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    Wyświetlanie 1-7 z 7
    Tytuł:
    Styrene oxidation by copper(II) complexes salen-type encapsulated into NaY zeolite
    Katalityczne utlenianie styrenu w obecności kompleksów miedzi(II) typu salen osadzonych na zeolicie NaY
    Autorzy:
    Kuźniarska-Biernacka, I.
    Carvalho, M. A.
    Correia Neves, I.
    Fonseca, A. M.
    Lisińska-Czekaj, A.
    Czekaj, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/352679.pdf
    Data publikacji:
    2013
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    copper(II) complexes
    Schiff base
    NaY zeolite
    kompleksy miedzi(II)
    zasada Schiffa
    zeolit NaY
    Opis:
    The copper(II) complex with a Schiff-base salen-type ligand has been encapsulated in the nanopores of a NaY zeolite by using two different methodologies, the flexible ligand and in situ complex preparation methods. The encapsulated and non-encapsulated copper(II) complexes were screened as catalysts for styrene oxidation by using TBHP as the oxygen source in acetonitrile solvent. Under the optimized conditions, the catalysts exhibited moderate activity with higher selectivity to benzaldehyde. Both heterogeneous catalysts were found to be reusable after the catalytic cycle, but with some loss of activity.
    Osadzenie kompleksu miedzi(II) z zasadą Schiffa typu salen na zeolicie typu NaY zostało przepowadzone za pomocą dwóch metod „flexible ligand" i „in situ”. Katalityczne właściwości otrzymanego kompleksu oraz jego heterogenizowanych analogów badano w reakcji utleniania styrenu w obecności TBHP. Jako rozpuszczalnik stosowano acetonitryl. Testowane katalizatory wykazują średnią aktywność katalityczną z tendencją wytwarzania aldehy du benzoesowego. Oba heterogenizowane katalizatory mogą być wykorzystywane ponownie bez utraty aktywności katalitycznych.
    Źródło:
    Archives of Metallurgy and Materials; 2013, 58, 4; 1291-1294
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Styrene epoxidation over heterogeneous manganese (III) complexes
    Autorzy:
    Kuźniarska-Biernacka, I.
    Lisinska-Czekaj, A.
    Czekaj, D.
    Alves, M. J.
    Fonseca, A. M.
    Neves, I. C.
    Powiązania:
    https://bibliotekanauki.pl/articles/958207.pdf
    Data publikacji:
    2016
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    styrene epoxidation
    heterogeneous manganes
    Opis:
    The manganes (III) complex functionalised with 2,3-dihydropyridazine has been encapsulated in the supercages of the NaY zeolite using two different procedures, flexible ligand and in situ complex. The parent zeolite and the encapsulated manganese (LTI) complexes were screened as catalysts for styrene oxidation by using t-BOOH as the oxygen source in acetonitrile. Under the optimized conditions, the catalysts exhibited moderate activity with high selectivity to benzaldehyde.
    Źródło:
    Archives of Metallurgy and Materials; 2016, 61, 3; 1477-1482
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Uncovering production flows from small farms: results from Poland and Portugal case studies
    Przepływy produkcyjne drobnych gospodarstw rolnych na przykładzie regionów badawczych z Polski i Portugalii
    Autorzy:
    Czekaj, M.
    Hernandez, P.
    Fonseca, A.
    Rivera, M.
    Żmija, K.
    Żmija, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/1790571.pdf
    Data publikacji:
    2019
    Wydawca:
    The Polish Association of Agricultural and Agribusiness Economists
    Tematy:
    small farms
    production flows
    Portugal
    Polska
    drobne gospodarstwa rolne
    przepływy produkcyjne
    Portugalia
    Polska
    Opis:
    This study is an attempt to assess the impact of small farms (SF) on the regional food product circulation of specific key products in selected, fragmented, agrarian regions in Poland and Portugal. The empirical study is based on the analysis of food product maps which were developed based on data from a survey conducted among owners of small farms and small food businesses at focus group meetings and workshops organized in 2017 and 2018 in the Nowotarski and Nowosądecki subregions in Poland and in the Alentejo Central and Oeste subregions in Portugal. Qualitative data analysis was conducted using uniform methodology. In each of the subregions, focus groups helped to confront the assumptions resulting from surveys and corroborate the flows and fluxes described in the developed food product maps. Data collected during focus groups were enriched by data gathered during regional workshops that focused on food system governance. It was concluded that food product maps indicate interesting relationship flows of small farmers’ products along the food system, highlighting the role of fluxes connecting small farmers with other actors regarding specific key products. Several similarities and disparities between regional KP production flows in the Portuguese and Polish subregions, based on the type of key product, the various distribution channels and farming capacities present in each subregion were observed.
    Źródło:
    Annals of The Polish Association of Agricultural and Agribusiness Economists; 2019, 21, 3; 49-61
    2657-781X
    2657-7828
    Pojawia się w:
    Annals of The Polish Association of Agricultural and Agribusiness Economists
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Stratigraphy, palynology and organic geochemistry of the Devonian-Mississippian metasedimentary Albergaria-a-Velha Unit (Porto-Tomar shear zone, W Portugal)
    Autorzy:
    Machado, G.
    Francu, E.
    Vavrdová, M.
    Flores, D.
    Fonseca, P. E.
    Rocha, F. T.
    Pereira, L. C. G.
    Gomes, A.
    Fonseca, M.
    Chaminé, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059150.pdf
    Data publikacji:
    2011
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    Mississippian
    Late Devonian
    Ossa-Morena Zone
    Porto-Tomar shear zone
    palynology
    organic geochemistry
    Opis:
    The Albergaria-a-Velha Unit is one of several tectonostratigraphic out-of-sequence units of the metamorphic belt associated with the Porto-Tomar shear zone (Ossa-Morena Zone, W Portugal). It is composed of considerably deformed - very low grade - metasediments, namely shales, siltstones and rare fine sandstones. In this work we present new sedimentological and biostratigraphical data that suggest the Albergaria-a-Velha Unit was deposited from the (?)early Frasnian to the Serpukhovian in a distal marine environment, where turbiditic and basinal sedimentation prevailed. Palynofacies analysis and lithological data point to a gradual increase of terrestrial input, suggesting a prograding system. Detrital framework data is indicative of a stable cratonic sediment source area composed of low grade metamorphic rocks. The timing of the onset of the Porto-Tomar shear zone activity and consequently its influence on the sedimentation of this unit is discussed. Organic petrology and geochemistry data indicate that the Albergaria-a-Velha Unit is within the dry gas window in terms of hydrocarbon generation ranges.
    Źródło:
    Geological Quarterly; 2011, 55, 2; 139-164
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of Shot Peening With Glass Microspheres on the Fatigue Behavior of a Low Carbon Steel
    Autorzy:
    de Lacerda, J. C.
    Pereira, I. R.
    Costa, J. M. G.
    Pinto, J. S.
    Souza, H. F. M.
    Fonseca, M. A.
    Powiązania:
    https://bibliotekanauki.pl/articles/352156.pdf
    Data publikacji:
    2019
    Wydawca:
    Polska Akademia Nauk. Czytelnia Czasopism PAN
    Tematy:
    fatigue
    shot peening
    Wöhler curve
    low carbon steel
    glass microspheres
    Opis:
    The present work has the objective of studying the effect of shot peening with glass microspheres on SAE 1020 steel in its resistance to fatigue. Fatigue tests were carried out by rotary bending with load control and loading on balance in specimens with and without shot peening. A rotation speed of approximately 750 rpm (12.5 Hz) was employed in the fatigue tests. Vickers microhardness tests were performed in order to verify the surface hardening produced by shot peening with glass microspheres. Analysis of the steel surface and fatigue fractures was performed using scanning electron microscopy (SEM). Fatigue tests were performed in order to obtain S-N curves (Wöhler curves). It was observed that shot peening with glass microspheres improved the fatigue strength of the steel at high cycle.
    Źródło:
    Archives of Metallurgy and Materials; 2019, 64, 4; 1513-1518
    1733-3490
    Pojawia się w:
    Archives of Metallurgy and Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Narażenie na nanocząstki w środowisku pracy w procesach ceramicznych wykorzystujących technologię laserową
    Workplace exposure to nanoparticles in ceramic processes using laser technology
    Autorzy:
    Fonseca, A.S.
    Viana, M.
    Querol, X.
    Moreno, N.
    De Francisco, I.
    Estepa, C.
    De La Fuente, G.F.
    Powiązania:
    https://bibliotekanauki.pl/articles/180101.pdf
    Data publikacji:
    2016
    Wydawca:
    Centralny Instytut Ochrony Pracy
    Tematy:
    ceramika
    pyły
    nanocząstki
    ablacja laserowa
    spiekanie laserowe
    pomiary
    ceramics
    dusts
    nanoparticles
    laser ablation
    laser sintering
    measurements
    Opis:
    W artykule przedstawiono wyniki oryginalnych badań dotyczących narażenia pracowników przemysłu ceramicznego na ultradrobnej nanocząstki, które powstają w trakcie wykorzystywania lasera do spiekania oraz w wyniku ablacji laserowej. Wyniki przeprowadzonych badań porównano z wartościami referencyjnymi, zalecanymi w stosunku do wymienionych cząstek, a także skomentowano poziom narażenia pracowników, który został uwidoczniony eksperymentalnie.
    The article presents original research results regarding the exposure of workers employed in the ceramic industry towards ultra small and nanoparticles created as a result of laser sintering as well a laser ablation. The results of the research were compared with the referential values for the abovementioned particles and the experimentally proven level of worker's exposure was awarded a commentary.
    Źródło:
    Bezpieczeństwo Pracy : nauka i praktyka; 2016, 7; 18-21
    0137-7043
    Pojawia się w:
    Bezpieczeństwo Pracy : nauka i praktyka
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Seroprevalence of SARS-CoV-2 and assessment of epidemiologic determinants in Portuguese municipal workers
    Autorzy:
    Barros Ferreira, Nuno
    Pereira, Helena
    Pereira, Ana M.
    Azevedo, Luís F.
    Santos, Mariana
    Maranhão, Priscila
    Correia, Ricardo
    Fonseca, João A.
    Canedo, Paulo
    da Costa Pereira, Altamiro
    Sousa-Pinto, Bernardo
    Powiązania:
    https://bibliotekanauki.pl/articles/2084912.pdf
    Data publikacji:
    2022-06-08
    Wydawca:
    Instytut Medycyny Pracy im. prof. dra Jerzego Nofera w Łodzi
    Tematy:
    SARS-CoV-2 infection
    COVID-19 pandemic
    COVID-19 virus
    COVID-19 serodiagnosis
    COVID-19 antibody testing
    SARS-CoV-2 infection serological testing
    Opis:
    ObjectivesTo assess the seroprevalence of SARS-CoV-2 antibodies in municipal employees of Northern Portugal during the first pandemic wave (May–June 2020) and its association with potentially related risk factors for infection.Material and MethodsThe authors assessed municipal employees of 2 cities in Northern Portugal, in whom serological tests to SARS-CoV-2 and an epidemiological survey were applied. The authors assessed the proportion of individuals presenting IgM and/or IgG antibodies to SARS-CoV-2, and evaluated the association between having positive serological test results, epidemiologic variables and clinical presentations. Reported symptoms were evaluated on their sensitivity, specificity, and predictive values.ResultsThe authors assessed 1696 employees, of whom 22.0% were firefighters, 10.4% were police officers, 10.3% were maintenance workers, and 8.1% were administrative assistants. The seroprevalence of SARS-CoV-2 infection was 2.9% (95% CI: 2.1–3.7%). Administrative assistants comprised the professional group with highest seroprevalence of SARS-CoV-2 (OR = 1.9 in the comparison with other occupational groups, 95% CI: 0.8–4.3, p = 0.126). The seroprevalence of SARS-CoV-2 infection among those who were in direct contact with COVID-19 patients in their professional activity was 3.9%, compared to 2.7% among those who were not in direct contact with such patients (OR = 1.5, 95% CI: 0.8–2.8, p = 0.222). The highest risk of infection was associated with the presence of a confirmed SARS-CoV-2 infection in the household (OR = 17.4, 95% CI: 8.3–36.8, p < 0.001). Living with a healthcare professional was not associated with a higher risk of infection (OR = 1.0, 95% CI: 0.4–2.5, p = 0.934). Anosmia/dysgeusia was the symptom with the highest positive predictive value (52.2%, 95% CI: 31.8–72.6, p < 0.001) and specificity (99.3%, 95% CI: 98.9–99.7, p < 0.001), while cough was the most prevalent symptom among SARS-CoV-2 seropositive participants (36%).ConclusionsThe authors observed a SARS-CoV-2 seroprevalence of 2.9% among assessed municipal employees. Anosmia/dysgeusia was the COVID-19 symptom which displayed the highest positive predictive value and specificity.
    Źródło:
    International Journal of Occupational Medicine and Environmental Health; 2022, 35, 3; 297-307
    1232-1087
    1896-494X
    Pojawia się w:
    International Journal of Occupational Medicine and Environmental Health
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-7 z 7

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