Electrokinetic properties of silica-titania mixed oxide particles dispersed in aqueous solution of C.I. Direct Yellow 142 dye – effects of surfactant and electrolyte presence
    Autorzy:
    Chibowski, Stanisław
    Wiśniewska, Małgorzata
    Wawrzkiewicz, Monika
    Hubicki, Zbigniew
    Goncharuk, Olena
    Powiązania:
    https://bibliotekanauki.pl/articles/1450752.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    silica-titania composite
    mixed oxides
    zeta potential
    solid surface charge density
    dye adsorption
    surfactant effect
    Opis:
    The mixed $SiO_2$-$TiO_2$ oxide obtained by the pyrogenic method with the silica:titanium percentage ratio equal to 20:80 (ST80) was used in the experiments. The influence of azo dye C.I. Direct Yellow 142 (DY) adsorption at the mixed oxide-solution interface on the electrokinetic properties of solid particles was studied. To determine solid surface charge density and zeta potential of examined suspensions the potentiometric titration and Doppler laser electrophoresis techniques were applied. The changes in structure of electrical double layer formed on the mixed oxide surface in the dye presence were specified as a function of DY concentration, inorganic salt addition and surfactant introduction. The effects of surfactant type and its concentration were determined. Three surfactants of different ionic character (anionic SDS, cationic CTAB and nonionic Triton X-100) were used in measurements. The obtained electrokinetic characteristics of ST80 mixed oxide dispersed in aqueous solutions with various adsorbate compositions is essential for such suspensions stability.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 6; 6-13
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-4 z 4

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