- Tytuł:
- X-ray Analysis of Intermolecular Interactions in Liquid 2-chloronaphthalene at 353 K
- Autorzy:
- Drozdowski, H.
- Powiązania:
- https://bibliotekanauki.pl/articles/2036984.pdf
- Data publikacji:
- 2003-11
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
- 61.25.Em
- Opis:
- The aim of the study was to examine the structure of liquid 2-chloronaphthalene C$\text{}_{10}$H$\text{}_{7}$-Cl at 353 K by the X-ray diffraction method. Monochromatic radiation Mo K$\text{}_{α}$,λ= 0.71069Å was used to determine the scattered radiation intensity between S$\text{}_{min}$=4πsinθ$\text{}_{min}$/λ=0.430Å$\text{}^{-1}$ and S$\text{}_{max}$= 4π sinθ$\text{}_{max}$/λ=14.311Å$\text{}^{-1}$. The curves of reduced intensity were analysed by the reduction method of Blum and Narten. Experimental distribution of X-ray scattered intensity was compared with theoretical results predicted for a proposed model of 2-chloronaphthalene molecule. The differential radial distribution function 4π r$\text{}^{2}$Σ$\text{}_{j,k}^{n}$ K$\text{}_{j}$[ρ$\text{}_{k}$(r)-ρ$\text{}_{0}$] was calculated and some intra- and intermolecular distances in liquid 2-chloronaphthalene were determined. X-ray structural analysis was applied to determine the packing coefficient of 2-chloronaphthalene molecules at 353 K. The intermolecular distance Cl ··· Cl' was also determined as 7.90±0.15Å. A simple model of short-range arrangement of the molecules was proposed, which seems to be valid for other weakly polar monosubstituted naphthalene derivatives in the liquid phase.
- Źródło:
-
Acta Physica Polonica A; 2003, 104, 5; 441-458
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł