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Tytuł:
Defect Sensitivity of Magnetic Dot Arrays Influenced by Thermal Activation and Intradot Anisotropy
Autorzy:
Baláž, P.
Horváth, D.
Gmitra, M.
Powiązania:
https://bibliotekanauki.pl/articles/1813931.pdf
Data publikacji:
2008-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.80.Az
74.25.Fy
74.72.Bk
02.70.Bf
Opis:
The influence of non-magnetic central node defect on magnetic hysteresis of regular square-shaped segment of magnetic dot array with perpendicular uniaxial anisotropy under the thermal activation was investigated via computer simulations based on stochastic Landau-Lifshitz-Gilbert equation. The aim of this study is to point out the simultaneous effect of anisotropy and thermal activation to the dynamical properties of magnetic dot arrays.
Źródło:
Acta Physica Polonica A; 2008, 113, 1; 583-586
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Current-Pulse-Induced Switching οf Asymmetric Spin Valves
Autorzy:
Baláž, P.
Gmitra, M.
Barnaś, J.
Powiązania:
https://bibliotekanauki.pl/articles/1810525.pdf
Data publikacji:
2009-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
72.25.Ba
73.21.Ac
Opis:
Dynamical behavior of an asymmetric spin valve, Co/Cu/Py nanopillar sandwiched between Cu electrodes, subject to a spin-polarized current was investigated in the diffusive transport regime. Using numerical macrospin simulations, the dynamical diagrams of the sensing layer were constructed, and the possibilities of switching from one collinear state to the other were discussed. A simple switching scheme for asymmetric spin valves, based on a sequence of current and magnetic field pulses, was proposed and illustrated on an example.
Źródło:
Acta Physica Polonica A; 2009, 115, 1; 278-280
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Geotouristic excursion to selected historical mining sites developed by Slovak and German miners in the Gelnica-Smolnik region, Slovakia
Wycieczka geoturystyczna do wybranych miejsc historycznej eksploatacji złóż rud przez słowackich i niemieckich górników w rejonie Gelnicy-Smolnika, Słowacja
Autorzy:
Rybar, P.
Sasvari, T.
Hvizdak, L.
Hvizdakova, J.
Balaz, B.
Powiązania:
https://bibliotekanauki.pl/articles/344547.pdf
Data publikacji:
2010
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Stowarzyszenie Naukowe im. Stanisława Staszica
Tematy:
Kamczatka
wulkany: Kluczewski, Płaski, Kamień, Bezimienny, Zimina, Wielka Udina, Tołbaczik
stratowulkany
kopuły ekstruzywne
history of mining towns
Gelnica
Smolnik
Rożnava
exploitation of precious and nonferrous metals
Opis:
The following paper summarizes the history of Gelnica, Smolnik and Rożnava gold, silver, copper and iron orefields in Eastern Slovakia, which have been mined since the Medieval ages by of Slovak and German miners. In Gelnica, where mining operations date back to the XIIth century, massive quartz-siderite- chalcopyrite veins with Fe-dolomite, pyrite and tetrahedrite (with silver) cut Lower Devonian phyllites and porphyroids. In Smolnik, where copper mining has commenced in the first half of the XIIIth century followed by gold, then silver and iron ore exploitation, 10-11 pyrite-chalcopyrite ore horizons are hosted in Silurian phyllites. In Rożnava mining operations for iron, silver gold and copper ores have been known since the XIIIth century and have lasted until 1992. Over 40 ore veins discovered in this field contain mostly siderite although quartz-siderite-sulphide paragenesis with Ag-bearing tetrahedrite was also observed. In all three mining districts there are numerous objects of mining heritage and other valuable historical monuments, reflecting the wealth of old Slovak mining towns.
Artykuł podsumowuje historię eksploatacji złóż rud złota, srebra, miedzi i żelaza w Gelnicy, Smolniku i Rożnavie we wschodniej Słowacji, które wydobywali od średniowiecza górnicy słowaccy i niemieccy. W Gelnicy, gdzie roboty górnicze rozpoczęto w XII w., występują żyły kwarcowo-syderytowo-chalkopirytowe z niewielką ilością dolomitu żelazistego, pirytu i tetraedrytu zawierającego srebro. Przecinają one dolnodewońskie fyllity i porfiroidy. W Smolniku, gdzie wydobywano miedź już w pierwszej połowie XIII w., a następnie eksploatowano złoto, srebro i rudę żelaza, w fyllitach wieku sylurskiego zalega 10-11 horyzontów rudnych z pirytem i chalkopirytem. W Rożnavie rudy żelaza, srebra, złota i miedzi były eksploatowane od wieku XIII do roku 1992. Znajduje się tutaj ponad 40 żył kruszcowych zawierających głównie syderyt, chociaż znana jest także parageneza kwarc-syderyt-siarczki ze srebronośnym tetraedrytem. We wszystkich trzech okręgach górniczych znajduje się wiele obiektów historycznego dziedzictwa górniczego, a także inne, cenne zabytki historyczne, dokumentujące bogactwo dawnych słowackich miast górniczych.
Źródło:
Geoturystyka; 2010, 1; 23-30
1731-0830
Pojawia się w:
Geoturystyka
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Properties and Sorption Activity of Mechanically Activated Magnetite $Fe_3O_4$
Autorzy:
Baláž, P.
Timko, M.
Kováč, J.
Bujňáková, Z.
Ďurišin, J.
Myndyk, M.
Šepelák, V.
Powiązania:
https://bibliotekanauki.pl/articles/1535173.pdf
Data publikacji:
2010-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.60.Ej
61.05.cp
76.80.+y
Opis:
It is known that the action of mechanical forces on solids (mechanical activation and/or mechanochemistry) leads to changes of their properties and reactivity. We have studied the physico-chemical and sorption properties of magnetite $Fe_3O_4$ (Kiruna, Sweden) mechanically activated in a planetary mill. Several methods such as X-ray diffractometry, Mössbauer spectroscopy, magnetometry, specific surface area measurement as well as arsenic sorption tests have been applied. By X-ray diffractometry strong amorphisation of magnetite has been evidenced. In parallel, specific surface area increased from 0.1 $m^2//g$ for the reference (non-milled) sample to the values 0.5-6.1 $m^2//g$ for milled samples. The Mössbauer spectrum of the reference sample is well fitted with two subspectra corresponding to tetrahedrally (A) and octahedrally (B) coordinated iron cations in the spinel structure of $Fe_3O_4$. In mechanically activated samples (B)-site subspectrum becomes asymmetric, while (A)-site spectrum remains more or less unchanged. The more covalent character of the Fe(A)-O bond compared to the Fe(B)-O bond can explain qualitatively why the spin-density transfer from (A) to (B) in the spinel structure is more effective than vice versa. The value of the saturation magnetization at room temperature was 67.4 ≈ 43.6 emu/g which is significantly lower than that of the bulk particles 92 emu/g. This reduction may be attributed to the surface disorder or spin canting at the particle surface. During the milling process the coercivity value increases from 150 Oe up to 460 Oe with milling time. This increase can be related to the fact that magnetic anisotropy may increase when particle size decreases. The sorption activity of $Fe_3O_4$ was enhanced as a consequence of its disordering: 88% of $As^{3+}$ was captured for the mechanically activated sample in comparison with 0% for the non-milled one.
Źródło:
Acta Physica Polonica A; 2010, 118, 5; 1005-1007
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Current-Induced Spin Accumulation and Spin Transfer Torque in a Néel Domain Wall
Autorzy:
Baláž, P.
Szymczyk, Ł.
Dugaev, V.
Barnaś, J.
Powiązania:
https://bibliotekanauki.pl/articles/1427608.pdf
Data publikacji:
2012-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.60.Ch
75.70.Cn
Opis:
Current-induced spin accumulation in a domain wall and the associated spin torque exerted on the wall are analyzed theoretically. The considerations are limited to a relatively thick Néel domain wall in a bulk ferromagnetic metal. The current-induced spin density is calculated using the linear response theory and the Green function formalism.
Źródło:
Acta Physica Polonica A; 2012, 121, 5-6; 1210-1212
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemical Synthesis and Characterization of II-VI Nanocrystals: Challenge for Cytotoxicity Issues
Autorzy:
Baláž, P.
Jardin, R.
Dutková, E.
Sayagués, M.
Baláž, M.
Mojžišová, G.
Mojžiš, J.
Turianicová, E.
Fabián, M.
Powiązania:
https://bibliotekanauki.pl/articles/1419910.pdf
Data publikacji:
2012-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Dz
81.07.Bc
81.20.Ka
81.20.Wk
Opis:
CdSe@ZnS nanocrystals have been prepared by a two-step solid state mechanochemical synthesis. CdSe prepared from elements in the first step is mixed with ZnS synthesized from zinc acetate and sodium sulfide in the second step. The crystallite size of the new type CdSe@ZnS nanocrystals determined by X-ray diffraction Rietveld refined method was 35 nm and 10 nm for CdSe and ZnS, respectively. Energy dispersive/transmission electron microscopy/energy dispersive spectroscopy methods show good crystallinity of the nanoparticles and scanning electron microscopy elemental mapping illustrate consistent distribution of Cd, Se, Zn and S elements in the bulk of samples. UV-VIS spectra show an onset at 320 nm with calculated bandgap 3.85 eV. This absorption arises from the vibration modes of Zn-S bonds. The nanocrystals show the blue shift from the bandgap of bulk ZnS (3.66 eV). The synthesized CdSe@ZnS nanocrystals have been tested for dissolution, cytotoxicity and L-cysteine conjugation. The dissolution of Cd was less than 0.05 μg $mL^{-1}$ (in comparison with 0.8 μg $mL^{-1}$ which was evidenced for CdSe alone). The very low cytotoxic activity for selected cancer cell lines has been evidenced. CdSe@ZnS nanocrystals coated with L-cysteine are water-soluble and have a great potential in biomedical engineering as fluorescent labels.
Źródło:
Acta Physica Polonica A; 2012, 122, 1; 224-229
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic Properties of Mechanochemically Synthesized Mixed Oxides
Autorzy:
Kostova, N.
Zorkovská, A.
Kováč, J.
Velinov, N.
Baláž, P.
Powiązania:
https://bibliotekanauki.pl/articles/1372521.pdf
Data publikacji:
2014-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
77.84.Bw
75.60.-d
76.80.+y
61.05.cp
81.07.Wx
Opis:
The mixed oxides $Fe_{2}O_{3}-ZnO$ have been obtained in nanocrystalline state by reactive milling in a high-energy planetary mill, from a stoichiometric mixture of hematite and ZnO. The magnetic properties of samples were evaluated by magnetization measurements and Mössbauer spectrometry. A post milling annealing promotes the solid state reaction and improves the zinc ferrite formation, paramagnetic $ZnFe_{2}O_{4}$ phase is formed. Further mechanical activation leads to structural transformation into Wüstite-type (FeZn)O mixed oxide, with ferromagnetic hysteresis and increased magnetization.
Źródło:
Acta Physica Polonica A; 2014, 126, 1; 411-412
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemical Dechlorination of PVC by Utilizing Eggshell Waste
Autorzy:
Baláž, M.
Baláž, P.
Bujňáková, Z.
Pap, Z.
Kupka, D.
Zorkovská, A.
Powiązania:
https://bibliotekanauki.pl/articles/1375093.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Lg
81.20.Wk
88.20.dr
Opis:
Within this work, the dechlorination of polyvinylchloride (PVC) chemical as a model by co-milling with eggshell was performed in a planetary ball mill in order to show that mechanochemistry can be utilized for the simultaneous treatment of two wastes, while the products of the treatment can be used in further applications. The products of the reaction are water-soluble calcium chloride ($CaCl_2$), which can be used e.g. for de-icing of roads in winter and organic residue on the basis of ethylene, which can be recovered as energy source. The highest dechlorination yield (almost 97%) was achieved under following milling conditions: molar ratio between Ca and Cl: 2.34, ball-to-powder ratio: 65, rotation speed of the planet carrier: 550 rpm, milling time: 4 h and material of milling media: tungsten carbide. The optimum conditions were then applied for the removal of chlorine from industrial waste - the abandoned PVC window parapet. In this case, 95% dechlorination was evidenced.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 884-887
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemically Synthesized Nanocrystalline $Sb_2S_3$ Particles
Autorzy:
Dutková, E.
Sayagués, M.
Real, C.
Zorkovská, A.
Baláž, P.
Šatka, A.
Kováč, J.
Ficeriová, J.
Powiązania:
https://bibliotekanauki.pl/articles/1375343.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Hd
81.07.Bc
81.20.Wk
Opis:
Nanocrystalline $Sb_2S_3$ particles have been synthesized from Sb and S powders by high-energy milling in a planetary mill using argon protective atmosphere. X-ray diffraction, particle size analysis, scanning electron microscopy, energy dispersive X-ray spectroscopy, transmission electron microscopy, electron diffraction, high resolution transmission electron microscopy, UV-VIS, and differential scanning calorimetry methods for characterization of the prepared particles were applied. The powder X-ray diffraction pattern shows that $Sb_2S_3$ nanocrystals belong to the orthorhombic phase with calculated crystallite size of about 36 nm. The nanocrystalline $Sb_2S_3$ particles are constituted by randomly distributed crystalline nanodomains (20 nm) and then these particles are forming aggregates. The monomodal distribution of $Sb_2S_3$ particles with the average hydrodynamic parameter 210 nm was obtained. The quantification of energy dispersive X-ray spectroscopy analysis peaks give an atomic ratio of 2:3 for Sb:S. The optical band gap determined from the absorption spectrum is 4.9 eV, indicating a considerable blue shift relative to the bulk $Sb_2S_3$. Differential scanning calorimetry curves exhibit a broad exothermic peak between 200 and 300°C, suggesting recovery processes. This interpretation is supported by X-ray diffraction measurements that indicate a 23-fold increase of the crystallite size to about 827 nm as a consequence of application of high temperature process. The controlled mechanochemical synthesis of $Sb_2S_3$ nanoparticles at ambient temperature and atmospheric pressure remains a great challenge.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 943-946
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Mechanochemistry of Solids: New Prospects for Extractive Metallurgy, Materials Science and Medicine
Autorzy:
Baláž, P.
Baláž, M.
Achimovičová, M.
Bujňáková, Z.
Dutková, E.
Powiązania:
https://bibliotekanauki.pl/articles/1375090.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Dz
81.20.Wk
81.07.Bc
Opis:
In this review paper recent advances in chalcogene mechanochemistry are described. Three selected areas are being covered, i.e. metallurgy, materials science, and medicine. In extractive metallurgy, the processing of copper arsenic mineral enargite ($Cu_3AsS_4$) with the aim of its dearsenification and subsequent preparation of a new anticancer drug ($Na_3AsS_4$) and of copper in nanocrystalline state ( ≈ 20 nm) illustrate the non-traditional prospect of ore treatment. In material science, the new nanocrystalline semiconductors were synthesized mechanochemically, e.g. selenides of zinc and lead (ZnSe, PbSe) and bismuth sulphide ($Bi_2S_3$). Metal and chalcogene were applied as reaction precursors. In some cases, the amino acids (cystine, cysteine) were applied as sulphur precursor, in order to provide reactive sites on synthesized solid (PbS) for bioconjugation and to prevent agglomeration. The concept of nanomilling is described as a way to prepare effective substances for cancer treatment in medicine. In vitro activity of realgar ($As_4S_4$) as an example is described. In all three areas the focus is aimed also on industrial applications where suitable large-scale mills are described. The described examples represent the contemporary aim of mechanochemists - to prepare substances with the desired properties in a reproducible way under easy-operating, environmentally friendly and essentially waste-free conditions.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 879-883
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photocatalytic Properties of Mechanochemically Synthesized Nanocrystalline $ZnAl_2O_4$ and CdSe
Autorzy:
Kostova, N.
Eliyas, Al.
Fabián, M.
Achimovičová, M.
Baláž, P.
Powiązania:
https://bibliotekanauki.pl/articles/1375494.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.20.-n
61.05.cp
61.46.-w
61.66.Fn
Opis:
Nanocrystalline powders of $ZnAl_2O_4$ and CdSe were prepared via mechanochemical synthesis. Powder slurries were coated as thin films on $SiO_2$ thin layer chromatography (TLC) sheet by capillary method. The photocatalytic activity of the film coating was tested in a self-made gas-phase flat-plate continuous-flow photocatalytic reactor with toluene as model air contaminant. The tested nanocrystalline $ZnAl_2O_4$ turned out to be poor oxidation photocatalyst under UV irradiation. CdSe displays considerable photocatalytic activity under visible light, where $TiO_2$ is inactive. The nonconventional one-step mechanochemical route to $ZnAl_2O_4$ and CdSe synthesis offers several advantages compared to traditional processing routes, including low-temperature solid state reactions at ambient temperature, absence of organic templates contamination and low expenses.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 967-970
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physico-Chemical and Biological Properties of Arsenic Sulfide ($As_{55}S_{45}$) Nanosuspension Prepared by Milling
Autorzy:
Bujňáková, Z.
Shpotyuk, O.
Sedlák, J.
Pastorek, M.
Turianicová, E.
Baláž, P.
Ingram, A.
Powiązania:
https://bibliotekanauki.pl/articles/1375164.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.20.Wk
81.05.Kf
81.07.-b
Opis:
Nanosuspension based on melt-quenched arsenic sulfide of nominal $As_{55}S_{45}$ composition was prepared by nanomilling and tested as potential anticancer drug. Polyvinylpyrrolidone was used as steric stabilizer and inhibitor of agglomeration. Individual nanoparticles had average size of 192 nm (determined by photon cross-correlation spectroscopy) and had several times better dissolution ability in comparison with bulk $As_{55}S_{45}$. Effect of nanomilling is shown to be associated with formation of arsenic sulfide crystalline nanoparticles and free-volume entities located at the interface between nanoparticles and surrounding matrix as it follows from positron annihilation measurements. Cytotoxicity tests were performed using human melanoma cell line Bowes and confirmed high toxicity of the studied nanosuspension.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 902-906
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study of the Mechanochemical Reduction of Ilmenite Concentrate by Addition of Aluminum
Autorzy:
Achimovičová, M.
Gock, E.
Turianicová, E.
Kostova, N.
Velinov, N.
Kaňuchová, M.
Baláž, P.
Powiązania:
https://bibliotekanauki.pl/articles/1382742.pdf
Data publikacji:
2014-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
77.84.Cg
81.20.Wk
81.20.Ev
82.33.Pt
Opis:
Mechanochemical reduction of ilmenite concentrate $(FeTiO_{3})$ with elemental aluminum powder was performed by high-energy milling in an industrial eccentric vibratory ball mill ESM 656-0.5 ks (Siebtechnik, Germany). The mechanochemically reduced ilmenite with various times of milling was characterized by X-ray diffraction analysis, which confirmed the presence of the $Al_2O_3$ and $Fe_2Ti$ phases after 120 min of milling. Thermal analysis evidenced the completion of a mechanochemical reduction during milling. After 360 min of milling, the $Fe_2Ti$ phase decomposed to α-(Fe,Ti) alloy, which was proven by $\text{}^{57}Fe$ Mössbauer spectroscopy. X-ray photoelectron spectroscopy detected the amorphous TiO phase in product after mechanochemical reduction, which is in accordance with thermodynamic prediction. Decreasing of specific surface area after 60 min of milling resulted from growing layers of the solid products of $FeTiO_3$ mechanochemical reduction.
Źródło:
Acta Physica Polonica A; 2014, 126, 4; 867-870
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Spin Pumping on Spin Waves in Antiferromagnetically Exchange-Coupled Double Layers with Surface Anisotropy
Autorzy:
Baláž, P.
Barnaś, J.
Powiązania:
https://bibliotekanauki.pl/articles/1402556.pdf
Data publikacji:
2015-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
75.40.Gb
75.76.+j
75.78.-n
Opis:
Spin wave modes in antiferromagnetically exchange-coupled magnetic double layers are analyzed theoretically. The considered structure is assumed to be covered by a nonmagnetic metallic layer. The spin wave frequencies and spin wave life times are determined from the macroscopic description based on the Landau-Lifshitz-Gilbert equation, which includes the torque due to spin pumping to the cap layer.
Źródło:
Acta Physica Polonica A; 2015, 128, 2; 150-152
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Copper Leaching from Chalcopyrite: Mechanochemical Approach
Ługowanie miedz z chalkopirytu – aspekt mechaniczny i chemiczny
Autorzy:
Tesinsky, M.
Balaz, P.
Powiązania:
https://bibliotekanauki.pl/articles/971182.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
mielenie
aktywacja mechaniczna
ługowanie
chalkopiryt
milling
mechanical activation
leaching
chalcopyrite
Opis:
In the presented work, possibilities of intensification of copper leaching from chalcopyrite CuFeS2 induced by mechanical activation was studied. In this article, the influence of mechanical activation time on copper leaching efficiency is compared. This study also shows how mechanical activation time influences selectivity of copper and iron leaching. For mechanical activation, planetary mill Fritsch Pulverisette 6 at 400 rpm and room temperature was used. Grinding chamber (250 cm3 in volume) and 50 balls (10 mm in diameter) made of tungsten carbide were used. Specifically, the effect of mechanical activation time (4, 20, 30 minutes), the effect of temperature (40, 60, 80°C) on the copper recovery by leaching and the effect of the leaching atmosphere (air, argon) were examined. The results showed that the highest possible recovery of copper from chalcopyrite was obtained after 20 minutes of milling and leached in hydrochloric acid at 80°C, with air atmosphere without any oxidizing reagents.
W artykule przedstawiono możliwości intensyfikacji procesu ługowania miedzi z chalkopirytu CuFeS2 za pomocą aktywacji mechanicznej. Zbadano wpływ czasu aktywacji mechanicznej na efektywność ługowania miedzi. Wyniki badań pokazały również wpływ czasu na selektywność rozdziału miedzi i żelaza. Do aktywacji mechanicznej wykorzystani młyn planetarny Fritsch Pulverisette 6, aktywację prowadzono przy obrotach 400 rpm, w temperaturze pokojowej. Do badan wykorzystano komorę mielenia o objętości 250 cm3 i 50 kul o średnicy 10 mm wykonanych z węglika wolframu. Określono wpływ czasu aktywacji mechanicznej (4, 20, 30 minut), wpływ temperatury (40, 60, 80°C) na odzysk miedzi w procesie lugowania w atmosferze powietrza i argonu. Wyniki wskazują, że najwyższy możliwy odzysk miedzi z chalkopirytu uzyskano po 20 minutach mielenia i ługowaniu w kwasie solnym w temperaturze 80°C, w atmosferze powietrza, bez jakichkolwiek czynników utleniających.
Źródło:
Inżynieria Mineralna; 2017, R. 18, nr 1, 1; 1-5
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 18

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