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Wyświetlanie 1-13 z 13
Tytuł:
New insights into the promotion mechanism of $(NH_4)_2SO_4$ in sulfidization flotation: a combined experimental and computational study
Autorzy:
Chen, Daixiong
Liu, Mengfei
Hu, Bo
Dong, Yanhong
Xue, Wei
He, Peng
Chen, Fang
Zhu, Jianyu
Zhang, Chenyang
Powiązania:
https://bibliotekanauki.pl/articles/1446762.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
malachite
promotion
sulfidization
flotation
mechanism
Opis:
Ammonium sulfate ((NH4)2SO4) exhibits promoting effects in malachite sulfidization flotation. However, the promotion mechanism remains poorly understood. In this study, micro-flotation tests, zeta-potential measurements, scanning electron microscopy coupled with energy-dispersive spectroscopy (SEM-EDS), atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS) and materials studio simulation (DFT) were used to investigated the promotion mechanism of $(NH_4)_2SO_4$. Micro-flotation test demonstrates that the recovery of malachite from 73% increased to 83%, when the (NH4)2SO4 was added. Contact angle and zeta potential test results indicate that addition of $Na_2S•9H_2O$ changes the surface properties of malachite and provide the conditions for adsorption of butyl xanthate (BX). After promoting the sulfidization by $(NH_4)_2SO_4$, BX is more effective in improving the hydrophobicity. SEM-EDS and AFM results show that $(NH_4)_2SO_4$ can improve performance and stability of sulfidization. X-ray photoelectron spectroscopy indicates that after sulfidization, polysulfides and cuprous were appeared in malachite surface, infers that a redox reaction occurs between sulfur and copper on the surface of malachite. After addition of $(NH_4)_2SO_4$, the percentage of polysulfides and cuprous were increased, it implies $(NH_4)_2SO_4$ can accelerate the redox reaction. Computational results show that after adding $(NH_4)_2SO_4$, the adsorption energy of HS- on the malachite surface is reduced, implies that $(NH_4)_2SO_4$ can improve the stability of HS-adsorption on the surface of malachite.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 5; 57-70
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ab Initio Studies on Structural, Elastic, Thermodynamic and Electronic Properties of FeCrAs under Pressures
Autorzy:
He, De-Chun
Peng, Yong
He, Yong-Wei
Powiązania:
https://bibliotekanauki.pl/articles/1400506.pdf
Data publikacji:
2015-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
62.20.de
65.40.Ba
65.40.De
72.15.-v
Opis:
The structural, elastic, thermodynamic and electronic properties of nonmetallic metal FeCrAs are studied within density function perturbation theory. The thermodynamic properties of FeCrAs were deduced based on phonon frequencies within the framework of the quasiharmonic approximation. The calculated elastic modulus under various pressures indicates that FeCrAs is mechanically stable under pressure. The pressure-dependence of bulk and shear modulus, transverse and longitudinal sound velocities V (i.e. $V_{S}$ and $V_{L}$), elastic Debye temperature $\Theta_{E}$ of FeCrAs have also been investigated. The calculated values of B/G indicate that FeCrAs presents high ductility under pressure. However, it is interesting that the value of B/G reaches a maximum under 40 GPa and almost remains unchanged when the pressure is above 70 GPa. The calculations show that the heat capacity $C_{V}$ of this material is close to the Dulong-Petit limit 3R (about 224.61 J $mol^{-1} K^{-1}$) at high temperature regime. The analysis of electronic properties find that as the pressure increases, the absolute value of charge for As and Fe atom increases while Cr remains nearly a constant, indicating that the mechanic properties of FeCrAs under pressure should be mostly attributed to the interaction between Fe and As atoms.
Źródło:
Acta Physica Polonica A; 2015, 127, 6; 1637-1644
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
First-principles calculations on phase transition and elastic properties of CoN
Autorzy:
De-Chun, He
Yong, Peng
Su-Yuan, Li
Yong-Lin, He
Powiązania:
https://bibliotekanauki.pl/articles/1075580.pdf
Data publikacji:
2016-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
62.20.-x
62.20.de
62.50.-p
62.20.dq
Opis:
The structural phase transition and elastic properties of CoN are investigated by ab initio plane-wave pseudopotential density function theory method. The equilibrium lattice parameters a₀, elastic constants C_{ij}, bulk modulus B₀ and its derivative B'₀ are calculated. From the usual condition of equal enthalpy, the phase transition of CoN from zinc-blende to rocksalt structure occurs at 35.4 GPa with a volume collapse of about 15.6%, consistent with the calculated result 36 GPa (FP-LDA), but an uncertainty is about 4.4 GPa compared with the 31 GPa (ASA-GGA). All three independent elastic constants, C₁₁, C₁₂, and C₄₄ for CoN are calculated from direct computation of stresses generated by small strains. Both C₁₂ and C₄₄ are less sensitive to pressure as compared with C₁₁. The calculated conclusions offer theoretical data for the further research of the mechanical properties for CoN.
Źródło:
Acta Physica Polonica A; 2016, 130, 3; 743-747
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Positronium time-of-flight Measurements of Mesoporous Silica Films
Autorzy:
Kuang, Peng
Zhang, Xiao
He, Chun
Cao, Xing
Wang, Bao
Powiązania:
https://bibliotekanauki.pl/articles/1029796.pdf
Data publikacji:
2018-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
61.05.-a
68.47.Mn
Opis:
Mesoporous silica films were synthesized with various concentrations of cetyltrimethylammonium bromide (CTAB) in precursor sols through the method of electro-assisted self-assembly (EASA). Oriented pore channels were observed in the films prepared with more CTAB in the precursor sols. Positronium time-of-flight (Ps-TOF) measurements were performed for the silica films with different porous structures. It is demonstrated that the Ps emission intensity and energies are well correlated to the apparent porosity, pore interconnectivity and possibly pore channel orientation. The results indicate that Ps-TOF can be a useful technique for probing the structures of porous films.
Źródło:
Acta Physica Polonica A; 2018, 133, 1; 3-6
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reliability and Risk Assessment of Aircraft Electric Systems
Niezawodność i ocena ryzyka układu elektrycznego samolotu
Autorzy:
He, L.
Yin, C.
Peng, W.
Yuan, R.
Huang, H.-Z.
Powiązania:
https://bibliotekanauki.pl/articles/301113.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Polskie Naukowo-Techniczne Towarzystwo Eksploatacyjne PAN
Tematy:
interval analytic hierarchy process
interval eigenvector method
Bayesian network
information fusion
risk assessment
proces przedziałowej hierarchii analitycznej
metoda przedziałowych wektorów własnych
sieć bayesowska
fuzja informacji
ocena ryzyka
Opis:
It is rather difficult in identifying the fault location and performing risk assessment for complex electronic systems. In this paper a reliability assessment method based on the interval analytic hierarchy process (IAHP) and Bayesian network is proposed to facilitate reliability and risk assessment. After considering the major fault factors, the interval eigenvector method (IEM) is also presented to assess the reliability and comprehensive weights of subsystems. The conditional probability matrices for the factors of risk are defined using an inference rule. Then an updating model of information fusion in the context of Bayesian network is established to assess the risk of system. The proposed method is demonstrated through the risk assessment of an aircraft electric system. The result of the illustrative example shows that the proposed method can not only incorporate the evidence information, but also synthesize all the historical information. A further dynamic adjustment in the safety and risk priority of control measures is quite effective to improve the reliability while mitigating the risk of the electric system.
Lokalizacja uszkodzeń oraz ocena bezpieczeństwa i ryzyka w przypadku złożonych systemów elektronicznych jest zadaniem dość trudnym. W niniejszej pracy zaproponowano metodę prognozowania niezawodności opartą na procesie przedziałowej hierarchii analitycznej (IAHP), która ma na celu ułatwienie diagnozy uszkodzeń i kontroli ryzyka. Po rozważeniu głównych czynników wywołujących uszkodzenia, zaprezentowano metodę przedziałowych wektorów własnych oraz zdefiniowano, przy użyciu reguły wnioskowania, macierze prawdopodobieństwa dla czynników wpływających na bezpieczeństwo i ryzyko. Następnie, stworzono odnawialny model fuzji informacji w kontekście wnioskowania bayesowskiego służący do oceny stanu zagrożenia Udowodniono, iż włączenie wiedzy eksperckiej do dynamicznej symulacji ułatwia lokalizację uszkodzeń oraz pozwala uzyskać informacje dotyczące diagnozy uszkodzeń. Studium przypadku pokazuje, że dynamiczne dostosowanie priorytetowości związanej z bezpieczeństwem i ryzykiem stosowanych środków kontroli w sposób dość skuteczny zwiększa niezawodność przy jednoczesnym zminimalizowaniu ryzyka w złożonym systemie elektronicznym.
Źródło:
Eksploatacja i Niezawodność; 2014, 16, 4; 497-506
1507-2711
Pojawia się w:
Eksploatacja i Niezawodność
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Electrostatic Hazards Assessment of Nitramine Explosives: Resistivity, Charge Accumulation and Discharge Sensitivity
Autorzy:
Peng, Q.
Cao, W.
Zhou, W.
He, Z.
Jiang, W.
Chen, W.
Powiązania:
https://bibliotekanauki.pl/articles/358757.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
nitramine explosives
electrostatic hazards
resistivity
charging characteristics
electrostatic discharge sensitivity
Opis:
The electrostatic hazards of nitramine explosives (RDX, HMX) were assessed in this paper. The resistivities of different particle-size RDX and HMX were tested by a device designed and manufactured according to the standard ISO/IEC 80079-20-2:2016. This work shows that the resistivities of uncompacted RDX and HMX increase as the particle size decreases. Charging characteristics test experiments were also carried out using a so-called sieve method. Using this method, the influence of aperture size on charge accumulation of RDX was studied, and the characteristics of electrostatic accumulation of different particle-size RDX and HMX sieved with 50 mesh standard sieve were compared. The results show that the absolute value of the charge accumulation increases as the mesh number increases (i.e. the aperture size decreases), and increases as the particle size is decreased, indicating that nano-sized RDX and nano-sized HMX accumulate static electricity more easily than conventional micron-sized ones. Finally, the electrostatic discharge (ESD) sensitivity of nano-sized RDX and nano-sized HMX was investigated. Nano-sized nitramine explosives were found to have a higher ESD sensitivity than micron-sized ones.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 3; 755-769
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of particle density on the classification efficiency of the static air classifier in Vertical Spindle Mill
Autorzy:
Li, Hong
He, Yaqun
Yang, Jinshan
Zhu, Xiangnan
Peng, Zhen
Xie, Weining
Powiązania:
https://bibliotekanauki.pl/articles/110134.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
static air classifier
classification efficiency
material density
Opis:
In order to investigate the impact of density on the classification behavior of particles in the static classifier of Vertical Spindle Mill, the sensitivity of overflow yield to the increase of air amount for narrowly sized pyrite, carborundum, quartz and coal samples were compared in a lab-scale classifier, respectively. Response surface methodology is used to analyze the combined effect of size and density on the classification. Wide size classification was also conducted and results show that both the yield and R90 of overflow increase with the decreasing of density, and the growth of air amount would also lead them to rise. The Whiten’s model was applied to illustrate the influence of density on the sharpness of classification, corrected cut size and fishhook effect. Results show that material with a lower density would have a higher fishhook effect parameter, classification sharpness and corrected cut size. The increase of air amount would result in a more evident fishhook effect for the high density material. Based on the Whiten’s model, a new classification efficiency model with the addition of particle density in various forms was established. This new model could describe the classification efficiency of materials with different density in the identical experiment conditions.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 494-503
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Ultraviolet Absorber on Photo-Degradation of Epoxy Coating Studied by Slow Positron Beam
Autorzy:
Wang, Zheng
Liu, Fuwei
Li, Jingjing
He, Chunqing
Peng, Xiangyang
Huang, Zhen
Fang, Pengfei
Powiązania:
https://bibliotekanauki.pl/articles/1033239.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
epoxy coating
photo-degradation
ultraviolet absorber
slow positron beam
microstructure
Opis:
The photo-degradation progress of epoxy coating and the effect of ultraviolet absorber under UV-B irradiation have been investigated in slow positron beam and by the Fourier transform infrared spectrometer. After 120 h of irradiation, the value of S parameter in sample bulk is reduced while compared with the virgin sample. The result is mostly due to post-cure process happening in this initial irradiation stage. As the irradiation time increases to 360 h, the S parameter decreases sharply. This is due to the growth of carbonyl group and the generation of free radical. After 528 h or longer time of irradiation, a very low S value was obtained near sample surface, indicating the formation of a dead surface layer. Positron results also reveal that the addition of ultraviolet absorber suppresses the development of the dead layer after long-term UV-B irradiation. Ultraviolet absorber has a suppressing effect on generation of polar groups towards sample bulk. The addition of ultraviolet absorber is a key factor that affects the photo-degradation of epoxy coating.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1523-1526
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on the mechanism and kinetics of sulfuric acid leaching scandium from rich scandium anatase
Autorzy:
He, Fei
Gao, Likun
Chen, Long
Rao, Bing
Shen, Hairong
Peng, Kebo
Gao, Guangyan
Powiązania:
https://bibliotekanauki.pl/articles/2146896.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
anatase ore
sulfuric acid
leaching
kinetics
scandium
Opis:
Scandium and its compounds have excellent properties, and are widely used in cutting-edge fields such as optics, electronics, and alloys. Thus, scandium is an important strategic metal. However, scandium is extremely sparsely distributed in the earth's crust, rarely occurs as an independent mineral, and requires a complex recovery process. Therefore, the study of the extraction of scandium is of great practical significance. This study examined the leaching test and kinetics of scandium under the acid leaching system of refractory anatase ore. Under appropriate two-stage countercurrent leaching conditions, the first stage of the particle size of fraction of -0.074 mm 82.6%, initial H2SO4 concentration of 6 mol/L, leaching temperature of 100 °C, acid/solid ratio of 3 ml/g, stirring speed of 300 rpm, and leaching time of 50 min; and the second stage of the initial H2SO4 concentration of 11 mol/L, leaching temperature of 150 °C, acid/solid ratio of 4 ml/g, stirring speed of 300 rpm, and leaching time of 50 min, a scandium leaching rate of 96.98% was achieved. The kinetics of scandium leaching conformed to a shrinking-core model, and sulfuric acid concentration and temperature were the most important parameters affecting the scandium leaching rate. The kinetic analysis of scandium leaching at different sulfuric acid concentrations showed that as the concentration increased, the sulfuric acid leaching of scandium changed from being chemical reaction-controlled to internal diffusion-controlled, and the apparent reaction order was 1.2429. The kinetics of scandium leaching at different temperatures showed that the sulfuric acid leaching of scandium was reaction-controlled and the apparent activation energy was 42.21 kJ-mol-1.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 146171
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photo-oxidative Aging Behaviors of Acrylic Coatings during UV Irradiation Investigated by Positron Annihilation Spectroscopy
Autorzy:
Zhao, Xipo
Cai, Xiaolin
Liu, Chang
Chen, Ting
He, Chunqing
Fang, Pengfei
Peng, Shaoxian
Powiązania:
https://bibliotekanauki.pl/articles/1033253.pdf
Data publikacji:
2017-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
Acrylic coating
UV irradiation
positron annihilation spectroscopy
Opis:
Slow positron annihilation spectroscopy, contact angle and scanning electron microscope (SEM) were employed to investigate the surface polarity and morphologies as functions of aging time in acrylic coatings during UV-a irradiation. The S parameter plots of each exposed sample are lower than that of the virgin sample in the whole range of E. The S parameter plots become lower as the exposing longer time, indicated that the irradiation generated more polar groups and increased the oxidation layer depth. Combined with surface morphology and the surface energy of acrylic coating, the variation of contact angle, and surface energy, polar component and dispersive component is related with surface polarity and morphologies.
Źródło:
Acta Physica Polonica A; 2017, 132, 5; 1527-1530
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of Molecular Perovskite (H2dabco)[NH4(ClO4)3]/Carbon Nanotubes Energetic Composite
Autorzy:
Hu, Li-shuang
Liu, Yang
He, Dan
Yang, Yajun
Gong, Shida
Guang, Chunyu
Deng, Peng
Hu, Shuangqi
Powiązania:
https://bibliotekanauki.pl/articles/27788083.pdf
Data publikacji:
2022
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
ammonium perchlorate
(H2dabco)[NH4(ClO4)3]
carbon nanotubes
mechanical sensitivity
thermal stability
Opis:
An ammonium perchlorate (AP, NH4(ClO4)3)-based molecular perovskite energetic material (H2dabco)[NH4(ClO4)3]/carbon nanotubes (DAP/CNTs) composite was prepared and characterized. Molecular perovskite DAP samples were synthesized by a facile one-pot reaction of triethylenediamine, perchloric acid (PCA, HClO4), and AP via a molecular assembly strategy. The results showed that the mechanical sensitivity (impact and friction sensitivities: >120 cm and 20%) and electrostatic spark sensitivity (8.90 J) of the DAP/CNTs energetic composite with 10 wt.% CNTs exhibited less sensitivity than that of DAP (impact, friction and electrostatic spark sensitivities: 112.3 cm, 45%, and 5.39 J, respectively), because of the mixing desensitization mechanism of CNTs. Compared with the pure DAP, the DAP/CNTs energetic composite has better performance with respect to thermal stability, exothermic capacity, and excellent continuous combustion properties. The DAP/CNTs energetic composite has potential application in a weapons system.
Źródło:
Central European Journal of Energetic Materials; 2022, 19, 1; 91--105
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular cloning, expression and characterization of Bmserpin-2 gene from Bombyx mori
Autorzy:
Pan, Ye
Xia, Hengchuan
Lü, Peng
Chen, KePing
Yao, Qin
Chen, Huiqin
Gao, Lu
He, Yuanqing
Wang, Lin
Powiązania:
https://bibliotekanauki.pl/articles/1040486.pdf
Data publikacji:
2009
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
serpin-2
Bombyx mori
bioinformatics
subcellular location
qPCR
Opis:
Serpins are a broadly distributed family of protease inhibitors. In this study, the gene encoding Bombyx mori serpin-2 (Bmserpin-2) was cloned and expressed in E. coli. The Bmserpin-2 cDNA contains a 1125 bp open reading frame (ORF). The deduced protein has 374 amino-acid residues, contains a conserved SERPIN domain and shares extensive homology with other invertebrate serpins. RT-PCR analysis showed that Bmserpin-2 was expressed in all developmental stages of B. mori larvae and various larval tissues. Subcellular localization analysis indicated that Bmserpin-2 protein was located in the cytoplasm. Interestingly, real-time quantitative PCR revealed that the expression of Bmserpin-2 in the midgut of susceptible B. mori strain 306 significantly increased at 72 hours post inoculation (hpi) when infected with BmNPV. However, there was no significant increase of the Bmserpin-2 expression in resistant strain NB infected with BmNPV. Thus, our data indicates that Bmserpin-2 may be involved in B. mori antiviral response.
Źródło:
Acta Biochimica Polonica; 2009, 56, 4; 671-677
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reverse flotation of collophanite at natural pH using isooctyl polyoxyethylene ether phosphate as a collector
Autorzy:
Li, Hongqiang
Zhang, Wen
Chen, Qian
Huang, Peng
Kasomo, Richard M.
Zou, Ze
Weng, Xiaoqing
He, Dongsheng
Yang, Siyuan
Song, Shaoxian
Powiązania:
https://bibliotekanauki.pl/articles/1445877.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
reverse flotation
dolomite
fluorapatite
AEP
selective adsorption
Opis:
Reverse flotation of collophanite at natural pH could significantly decrease the cost of pH regulators. In this study, isooctyl polyoxyethylene ether phosphate (AEP) was tested as a new surfactant in the reverse flotation of collophanite. Micro-flotation tests were conducted, and the adsorption mechanism of the new collector was analysed using X-ray photoelectron spectroscopy (XPS) and zeta potential analyses. The results of the flotation tests demonstrated that AEP could enable dolomite to float under natural pH (pH=7.2) and showed profound selectivity towards dolomite as opposed to fluorapatite. Based on the zeta potential and XPS results, the adsorption phenomena are mainly attributed to calcium active sites on both mineral surfaces. Dolomite possesses more magnesium active sites than fluorapatite, which tend to reinforce the interaction effect between AEP and dolomite. Furthermore, when compared to CO32- ions on the dolomite surface, PO43- ions on the fluorapatite surface tend to exhibit a stronger hindrance to the adsorption of AEP on the fluorapatite surface. This is attributed to their larger volumes and more charges on their surfaces, thereby causing a floatability difference between the two minerals.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 78-86
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-13 z 13

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