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Wyszukujesz frazę "Hryniewicz, Tadeusz" wg kryterium: Autor


Tytuł:
On the Nitinol properties improvement after electrochemical treatments
Autorzy:
Hryniewicz, Tadeusz
Rokicki, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/1178042.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Nitinol
SMA
electropolishing (EP)
fatigue resistance
inclusions
magnetoelectropolishing (MEP)
Opis:
Shape Memory Alloys (SMAs) are a group of intermetallic compounds, which can undergo deformation at one temperature, and then recover their original undeformed shape upon heating above their transformation temperature. Superelasticity occurs just above the alloy’s transformation temperature in a very narrow range. In this case no heating is necessary to cause the deformed shape to recover upon load relieve to its original undeformed shape. It has to be emphasized that nitinol exhibits enormous elasticity when compared with other medical metal alloys. In recent years, the use of nitinol (NiTi), almost equiatomic binary (50:50 ratio) intermetallic compound of nickel and titanium, has been steadily growing, particularly in medical and dental devices markets. However, broader and further application of nitinol has been slowed down by leaking nickel and unavoidable inclusions during producing in this compound. This work is to present some electrochemical treatment methods in view of reducing of both these phenomena. It appears that changing electrical conditions of electropolishing (EP) above the plateau region (EP+) may improve the quality of surface obtained on NiTi of over 60% in comparison with as-received (AR) nitinol part. What’s more, introducing a magnetic field into the electrolysis system results in numerous positive features of nitinol surface and increase of mechanical properties. Thus the magnetoelectropolishing (MEP) process appears to increase higher the fatigue resistance of the treated NiTi part. The experiments carried out on chirurgical needles show an unusual triple (and higher) growth in resistance to bending until fracture. Further increase in fatigue resistance is usually limited by different size inclusions appearing on the nitinol part surface under magnetoelectropolishing (MEP).
Źródło:
World Scientific News; 2018, 95; 52-63
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
XPS Analysis of nanolayers obtained on AISI 316L SS after Magnetoelectropolishing
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Powiązania:
https://bibliotekanauki.pl/articles/1192093.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
XPS Analysis
Magnetoelectropolishing (MEP)
AISI 316L SS
Nanolayers
Opis:
In the present paper, the passive layers' chemical compositions of AISI 316L austenitic stainless steel samples after three treatments, such as mechanical/abrasive polishing (MP), standard electropolishing (EP) and magnetoelectropolishing (MEP) are displayed. For the surface studies after each treatment, XPS analysis was performed. It has been noted that after MP treatment the Cr/Fe ratio in the passive layer is the lowest and equals to about 1, whereas after the MEP it is close to 3. Additionally, it has to be reported that the passive layers after MP consist mainly of Cr2O3 and Fe2O3, after a standard EP treatment – of CrOOH and FeOOH, and after MEP – of Cr(OH)3 and FeOOH compounds. Concerning the surface layer compositions, in the passive layer formed after MP the detected iron consisted partly of Fe0 (46.5 at %) and partly of iron compounds Fe2+ and Fe3+ (53.5 at %), whereas the detected chromium consisted of Cr0 (16.5 at %) and mostly of chromium compounds Cr3+ (80.8 at%), with a small amount of Cr6+ (2.7 at %). In case of the nanolayer after EP treatment, the detected iron consisted of Fe0 (39.5 at %) and iron compounds Fe2+ and Fe3+ (60.5 at %), whereas the detected chromium consisted in a small amount of Cr0 (6.6 at %), and mostly chromium compounds Cr3+ (83.8 at %) with some Cr6+ (9.6 at %). The XPS analysis of nanolayer formed on AISI 316L after MEP indicates that the detected iron consisted partly of Fe0 (27.1 at %) and mostly of iron compounds Fe2+ and Fe3+ (72.9 at %) whereas the detected chromium contained Cr0 (18 at %) and chromium compounds of Cr3+ (76 at %) and Cr6+ (6 at %).
Źródło:
World Scientific News; 2016, 37; 232-248
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Highly improved Nitinol biomaterial devices by magnetoelectropolishing (MEP)
Autorzy:
Hryniewicz, Tadeusz
Rokicki, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/1166214.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Biocompatibility
Fatigue resistance
Nitinol biomaterial
Surface roughness
XPS
magnetoelectropolishing
Opis:
In recent years, the use of Nitinol as a metallic biomaterial being compound of nickel and titanium, has been steadily growing, particularly in medical and dental devices markets. However, further application of Nitinol has been slowed down due to leaching nickel and unavoidable inclusions appearing on the surface during manufacture of this intermetallic compound. Electropolishing of Nitinol biomaterial samples as-received (AR) was carried out under different conditions: (a) on the plateau level (EP), (b) above the plateau (EP+), and (c) in the magnetic field (MEP). This work is to present magnetoelectropolishing (MEP) as an electrochemical processing method able to significantly improve the Nitinol biomaterial properties. Following our previous SEM/EDS studies, and corrosion resistance improvement of Nitinol, in this work XPS and XRD study methods were used. First of all, as indicated by XPS study results concerning biocompatibility, it was proved that MEP leaves Nitinol surface enriched in oxygen and with nickel reduced to zero. Thus the titanium oxides, generally TiO2, are formed on Nitinol surface. It appears that by introducing a magnetic field into the electrolysis system, another effect relying on a considerable increase of Nitinol mechanical properties is obtained. The experiments carried out on surgical needles show an unusual multiple growth in resistance to bending until fracture. Further increase in fatigue resistance is usually limited by different size of inclusions which happen to appear on the Nitinol part surface. Moreover, in this work also a simple method is proposed to reject the Nitinol parts, with the inclusions detected on the biomaterial surface, before their application.
Źródło:
World Scientific News; 2018, 106; 175-193
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modification of Nitinol Biomaterial for Medical Applications
Autorzy:
Hryniewicz, Tadeusz
Rokicki, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/1177981.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Nitinol biomaterial
electropolishing
fatigue resistance
magnetoelectropolishing (MEP)
modification methods
sterilization
Opis:
In the paper, a review of modification methods which have been applied to Nitinol intermetallic compound used as biomaterial for medical applications, is carried out. A variety of methods used for Nitinol improvement, beginning from its manufacture, covers mechanical treatment, heat treatment, chemical processing including water boiling, electropolishing, plasma ion implantation, coating to improve the corrosion resistance, minimize nickel leaching, improve osseointegration, and/or vascular compatibility, sterilization and disinfection. Nitinol alloying by addition of a third element to replace Ti or Ni has an enormous effect on phase transformation, corrosion resistance and biocompatibility of the newly created ternary Nitinol alloy. Unfortunately, the ternary nitinol alloys – apart from NiTiCu in actuators and NiTiCr in wires used as a pulling-pushing tool in minimally invasive spine operation – have not found a widespread industrial application yet. One of the most effective surface finishing operations used for metallic biomaterials, with a special attention directed to Nitinol, appears to be magnetoelectropolishing (MEP). A uniform magnetic field used in MEP process can be generated by permanent magnets or by electromagnets. MEP leads to refinement of surface chemical composition impossible to achieve by standard electropolishing. During MEP of alloys and intermetallic compounds, ferromagnetic elements, such as Fe (from stainless steels) or Ni, are primarily removed from the surface so that the passive film on Nitinol is totally composed of titanium oxide. One more unique feature of metal samples after MEP is their de-hydrogenation noticed both in stainless steels, niobium, titanium and Nitinol. In fact, the fatigue resistance of Nitinol after MEP referred to as-received, dependent on the refinement and displacement of inclusions, increases from three to seven times.
Źródło:
World Scientific News; 2018, 96; 35-58
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Plasma Electrolytic Oxidation as a modern method to form porous coatings enriched in phosphorus and copper on biomaterials
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Powiązania:
https://bibliotekanauki.pl/articles/1190116.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Plasma Electrolytic Oxidation (PEO)
Niobium
Ti6Al4V
TNZ
Porous coatings
Opis:
In the paper, the porous coatings obtained on niobium and two titanium alloys (Ti6Al4V, and TNZ) after Plasma Electrolytic Oxidation (PEO), known also as Micro Arc Oxidation, were studied. The samples were treated at the voltage of 450 V for 3 minutes in the electrolyte consisting of 300 g and 600 g of copper nitrate Cu(NO3)2 in 1 litre of concentrated phosphoric acid H3PO4, consecutively. SEM and EDS studies were performed on the samples. Based on the obtained results it may be concluded that enriched in copper porous coatings on all studied materials were created in the electrolyte within copper nitrate amounting for 600 g. The proposed by the Authors factor to evaluate the obtained coatings, i.e. copper-to-phosphorus ratio, which for the studied materials amounted to 0.21, clearly indicates that the performed electrochemical PEO treatment for surface modification especially of bioimplants may be advised.
Źródło:
World Scientific News; 2016, 35; 44-61
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The studies of corrosion resistance of AISI 316Ti SS in Ringer’s solution after electropolishing and passivation in nitric acid
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Solecki, Grzegorz
Powiązania:
https://bibliotekanauki.pl/articles/1177846.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
AISI 316Ti/EN 1.4571
austenitic stainless steel
electropolishing
passivation
pitting corrosion
potentiodynamic corrosion measurements
Opis:
In present work, the continuation of general and pitting corrosion analysis of austenitic AISI 316Ti (EN 1.4571) stainless steel in Ringer's solution, is presented. The corrosion was studied by using the ATLAS 98 potentiostat with platinum EPT-101 and calomel reference EK-101P electrodes. The three types of specimens, i.e. as received (without any pretreatment), after abrasive mechanical polishing (MP), and after electrochemical polishing (EP), were used. The best pitting corrosion resistance was recorded for electropolished and passivated (in 20% vol. HNO3 for 30 minutes) surface, i.e. the pitting potential was equal to 761 mVSCE (855.4 ± 58.5 mVSCE), while the worst one was recorded for mechanically ground samples and the pitting corrosion potential was equal to 270 mVSCE (378.8 ± 60.3 mVSCE).
Źródło:
World Scientific News; 2018, 98; 46-60
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
SEM and EDS studies of porous coatings enriched in calcium and zinc obtained by PEO with ramp voltage
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Pietrzak, Kornel
Powiązania:
https://bibliotekanauki.pl/articles/1178366.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
CP Titanium Grade 2
Micro Arc Oxidation (MAO)
Plasma Electrolytic Oxidation (PEO)
calcium nitrate Ca(NO3)2∙4H2O
linear polarization
ramp voltage
zinc nitrate Zn(NO3)2∙6H2O
Opis:
In this work, the SEM and EDS results of porous and enriched in calcium or zinc coatings, which were obtained during 3-minute treatments using Plasma Electrolytic Oxidation (Micro Arc Oxidation) processes on CP Titanium Grade 2 at ramp potentials (linear polarization) from 0 up to 650 VDC in electrolytes containing 500 g Ca(NO3)2∙4H2O and/or 500 g Zn(NO3)2∙6H2O in 1 L H3PO4, are presented. It was found that obtained coatings have pores with different shapes and diameters. The Ca/P and Zn/P ratios by atomic concentration are the same and equal to 0.2, what may suggest hydroxyapatite-like structure (M,Ti)x(PO4)y, where M = {Ca, Zn}.
Źródło:
World Scientific News; 2017, 77, 2; 242-255
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characterisation of porous, calcium enriched coatings formed on Titanium via Plasma Electrolytic Oxidation
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Pietrzak, Kornel
Powiązania:
https://bibliotekanauki.pl/articles/1179160.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
85% orthophosphoric acid H3PO4
CP Titanium Grade 2
Micro Arc Oxidation (MAO)
Plasma Electrolytic Oxidation (PEO)
calcium nitrate tetrahydrate Ca(NO3)2∙4H2O
Opis:
The SEM and EDS study results of porous and calcium enriched coatings obtained via Plasma Electrolytic Oxidation (Micro Arc Oxidation) on the Commercial Purity Titanium Grade 2 samples, at three potentials 450 VDC, 550 VDC, 650 VDC in electrolytes containing 500 g Ca(NO3)2∙4H2O in 1000 mL H3PO4, are presented in the paper. In the same electrolyte three Titanium samples, one after other, were treated, with the PEO processing time equaling 3 minutes after each immersion. Based on SEM and EDS results, it was possible to state that all obtained coatings are porous and their calcium-to-phosphorus (Ca/P) ratio decreases with decreasing PEO voltage. In addition, it was found out that electrolyte aging results in decreasing Ca/P ratio, too.
Źródło:
World Scientific News; 2017, 83; 29-44
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Fields for Electropolishing Improvement: Materials and Systems
Autorzy:
Hryniewicz, Tadeusz
Rokosz, Krzysztof
Rokicki, Ryszard
Powiązania:
https://bibliotekanauki.pl/articles/411721.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Magnetic field
Magnetoelectropolishing MEP
Materials
Electrochemical systems
Opis:
The paper aims to present the main objectives for using magnetic fields to improve process of electropolishing (EP), firstly by focusing on materials and electrochemical systems. The general introduction has been concerned on the sample surface treated under pseudopassivity conditions, in the process generally known as magnetoelectropolishing (MEP). Long-term up-to-date experiments have shown profound changes observed on metals and alloys. The advantageous effects gained by applying MEP to metals and alloys cover: improvement of corrosion resistance, bio- and haemocompatibility, roughness by modification of their surfaces. The improvements are also referred to the mechanical properties of metals and alloys treated by MEP namely: removal of hydrogen, fatigue resistance enhancement, etc. Further developments and the effects of magnetic fields on electropolishing of metals and alloys are to be presented in the next publications.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 4; 98-108
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparative corrosion studies of 2205 duplex steel after electropolishing and passivation in Ringer’s solution
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Solecki, Grzegorz
Powiązania:
https://bibliotekanauki.pl/articles/1178066.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
electropolishing
passivation
pitting corrosion
potentiodynamic corrosion measurements
stainless steel duplex 2205
Opis:
In present work, the results of corrosion analysis of pitting and general corrosion of austenitic duplex 2205 (EN 1.4462) stainless steel in Ringer's solution, are presented. The corrosion rate was studied using potentiodynamic polarisation method by means of the ATLAS 98 potentiostat with POL 98 software. For these measurements the platinum EPT-101 and calomel reference EK-101P electrodes were used. For each run, the electrolytic cell made of glass was used, containing up to 500 ml of the electrolyte. The specimens used for the studies were obtained from a cold-rolled sheet of steel in three forms: as received (without any pretreatment), after abrasive polishing, and after electrochemical polishing. Some of them were passivated for 15 and 30 minutes, respectively, in 20% HNO3 by volume. The study results show clearly that the samples of duplex 2205 stainless steels after electropolishing and passivation for 15 minutes in 20% HNO3 by volume revealed the highest corrosion resistance.
Źródło:
World Scientific News; 2018, 95; 167-181
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł

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