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Wyszukujesz frazę "Dybczyński, R. S." wg kryterium: Autor


Wyświetlanie 1-3 z 3
Tytuł:
The use of definitive methods based on radiochemical neutron activation analysis for the determination of selenium and arsenic in materials used in proficiency testing
Autorzy:
Chajduk, E.
Polkowska-Motrenko, H.
Dybczyński, R. S.
Powiązania:
https://bibliotekanauki.pl/articles/147273.pdf
Data publikacji:
2008
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
selenium
arsenic
RNAA definitive methods
proficiency testing
Opis:
This article describes the use of two definitive methods for the determination of Se and As traces in biological materials intended for proficiency testing. Radiochemical neutron activation analysis (RNAA) definitive methods are based on reactor neutron activation with a very selective and quantitative post-irradiation separation of the indicator radionuclide by column chromatography, followed by γ-ray spectrometric measurement. Each of these methods has detection limit of the order of ng·g–1 or better, and yields accurate results. The expanded standard uncertainty for both methods is ca. 4%. Definitive RNAA methods were used for establishing assigned values for Se and As in materials employed in proficiency testing of “Plants” series.
Źródło:
Nukleonika; 2008, 53, suppl. 2; 49-54
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Two new separation schemes for the group isolation of rare earth elements (REE) from biological and other matrices and their determination by ICP-MS, NAA and chromatographic methods
Autorzy:
Dybczyński, R. S.
Samczyński, Z.
Bartosiewicz, I.
Kulisa, K.
Polkowska-Motrenko, H.
Pyszynska, M.
Zuba, I.
Powiązania:
https://bibliotekanauki.pl/articles/147581.pdf
Data publikacji:
2017
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
rare earth elements
REE
lanthanides
ion exchange chromatography
NAA
ICP-MS
accuracy
certified reference materials
CRM
Opis:
Two new group separation schemes, based on ion exchange chromatography, for the selective and quantitative isolation of rare earth elements (REE) from accompanying elements, were devised. After checking their performance with the aid of radioactive tracers, the schemes were further used together with ICP-MS, NAA and ion exchange chromatography for the determination of Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu in two certified reference materials (CRMs). The results were compared with another series of analyses, where the REEs were determined directly, i.e. without pre-separation, by instrumental neutron activation analysis (INAA) and inductively coupled plasma mass spectrometry (ICP-MS). It was demonstrated that while direct INAA and ICP-MS in most instances provide reliable results for the majority of REEs, for some elements, notably Sc, Yb and Tm in the cases of ICP-MS and INAA, respectively, systematic errors occur or may potentially occur.
Źródło:
Nukleonika; 2017, 62, 3; 199-211
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ion exchange investigation for recovery of uranium from acidic pregnant leach solutions
Autorzy:
Danko, B.
Dybczyński, R. S.
Samczyński, Z.
Gajda, D.
Herdzik-Koniecko, I.
Zakrzewska-Kołtuniewicz, G.
Chajduk, E.
Kulisa, K.
Powiązania:
https://bibliotekanauki.pl/articles/147778.pdf
Data publikacji:
2017
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
uranium recovery
acidic pregnant leach solution
ion exchange separation
Opis:
The article describes studies on the separation of uranium from acid pregnant leach solutions obtained from Polish uranium ores: dictyonema shales and sandstone rocks. Ion exchange chromatography was applied for uranium sorption, using commercially available, strongly basic anion exchanger, Dowex 1. In model experiments, the influence of degree of crosslinking of Dowex 1 on the efficiency of uranium extraction was investigated. The effect of H2SO4 concentration on the breakthrough curve of uranyl ions for the Dowex 1 resins, of different crosslinking: X4, X8 and X10, was examined. Unexpectedly high increase of exchange capacity of uranium was observed in case of Dowex 1X10. This gives potential opportunity of improving the effectiveness of uranium recovery process. Applying column packed with Dowex 1X10, ‘yellow cake’ with ca. 92% yield and high purity of recovered uranium was obtained. A block diagram of the procedure for uranium and lanthanides extraction from acidic leach liquor has been proposed.
Źródło:
Nukleonika; 2017, 62, 3; 213-221
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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