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Tytuł:
Water-based poly(urethane-urea) dispersions —meeting the European Union legislation
Dyspersje wodne poli(uretanowo-mocznikowe) w świetle wymagań prawodawstwa Unii Europejskiej
Autorzy:
Fernandes, I. P.
Costa, M. R.
Ferreira, M. J.
Barreiro, M. F.
Powiązania:
https://bibliotekanauki.pl/articles/947121.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
poly(urethane-urea)
water-based dispersion
European Union legislation
N-methyl-pyrrolidone free products
poli(uretano-mocznik)
dyspersja wodna
prawodawstwo Unii Europejskiej
produkty wolne od N-metylo-pirolidonu
Opis:
This article discusses the synthesis methods of water-based poly(urethane-urea) dispersions (PUD), which over the past few decades have developed a solid reputation for high performance applications, particularly in the field of adhesives and coatings. PUDs are mostly environmentally compatible products since they do not contain or contain only low amounts of volatile organic compounds (VOC). This is an important feature in view of the present environmental policies, where governments and internal agencies are placing emphasis on developing sustainable processes, improving work conditions and reducing emissions of toxic and polluting substances into the atmosphere. In this context, this paper will discuss the main approaches applied to PUD synthesis in order to meet severe environmental restrictions resulting from the EU legislation.
Omówiono metody syntezy dyspersji wodnych poli(uretanowo-mocznikowych) (PUD), które znajdują coraz szersze zastosowanie, szczególnie w produkcji klejów i powłok. PUD są na ogół produktami bezpiecznymi dla środowiska, ze względu na brak lub małą zawartość lotnych związków organicznych (VOC), co jest ważne w świetle obecnej polityki ochrony środowiska. Przedstawione w pracy metody syntezy PUD uwzględniają wymagania wynikające z prawodawstwa Unii Europejskiej w zakresie spełniania surowych ograniczeń środowiskowych.
Źródło:
Polimery; 2015, 60, 9; 536-540
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sol-Gel Derived Lanthanide-Substituted Layered Double Hydroxides $Mg_3//Al_{1-x}Ln_{x}$
Autorzy:
Smalenskaite, A.
Şen, S.
Salak, A.
Ferreira, M.
Beganskiene, A.
Kareiva, A.
Powiązania:
https://bibliotekanauki.pl/articles/1398236.pdf
Data publikacji:
2018-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.66.Fd
82.70.Gg
82.33.Ln
71.20.Eh
78.55.Hx
Opis:
Mg/Al/Ln (Ln = Nd, Sm, Eu) layered double hydroxides (LDHs) were synthesized using sol-gel method for the first time to the best our knowledge. The obtained materials were characterized by X-ray diffraction analysis and fluorescence spectroscopy. The phase composition and luminescent properties of these LDHs were investigated and discussed. The Ln³⁺ substitution effects were investigated in the $Mg_3Al_{1-x}Ln_{x}$ LDHs by changing the Ln³⁺ concentration in the metal cation layers up to 10 mol%. It was demonstrated that only $Mg_3Al_{1-x}Eu_{x}$ LDHs showed luminescence properties, however, no any light emission was observed for the $Mg_3Al_{1-x}Nd_{x}$ and $Mg_3Al_{1-x}Sm_{x}$ LDH samples.
Źródło:
Acta Physica Polonica A; 2018, 133, 4; 884-886
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on the Structure of Defects in a-Si:H Films by Positron Annihilation and Micro-Raman Spectroscopy
Autorzy:
Gordo, P.
de Lima, A.
Ferreira Marques, M.
Kajcsos, Zs.
Powiązania:
https://bibliotekanauki.pl/articles/1812497.pdf
Data publikacji:
2008-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.66.Jg
78.70.Bj
78.30.Ly
Opis:
Thin films of hydrogenated amorphous silicon deposited on glass and crystalline silicon substrates by rf plasma enhanced chemical vapor deposition at different rf power were studied using slow positron beam and the Raman scattering spectroscopy in order to verify the influence of that deposition parameter on the film defect structure and on the degree of disorder. By positron annihilation spectroscopy, it was found that there are mainly two types of defects in the films: large vacancy clusters or voids and small vacancy type defects. By micro-Raman spectroscopy it was observed that the degree of structural disorder is lower for the film with large vacancy clusters and this finding was related to structural relaxation process. Light soaking induced changes attributed to major atomic rearrangements were also observed.
Źródło:
Acta Physica Polonica A; 2008, 113, 5; 1373-1378
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Integrating coagulation and Fenton’s oxidation for pharmaceutical effluents treatment
Koagulacja połączona z utlenianiem Fentona w oczyszczaniu ścieków farmaceutycznych
Autorzy:
Martins, R. C.
Oliveira, A. C.
Quinta-Ferreira, R. M.
Powiązania:
https://bibliotekanauki.pl/articles/2073214.pdf
Data publikacji:
2015
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
pharmaceutical wastewater
heterogeneous Fenton's process
photo-Fenton process
low cost catalysts
biodegradability
ścieki farmaceutyczne
heterogeniczny proces Fentona
reakcja foto-Fentona
kataliza nisko-kosztowa
biodegradowalność
Opis:
Pharmaceutical industry produces complex and bio-refractory wastewater whose discharge throughout water courses constitutes an environmental danger. Although several works can be found handling with simulated pharmaceutical effluents, data reporting results gathered using actual wastewater is still scarce. This work reveals that Fe-Ce-O and red volcanic rock are interesting catalysts for dark and photo-Fenton. Furthermore, the light/H2O2 system showed interesting results and it is now being explored at the pilot scale by the pharmaceutical industry that provided the effluent.
Przemysł farmaceutyczny wytwarza złożone i bioodporne ścieki, których zrzut zwykła drogą stwarza zagrożenie dla środowiska. Pomimo tego, że kilka prac zajmuje się transportem symulowanych ciekłych odpadów farmaceutycznych, dane dotyczące rzeczywistych ścieków są wciąż skąpe. W prezentowanej pracy stwierdzono, że Fe-Ce-O i czerwona skała wulkaniczna są ciekawymi katalizatorami w reakcji foto-Fentona. Ponadto układ światło/H2O2 wykazał się interesującymi właściwościami i obecnie jest badany w skali pilotowej przy obróbce ścieków w przemyśle farmaceutycznym.
Źródło:
Inżynieria i Aparatura Chemiczna; 2015, 4; 174--177
0368-0827
Pojawia się w:
Inżynieria i Aparatura Chemiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Air-assistance in spray booms which have different spray volumes and nozzle types for chemically controlling Spodoptera frugiperda on corn
Autorzy:
Gimenes, M.J
Raetano, C.G.
Ferreira, M.H
Pereira-Prado, E.
Souza-Christovam, R.
Tourino-Rezende, D.
Almeida-Costa, S.I.
Powiązania:
https://bibliotekanauki.pl/articles/66410.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
The study aimed to evaluate the performance of air assistance in spray booms using different types of nozzles and spray volumes. We took into account spray deposits, fall armyworm control and crop corn performance in a narrow row cropping system. The experiment was carried out at the experimental area of Sao Paulo State University, Botucatu/SP, Brazil, during the 2008/2009 agricultural season, in randomized blocks with a factorial scheme (2×2+1) and four replications. Two spray nozzles (flat fan nozzle and hollow cone nozzle) were tested, combined with two air assistance levels in the spray boom (with and without air assistance) and a treatment control. In the experimental spraying, Spinosad insecticide was sprayed in amounts of 48 g active substance (a.s.)/ha. The air assistance in the spray boom increased the spray deposits in the V4 growth stage of the corn plants. Moreover, the application of this technology showed higher efficiency on fall armyworm control, reaching a 100% level 15 days after spraying, in the V10 growth stage of the plants. The hollow cone nozzle increased the spray deposit level on the corn plants compared with the flat fan nozzle, at growth stage V4. However, the flat fan nozzle, combined with air assistance technology, was more effective for controlling fall armyworm in the same growth stage (V4), although the hollow cone nozzle increased the deposit levels on the plants. All the technologies tested in the study promoted a reduction of plant damage from fall armyworm attack. Corn productivity is directly related to the control efficiency of fall armyworm.
Źródło:
Journal of Plant Protection Research; 2012, 52, 2
1427-4345
Pojawia się w:
Journal of Plant Protection Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Free-Volume Studies in Polycaprolactone/Poly(propylene oxide) Urethane/Urea Membranes by Positron Lifetime Spectroscopy
Autorzy:
Ferreira Marques, M.
Gordo, P.
de Lima, A.
Queiroz, D.
Norberta de Pinho, M.
Major, P.
Kajcsos, Zs.
Powiązania:
https://bibliotekanauki.pl/articles/1812490.pdf
Data publikacji:
2008-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.41.+e
78.70.Bj
82.30.Gg
Opis:
Positron annihilation lifetime spectroscopy was used to study the free volume parameters in polypropylene oxide-based tri-isocyanate terminated prepolymer/polycaprolactone diol bi-soft urethane/urea membranes (PU/PCL) with PCL content from 5 up to 25 wt%. Positron annihilation lifetime spectroscopy measurements carried out in the temperature range 298-324 K mirrored the phase separation of the various soft and hard segments present in the membranes. The size and amount of free volume holes determined by positron annihilation lifetime spectroscopy appear to be correlated with the $CO_2$ gas permeability through the membranes.
Źródło:
Acta Physica Polonica A; 2008, 113, 5; 1359-1364
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Positron and Positronium Trapping in Heat Treated Zeolites (Ceramics), the Effect of Swift Heavy Ion Irradiation
Autorzy:
Major, P.
Kajcsos, Zs.
Liszkay, L.
Zalán, P.
Kosanović, C.
Bosnar, S.
Subotić, B.
Lázár, K.
Skuratov, V.
Havancsák, K.
Gordo, P.
Ferreira Marques, M.
Powiązania:
https://bibliotekanauki.pl/articles/1812537.pdf
Data publikacji:
2008-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.70.Bj
61.43.Gt
36.10.Dr
61.80.Jh
Opis:
A systematic study of zeolite precursor gels, zeolites, and products of their recrystallization to ceramics was carried out in presence of various alkali ions. The investigation of radiation damage induced by high-energy ion beam irradiation with swift heavy ions (Bi ions at 670 MeV energy with $4×10^{12}$ ion/$cm^2$ fluence) was also included. The shortening of lifetimes found after irradiation in ceramics might probably be ascribed to interactions of o-Ps with free radicals and other quenching agents created through the ion irradiation. These lifetime-shortening interactions probably partly hide the o-Ps trapping in free volume sites.
Źródło:
Acta Physica Polonica A; 2008, 113, 5; 1441-1446
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Positronium Trapping in Porous Solids: Means and Limitations for Structural Studies
Autorzy:
Kajcsos, Zs.
Liszkay, L.
Duplâtre, G.
Varga, L.
Lohonyai, L.
Pászti, F.
Szilágyi, E.
Lázár, K.
Kótai, E.
Pál-Borbély, G.
Beyer, H. K.
Caullet, P.
Patarin, J.
Azenha, M. E.
Gordo, P. M.
Lopes Gil, C.
de Lima, A. P.
Ferreira Marques, M.
Powiązania:
https://bibliotekanauki.pl/articles/2042216.pdf
Data publikacji:
2005-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
36.10.Dr
78.70.Bj
61.43.Gt
Opis:
Positron annihilation techniques are used for the structural investigation of solids but the interpretation of results in grainy and porous media is still unclear. A unique picture can be obtained assuming that the dominant process is Ps trapping in competing "extended free volume" sites. In samples with a large amount of free volumes near-saturation Ps trapping will rule the lifetime pattern, and very long lifetimes of over 100 ns might arise from o-Ps trapped in mesopores. It is shown that lifetime parameters must be corrected for the 3γ/2γ counting efficiency ratio. The results demonstrate the high sensitivity of Ps to mesopores in zeolites but also that Ps-trapping poses limitations on the applicability of lifetime to structural investigation in porous systems. The evolution of the lifetime spectra upon changes in the sample and measuring conditions should be considered in a complex way, observing not only changes in some selected components but in the whole lifetime pattern simultaneously.
Źródło:
Acta Physica Polonica A; 2005, 107, 5; 729-737
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Natural versus anthropic causes in variations of sand export from river basins: an example from the Guadiana River Mouth (Southwestern Iberia)
Autorzy:
Dias, J. M. A.
Gonzales, R.
Ferreira, Ó.
Powiązania:
https://bibliotekanauki.pl/articles/1187374.pdf
Data publikacji:
2004
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
Guadiana River
sediment transport
estuarine sand bodies
floods
NAO
anthropic influence
Opis:
Flood events in many river basins with highly variable discharge values remove accumulated sediments from the riverbed and estuaries. These sediments are exported to the shelf and the adjacent coastlines. Data for rainfall and river discharge for the Guadiana River basin in southwestern Iberia show a strong link with North Atlantic Oscillation (NAO) index patterns. A negative NAO index usually results in more rainfall, and subsequent flooding in the river basin during winter months. During the second half of the 20th century, the flow regime of the Guadiana River and its tributaries have been increasingly constrained by the construction of dams. The consequences were a reduction of coarse-grained sediment export from the upper river basin to the estuary, and a reduction in the number and type of floods.
Źródło:
Polish Geological Institute Special Papers; 2004, 11; 95-102
1507-9791
Pojawia się w:
Polish Geological Institute Special Papers
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Time-of-Flight Positron Emission Tomography with Resistive Plate Chamber Detectors: An Unlikely but Promising Approach
Autorzy:
Couceiro, M.
Crespo, P.
Blanco, A.
Ferreira, N.
Mendes, L.
Ferreira Marques, R.
Fonte, P.
Powiązania:
https://bibliotekanauki.pl/articles/1402607.pdf
Data publikacji:
2015-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
87.57.uk
29.40.Cs
87.57.cf
87.57.cm
Opis:
The cost-effectiveness of resistive plate chamber detectors and their very good timing characteristics, open the possibility to build affordable time-of-flight positron emission tomography systems with a large axial field-of-view. Simulations suggest that, under reasonable assumptions, the absolute 3D true sensitivity, spatial resolution, and noise equivalent count rate of such systems for human whole-body screening, may exceed that of present crystal-based PET technology. However, due to the lack of energy resolution, although having energy sensitivity, the scatter fraction is expected to be considerably higher than that presented by crystal-based PET scanners. In the present paper, the simulation work done so far to access the expected performance of a resistive plate chamber time-of-flight-PET system with 2400 mm length axial field-of-view, a time resolution of 300 ps full width at half maximum for photons pairs, and depth-of-interaction information, will be revised.
Źródło:
Acta Physica Polonica A; 2015, 127, 5; 1453-1461
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Navigation Simulator: professional and academic learning tool for the students of the Portuguese Naval Academy
Autorzy:
Lopes-Ferreira, A.
Bué, I.M.
Lopes, C.F.
Powiązania:
https://bibliotekanauki.pl/articles/115983.pdf
Data publikacji:
2017
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
Maritime Education and Training (MET)
Navigation Simulator
academic learning
Portuguese Naval Academy
MET System in Portugal
NAVSIM
training model
competences
Opis:
The Portuguese Naval Academy is a military school with an university status and is equipped with one modern navigation and maneuvering simulator. The Navigation Simulator (NAVSIM) plays an essential role in the academic training for the Naval Academy and for its cadets, that are using this capacity since their first academic year as a learning tool. Identifying the non-technical skills that could be trained and focusing on the specific training of the technical skills is paramount, in order to maximize the training sessions for each cadet’s year. The assessment of statistical data referring to the last 6 years is important to identify where there are gaps in the exercises, as well as how the midshipman are prepared to perform functions of watch keeping on the ships fleet.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2017, 11, 1; 141-148
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Manufacturing and characterization of resorbable PLGA membranes for biomedical applications
Autorzy:
Krok, M.
Ferreira, C.
Fernandes, S.
Kościelniak, D.
Dobrzyński, P.
Pamuła, E.
Powiązania:
https://bibliotekanauki.pl/articles/284710.pdf
Data publikacji:
2011
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
PLGA
PEG
porous membrane
phase-separation method
GTR
Opis:
Porous poly(L-lactide-co-glycolide) (PLGA) membranes were prepared by solvent-casting/porogen leaching method. Poly(ethylene-glycol) (PEG) with two molecular weights was used as a pore former. Mechanical properties of the membranes were analyzed in tensile test. Topography, pore size and surface roughness were characterized by atomic force microscopy on both sites of the membranes. PEG leached out percentage, thickness and wettability were also measured. Osteoblast-like cells were cultured on the membranes for 24 h and 6 days, and morphology, distribution and number of adhered cells as well as secretion of proteins and nitric oxide were measured. The results show that PEG molecular weight affected size and distribution of pores on both surfaces of the membranes. It resulted also in different mechanical characteristics of the membranes. In vitro experiments show that the membranes support adhesion and growth of osteoblast-like cells suggesting their usefulness for guided tissue regeneration (GTR).
Źródło:
Engineering of Biomaterials; 2011, 14, 104; 8-13
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Shape memory process in resorbable polymers: effect on surface properties and cell adhesion
Autorzy:
Costa, A. M.
Ferreira, A. S.
Posadowska, U.
Krok, M.
Smola, A.
Dobrzyński, P.
Pamuła, E.
Powiązania:
https://bibliotekanauki.pl/articles/286068.pdf
Data publikacji:
2012
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
shape memory
PLGA
tissue regeneration
foil
Opis:
The objectives of this study were to confirm the shape memory behavior of two new bioresorbable terpolymers (L-lactide, glycolide, and trimethylene carbonate: L-PLGTMC and B-PLGTMC), to follow the influence of the shape memory process on their surface properties and to test their cytocompatibility using osteoblast-like cells. For this purpose, foils of both terpolymers were prepared. The terpolymers' ability to recover up to 92-93% of the memorized shape within 10 seconds was obtained. The influence of shape memory process on the surface properties was assessed by water contact angle (WCA) measurement and atomic force microscopy (AFM) and the results suggested that both terpolymers preserved the hydrophilicity after recovery and also that B-PLGTMC polymer was rougher than L-PLGTMC (about 9 folds more). The AFM pictures showed the presence of spherical shape hills on the B-PLGTMC foil surface which after the stretching procedure became oriented toward the direction of the applied load. The terpolymers were seeded on both sides (Top and Bottom faces) with human MG63 osteoblast-like cells. Cell viability was assessed after 1, 3 and 7 days, using MTT assay. Results revealed an increasing number of metabolically active cells with the incubation time, suggesting, together with nitric oxide (NO) level determination, the cytocompatibility of both terpolymers. Cell spreading and morphology were investigated by H&E staining and obtained results corresponded well with ones of MTT and NO.
Źródło:
Engineering of Biomaterials; 2012, 15, 114; 8-11
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Numerical study of Hough technique in surgery of otosclerosis, using the finite element method
Autorzy:
Gentil, F.
Parente, M.
Martins, P.
Santos, C.
Almeida, E.
Ferreira, A.
Natali, R.
Powiązania:
https://bibliotekanauki.pl/articles/307201.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
metoda elementów skończonych
otoskleroza
wycięcie strzemiączka
strzemiączko
finite element method
otosclerosis
stapedectomy
stapedotomy
stapes
Opis:
Purpose: Otosclerosis is a metabolic bone disease of the otic capsule that can cause the stapes fixation, resulting in conductive hearing loss or, in a profound sensorineural deafness threshold. Surgery is one of the possible treatments for the otosclerosis. To repair small focus of otosclerosis in the anterior crus of the stapes, in 1960, Hough suggested the implementation of a technique in which part of the anterior crus is fractured and the stapes turned. As a result, the posterior crus of the stapes is the only connection with the inner ear. In this work, the outcome of Hough’s surgical technique was simulated. Methods: Based on computerized images, a finite element model of middle ear ossicles and tympanic membrane was created, as well as a model where the stapes has changed. The discretization of the tridimensional solid model was made using the ABAQUS software. The mechanical properties used were taken from the literature and adequate boundary conditions were applied. Results: The results obtained with the Hough technique simulation were compared with a representative model of the normal ear, taking into account the displacements obtained on the central part of the stapes footplate and the maximum principal stress in the stapes crus. Conclusions: The results obtained are closer to the normal ear model, therefore Hough technique stands out as a good option to correct small focus of otosclerosis.
Źródło:
Acta of Bioengineering and Biomechanics; 2015, 17, 4; 149-153
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oxidative stress and antioxidant responses in olive tree subjected to cover crops under rainfed conditions
Autorzy:
Correia, C.
Brito, C.
Santos, D.
Bacelar, E.
Goncalves, B.
Ferreira, H.
Moutinho-Pereira, J.
Rodrigues, M.
Powiązania:
https://bibliotekanauki.pl/articles/80569.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
conference
oxidative stress
antioxidative response
olive tree
cover crop
rainfed condition
reactive oxygen species
oxidative damage
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2013, 94, 2
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
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