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Tytuł:
Reactivity of nano zero-valent iron in permeable reactive barriers
Autorzy:
Pawluk, K.
Fronczyk, J.
Garbulewski, K.
Powiązania:
https://bibliotekanauki.pl/articles/779492.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
contaminated groundwater
permeable reactive barrier
nano zero-valent iron
reactivity
Opis:
In this paper, the ability of nZVI to remove heavy metals (Cd, Cu, Ni, Pb, Zn) from multicomponent aqueous solutions was investigated through batch experiments. The experimental data were fitted to a second-order kinetic model based on solid capacity. The data for copper and lead fitted well into the second-order kinetic model, thus suggesting that the adsorption had a physical character. The values of the removal ratio and the second-order rate constant indicated that the order of adsorption priority of nZVI was as follows: Pb>Cu>Zn>Cd>Ni. The adsorption isotherm data were described by the most conventional models (Henry, Freundlich, and Langmuir). Equilibrium tests showed that copper and zinc were removed from the solution by adsorption processes, i.e., complexation and competitive adsorption. The test results suggested that the removal processes using nZVI are more kinetic than equilibrium. The study demonstrated that nZVI is favorable reactive material; however, comprehensive investigation should be performed for further in situ applications in PRB technology.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 7-10
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Desalination of groundwater and impoundments using Nano-Zero Valent Iron, n-Fe°
Autorzy:
Antia, D.D.J.
Powiązania:
https://bibliotekanauki.pl/articles/108538.pdf
Data publikacji:
2015
Wydawca:
Instytut Meteorologii i Gospodarki Wodnej - Państwowy Instytut Badawczy
Tematy:
desalination
zero-valent iron
ZVI
diffusion
saline aquifers
saline impoundments
Opis:
Salinization of groundwater is a major problem, particularly in areas with limited infrastructure. 14 diffusion reactors are operated diabatically at -8°C to 20°C to determine the amount of NaCl removed by n-Fe°. The reactors establish NaCl removal by Fe°: (i) 44,000-77,000 nm particle size (PS) = 0.0675-0.1925 g L-1 [feed water (FW) = 0.89 g L-1]; (ii) 50 nm PS = 0.953-1.14 g L-1 [FW = 1.095-1.19 g L-1]; (iii) 50 nm PS under nitrogen saturation (0.1-0.2 MPa) = 9.693 g L-1 [FW = 10 g L-1]; (iv) <0.01 g 50 nm PS L-1 under nitrogen saturation (0.1-0.2 MPa) = 1.564 g L-1 [FW = 4 g L-1]; (v) 50 nm PS modified by nitrogen saturation (PSN) = 5.52 g L-1 [FW = 6.89 g L-1]. Desalination commences at a time, t, after the n-Fe° is added to the water, and continues with an exponential decline until a base (equilibrium) salinity is reached. The effectiveness of n-Fe° as a desalination agent appears to increase with increased water salinity. Placement of PSN in an existing impoundment, or aquifer, may provide a cost effective, zero energy, partial desalination solution, which can be used to support emergency relief, agriculture and extractive industries.
Źródło:
Meteorology Hydrology and Water Management. Research and Operational Applications; 2015, 3, 1; 21-38
2299-3835
2353-5652
Pojawia się w:
Meteorology Hydrology and Water Management. Research and Operational Applications
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zero-valent iron for removal of inorganic contaminants from low pH water
Autorzy:
Suponik, T.
Powiązania:
https://bibliotekanauki.pl/articles/206918.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chemicals removal (water treatment)
alkalinity
aquifers
coal mines
groundwater
groundwater pollution
groundwater resources
impurities
redox reactions
water pollution control
uzdatnianie wody
zasadowość
warstwy wodonośne
kopalnie węgla
wody gruntowe
zanieczyszczenie wód gruntowych
zasoby wód podziemnych
zanieczyszczenia wody
żelazo
reakcje redoks
zanieczyszczenia nieorganiczne
Opis:
The coal mine waste dumps located in the southern provinces of Poland pollute groundwater with metals. As a result of batch experiments presented in the paper, it can be said that it is possible to remove chromium and copper from the groundwater (which is affected by acid mine drainage, thus characterized by low pH) with the use of zero-valent iron in permeable reactive barrier technology. The contaminants are removed from the aquifer by the flow of groundwater through a reactive barrier filled with a special reactive material. Rapid metal removal likely occurred due to the reduction and the precipitation/co-precipitation and/or due to the adsorption onto the iron metal surface or/and onto the iron corrosion products. In accordance with the research it has also been found that in more alkaline environment, the oxidation of Fe(0) proceeds slower. A rapid decrease of the redox potential as well as the increases of pH have also been observed in the batch tests when the dose of Fe(0) in solutions increased.
Źródło:
Environment Protection Engineering; 2015, 41, 1; 15-27
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydraulic performance of zero-valent iron and nano-sized zero-valent iron permeable reactive barriers-laboratory test
Właściwości filtracyjne przepuszczalnych barier reaktywnych zbudowanych z żelaza zero-wartościowego i nano-żelaza zero-wartościowego-badania laboratoryjne
Autorzy:
Fronczyk, J.
Pawluk, K.
Powiązania:
https://bibliotekanauki.pl/articles/81719.pdf
Data publikacji:
2014
Wydawca:
Szkoła Główna Gospodarstwa Wiejskiego w Warszawie. Wydawnictwo Szkoły Głównej Gospodarstwa Wiejskiego w Warszawie
Opis:
The hydraulic conductivity of zero-valent iron treatment zone of permeable reactive barriers (PRBs) may be decreased by reducing the porosity caused by gas production and solids precipitation. The study was undertaken in order to evaluate the influence of chloride and heavy metals on the hydraulic conductivity of ZVI and nZVI using hydraulic conductivity tests as well as continuous column tests. Results show that the lead retention in the solution had no impact for hydraulic conductivity in ZVI sample, on the other hand the calculated hydraulic conductivity losses in nZVI sample (from 4.10·10–5 to 2.30·10–5 m·s–1) were observed. Results also indicate that liquids containing the mixture of heavy metals may cause signifi cant decrease in hydraulic conductivity (from 1.03·10–4 to 1.51·10–6 m·s–1). During the column tests, several number of clogging of the reactive material caused by iron hydroxides precipitation was observed over the course of injection of heavy metals solution. In contrast, the hydraulic conductivity of ZVI and nZVI is unaffected when they are permeated with chloride ions solution (k = 1.03·10–4 m·s–1). Finally, the results indicate the need to take account of changes in the hydraulic conductivity of reactive materials for successful implementation of PRBs technology.
Produkcja gazów oraz wytrącanie się nierozpuszczalnych cząstek stałych może być przyczyną zmian współczynnika filtracji przepuszczalnych barier reaktywnych PBR wykonanych z żelaza zero-wartościowego (ZVI). Zmiany te mogą być przyczyną nieprawidłowego przebiegu procesów oczyszczania środowiska gruntowo-wodnego. W artykule przedstawiono wyniki laboratoryjnych badań przepuszczalności hydraulicznej mających na celu sprawdzenie wpływu chlorków i metali ciężkich (Cd, Cu, Ni, Pb, Zn) na wartość współczynnika filtracji (k) wybranych materiałów reaktywnych – ZVI i nZVI. Analiza uzyskanych wyników badań wykazała brak wpływu chlorków oraz jonów ołowiu na współczynnik filtracji ZVI (k = 1,03·10–4 m·s–1). Obecność Pb(II) w roztworze spowodowała natomiast znaczące zmniejszenie wartości k nZVI z 4,10·10–5 do 2,30·10–5 m·s–1. Przepływ roztworu zawierającego mieszaninę metali ciężkich przez próbkę ZVI również spowodował zmniejszenie zdolności filtracyjnych materiału, co mogło być spowodowane intensywnie zachodzącymi procesami redukcji materiału. Współczynnik filtracji podczas trwania badania zmniejszył się z wartości 1,03·10–4 do 1,51·10–6 m·s–1. Podczas filtracji roztworu mieszaniny metali ciężkich przez kolumny wypełnione ZVI zaobserwowano kolmatację materiału spowodowaną wytracaniem się wodorotlenków żelaza i metali ciężkich, czemu towarzyszyło zwiększenie odczynu oraz zmniejszenie potencjału oksydacyjno-redukcyjnego roztworu wypływającego z kolumny. Zaprezentowane w artykule wyniki badań wskazują na konieczność uwzględnienia podczas projektowania PBR wpływu zanieczyszczeń na zmiany właściwości filtracyjnych materiałów reaktywnych.
Źródło:
Annals of Warsaw University of Life Sciences - SGGW. Land Reclamation; 2014, 46, 1
0208-5771
Pojawia się w:
Annals of Warsaw University of Life Sciences - SGGW. Land Reclamation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
3-aminopropyltriethoxysilane functionalized nanoscale zero-valent iron for the removal of dyes from aqueous solution
Autorzy:
Zhang, J.
Liu, Q.
Ding, Y.
Bei, Y.
Powiązania:
https://bibliotekanauki.pl/articles/779270.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
3-aminopropylotrietoksysilan
żelazo zerowartościowe
separacja magnetyczna
3-aminopropyltriethoxysilane
nano zero-valent iron
acid brilliant scarlet GR
reactive brilliant red K-2BP
magnetic separation
Opis:
Batch studies were conducted to investigate the potential of 3-aminopropyltriethoxysilane modified nano zero-valent iron (APS-NZVI) to adsorb two dyes (acid brilliant scarlet GR and reactive brilliant red K-2BP) from aqueous solution. APS-NZVI showed good adsorption performance for two dyes. Under the adsorption conditions of pH 4.5, initial concentration was 100 mg/L, and time=4h, the maximum adsorption capacities of APS-NZVI were 121.06 mg/g for acid brilliant scarlet GR and 191.5 mg/g for reactive brilliant red K-2BP, respectively. The results revealed that the adsorption behavior of the dyes on the nano-particles fitted well with the Langmuir model and the sorption kinetics fits well the pseudo-second-order rate equation.
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 2; 35-39
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Groundwater treatment with the use of zero-valent iron in the permeable reactive barrier technology
Autorzy:
Suponik, T.
Powiązania:
https://bibliotekanauki.pl/articles/110810.pdf
Data publikacji:
2013
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
remediation
dumping site
groundwater
PRB technology
metals
Opis:
The industrial dumping sites located in the southern provinces of Poland pollute groundwaters with metals. In the article, the possibility of groundwater (polluted by metals) treatment with the use of Permeable Reactive Barrier Technology has been presented. In this technology, the contaminants are removed from the aquifer by a flow of the groundwater through a PRB filled with a special reactive material. The wastewater (which simulated groundwater) circulated through the column filled with zero-valent iron in the laboratory tests. During the tests, the treatment processes proceeded. Chromium, copper, nick-el, cobalt, lead, cadmium and zinc, occurring in the water as cations and anions, have been removed in the iron bed. The rapid metal removal has likely occurred due to the reduction and precipitation/co-precipitation and/or due to adsorption onto the iron metal surface or/and onto the iron corrosion products. Barium Ba2+ was the only metal, which has not been removed from the wastewater in the column. A rapid decrease of the redox potential and oxygen concentration as well as an increases of the pH value and stabilizations have also been observed during the flow of water through the column. Due to the Fe/Fe2+ half reaction during the treatment processes, the iron concentration has increased as well.
Źródło:
Physicochemical Problems of Mineral Processing; 2013, 49, 1; 13-23
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Efficiency of Pb(II) and Mo(VI) removal by kaolinite impregnated with zero-valent iron particles
Autorzy:
Rybka, Karolina
Suwała, Katarzyna
Maziarz, Paulina
Matusik, Jakub
Powiązania:
https://bibliotekanauki.pl/articles/127609.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Mineralogiczne
Tematy:
zero-valent iron particles
kaolinite
adsorption
Pb(II)
Mo(VI)
Opis:
In this work, kaolinite modified with zero-valent iron was synthesized and used as a sorbent for Pb(II) and Mo(VI) removal from aqueous solutions. The obtained material was characterized by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The methods revealed successful modification by the Fe0 particles precipitation on the surface of well-ordered kaolinite. The sorption experiment results showed a significant increase of sorption capacity in relation to the raw kaolinite. The kaolinite with 25% content of Fe0 was found to be the best material for Pb(II) and Mo(VI) removal, resulting in approximately 500 mmol•kg-1 and 350 mmol•kg-1 sorption, respectively. The possible mechanisms responsible for metals’ removal were identified as reduction by Fe0 ‘core’ and adsorption on the iron hydroxides ‘shell’. The study indicated that the obtained material is capable of efficient Pb(II) and Mo(VI) removal and may be an interesting alternative to other methods used for heavy metals’ removal.
Źródło:
Mineralogia; 2017, 48, 1/4; 71-86
1899-8291
1899-8526
Pojawia się w:
Mineralogia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comments on “3-aminopropyltriethoxysilane functionalized nanoscale zero-valent iron for the removal of dyes from aqueous solution”
Autorzy:
Ho, Y. S.
Powiązania:
https://bibliotekanauki.pl/articles/779896.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 4; 89-89
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of nanoscale zero-valent iron doped carbonized zeolitic imidazolate framework-8 for methylene blue removal in water
Autorzy:
Chen, Shuai
Qiao, Lemeng
Feng, Xuejiao
Huang, Yufu
Gao, Guilan
Guan, Jie
Lin, Donghai
Powiązania:
https://bibliotekanauki.pl/articles/2204144.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Nanoscale zero-valent iron
Carbonized zeolitic imidazolate framework-8
Mesoporous carbon
Methylene blue
Opis:
Nanoscale zero-valent iron-doped carbonized zeolitic imidazolate framework-8 (nZVI/CZIF-8) was prepared by carbonation of ferric nitrate and ZIF-8 at 800 °C and used as an adsorbent to remove methylene blue (MB) from water. The synthesized nZVI/CZIF-8 has a specific surface area of 806.9 m2/g, a pore volume of 0.86 cm3/g and an nZVI content of 1.35%, respectively. Both the nZVI/CZIF-8 and CZIF-8 have identical functional groups of O-H, C-H and C=C. With the increase of CZIF-8 size, MB removal rate increased. The doping of nZVI increased the MB removal percentage from 74.5% for ZIF-8 to 96.2% within 80 min for nZVI/CZIF-8. The MB removal percentage increased with the dosage of nZVI/CZIF-8. The MB adsorption with the adsorbents conforms to the Freundlich adsorption isothermal model and the removal rate fitted well to a pseudo-first-order model. The results demonstrate the feasibility of synthesizing high active and stable nZVI/CZIF-8 particles.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 1; 12--19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of zero-valent iron and enzymes on the anaerobic co-digestion of sewage sludge and corn silage
Autorzy:
Zhou, Haidong
Cao, Zhengcao
Ying, Zhenxi
Liu, Jicheng
Hu, Tao
Zhang, Mingquan
Zhang, Jingyuan
Powiązania:
https://bibliotekanauki.pl/articles/2032872.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
corn silage
COD
sewage sludge
anaerobic digestion
kiszonka z kukurydzy
ChZT
osad ściekowy
beztlenowa fermentacja
Opis:
Anaerobic co-digestion of sewage sludge and corn silage with zero-valent iron powder (Fe0), cellulase, and papain as reinforcement means was conducted. COD-based feeding ratio of sewage sludge to corn silage was set to 2:1, the solids retention time (SRT) 20 day, digestion temperature 35 °C, and mixing speed 60 rpm. Removal rates of total COD during the control group, and Fe0, papain, cellulase, and papain, Fe0, and the two kinds of enzyme-added tests were 38.04, 41.02, 34.62, 34.55, 35.42, and 48.21%, respectively. The corresponding biogas production was 2.12, 2.62, 2.22, 2.41, 2.25, and 2.81 dm3/day, respectively. The results indicated the addition of cellulase, and papain could maximize the decomposition and hydrolysis of organic matter in sewage sludge and corn silage to volatile fatty acids. Fe0 could reduce the redox potentials of the anaerobic co-digestion, optimize the circumstances of the methanogenesis stage, accelerate biogas production, and improve biogas components. Fe0 and enzymes played a synergistic role in the anaerobic co-digestion system. Life cycle assessment indicated that the anaerobic co-digestion of sludge and corn silage co-substrates could benefit the economy, environment, and social development under the synergistic action of Fe0 and enzymes.
Źródło:
Environment Protection Engineering; 2020, 46, 4; 41-56
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-10 z 26

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