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Wyświetlanie 1-50 z 162
Tytuł:
Selected small molecules as inducers of pluripotency
Autorzy:
Baranek, Małgorzata
Markiewicz, Wojciech
Barciszewski, Jan
Powiązania:
https://bibliotekanauki.pl/articles/1038727.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
reprogramming
pluripotency
small molecules
iPSCs
Opis:
The general idea of regenerative medicine is to fix or replace tissues or organs with live and patient-specific implants. Pluripotent stem cells are capable of indefinite self-renewal and differentiation into all cell types of the body. An easily accessible source of induced pluripotent stem cells (iPSCs) may allow obtaining and culturing tissues in vitro. Many approaches in the methods leading to obtain iPSCs have been tested in order to limit immunogenicity and tumorigenesis, and to increase efficiency. One of the approaches causing pluripotency is usage of small molecule compounds. It would be of great importance to assess their specific properties and reveal their new capacity to induce pluripotent stem cells and to improve reprogramming efficiency. Identification of the epigenetic changes during cellular reprogramming will extend our understanding of stem cell biology and many therapeutic applications. In this paper we discuss mainly the nucleotide derivatives, already proven or for now only putative inducers of the cells' pluripotency, that modulate the epigenetic status of the cell.
Źródło:
Acta Biochimica Polonica; 2016, 63, 4; 709-716
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Distribution of gas molecules by their temperatures
Autorzy:
Golovkin, Boris Georgievich
Powiązania:
https://bibliotekanauki.pl/articles/1030475.pdf
Data publikacji:
2020
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Clapeyron equation
Maxwell distribution
distribution of molecules by temperatures
gas density
gas pressure
Opis:
A formula is derived for the distribution of gas molecules over their temperatures depending on the total temperature of the gas. Formulas are proposed for the distribution of velocities and kinetic energies of gas molecules depending on the pressure and density of the gas. It is shown that these formulas are equivalent to the formulas of the corresponding Maxwell distributions, which depend only on temperature. A formula is derived for the distribution of the mean free paths of gas molecules depending only on the gas density. An example of calculating the distribution of gas molecules by their temperatures is given.
Źródło:
World Scientific News; 2020, 144; 89-102
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Calcium phosphate nanoparticles for delivering synthetic drug molecules across the cell membrane
Autorzy:
Rotan, O.
Sokolova, V.
Schrader, T.
Epple, M.
Powiązania:
https://bibliotekanauki.pl/articles/285174.pdf
Data publikacji:
2014
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
nanoparticles
cell membranes
drug molecules
Źródło:
Engineering of Biomaterials; 2014, 17, no. 128-129; 77-78
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cell adhesion molecules and their possible role in the pathology of the peripheral nerves – a review of the literature
Autorzy:
Niezgoda, Adam
Powiązania:
https://bibliotekanauki.pl/articles/552657.pdf
Data publikacji:
2015
Wydawca:
Stowarzyszenie Przyjaciół Medycyny Rodzinnej i Lekarzy Rodzinnych
Tematy:
cell adhesion molecules
demyelination
polyneuropathies.
Źródło:
Family Medicine & Primary Care Review; 2015, 4; 323-326
1734-3402
Pojawia się w:
Family Medicine & Primary Care Review
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Distribution of the lengths of tree paths of gas molecules
Autorzy:
Golovkin, B. G.
Powiązania:
https://bibliotekanauki.pl/articles/1075713.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
distribution of molecules
gas
mean free path
pressure
radius of the molecule
temperature
Opis:
It is shown that the formula available in the literature for the distribution of the mean free paths of gas molecules, independent of pressure and temperature, produces obviously incorrect results. Accordingly, a conclusion is given for another formula for a given distribution, which depends on the size of the gas molecules, as well as temperature and pressure. In accordance with this formula, the distribution curve for oxygen at 1000 K and pressures 1 and 0.001 atm has been calculated.
Źródło:
World Scientific News; 2019, 119; 243-247
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analitical criteria of homogeneous and heterogeneous detonation of liquid energetic materials
Autorzy:
Kaim, S.
Powiązania:
https://bibliotekanauki.pl/articles/92588.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
mechanism detonation initiation
hot spots
nanopores
emission atoms and molecules
shock dissociation molecules
Opis:
Statistical theory of liquids is used to investigate mechanism of detonation initiation on fronts of flat shock waves in homogeneous liquid and in liquid containing spherical nanopores. We calculated thermodynamic parameters of liquid methane sufficient for shock dissociation of molecules at a front of a shock wave. Calculations of the average single-particle force potential show that at high pressures and temperatures atoms and molecules get emitted from the surface into a nanopore with hyper-thermal speeds. Implosion of spherically symmetric stream of molecules may lead to destruction of the molecules at impact. We explained existence of top and bottom bounds for pressure during detonation initiation in heterogeneous energetic materials. In terms of pair interaction potentials and correlation functions there are formulated criteria for boundary values of thermodynamic parameters which are required for initiation of homogeneous and heterogeneous detonations based on the "hot spot"’ mechanism.
Źródło:
Materiały Wysokoenergetyczne; 2013, T. 5; 5-13
2083-0165
Pojawia się w:
Materiały Wysokoenergetyczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication Of Colloidal Clusters Decorated With Dye Molecules For Potential Application As Photonic Molecules
Wytwarzanie koloidalnych klasterów zdobionych cząsteczkami barwnika do potencjalnego zastosowania jako cząsteczki fotoniczne
Autorzy:
Cho, Y. S.
Powiązania:
https://bibliotekanauki.pl/articles/356171.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
colloidal clusters
fluorescent dyes
photonic molecules
particle self-assembly
klaster koloidalny
barwniki fluorescencyjne
cząsteczki fotoniczne
Opis:
In this study, colloidal clusters decorated with fluorescent dyes were fabricated by evaporation-driven self-assembly using emulsion droplets as confining geometries. Silica microspheres were synthesized by Stober method followed by the modification with dye molecules through additional surface sol-gel reaction for the formation of thin silica shell. The surface of the resultant dye-doped silica microspheres was modified with hydrophobic silane coupling agent to disperse the particle suspension in organic solvent such as hexane. The fluorescent silica microspheres were self-assembled inside oil-in-water emulsions by evaporation-driven self-assembly for the formation of colloidal clusters, potentially applicable for photonic molecules. The clusters with fluorescent emission were observed using confocal microscope.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1221-1225
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
First-principles study on the adsorption structure of water molecules on a pyrite (100) surface
Autorzy:
Liu, Yingchao
Chen, Jianhua
Li, Yuqiong
Zhang, Junjie
Kang, Duan
Powiązania:
https://bibliotekanauki.pl/articles/1447970.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
pyrite
water molecules
adsorption
Opis:
The hydration structure of water molecule adsorption at different coverages of a monolayer on a pyrite (100) surface were simulated using the density functional theory (DFT) method. The results demonstrate that the Fe-O interaction weakens and the adsorption energy per water molecule decreases with increasing water coverage, except at a monolayer coverage of 12/12 (i.e., full coverage). H-S and H-O hydrogen bonds were formed on the nearest surface layer. When large amounts of water molecules adsorb onto the surface, the adsorbed water molecules can be divided into three layers: the layer nearest to the surface, the second nearest to the surface, and the layer farthest from the surface. The thickness of the former two layers is approximately 5.5 Å. The three layers have water densities of 1.12 g/cm3, 1.08 g/cm3, and 0.95 g/cm3, respectively, suggesting that there is a strong interaction between the pyrite surface and water molecules and the influence of surface structure on water adsorption reaches a distance of more than 10 Å. Dynamics simulations suggest that the water molecules close to the mineral surfaces are in an orderly arrangement while those far from the surface are disordered.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 2; 121-130
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dendrimers: properties and applications.
Autorzy:
Klajnert, Barbara
Bryszewska, Maria
Powiązania:
https://bibliotekanauki.pl/articles/1044187.pdf
Data publikacji:
2001
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
cascade molecules
dendrimers
PAMAM dendrimers
Opis:
Dendrimers are a new class of polymeric materials. They are highly branched, monodisperse macromolecules. The structure of these materials has a great impact on their physical and chemical properties. As a result of their unique behaviour dendrimers are suitable for a wide range of biomedical and industrial applications. The paper gives a concise review of dendrimers' physico-chemical properties and their possible use in various areas of research, technology and treatment.
Źródło:
Acta Biochimica Polonica; 2001, 48, 1; 199-208
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Signaling molecules from Lactuca sativa L. induced quorum sensing phenotypes in bacteria
Autorzy:
Mahmoudi, E.
Powiązania:
https://bibliotekanauki.pl/articles/66200.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
The outcome of the present investigation revealed that lettuce (Lactuca sativa L.) extract strongly interferes with acyl homoserine lactone (AHL) regulated physiological functions in the bioreporter strain, Chromobacterium violaceum CV026. Extracts of L. sativa also promoted production of virulence factors in plant pathogen, Pectobacterium carotovorum, and significantly increased tissue maceration on potato tubers when there was a low concentration (103 cfu · ml–1) of the bacterium was used. The thin layer chromatogram which visualised with AHL bioreporter strain, CV026, showed that L. sativa extract produced a circular spot with a diffuse edge tail and migrated with the same mobility as standard N-hexanoyl-L-homoserine lactone (C6-HSL). Gas Chromatography Mass Spectroscopy (GC-MS) analysis of the lettuce extract resulted in the identification of 19 compounds of which homoserine was identified for the first time in plants. Homoserine accounted for 2.37% of the total constituents. It is a new finding that lettuce contains AHL like substances (homoserine) which excite AHL related quorum sensing (QS) in bacteria.
Źródło:
Journal of Plant Protection Research; 2015, 55, 2
1427-4345
Pojawia się w:
Journal of Plant Protection Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of Dynamic Dichroism Properties of Disperse Orange 11 Molecules and Azo-Molecules Doped in Poly(Methyl Methacrylate) Thin Films: A Comparison
Autorzy:
Abbas, B.
Alshikh Khalil, M.
Powiązania:
https://bibliotekanauki.pl/articles/1537688.pdf
Data publikacji:
2010-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.55.+b
78.20.e
78.66.Qn
Opis:
We investigate the dichroism characteristics of poly (methyl methacrylate) PMMA thin films doped with DO11, DO3, DSR13 and DSR1 dye molecules, which change under illumination with visible light. Our data show that photoisomerisation, phototautomerization reactions and light-induced polar orientation are dependent on the molecular structure of the polymer. Polar structure and molecular size, as well as the chemical structure of PMMA host, are the dominant parameters that determine both the extent and speed of dichroism buildup and relaxation processes. Two forms of DO11 molecules (keto and enol forms), and two other forms of azo-based dyes ( trans and cis forms) are responsible for the interaction with irradiating laser light and forming an anisotropic structure inside the PMMA/dye thin films.
Źródło:
Acta Physica Polonica A; 2010, 117, 6; 904-910
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oddziaływanie elektronów z cząsteczkami o biologicznym znaczeniu
Interaction of electrons with biologically relevant molecules
Autorzy:
Kopyra, J.
Powiązania:
https://bibliotekanauki.pl/articles/171628.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Chemiczne
Tematy:
dysocjacyjny wychwyt elektronów
spektrometria mas
jony ujemne
cząsteczki o biologicznym znaczeniu
dissociative electron attachment
mass spectrometry
negative ions
biologically relevant molecules
Opis:
Recent years have witnessed an increase of the interest in the studies of the interaction of electrons with biologically relevant molecules. This has been mainly motivated by the seminal work, where it has been demonstrated that low energy electrons can induce single and double strand breaks in DNA in the energy range below the level of ionization. Since the damage profile as a function of electron energy showed pronounced resonances it was proposed that resonant electron capture could occur at particular molecular components of the DNA as the initial step towards strand breaks. From a series of experiments on electron attachment to DNA building blocks (nucleobases, the sugar moiety and the phosphate unit) became obvious that they effectively capture electrons leading to the formation of low energy resonances associated with the decomposition of the corresponding molecule. Recent dissociative electron attachment experiments on an entire gas phase nucleotide 2’-deoxycytidine-5´-monophosphate give also insight into the molecular mechanism involved, which comprises both direct electron attachment to the backbone and transfer of the excess electron from cytosine to the backbone resulting in single strand breaks. The results further allow an estimate of the relative contribution of these different mechanisms to single strand breaks.
Źródło:
Wiadomości Chemiczne; 2015, 69, 9-10; 893-907
0043-5104
2300-0295
Pojawia się w:
Wiadomości Chemiczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A Mathematical Model of Membrane Gas Separation with Energy Transfer by Molecules of Gas Flowing in a Channel to Molecules Penetrating this Channel from the Adjacent Channel
Autorzy:
Szwast, M.
Szwast, Z.
Powiązania:
https://bibliotekanauki.pl/articles/185043.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
membrane
membrane module
reciprocal transfer of energy between gas molecules
changes of the pressure of gas along the length of flow channel
membrana
wzajemne przekazywanie energii między cząsteczkami gazu
zmiany ciśnienia gazu na długości kanału przepływowego
Opis:
The paper presents the mathematical modelling of selected isothermal separation processes of gaseous mixtures, taking place in plants using membranes, in particular nonporous polymer membranes. The modelling concerns membrane modules consisting of two channels – the feeding and the permeate channels. Different shapes of the channels cross-section were taken into account. Consideration was given to co-current and counter-current flows, for feeding and permeate streams, respectively, flowing together with the inert gas receiving permeate. In the proposed mathematical model it was considered that pressure of gas changes along the length of flow channels was the result of both – the drop of pressure connected with flow resistance, and energy transfer by molecules of gas flowing in a given channel to molecules which penetrate this channel from the adjacent channel. The literature on membrane technology takes into account only the drop of pressure connected with flow resistance. Consideration given to energy transfer by molecules of gas flowing in a given channel to molecules which penetrate this channel from the adjacent channel constitute the essential novelty in the current study. The paper also presents results of calculationsobtained by means of a computer program which used equations of the derived model. Physicochemical data concerning separation of the CO2/CH4 mixture with He as the sweep gas and data concerning properties of the membrane made of PDMS were assumed for calculations.
Źródło:
Chemical and Process Engineering; 2015, 36, 2; 151-169
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Free electrons: fundamental interactions, applications and data needs
Autorzy:
Christophorou, L.
Powiązania:
https://bibliotekanauki.pl/articles/148509.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
applications
data
interactions
low-energy electrons
molecules
Opis:
In spite of the important recent advances in the field of low-energy electron interactions with atoms and molecules, there still exist fundamental needs and challenges, some of which are generic in their basic and applied significance. These include measurements of cross sections for a number of fundamental low-energy electron–ground-state molecule interaction processes such as vibrational excitation (direct and indirect) and dissociation into neutral fragments, studies of low-energy electron–excited molecule interactions, investigations of low-energy electron interactions with radicals and transient species, and measurements of electron energy losses in electron–molecule collision processes. They also include studies for linking of knowledge on isolated electron–molecule interactions to that in the condensed phases of matter, and the systematic and quantitative exploration of the interactions of low-energy electrons with molecular and macromolecular biological structures.
Źródło:
Nukleonika; 2003, 48, 2; 67-74
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
On molecules and fractional integrals on spaces of homogeneous type with finite measure
Autorzy:
Eduardo Gatto, A.
Vági, Stephen
Powiązania:
https://bibliotekanauki.pl/articles/1293114.pdf
Data publikacji:
1992
Wydawca:
Polska Akademia Nauk. Instytut Matematyczny PAN
Opis:
In this paper we prove the continuity of fractional integrals acting on nonhomogeneous function spaces defined on spaces of homogeneous type with finite measure. A definition of the molecules which are used in the $H^p$ theory is given. Results are proved for $L^p$, $H^p$, BMO, and Lipschitz spaces.
Źródło:
Studia Mathematica; 1992, 103, 1; 25-39
0039-3223
Pojawia się w:
Studia Mathematica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phonon-Assisted Excitation Transfer in Quantum Dot Molecules
Autorzy:
Rozbicki, E.
Machnikowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/2047376.pdf
Data publikacji:
2007-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
63.20.Kr
73.63.Kv
Opis:
We derive a quantum-kinetic description of phonon-assisted Förster transfer between two coupled quantum dots (a quantum dot molecule). We show that the exciton state decays to the ground state of the quantum dot molecule via a combination of the Rabi rotation and exponential decay. For moderately spaced dots this process takes place on a picosecond timescale.
Źródło:
Acta Physica Polonica A; 2007, 112, 2; 197-202
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cell Adhesion Molecules in Terms of Carcinogenesis
Autorzy:
Opiłka, Mieszko Norbert
Lorenc, Zbigniew
Starzewska, Małgorzata
Lorenc, Justyna
Rajs, Antoni
Powiązania:
https://bibliotekanauki.pl/articles/1395725.pdf
Data publikacji:
2014-03-01
Wydawca:
Index Copernicus International
Źródło:
Polish Journal of Surgery; 2014, 86, 3; 151-157
0032-373X
2299-2847
Pojawia się w:
Polish Journal of Surgery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Centrifugal Distortion Effect in Diatomic Molecules Described by Morse Potential
Autorzy:
Molski, M.
Powiązania:
https://bibliotekanauki.pl/articles/1929146.pdf
Data publikacji:
1993-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.10.Cs
33.10.Jz
Opis:
An attempt at including the centrifugal distortion effect in description of the rovibrational states of diatomic systems with a molecular potential approximated by the Morse function is presented. The derived Schrödinger equation can be rigorously solved leading to the eigenvalues in the form of a continued fraction, which are applied for evaluation of the molecular constants and for prediction of the rovibrational spectra of the selected diatomic molecules giving quite satisfactory reproduction of the experimental data. A simple extension of the method developed, by assuming the rotational dependence of the dissociation constant, is also proposed.
Źródło:
Acta Physica Polonica A; 1993, 83, 4; 417-423
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Four-Wave Mixing Spectroscopy of Quantum Dot Molecules
Autorzy:
Sitek, A.
Machnikowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/2047371.pdf
Data publikacji:
2007-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.67.Hc
78.47.+p
Opis:
We study theoretically the nonlinear four-wave mixing response of an ensemble of coupled pairs of quantum dots (quantum dot molecules). We discuss the shape of the echo signal depending on the parameters of the ensemble: the statistics of transition energies and the degree of size correlations between the dots forming the molecules.
Źródło:
Acta Physica Polonica A; 2007, 112, 2; 167-172
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flexible magnetic coordination networks sensitive to guest molecules
Autorzy:
Heczko, M.
Nowicka, B.
Powiązania:
https://bibliotekanauki.pl/articles/134881.pdf
Data publikacji:
2015
Wydawca:
Tomasz Mariusz Majka
Tematy:
coordination polymer
molecular magnets
polycyanometallates
advanced materials
Opis:
Structurally flexible coordination networks that react to different external stimuli with structure deformation, and consequently changes in magnetic properties, are potential candidates for molecular switches and sensors. The design of guest-sensitive molecular magnetic materials based on the specific building blocks: [Ni(cyclam)]2+ (cyclam = 1,4,8,11-tetraazacyclotetradecane) cation and polycyanometallate anions is discussed. The examples of different dimensionality networks and the changes in their structure and magnetic properties in response to sorption of small molecules are presented.
Źródło:
Journal of Education and Technical Sciences; 2015, 2, 1; 19-21
2300-7419
2392-036X
Pojawia się w:
Journal of Education and Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Proteolysis as the compactness index of wheat molecules
Proteoliza jako wskaźnik zwartości cząsteczki glutenu pszenicy
Autorzy:
Liss, W.
Kaczkowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/10247.pdf
Data publikacji:
1975
Wydawca:
Instytut Rozrodu Zwierząt i Badań Żywności Polskiej Akademii Nauk w Olsztynie
Opis:
Wykazano, że szybkość trawienia dyspersji białek w kwasie octowym prób mąki pszennej o różnej wartości technologicznej jest tym większa, im gorszej jakości próba. Przeprowadzono badania szybkości trawienia wyciągu wyjściowego gluteniny i gliadyny z udziałem nieoczyszczonych i częściowo oczyszczonych proteinaz rodzimych pszenicy oraz preparatu bromelainy. W doświadczeniach tych wykazano, że hydroliza białek rozpuszczalnych w kwasie octowym i gliadyny pod działaniem bromelainy przebiegała z szybkością niezależną od jakości próby, a jedynie glutenina wykazała zróżnicowanie, ale nie w pełni zależne od tej cechy. Bardziej specyficzne proteinazy rodzime wykazały bardziej ścisłą odwrotną zależność szybkości hydrolizy gluteniny od jakości próby, co wskazywało na zróżnicowaną dostępność wiązań peptydowych w tych białkach. Podobnie jak przy trawieniu bromelainą wyciąg wyjściowy nie wykazał różnic w szybkości hydrolizy, a w przypadku proteinaz rodzimych, oczyszczonych również, gliadyna wykazała dostępność wiązań peptydowych, zależną od jakości próby, ale w sposób odwrotny niż glutenina. Sugeruje się, że związana z dostępnością wiązań peptydowych zwartość cząsteczek, zwłaszcza gluteniny, może mieć wpływ na cechy reologiczne glutenu i ciasta, a tym samym na jakość mąki. Istnieje możliwość opracowania na podstawie tej cechy opracowania metody określania wartości wypiekowej pszenicy.
Źródło:
Acta Alimentaria Polonica; 1975, 01, 3-4
0137-1495
Pojawia się w:
Acta Alimentaria Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular basis of quorum sensing signal-response systems in bacteria
Autorzy:
Ziemichód, Alicja
Skotarczak, Bogumiła
Powiązania:
https://bibliotekanauki.pl/articles/1386055.pdf
Data publikacji:
2017
Wydawca:
Uniwersytet Szczeciński. Wydawnictwo Naukowe Uniwersytetu Szczecińskiego
Tematy:
autoinducers 2 and 3
QS phenomenon
quinolone signal molecules
signal molecules of Grampositive and Gram-negative bacteria
autoinduktory 2 i 3
chinolonowe cząsteczki sygnałowe
cząsteczki sygnałowe bakterii Gramdodatnich i Gram-ujemnych
zjawisko QS
Opis:
Bacteria use quorum sensing (QS) to conduct gene expression programmes connected with collective behaviors. QS indicates on the capacity of bacteria to monitor their population density and regulate gene expression. QS activates from tens to hundreds of genes that underlie different biological processes. The QS-regulated processes organize horizontal gene transfer, the formation of biofilms, multicellular behaviors, microbe–host and microbe–microbe relations. The QS signaling requires the production, release, detection, exchange and perception of bacterial compounds, known as autoinducers or QS signals. Recently, new autoinducers have been discovered in bacteria and it has been shown how these molecules are recognized by the respective receptors. Autoinducers belong to three major classes: acyl-homoserine lactones (AHLs) used by Gram-negative bacteria, specific oligopeptides used by Gram-positive bacteria and universal autoinducers. The aim of this paper is to provide an overview of molecular basis of the QS phenomenon, characterization of intra- and interspecies QS signaling molecules and biological processes regulated by these molecules.
Bakterie używają quorum sensing (QS) do przeprowadzania programów ekspresji genów związanych z zachowaniami grupowymi. QS oznacza zdolność bakterii do monitorowania gęstości swojej populacji i regulacji ekspresji genów. QS aktywuje od dziesiątek do setek genów, które są związane z różnymi procesami biologicznymi. Procesy regulowane przez QS są związane z horyzontalnym przepływem genów, tworzeniem biofilmów, zachowań wielokomórkowych, oraz relacji bakteria–żywiciel i bakteria–bakteria. Sygnalizacja QS wymaga wytwarzania, uwalniania, wykrywania, wymiany i percepcji komponentów nazywanych autoinduktorami lub sygnałami QS. Ostatnio u bakterii zostały odkryte nowe autoinduktory oraz wykazano jak te cząsteczki są rozpoznawane przez odpowiednie receptory. Autoinduktory należą do trzech głównych klas: do acylowanych laktonów homoseryny (AHLs) używanych przez bakterie Gram-ujemne, specyficznych oligopeptydów używanych przez bakterie Gram dodatnie i do autoinduktorów uniwersalnych. Celem artykułu jest przegląd bazy molekularnej zjawiska QS, w tym wewnątrz i międzygatunkowych cząsteczek sygnałowych QS oraz procesów biologicznych regulowanych przez te cząsteczki
Źródło:
Acta Biologica; 2017, 24; 133-140
2450-8330
2353-3013
Pojawia się w:
Acta Biologica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The dynamics of biochemical markers of enzymoemia and middle-weight molecules in the early post-traumatic period of brain injury
Autorzy:
Ziablitsev, S. V.
Elskyy, V. N.
Pischulina, S. V.
Strelchenko, U. I.
Antonov, E. V.
Sudilovskaya, U. L.
Khudoley, S. A.
Powiązania:
https://bibliotekanauki.pl/articles/1032378.pdf
Data publikacji:
2014
Wydawca:
Uniwersytet Kazimierza Wielkiego w Bydgoszczy
Tematy:
brain injury
biochemical markers
enzymoemia
middle-weight molecules
Opis:
In the experimental model of brain injury (BI) markers of enzymoemia (aminotransferases ALT and AST, alkaline and acid phosphatase (AlP and AcP), cathepsin D (CD)) and middle-weight molecules (MWM) were estimated. 3 hours after trauma there were increase of all enzymes that evidences about damage of cytoplasmic (ALT, AST, AlF) and lysosomal membranes (AcP, CD). During period of observation different dynamics of enzymatic changes occurred: plateau phase for ALT and CD and progressive increase of concentration with the maximum on the 5th day of the experiment for AlP and AcP. Increase of the level of MWM displayed the development of endogenous intoxication in the post-traumatic period. Relation between particular components of MWM was studied. It was shown that primary accumulation of nucleotide fraction and aromatic peptides is adverse factor of the course of post-traumatic period, development of endotoxicosis, and multiorgan failure.
Źródło:
Journal of Health Sciences; 2014, 4, 1; 297-302
1429-9623
Pojawia się w:
Journal of Health Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theory of the Dielectric Susceptibility of Liquid Crystals with Bent-Core Molecules
Autorzy:
Kapanowski, A.
Powiązania:
https://bibliotekanauki.pl/articles/1493613.pdf
Data publikacji:
2011-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.30.Cz
77.84.Nh
Opis:
Statistical theory of the dielectric susceptibility of polar liquid crystals is proposed. The molecules are calamitic or bent-core but the permanent dipole moment is perpendicular to the molecule long axis. The ordering of the phase is described by means of the mean-field theory based on the Maier-Saupe approach. The theory is used to calculate the temperature dependence of the order parameters and the susceptibilities. The phase diagram with four phases is obtained: isotropic, uniaxial nematic, uniaxial ferroelectric, and biaxial ferroelectric. Four critical points are predicted.
Źródło:
Acta Physica Polonica A; 2011, 120, 3; 473-479
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rozciąganie molekuł białek — porównywanie ich własności mechanicznych
Stretching of molecules of proteins — comparison of their mechanical properties
Autorzy:
Cieplak, Marek
Sułkowska, Joanna
Powiązania:
https://bibliotekanauki.pl/articles/1198454.pdf
Data publikacji:
2006
Wydawca:
Polskie Towarzystwo Przyrodników im. Kopernika
Opis:
Mechanical stretching of single proteins has been studied experimentally for about 55 proteins yielding a variety of force patterns and peak forces. Here, we perform a theoretical survey of proteins of known native structure and map out the landscape of possible dynamical behaviors under stretching at a constant speed. We consider 7510 proteins each comprising not more than 150 amino acids. The model used is constructed based on the native geometry. It is solved by methods of molecular dynamics and validated by comparing the theoretical predictions to experimental results. We characterize the distribution of peak forces and correlations with the system size and with the structure classification as characterized by the hierarchical classification of protein domain structures (CATH). Despite the presence of such correlations, proteins with the same CATH index may belong to different classes of the dynamical behavior. We identify proteins with the biggest forces and show that they belong to few topology classes. We determine which protein segments act as mechanical clamps and show that, in most cases, they correspond to long stretches of parallel β-strands, but other mechanisms are also possible.
Źródło:
Kosmos; 2006, 55, 4; 321-330
0023-4249
Pojawia się w:
Kosmos
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectral Expansion of the Rovibrational Energy of Diatomic Molecules Described by Morse Potential
Autorzy:
Molski, M.
Powiązania:
https://bibliotekanauki.pl/articles/1929815.pdf
Data publikacji:
1993-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.10.Cs
33.10.Jz
Opis:
On the basis of the deformable body model and the Morse potential approximation a six-parametric spectral expansion of the rovibrational energy of diatomic molecules, competitive to the standard Dunham approach, is proposed. The considered formula takes into account the centrifugal distortion effect and anharmonic corrections, which permit investigation of the molecular spectra over a wide range of rotational and vibrational states.
Źródło:
Acta Physica Polonica A; 1993, 84, 6; 1041-1048
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modified Kratzer-Fues Formula for Rotation-Vibration Energy of Diatomic Molecules
Autorzy:
Molski, M.
Konarski, J.
Powiązania:
https://bibliotekanauki.pl/articles/1924270.pdf
Data publikacji:
1992-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.10.Cs
33.10.Jz
Opis:
An extension of the Kratzer-Fues approach to analytical calculation of the rotation-vibration energy of diatomic molecules is proposed. The eigen-values from this approach are applied in calculation of the rotational and rovibrational energies and in evaluation of molecular constants of selected diatomic molecules, resulting in satisfactory reproduction of experimental frequencies over a wide range of rotational states. In contrast to our previous proposition the rotational dependence of vibration energy is taken into account. An additional set of fitted parameters which include equilibrium distance and dissociation constant was also employed.
Źródło:
Acta Physica Polonica A; 1992, 82, 6; 927-936
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sonochemical synthesis of drug molecules nanoparticles: towards controlled drug release
Autorzy:
Chytrosz, P.
Golda-Cepa, M.
Kotarba, A.
Powiązania:
https://bibliotekanauki.pl/articles/286014.pdf
Data publikacji:
2018
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
nanoparticles
drugs
sonochemical synthesis
Źródło:
Engineering of Biomaterials; 2018, 21, 148; 69
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Expansion of the Rotational Energy of Diatomic Molecules into a Continued Fraction
Autorzy:
Molski, M.
Konarski, J.
Powiązania:
https://bibliotekanauki.pl/articles/1920626.pdf
Data publikacji:
1992-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.10.Cs
33.10.Jz
Opis:
A new expansion of the rotational energy of diatomic molecules, in the form of a continued fraction has been investigated. The considered formula is applied in calculation of molecular constants and reproduction of rotational spectra of rigid-, semirigid- and van der Waals-type molecules. A physical interpretation of semiempirical expansion parameters is proposed and a connection between the method considered and the Dunham approach is also discussed.
Źródło:
Acta Physica Polonica A; 1992, 81, 4-5; 495-501
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modification of the Spontaneous Emission of Dye Molecules in Photonic Crystals
Autorzy:
Petrov, E.
Bogomolov, V.
Kalosha, I.
Gaponenko, S.
Powiązania:
https://bibliotekanauki.pl/articles/1992744.pdf
Data publikacji:
1998-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
42.50.-p
Opis:
Modification of the spontaneous emission of dye molecules embedded in artificial opals exhibiting stop bands in the visible range is observed. Molecules embedded in artificial opals show dips in spontaneous emission spectra and modified fluorescence decay kinetics. Results are interpreted in terms of redistribution of the photon density of states. Effects of the multiple reabsorption and reemission of fluorescence photons and interaction of dye molecules with the silica surface are discussed.
Źródło:
Acta Physica Polonica A; 1998, 94, 5-6; 761-771
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Theory of the Dielectric Susceptibility of Liquid Crystals with Polar Nonuniaxial Molecules
Autorzy:
Kapanowski, A.
Wietecha, T.
Powiązania:
https://bibliotekanauki.pl/articles/2038179.pdf
Data publikacji:
2004-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.30.Cz
77.84.Nh
Opis:
Statistical theory of the dielectric susceptibility of polar liquid crystals is proposed. The molecules are not uniaxial but similar to cones. It is assumed that the permanent dipole moment of a molecule is parallel to the axis of the rotational symmetry. The ordering of the phase is described by means of the mean field theory based on the Maier-Saupe approach. The theory was used to calculate the temperature dependence of the order parameters and the susceptibilities. Predictions of the model for different sets of parameters are investigated.
Źródło:
Acta Physica Polonica A; 2004, 106, 1; 51-68
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Improving the efficiency of fuel plants at photoactivation molecules reagents
Povyshenie ehffektivnosti sgoranija topliva na molekuly reagentov fotoaktivacii
Autorzy:
Chervinsky, L.
Kovalyshyn, B.
Powiązania:
https://bibliotekanauki.pl/articles/792020.pdf
Data publikacji:
2015
Wydawca:
Komisja Motoryzacji i Energetyki Rolnictwa
Źródło:
Teka Komisji Motoryzacji i Energetyki Rolnictwa; 2015, 15, 2
1641-7739
Pojawia się w:
Teka Komisji Motoryzacji i Energetyki Rolnictwa
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Na-montmorillonite modified with ammonium salts and azobenzene as a photoactive nanomaterial
Autorzy:
Koteja, A.
Matusik, J.
Powiązania:
https://bibliotekanauki.pl/articles/184535.pdf
Data publikacji:
2016
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
inorganic solid structures
organic molecules
minerals
Opis:
Modification of inorganic solid structures (e.g. minerals) with organic molecules is a constantly developed topic in material sciences. The organic functionalization leads to the production of new materials with integrated properties of both the organic and inorganic component. In the presented study we have modified a Na-montmorillonite with alkylammonium surfactants and subsequently azobenzene, in order to obtain a nanomaterial that shows response to UV radiation. Azobenzene is a photoswitchable organic molecule capable to change its conformation upon UV radiation from the trans- to cis-azobenzene isomer. This reaction is coupled with a change of the molecules shape and dimensions (Klajn 2010). The montmorillonite is a layered aluminosilicate that serves as an excellent host structure for organic guest species. Due to the net negative layer charge it shows the ability to swell and to exchange the originally present interlayer cations. These properties allow the intercalation of bulk organic molecules and to control their arrangement. Much attention has been paid to the possibility of transferring the photoswitching ability of organic molecule into the motion of the whole organo-mineral structure (Heinz et al. 2008). Such nanoswitch is particularly appealing as it is controlled with radiation – remotely and at a precise location. The efficiency of a synthesized nanoswitch depends on an accurate selection of the host and guest component. The target of this study to test a series of organic surfactants and to establish a modification pathway that leads to obtaining a material most promising in the view of its photoresponsive behavior. The montmorillonite modification was performed in a two-step procedure, as the direct intercalation of a nonionic azobenzene is not possible. First, the Na-montmorillonite (denoted SWy) was ion-exchanged with trimethylalkylammonium cations abbreviated C n and benzyldimethylalkylammonium cations – BC n , where n refers to the number of carbon atoms in the alkyl chain and is equal to 12, 14 or 16. In the second step the organo-montmorillonites were reacted with azobenzene (AzBz) for 24 h at 120°C in a hermetically closed teflon vessel. The yellowish products were characterized with the X-Ray diffraction (XRD), the infrared spectroscopy (FTIR) and CHN elemental analysis. In all cases the intercalation of the ammonium cation caused an increase of the montmorillonites basal spacing ( d 001 ). The d 001 values were equal to 16.4 Å, 18.2 Å and 20.5 Å for SWy-C 12 , SWy-C 14 and SWy-C 16 , respectively. The samples modified with the BC n cations showed ~1.5 Å larger basal spacing, due to the presence of the benzyl group in the intercalated molecule. A linear relationship was observed between the d 001 value and the alkyl chain length of the introduced salts. This suggests that the organic cations formed paraffin-type aggregates in the interlayer (Ogawa et al. 1999) where the molecules are inclined to the layer surface. The FTIR spectra of modified SWy sample showed intense bands corresponding to CH 2 vibration modes. Along with the increasing alkyl chain length the CH 2 stretching bands shifted towards lower energies. This is an effect of growing packing density of alkylammonium molecules in the interlayer (He et al. 2004) and it is coupled with straightening of the alkyl chains due to transformation of disordered gauche conformer to the ordered all-trans conformer (Vaia et al. 1994). It can be concluded that the longer alkyl chains (C 16 and BC 16 ) form more ordered, solid-like aggregates in the interlayer space. The molar content of organic molecules was calculated basing on the CHN elemental analysis. The amount of intercalated alkylammonium cations was nearly equal to the cation exchange capacity (CEC) of montmorillonite – 88.9 meq/100 g. The reaction with azobenzene was most effective for montmorillonite modified with the alkylammonium cations having the longest chains as confirmed by the XRD patterns. The d 001 values of SWy-C 16 and SWy-BC 16 samples after reaction with AzBz increased to 36.9 Å and 35.9 Å, respecively. Well resolved and intense (001) peaks as well as the presence of the 2 nd and 3 rd order reflections indicated a highly ordered structure of these intercalates. On the contrary, diffraction peaks were less resolved and broadened for samples prepared with the shorter C 12 , C 14 , BC 12 and BC 14 molecules after reaction with AzBz. Based on these results, it is assumed that the long chain alkylammonium ions are more effective surfactants for the further intercalation of azobenzene into the montmorillonites interlayer space. The obtained highly ordered structures are promising materials for application as photo-actuated nanoswitches.
Źródło:
Geology, Geophysics and Environment; 2016, 42, 1; 87-88
2299-8004
2353-0790
Pojawia się w:
Geology, Geophysics and Environment
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Some results of an analysis of polyhydric alcohols effect on detoxication processes
Autorzy:
Konovchuk, V.
Andrushchak, A.
Powiązania:
https://bibliotekanauki.pl/articles/2052425.pdf
Data publikacji:
2015
Wydawca:
Akademia Bialska Nauk Stosowanych im. Jana Pawła II w Białej Podlaskiej
Tematy:
severe sepsis
rheosorbilact
endotoxicosis
medium weight molecules
Opis:
Rheosorbilact action on antitoxic function of the kidneys has been analysed using the values of medium weight molecules in patients with severe sepsis. The study design includes the criteria of inclusion, exclusion and cessation. Patients with pyoceptic complications (mainly surgical abdominal sepsis) with signs of severe endotoxicosis, dopaminergic activity (5-10 mcg/kg min), biochemical criteria of SS (lactate >4 mmole/l, С-reactive protein >2 standard departures from the norm) and other signs of severe sepsis with generalized disorders in homeostasis (assessing the multiple organ damage course by H.Celye-I.A. Yeriuhin scale- 20-27 points, MODS scale – 6-10 points) corresponded to the inclusion criterion. All patients were provided with appropriate debridement and intensive traditional therapy. For control studies we involved patients with systemic inflammatory response syndrome who had 2-3 signs of SIRS in stage A. It was found that rheosorbilact activates the transportation of medium weight molecules out of the extracellular space and increases their excretion by the renal nephrons in patients with severe sepsis. It was established that in severe sepsis rheosorbilact provides a high level of excretion of medium weight molecules by suppressing processes of reabsorption in the proximal nephron portions caused by peptidase dependent metabolism.
Źródło:
Health Problems of Civilization; 2015, 09, 2; 35-38
2353-6942
2354-0265
Pojawia się w:
Health Problems of Civilization
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Desorption Activation Energy of $SiBr_2$ Molecules according to Steady-State Approximation
Autorzy:
Knizikevičius, R.
Powiązania:
https://bibliotekanauki.pl/articles/1365355.pdf
Data publikacji:
2014-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.65.Cf
82.20.Db
82.20.Pm
Opis:
The chemical etching of intrinsic and n-type polycrystalline silicon in $Br_2$ ambient is considered. The theoretically calculated dependences of silicon etching rates on pressure of $Br_2$ molecules at different temperatures are compared with experimentally measured ones. The reaction and desorption activation energies are evaluated. It is found that activation energy of Si + $Br_2$ → $SiBr_2$ reaction for intrinsic silicon is equal to (1.82 ± 0.24) eV, and decreases to (1.45 ± 0.24) eV when n-type silicon films are used. Desorption activation energy of $SiBr_2$ molecules for intrinsic silicon is equal to (1.94 ± 0.17) eV, and decreases to (1.51 ± 0.17) eV when n-type silicon films are used. Desorption of $SiBr_2$ molecules is an etching-rate limiting process at high pressure of $Br_2$ molecules.
Źródło:
Acta Physica Polonica A; 2014, 125, 5; 1240-1243
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dynamics of the Molecules in Solid Phases of Few Chosen Schiff Bases Compounds
Autorzy:
Bąk, A.
Massalska-Arodź, M.
Powiązania:
https://bibliotekanauki.pl/articles/2037298.pdf
Data publikacji:
2004-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
64.70.Md
77.22.Gm
Opis:
The dielectric relaxation processes observed in solid phases of MBBA, OH-MBBA, and EBBA belonging to the homologous series of the Schiff bases are discussed. The data are compared with the results completed by the present authors for EBPA compound. The uniform interpretation of the temperature changes of relaxation for all mentioned compounds is proposed.
Źródło:
Acta Physica Polonica A; 2004, 105, 5; 467-474
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dynamic of water molecules in natrolite
Autorzy:
Paczwa, M.
Sergeev, N. A.
Olszewski, M.
Sapiga, A. A.
Sapiga, A. V.
Powiązania:
https://bibliotekanauki.pl/articles/1202501.pdf
Data publikacji:
2015
Wydawca:
Tomasz Mariusz Majka
Tematy:
zeolite
NMR
natrolite
water mobility
Opis:
Molecular mobility of water molecules has been investigated in the natural zeolite natrolite (Na2Al2Si3O10 ·2H2O) by 1H NMR. Spin-lattice relaxation times in the laboratory and rotating frames (T1 and T1-) have been measured as a function of temperature for a polycrystalline sample. It has been shown that the spin-lattice relaxations times of 1H are governed by the translation motions of water molecules in the natrolite pores. From experimental T1 data it follows that at T > 286 K the diffusion of water molecules along channels parallel to the c axis is observed. From experimental T1 data it follows that at T > 250 K the diffusion of water molecules in transversal channels of natrolite is observed also. At low temperature (T < 250 K) the dipolar interaction with paramagnetic impurities (presumably with Fe3+ ions) become significant as a relaxation mechanism of 1H nuclei.
Źródło:
Journal of Education and Technical Sciences; 2015, 2, 1; 15-20
2300-7419
2392-036X
Pojawia się w:
Journal of Education and Technical Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nanoantibodies: small molecules, big possibilities
Autorzy:
Pedreanez, A.
Mosquera-Sulbaran, J.
Munoz, N.
Tene, D.
Robalino, J.
Powiązania:
https://bibliotekanauki.pl/articles/2096419.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
camelids
nanoantibodies
nanotechnology
nanoreagents
SARS-CoV-2
therapy
Opis:
Camelids (camels, dromedaries, alpacas, llamas, and vicuZas) contain in their serum conventional heterodimeric antibodies as well as antibodies with no light chains (L) in their structure and composed of only heavy chains (H), called as HcAbs (heavy chain antibodies). Variable fragments derived from these antibodies, called as VHH or nanoantibodies (Nbs), have also been described. Since their discovery, Nbs have been widely used in the fields of research, diagnostics, and pharmacotherapy. Despite being approximately one-tenth the size of a conventional antibody, they retain similar specificity and affinity to conventional antibodies and are much easier to clone and manipulate. Their unique properties such as small size, high stability, strong antigen binding affinity, water solubility, and natural origin make them suitable for the development of biopharmaceuticals and nanoreagents. The present review aims to describe the main structural and biochemical characteristics of these antibodies and to provide an update on their applications in research, biotechnology, and medicine. For this purpose, an exhaustive search of the biomedical literature was performed in the following databases: Medline (PubMed), Google Scholar, and ScienceDirect. Meta-analyses, observational studies, review articles, and clinical guidelines were reviewed. Only original articles were considered to assess the quality of the evidence.
Źródło:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology; 2021, 102, 3; 321-336
0860-7796
Pojawia się w:
BioTechnologia. Journal of Biotechnology Computational Biology and Bionanotechnology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Molecular dynamic simulations of large RNA molecules: the yeast tRNA^{Phe}
Autorzy:
Pliszka, B.
Ołodziej, S.
Powiązania:
https://bibliotekanauki.pl/articles/1954518.pdf
Data publikacji:
1999
Wydawca:
Politechnika Gdańska
Tematy:
tRNA Phe
molecular dynamics
modified bases
nucleic acids
electrostatic interaction
Opis:
Molecular dynamics trajectories (700 ps) of the solvated and neutralized 75-residue yeast tRNA Phe were generated using the AMBER 5.0 molecular dynamics software package. The cut-off scheme was used to treat electrostatic interactions; consequently, all long-range interactions beyond 12 angstroms were neglected. The equilibration procedure and conditions during simulations led to a dynamically stable model of the tRNA molecule. During the simulations all base-base interactions (which determine the secondary and the tertiary structure of the molecule) were well preserved. Consequently, the global shape of the molecule was preserved well and the RMS deviation calculated between the starting x-ray structure and the final structure after 700 ps of simulations was 3.25 angstroms. The biggest deviation is observed in the region of the anticodon hairpin loop; this high mobility is associated with the presence of a very unusual Y-base and a binding site of a magnesium ion in this region.
Źródło:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk; 1999, 3, 3; 333-342
1428-6394
Pojawia się w:
TASK Quarterly. Scientific Bulletin of Academic Computer Centre in Gdansk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Orientational Ordering for System of Ellipsoidal Molecules Dispersed in Cubic Lattice
Autorzy:
Mejdani, R.
Powiązania:
https://bibliotekanauki.pl/articles/1952744.pdf
Data publikacji:
1996-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
05.50.+q
64.60.Cn
64.60.My
64.70.Md
Opis:
We represent here some results for a model of migrating and nonmigrating ellipsoidal molecules dispersed in a cubic lattice, describing: the orientational ordering in nematics, the possibility of a biaxial ordered liquid state, the orientational ordering in solid hydrogen (orto-H$\text{}_{2}$ or para-D$\text{}_{2}$) or the orientational glassy structure (the "higher rank"glass state). Through this kind of molecular ensemble (in the case of the system of ellipsoidal and spherical molecules) it is also possible to study the orientational and positional orderings in binary mixtures and to obtain the so-called plastic state.
Źródło:
Acta Physica Polonica A; 1996, 90, 6; 1127-1141
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Natural Semantic Metalanguage as Terminology
Autorzy:
Bułat Silva, Zuzanna
Powiązania:
https://bibliotekanauki.pl/articles/2015041.pdf
Data publikacji:
2021
Wydawca:
Komisja Nauk Filologicznych Polskiej Akademii Nauk, Oddział we Wrocławiu
Tematy:
natural semantic metalanguage (NSM)
semantic primes and molecules
reductive paraphrase
concrete and abstract nouns
terms
terminology
ontology
Opis:
In this paper I present the Natural Semantic Metalanguage approach (Goddard & Wierzbicka 2014; Goddard 2018; Wierzbicka 1996, 2013), arguing that it can be perceived as a terminological system, a terminology sui generis. NSM is a decompositional approach to semantics, based on the assumption that there are 65 basic concepts, known as semantic primes, and that all other concepts can be paraphrased in terms of elements taken from this set of 65. These elements are said to exist in all human languages – as words, phrases or morphemes – and they cannot be reduced any further. The system has been tested on more than 30 different languages so far and is considered one of the most comprehensive approaches to cross-linguistic semantics today. I want to shed light on the formal structure of NSM, and explain its most important theoretical concepts, such as semantic primes and molecules, reductive paraphrase and semantic template, in order to demonstrate its practical value across many domains. As an example of how NSM is used in practice, I will look at the meaning of one concrete and one abstract noun (beach and comfort, respectively).
Źródło:
Academic Journal of Modern Philology; 2021, 13; 61-73
2299-7164
2353-3218
Pojawia się w:
Academic Journal of Modern Philology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nonlinear Dielectric Relaxation in Solutions of the Polar Mesogenic Molecules in the Isotropic Phase
Autorzy:
Kędziora, P.
Powiązania:
https://bibliotekanauki.pl/articles/2036876.pdf
Data publikacji:
2003-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
64.70.Md
72.20.Ht
68.35.Rh
Opis:
The nonlinear spectra of 4,4'-n-hexylcyanobiphenyl (C$\text{}_{6}$H$\text{}_{13}$-Ph-Ph-CN) in benzene solutions were recorded in the frequency range of 300~kHz-100~MHz in the presence of the strong static electric field E$\text{}_{0}$=1.1×10$\text{}^{7}$ V/m, at 25˚C. The dynamic pretransitional phenomena revealed for polar C$\text{}_{6}$H$\text{}_{13}$-Ph-Ph-CN were interpreted in the frame of the Landau-de Gennes theory. The identical concentration-dependent behavior of nonlinear relaxation time in the vicinity of the transition from the isotropic to the nematic phase for polar and nonpolar compounds was discussed.
Źródło:
Acta Physica Polonica A; 2003, 104, 1; 45-53
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Inductive-Resonant Theory of Nonradiative Transitions for Complex Organic Molecules in Condensed Phase
Autorzy:
Ermolaev, V. L.
Sveshnikova, E. B.
Powiązania:
https://bibliotekanauki.pl/articles/1995259.pdf
Data publikacji:
1999-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.50.Dq
78.30.Jw
Opis:
Ours and literature data on influence of replacement of deuterium by protium in complex organic molecules on nonradiative triplet-singlet transition rates are discussed from the standpoint of the inductive-resonant theory of this process. It has been shown that the extent to which the protium introduction in molecule affects the nonradiative rate depends on distance between protium atom and the vibronic molecular oscillator of triplet-singlet transition and on π -electronic density near-by protium.
Źródło:
Acta Physica Polonica A; 1999, 95, 3; 299-308
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physical meaning temperature of gas and separate molecule
Autorzy:
Golovkin, B. G.
Powiązania:
https://bibliotekanauki.pl/articles/1157177.pdf
Data publikacji:
2018
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
distribution of molecules by temperature
gas cell
mean free path
temperature of a molecule
Opis:
Starting from the equation of state of the Clapeyron gas, it is shown that the temperature of a monatomic molecule of radius and mass moving with velocity is equal to , where: l are the length of a molecule without collisions, the Boltzmann constant, the kinetic energy of the molecule. The physical meaning of the temperature of a molecule should be understood as the kinetic energy that it has in the path without collisions l. The dimension of temperature coincides with the size of energy, but quantitatively the energy differs by the presence of a dimensionless factor , characterizing the motion of a molecule in fractions of its radius. Based on the temperatures of the individual molecules and their relative amounts contained in the gas, a formula is proposed for the overall gas temperature, for any, even nonequilibrium, distribution. The physical meaning of the gas temperature is determined by the product of the mean kinetic energy, the average mean free path of its molecules, and their size.
Źródło:
World Scientific News; 2018, 94, 2; 313-320
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Is a Molecular Adiabatic Approximation Appropriate to Positronic Atoms and Molecules?
Autorzy:
Mohallem, J.
Powiązania:
https://bibliotekanauki.pl/articles/1812542.pdf
Data publikacji:
2008-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
36.10.-k
36.10.Dr
78.70.Bj
82.30.Gg
Opis:
The adiabatic approximation to positronic atoms and molecules was considered as an option to the computationally unfeasible methods that treat all particles in a common footing, in two different approaches communicated in the 37th PSPA. Here we present further assessment and comparison of the two approaches as a way of evaluating the potential of adiabatic or, as we found preferable, molecular approaches.
Źródło:
Acta Physica Polonica A; 2008, 113, 5; 1465-1469
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Nonlinear Influence of Sound on the Vibrational Energy of Molecules in a Relaxing Gas
Autorzy:
Perelomova, A.
Powiązania:
https://bibliotekanauki.pl/articles/177217.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
relaxing gas
non-equilibrium media
nonlinear effects of sound
Opis:
Dynamics of a weakly nonlinear and weakly dispersive flow of a gas where molecular vibrational relaxation takes place is studied. Variations in the vibrational energy in the field of intense sound is considered. These variations are caused by a nonlinear transfer of the acoustic energy into energy of vibrational degrees of freedom in a relaxing gas. The final dynamic equation which describes this is instantaneous, it includes a quadratic nonlinear acoustic source reflecting the nonlinear character of interaction of high-frequency acoustic and non-acoustic motions in a gas. All types of sound, periodic or aperiodic, may serve as an acoustic source. Some conclusions about temporal behavior of the vibrational mode caused by periodic and aperiodic sounds are made.
Źródło:
Archives of Acoustics; 2012, 37, 1; 89-96
0137-5075
Pojawia się w:
Archives of Acoustics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Superradiance Effects in the Linear and Nonlinear Optical Response of Quantum Dot Molecules
Autorzy:
Sitek, A.
Machnikowski, P.
Powiązania:
https://bibliotekanauki.pl/articles/1811988.pdf
Data publikacji:
2008-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.67.Hc
78.47.nj
42.50.Ct
Opis:
We calculate the linear optical response from a single quantum dot molecule and the nonlinear, four-wave-mixing response from an inhomogeneously broadened ensemble of such molecules. We show that both optical signals are affected by the coupling-dependent superradiance effect and by optical interference between the two polarizations. As a result, the linear and nonlinear responses are not identical.
Źródło:
Acta Physica Polonica A; 2008, 114, 5; 1355-1360
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Orientation of Single Dibenzanthanthrene Molecules in Solid Xenon
Autorzy:
Sepioł, J.
Kołos, R.
Jasny, J.
Powiązania:
https://bibliotekanauki.pl/articles/1814017.pdf
Data publikacji:
2007-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.50.-j
61.66.Bi
61.66.Hq
61.72.Ww
Opis:
The spatial distributions of individual dibenzanthanthrene electronic transition dipole moments in solid Xe was investigated at the single molecule level, with the high-resolution fluorescence spectroscopy. Samples were prepared by the co-deposition of dibenzanthanthrene/Xe vapours onto the 50 K surface. The results indicate that the orientation of planar aromatic molecules is preferentially parallel to the trapping surface.
Źródło:
Acta Physica Polonica A; 2007, 112, S; S-121-S-126
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Double tunneling induced transparency in the asymmetry quantum dot molecules
Autorzy:
Yu, C.
Huang, H.
Zhang, L.
Xu, D.
Powiązania:
https://bibliotekanauki.pl/articles/173599.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quantum dot molecule
slow light
tunneling induced transparency
Opis:
Using the density matrix theory, we have studied the double tunneling induced transparency slow light in the double asymmetry quantum dot molecules. With applied electric field, double tunneling induced transparency occur in the same time. Four absorption peaks are found near the resonance energy level in the absorption spectrum and the absorption peak can be tuned by the applied electric field. The velocity and bandwidth of the multiple-windows slow light can also be controlled by the applied electric field. In our model, with Te =0.1meV, we can get about 0.001c and 20GHz bandwidth in each transparency window. Such a property may be applied in all optical buffers, optical switching and filter.
Źródło:
Optica Applicata; 2016, 46, 3; 473-481
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
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