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Wyszukujesz frazę "Çelik, Mehmet S." wg kryterium: Autor

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    Wyświetlanie 1-5 z 5
    Tytuł:
    Modelling of selective retention of Cd-Ni ions from aqueous solutions by polymer enhanced ultrafiltration
    Autorzy:
    Can, Muhammed F.
    Arslan, Fatma
    Çelik, Mehmet S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2146925.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cadmium
    nickel
    polymer enhanced ultrafiltration
    polyethylenimine (PEI)
    selective heavy metal ion retention
    Opis:
    Polymer enhanced ultrafiltration (PEUF) technique economically enables separation and/or retention of various heavy metal ions from aqueous solutions for environmental and engineering problems. Polyethylenimine as the water-soluble complexation agent utilized to interact with heavy metal ions of Cd and Ni as cations in ultrafiltration experiments were modeled with protonation data to understand the mechanism. Test runs showed that an enrichment coefficient (the ratio of Cd over Ni in permeate) up to 10 was obtained at pH 4.2 in the temperature range of 20-22oC, whereas full retention of both cations is possible above pH 5.0 and those results are highly compatible with the model developed.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 151913
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of crystallinity and surface silanol groups on rheological properties of different sepiolites
    Autorzy:
    Çınar, Mustafa
    Gülgönül, Ilhan
    Ozdemir, Orhan
    Çelik, Mehmet S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2146875.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    sepiolite
    rheology
    crystallinity
    pH
    Opis:
    In this study, differences in the rheological properties of three different types of brown sepiolites (K1, K2, and K3) along with one beige (B) sepiolite with different physicochemical properties were explained based on their crystallinity and level of surface silanol groups. Towards this aim, SEM images, XRD and chemical analyses, cation exchange capacity (CEC), and water absorption tests were conducted along with surface area measurements and time-dependent pH profiles. The pH profiles at 3% by wt. revealed that each sepiolite sample attained the equilibrium at different times. These differences showed a parallel behavior with the degree of crystallinity. While sepiolite with better crystallinity (K1) was rather slow in reaching the equilibrium pH, the sepiolites with poor crystallinity (B and K3) reached their equilibrium pH more quickly. The rheological studies conducted with different sepiolites at 3% solids concentration exhibited time-dependent flow of the Bingham plastic model and thixotropic. Differences observed in the rheological behavior of sepiolites were found to correlate with the fiber size, CEC, surface area, and water absorption. The results further indicated that sepiolites with low crystallinity or high level of surface silanol groups (K3 and B sepiolites) show the best rheological properties.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 153947
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Morphological changes of glass bead particles upon an abrasive blasting as characterized by settling and flotation experiments
    Autorzy:
    Behzad, Vaziri Hassas
    Güven, Onur
    Baştürkcü, Esra
    Çelik, Mehmet S.
    Powiązania:
    https://bibliotekanauki.pl/articles/1448218.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    roundness
    flotation
    settling rate
    energy barrier
    Opis:
    The recent developments in mineral processing led researchers to look for alternative methods and propose new mechanisms for enhancing the efficiency of relatively costly processes (e.g., flotation, aggregation), where especially dealing with fine particles. Finer the particles, the higher the role of their surface on their behavior and properties. The importance of particle morphology becomes even clearer when particle-particle and particle-bubble interactions are considered. In this study, the effect of particle shape “roundness” on the surface wettability and flotation response was investigated upon producing fine particles with the “abrasion blasting” method. In order to provide a fundamental perspective, adsorption measurements were also carried out along with the flotation experiments under the same conditions. In addition to these, zeta potential measurements were also carried out with both spherical and blasted particles as a function of collector concentration. The results suggested that the roundness of particles decreased up to a certain nozzle pressure value, which was followed by higher adsorption degrees and consequently higher flotation recoveries. Additionally, settling rate tests were also performed with very fine material to show the effect of particle morphology on particle-particle interactions. The results showed that while lower settling rate values were obtained for spherical ones, higher values were obtained in the case of the ground and blasted samples in the presence of DI water. It was concluded from this study that the “Abrasive blasting method” could be an effective alternative for tuning the surface morphology of particles and their wettability, which in turn can affect the particle interactions in the system.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 2; 157-168
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Morphological analysis of organo-montmorillonites via MD simulations
    Autorzy:
    Karataş, Deniz
    Tekin, Adem
    Can, Muhammed F.
    Xu, Zhenghe
    Çelik, Mehmet S.
    Powiązania:
    https://bibliotekanauki.pl/articles/2146936.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    organo-montmorillonite
    tetradecyl dimethyl ethyl benzyl ammonium chloride
    molecular dynamics simulation
    cation exchange capacity
    binding energy
    Opis:
    Adsorption on clay surfaces has been studied intensively in recent years. The most curious subject of these studies, which are generally experimental, is how the surfactants are adsorbed at the atomic level to the surface. In this study, the adsorption of quaternary amine salt (tetradecyl dimethyl ethyl benzyl ammonium chloride–TDEBAC) to sodium montmorillonite (Na-MMT) with various cation exchange capacities (CEC) was investigated by using Molecular Dynamics (MD) simulation. In the simulations, as in the experimental studies, it was revealed that the surfactants were both adsorbed on to basal surfaces and settled between the layers. From the morphological analysis obtained from MD simulations, it was calculated that the inter-molecular interaction between the layers was higher than on the basal surface. For example, for the model with 118 CEC motif, the binding energy of all three surfactants in the models with the hydrophilic heads facing the same direction was calculated as -678.18 kcal/mol at the basal surface, while this value was found to be -688.90 kcal/mol in the interlayer. The more striking result is that in the simulations made by turning the head of the middle one of the three surfactants towards the tails of the right and left ones, only -34.86 kcal/mol binding energy was calculated on the basal surface, while this value was -525.63 kcal/mol in the interlayer. As compared middle reversed surfactant models with the same direction ones, despite increased CEC the intermolecular interaction decreased for the basal surface, but the interaction increased between the layers.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2022, 58, 5; art. no. 152499
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Effect of particle shape properties on selective separation of chromite from serpentine by flotation
    Autorzy:
    Guven, Onur
    Serdengecti, M. Tayhan
    Tunc, Berivan
    Ozdemir, Orhan
    Karaagaclioglu, Ibrahim E.
    Çelik, Mehmet S.
    Powiązania:
    https://bibliotekanauki.pl/articles/1845205.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    chromite
    serpentine
    morphology
    flotation
    mineral mixtures
    Opis:
    Although many studies have been conducted on the morphological variations and its effects on flotation recoveries of a single mineral system, a systematic study for the flotation behavior of mixtures of minerals has not dwelled much. In this study, th flotation behavior of chromite and serpentine minerals was investigated to distinguish and isolate the contribution of morphology in single and binary systems. For this purpose, the shape analyses for the minerals ground as single and mixture were performed, and their flotation behaviors determined with the micro-flotation experiments. Additionally, the zeta potential measurements were carried out in the presence of sodium oleate as a collector. The shape analysis of the ground samples showed that while the roundness values of chromite and serpentine (gangue) minerals as single were quite different, the particle shape of chromite favored serpentine in the mixture system which in turn suggested that the mineral with the high hardness value dominates the shape characteristics in binary grinding conditions. Accordingly, while the flotation characteristics of chromite in the mixture followed the same trend with the flotation of a single chromite system as a function of particle shape, almost a reverse trend was obtained for the shape and flotation of serpentine in the mixture compared to a single serpentine system. Thus, at roundness values of chromite particles from 0.797 to 0.732, the flotation recoveries of chromite in the mixture increased from 51.0% to 75.4%. On the other hand, likewise chromite, the flotation recoveries of serpentine increased from 20.0% to 37.3% proportional to the roundness range of 0.757 and 0.709. These findings in turn showed that the grinding conditions dictate the soft component to be monitored by the harder and denser component which dominates the angularity and floatability of the mixture.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 5; 818-828
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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