- Tytuł:
- Intrinsic Luminescence of the Undoped Glasses of (CaO-Ga$\text{}_{2}$O$\text{}_{3}$-GeO$\text{}_{2}$) System
- Autorzy:
-
Padlyak, B. V.
Bordun, O. M.
Buchynskii, P. P. - Powiązania:
- https://bibliotekanauki.pl/articles/2010938.pdf
- Data publikacji:
- 1999-06
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
42.70.Ce
78.60.-b
76.30.Mi - Opis:
- For the first time the intrinsic luminescence in the undoped (CaO-Ga$\text{}_{2}$O$\text{}_{3}$-GeO$\text{}_{2}$) glasses with different composition has been found and investigated in the 80÷300 K temperature range. The new glasses of high chemical purity and optical quality with stoichiometric composition similar to that in calcium-gallium- germanium garnet (Ca$\text{}_{3}$Ga$\text{}_{2}$Ge$\text{}_{3}$O$\text{}_{12}$), trigonal Ca-gallogermanate (Ca$\text{}_{3}$Ga$\text{}_{2}$Ge$\text{}_{4}$O$\text{}_{14}$), and Ca$\text{}_{3}$Ga$\text{}_{2}$O$\text{}_{6}$ crystals were obtained by the high-temperature synthesis method. The luminescence and photoexcitation spectra analysis, supported by EPR spectroscopy data, yields the following results: (i) the UV-excited non-elementary broad emission band with maxima at roughly 500 nm and 420 nm in the (CaO-Ga$\text{}_{2}$O$\text{}_{3}$-GeO$\text{}_{2}$) glasses is due to recombination of ensemble of the transient hole O$\text{}^{-}$ centres; (ii) the emission bands with maxima at nearly 380 and 710 nm, which were distinctly revealed in glasses with the Ca$\text{}_{3}$Ga$\text{}_{2}$Ge$\text{}_{4}$O$\text{}_{14}$ and Ca$\text{}_{3}$Ga$\text{}_{2}$O$\text{}_{6}$ compositions, are assigned to the luminescence of UV-induced electron centres of two different types. Possible models of the luminescence centres in (CaO-Ga$\text{}_{2}$O$\text{}_{3}$-GeO$\text{}_{2}$) glass network are discussed.
- Źródło:
-
Acta Physica Polonica A; 1999, 95, 6; 921-929
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł