- Tytuł:
- Modification of industrial divinyl rubber by oxidative chlorophosphorylation and assess-ment of metal ion removal efficiency of obtained polymer sorbent
- Autorzy:
-
Akhmedov, V. M.
Alfadul, S.
Maharramov, A. M.
Azizov, A. A.
Alosmanov, R. M.
Buniyad-Zadeh, I. A. - Powiązania:
- https://bibliotekanauki.pl/articles/778480.pdf
- Data publikacji:
- 2015
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
Divinyl rubber
modification by chlorophosphorylation
nature and distribution of phosphoric functionalities in the polymer matrix
heavy metal ions
sorption - Opis:
- The main goal of this study was the preparation of materials containing phosphoric functionalities on the base of industrial polymer - divinyl rubber and the assessment of their removal efficiency of heavy metals from aqueous solutions. The new method concerns the oxidative chlorophosphorylation of divinyl rubber by PCl3 with the following modification of obtained inter-mediates to create -PO(OH)2, -OPO(OH)2&enspgroups in the polymer chain. The obtained modified polymers get some new properties such as complex formation and capability for ion exchange. The nature and distribution of phosphoric functionalities in the polymer were studied by the methods of NMRand FTIR- spectroscopy, thermal analysis and scanning electron microscopy. The sorption properties of synthesized polymers towards some cations (Cu+2, Ni+2, Co+2 and Zn+2) from water solutions have been tested. It has been shown that the metal removal efficiency of prepared material depends on pH of medium, initial concentration and type of metal ions
- Źródło:
-
Polish Journal of Chemical Technology; 2015, 17, 2; 112-118
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł