- Tytuł:
- $Cu_3(tmen)_3(tma)_2(H_2O)_2$ · $6.5H_2O$ - New S = 1/2 "Sawtooth" Chain?
- Autorzy:
-
Vrábel, P.
Orendáčová, A.
Černák, J.
Orendáč, M. - Powiązania:
- https://bibliotekanauki.pl/articles/1535093.pdf
- Data publikacji:
- 2010-11
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
75.10.Jm
75.10.Pq
75.30.Et - Opis:
- The results of the investigation of magnetic susceptibility, magnetization and specific heat of $Cu_3(tmen)_3(tma)_2(H_2O)_2$ · $6.5H_2O$ (tmen = N,N,N',N'-tetramethylethane-1,2 diamine; $H_3$ tma = 1,3,5-benzenetricarboxylic acid) are reported. The spatial arrangement of magnetic Cu(II) ions and network of covalent bonds suggest that the studied material might be a representative of S = 1/2 sawtooth chain with moderate exchange coupling J/$k_{B}$. The investigation of the temperature dependence of susceptibility and magnetic field dependence of magnetization yielding J/$k_{B}$ ≈ - 0.63 K is consistent with the structural features. In addition, specific heat data reveal short-range correlations in milikelvin temperature range and indicate long-range ordering below 150 mK.
- Źródło:
-
Acta Physica Polonica A; 2010, 118, 5; 993-994
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł