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Tytuł:
Performance of cryogenic oxygen production unit with exhaust gas bleed for sewage sludge gasification and different oxygen purities
Autorzy:
Kaszuba, Maja
Ziółkowski, Paweł
Mikielewicz, Dariusz
Powiązania:
https://bibliotekanauki.pl/articles/27312208.pdf
Data publikacji:
2023
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
thermodynamic analysis
oxy-combustion of syngas
BECCS
cryogenic air separation
penalty production
oxygen production
Opis:
The paper presents a thermodynamic analysis of the integration of a cryogenic air separation unit into a negative CO2 emission gas power plant. The power cycle utilizes sewage sludge as fuel so this system fits into the innovative idea of bioenergy with carbon capture and storage. A cryogenic air separation unit integrated with the power plant was simulated in professional plant engineering and thermodynamic process analysis software. Two cases of the thermodynamic cycle have been studied, namely with the exhaust bleed for fuel treatment and without it. The results of calculations indicate that the net efficiencies of the negative CO2 emission gas power plant reach 27.05% (combustion in 95.0% pure oxygen) and 24.57% (combustion in 99.5% pure oxygen) with the bleed. The efficiencies of the cycle without the bleed are 29.26% and 27.0% for combustion in 95.0% pure oxygen and 99.5% pure oxygen, respectively. For the mentioned cycle, the calculated energy penalty of oxygen production was 0.235 MWh/kgO2 for the lower purity value. However, for higher purity namely 99.5%, the energy penalty of oxygen production for the thermodynamic cycle including the bleed and excluding the bleed was indicated 0.346 and 0.347 MWh/kgO2, respectively. Additionally, the analysis of the oxygen purity impact on the carbon dioxide purity at the end of the carbon capture and storage installation shows that for the case with the bleed, CO2 purities are 93.8% and 97.6%, and excluding the bleed they are 93.8% and 97.8%, for the mentioned oxygen purities respectively. Insertion of the cryogenic oxygen production installation is required as the considered gas power plant uses oxy-combustion to facilitate carbon capture and storage method.
Źródło:
Archives of Thermodynamics; 2023, 44, 3; 63--81
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reduction of carbon footprint from spark ignition power facilities by the dual approach
Autorzy:
Janusz-Szymańska, Katarzyna
Grzywnowicz, Krzysztof
Wiciak, Grzegorz
Remiorz, Leszek
Powiązania:
https://bibliotekanauki.pl/articles/1845486.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
spark ignition engines
digestion
gas
cofiring
CO2 emissions
membrane
separation
Opis:
Power generation units, suitable for individual users and small scale applications, are mainly based on spark ignition engines. In recently performed research, reductions of emissions coming from such units, especially considering carbon dioxide emissions, are deemed as the issue of particular importance. One of solutions, postponed to reduce impact of spark ignition engine-based units on the natural environment, is transition from fossil fuels into renewable gaseous fuels, as products of organic digestion. Nonetheless, development of new solutions is required to prevent further carbon dioxide emissions. The paper presents a novel dual approach developed to reduce carbon dioxide emissions from stationary power units, basing on spark ignition engine. The discussed approach includes both reduction in carbon content in the fuel, which is realized by its enrichment with hydrogen produced using the solar energy-supported electrolysis process, as well as application of post-combustion carbon dioxide separation. Results of the performed analysis suggest profitability of transition from fossil into the hydrogen-enriched fuel mixture, with significant rise in operational parameters of the system following increase in the hydrogen content. Nevertheless, utilization of the carbon dioxide separation leads to vital soar in internal energy demand, causing vital loss in operational and economical parameters of the analyzed system.
Źródło:
Archives of Thermodynamics; 2021, 42, 2; 171-192
1231-0956
2083-6023
Pojawia się w:
Archives of Thermodynamics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The mechanism of $CaCO_3$ in the gas-based direct reduction of a high-phosphorus oolitic iron ore
Autorzy:
Wu, Shichao
Li, Zhengyao
Sun, Tichang
Kou, Jue
Xu, Chengyan
Powiązania:
https://bibliotekanauki.pl/articles/1446124.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
high-phosphorus oolitic iron ore
gas-based direct reduction
magnetic separation
$Fe_3PO_7$
$CaCO_3$
Opis:
Gas-based direct reduction and magnetic separation process was applied in treating a high-phosphorus oolitic iron ore, of which phosphorus mainly occured as $Fe_3PO_7$ and apatite. The mechanism of $CaCO_3$ was investigated using XRD, SEM-EDS, and mineral phase analysis. Results showed that when no CaCO3 was added, most of the iron minerals were reduced to metallic iron, while $Fe_3PO_7$ was reduced to elemental phosphorus and mixed with the metallic iron particles. When a small amount of $CaCO_3$ was added, $CaCO_3$ preferentially reacted with $SiO_2$, $Al_2O_3$ and other components, preventing them from reacting with FeO and resulting in the increase of iron recovery. When the amount of $CaCO_3$ reached 25%, apatite was produced from the reaction of CaO and $Fe_3PO_7$, which could be later removed by grinding and magnetic separation.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 4; 117-124
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A new intelligentapproach in predictive maintenance of separation system
Autorzy:
Marichal, G. N.
Ávila, D.
Hernández, A.
Padrón, I.
Powiązania:
https://bibliotekanauki.pl/articles/116306.pdf
Data publikacji:
2020
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
marine fuel separators
separation system
predictive maintenance
greenhouse gas (GHG)
Fast Fourier Transformation (FFT)
genetic neuro-fuzzy system
genetic algorithm
supervised learning
Opis:
Reducing contaminant emissions is an important task of any industry, included the maritime one. In fact, in April 2018, IMO (International Maritime Organization) adopted an Initial Strategy on reduction of Greenhouse gas (GHG) emissions from ships. An essential part responsible for producing these emissions is the diesel engine. For that reason vessels include separation systems for heavy fuel oils. The purpose of this work is to improve the predictive maintenance techniques incorporating new intelligent approaches. An analysis of vibrations of this separation system was made and their characteristics were used in a Genetic Neuro-Fuzzy System in order to design an intelligent maintenance based on condition monitoring. The achieved results show that the proposed method provides an improvement since it indicates if a maintenance operation is necessary before the schedule one or if it could be possible extend the next maintenance service.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2020, 14, 2; 385-390
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Computational fluid dynamics simulation of gas–liquid multiphase flow in T-junction for CO2 separation
Autorzy:
Wrzesień, Sylwia
Madejski, Paweł
Ziółkowski, Paweł
Powiązania:
https://bibliotekanauki.pl/articles/37215646.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Computational Fluid Dynamics
CFD
Multiphase Flow
Numerical Simulations
T-junction
Opis:
The article presents the results of a computational fluid dynamics (CFD) analysis of gas-liquid multiphase flow. The simulation was conducted using CFD code and the Euler–Euler approach. The presented study relates to the non–reactive, steady-state, turbulent flow of water and carbon dioxide mixture in a 3D pipe. Separation phenomenon between phases is observed. The solution was obtained using a mixture model. Different values of carbon dioxide volume fraction were taken into account in the analysis of the results. The analysed cases were compared thanks to the obtained calculations results. The main purpose of the simulations was to show streamlines, velocity, pressure, and volume fraction distribution that could be useful in developing pipeline systems in many industrial applications, especially for CO2 separators.
Źródło:
Zeszyty Energetyczne; 2020, 7; 403-414
2658-0799
Pojawia się w:
Zeszyty Energetyczne
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Opracowanie koncepcji uzyskiwania strumieni gazu o podwyższonej zawartości helu na membranach
Development of the concept of obtaining gas streams on membranes with increased helium content
Autorzy:
Janocha, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/1834061.pdf
Data publikacji:
2020
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
separacja membranowa
hel
gaz ziemny
membrane separation
helium
natural gas
Opis:
Due to the constantly rising helium prices, resulting from the shrinking supply, reserves of helium from niche sources, including those of low quality, will become attractive. Conventional helium production technologies are energy-consuming and were designed for large streams to process (recover) helium from natural gas. Alternative technologies, e.g. using membrane separation, are being more and more often explored because of the economic benefits they can potentially have over the conventional approach. This article reviews the literature on the technologies used for membrane separation of helium from natural gas. The project was developed and a test stand was created for separation tests on membrane modules of gas mixtures with different helium content. Several series of studies were carried out with interpretation of the results of experimental dependence of the effects of helium permeate enrichment on stage cut. Simulations and calculations of the size of streams were carried out in a multi-stage helium separation system from natural gas as a function of stage cuts with retentate streams being recycled to earlier stages of separation. The concept of obtaining natural gas containing 0.3% helium gas stream with high helium content – over 90% – using membrane technology was developed. The tests were carried out on a commercially available polyimide membrane. The subsequent stages of enrichment of the gas stream in helium, 1.3, 8, 37 and over 93% helium in the final concentrate were obtained. In the high-pressure retentate stream, a helium-free product (<0.02%) was obtained which was also a gas with increased calorific value with a reduced content of carbon dioxide and nitrogen. During the experiments, a lot of effort was put into making the results broadly useful in process calculations. The general simulation problem of flow shaping (stream sizes) for a four-stage gas enrichment system on membranes has been solved. The calculation results can serve many variants depending on the flow and on stage cut Ѳ. The influence of permeate throttling pressure on separation effects was determined and the optimal range of this pressure was determined taking into account the need to compress this stream. The engineering calculations carried out for one of the variants showed the effectiveness and the possibility of its implementation. After each separation stage (degree), the permeate must be compressed again, which entails specific operating expenses related to the energy costs for compressing and cooling individual gas streams. The required power for compressing and cooling these streams was calculated.
Źródło:
Nafta-Gaz; 2020, 76, 10; 719-727
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Separacja siarkowodoru z gazu ziemnego w kaskadowych układach technologii membranowej
Separation of hydrogen sulphide from natural gas in cascade systems of membrane technology
Autorzy:
Janocha, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/1833995.pdf
Data publikacji:
2020
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
moduły membranowe
separacja gazowa
siarkowodór
gaz ziemny
membrane modules
gas separation
hydrogen sulphide
natural gas
Opis:
Under the new economic conditions, the exploitation of sour gas deposits reduces profits when using the conventional processes used to prepare gas for transport. Adding an inexpensive membrane unit as a preliminary technology before the classic quite energyconsuming amine absorption process (hybridization) can significantly reduce the cost of removing acidic components from natural gas. The article is a continuation of the author’s previous publications related to the research on the separation of several CH4–H2S mixtures. Gaseous separation tests were carried out on modules with polyimide membranes in a wide range of pressures. The scope of the conducted separation tests was extended to concentrations of 22% H2S in the gas mixture. Based on the experimental results, data for simulations and forecasts necessary for the evaluation and comparison of two-module cascade systems were obtained. The influence of the pressure of the gas flowing through the membrane (permeate) on the separation effects was determined. Increasing the pressure of the permeate flux reduces the concentration of hydrogen sulphide in it and increases the loss of methane. It was found that the ratio of the inlet gas pressure to the permeate pressure is of greater importance than the pressure difference. Single-stage membrane systems are sufficient for gas containing more than 12% H2S, for less sulfurized gases a two-stage cascade system is suggested. In the case of low concentrations of H2S in the gas, the methane losses in the one-stage system are too high. The article compares two variants of two-module cascade membrane systems. The paper presents comparative results of hydrogen sulphide content in simulation calculations for inlet gas with a concentration of 7.73% for both systems with a compressor before and after the second separation stage. The calculations showed that for the variant with the compressor before the second modulus, the H2S concentrations in the product streams are more favourable. H2S removal rates from the inlet gas were calculated for both systems. The influence of the permeate composition on the phase phenomena related to their condensation and compression for injection into the bed together with the acid gas from the amine part of the hybrid installation was considered.
Źródło:
Nafta-Gaz; 2020, 76, 12; 935--943
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Badania separacji siarkowodoru z gazu zasiarczonego przy różnych konfiguracjach modułów membranowych
Investigation of hydrogen sulphide separation from sour gas at various configurations of membrane modules
Autorzy:
Janocha, Andrzej
Powiązania:
https://bibliotekanauki.pl/articles/1835016.pdf
Data publikacji:
2019
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
moduły membranowe
separacja gazowa
siarkowodór
gaz ziemny
membrane modules
gas separation
hydrogen sulphide
natural gas
Opis:
W artykule zawarto studium przypadku zastosowania dwustopniowych układów membranowych w technologii separacji siarkowodoru z gazu. Zaprojektowano laboratoryjną instalację ciśnieniową, dostosowując ją do prowadzenia testów z dwoma modułami membranowym. Testy wykonano na mieszance wzorcowej o stężeniu 7,73% H2S w metanie przy różnych stosunkach przepływu permeatu do nadawy dla różnych konfiguracji modułów membranowych. Testy prowadzono w układzie jednomodułowym i w układach dwumodułowych w konfiguracji szeregowej i kaskadowej. Przedstawiono równania bilansowe charakteryzujące poszczególne układy modułowe. Obliczono i zbilansowano stężenia i przepływy strumieni pośrednich oraz produktowych w zależności od przepływu i współczynnika podziału. Stwierdzono, że moduły różnią się przepuszczalnością i selektywnością. Symulowano zawracanie sprężonych części strumieni produktowych o stężeniu równym nadawie w warunkach pomiarowych badanych modułów dla układu szeregowego i kaskadowego. W konfiguracji szeregowej dla ciśnienia 60 bar współczynniki podziału wynosiły odpowiednio: Ѳ1 = 0,15; Ѳ2 = 0,52. W konfiguracji kaskadowej ciśnienia wlotowe na moduły wynosiły 76 bar i 16 bar, a współczynnik podziału Ѳ1 = 0,11; Ѳ2 = 0,37. Stopień usunięcia H2S ze strumienia gazu wlotowego w układzie szeregowym jest wyższy (74%) niż w układzie kaskadowym (25%). Straty metanu w układzie szeregowym wynoszą 23% i są znacznie wyższe niż w układzie kaskadowym, w którym ubytek metanu wynosił 2,2%. Wypracowana metoda symulacji i prognoz na podstawie testów eksperymentalnych na membranach mieszanin CH4 – H2S umożliwi uzyskanie danych niezbędnych do praktycznego zastosowania technologii membranowej, w tym w hybrydowych procesach odsiarczania gazu ziemnego. Praca wykazała możliwość wykorzystania technologii membranowej do odsiarczania gazu ziemnego. Wyniki testów wykazały możliwość znaczących zmian w składach strumieni produktowych w prowadzonym procesie separacji membranowej.
The article contains a case study of the use of two-stage membrane systems in the technology of hydrogen sulphide separation from gas. A laboratory pressure system was designed to be used for testing with two membrane modules. The tests were carried out on a standard mixture with a concentration of 7.73% H2S in methane, at different permeate flow rates for feed for various membrane modules configurations. The tests were carried out in a one-module system and in two-module systems in a serial and cascade configuration. The concentrations and flows of intermediate and product streams were calculated and balanced, depending on the flow and stage cut. It was found, that the modules differ in their permeability and selectivity. The recycle of compressed parts of product streams at a concentration equal to the feed in the measurement conditions of the tested modules for the serial and cascade systems was simulated. Balance equations characteristic for individual modular systems were presented. Concentrations and flows of streams (intermediate and products) were calculated and balanced depending on the flow and partition coefficient. It was found that the tested modules displayed differences in their permeability and selectivity. The recycle of compressed parts of product streams at a concentration equal to the feed were simulated. Simulations were done for the measurement conditions of the tested modules and for the serial and cascade systems. In the serial configuration, for 60 bar inlet pressure, the value of partition coefficients Ѳ1 and Ѳ2 were 0.15 and 0.52 respectively. In the cascade configuration (inlet pressure for module 1st was 76 bar and for 2nd 16 bar) the partition coefficients were equal Ѳ1 = 0.11, Ѳ2 = 0.37. The degree of H2S removal from the feed gas stream in the serial system was higher (74%) than in the cascade system (25%). Methane loss in the serial system was 23%, and it was much higher than in the cascade system (2.2%). The developed method of simulations and forecasts based on experimental tests on CH4 – H2S mixtures membranes will enable obtaining data necessary for the practical application of membrane technology, including hybrid processes of natural gas desulfurization. The work showed the possibility of using membrane technology for natural gas desulfurization. The test results showed the possibility of significant changes in the composition of product streams the membrane separation process.
Źródło:
Nafta-Gaz; 2019, 75, 4; 222-229
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fluidization characteristics and separation performance of mild-hot gas-solid fluidized bed
Autorzy:
Lv, Bo
Luo, Zhenfu
Zhang, Bo
Zhao, Yuemin
Qin, Yunfei
Powiązania:
https://bibliotekanauki.pl/articles/109724.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
dry coal separation
mild-hot gas-solid fluidized bed
bed temperature
fluidization characteristics
Opis:
In recent years, the mild-hot gas-solid fluidized bed had a crucial influence on wet-in-feed sorting when it comes to moist feed (e.g., lignite) because of its expanding sorting range. To explain the favorable sorting effect of the mild-hot gas-solid fluidized bed, the fluidization characteristics (e.g., the pressure drop, density, etc.) was studied under different work conditions. In addition, a high-speed dynamic camera was used in this study to compare the slumping behavior of the magnetite slag at different temperatures. The optimum conditions for coal separation was also studied by Design-Expert software. It was shown that the bed temperature of the fluidized bed has a particular effect on its stability when the bed temperature was below 120 °C, which had a great influence on the separation. Finally, the probable deviation E of the mild-hot gas-solid fluidized bed under optimum operation conditions could be as low as 0.09 g/cm3 which showed the good separation ability.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 184-195
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Membrane gas separation module with pulsed retentate for low-permeable component recovery
Autorzy:
Battalov, Stanislav V.
Trubyanov, Maxim M.
Puzanov, Egor S.
Sazanova, Tatyana S.
Drozdov, Pavel N
Vorotyntsev, Ilya V.
Powiązania:
https://bibliotekanauki.pl/articles/185429.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
membrane gas separation
unsteady-state operation
process intensification
separation
efficiency
membrane module
separacja gazów membranowych
operacja niestabilna
intensyfikacja procesu
separacja
wydajność
moduł membranowy
Opis:
The paper presents the experimentalstudy of a novel unsteady-statemembrane gas separation approachfor recovery of a slow-permeant component in the membrane module with periodical retentate with-drawals. The case study consisted in the separation of binary test mixtures based on the fast-permeantmain component (N2O, C2H2) and the slow-permeant impurity (1% vol. of N2)using a radial counter-current membrane module. The novel semi-batch withdrawal technique was shown to intensify theseparation process and provide up to 40% increase in separation efficiency compared to a steady-stateoperation of the same productivity.
Źródło:
Chemical and Process Engineering; 2019, 40, 1; 57--65
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rozdział mieszanin gazowych przy wykorzystaniu ciekłych membran na podłożu ceramicznym impregnowanym cieczą jonową
Gas mixture separation on ceramic membranes impregnated with ionic liquid
Autorzy:
Rotkegel, Adam
Ziobrowski, Zenon
Powiązania:
https://bibliotekanauki.pl/articles/306026.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Inżynierii Chemicznej PAN
Tematy:
absorpcja
ditlenek węgla
ciecze jonowe
absorption
carbon dioxide
ionic liquids
Opis:
W pracy przedstawiono wyniki badań separacji ditlenku węgla i azotu na ceramicznych membranach ciekłych impregnowanych cieczą jonową [Emim][Ac] ] (octan 1-etylo-3-metyloimidazolowy). Badania przeprowadzono dla membrany ceramicznej firmy Pervatech BV w temperaturach 20-60°C dla ciśnień 1- 7 bar. Ciecz jonową nanoszono metodą pokrywania oraz zanurzania. Stwierdzono, że otrzymane membrany SILMs charakteryzują się niewielkimi strumieniami masowymi oraz dużymi wartościami selektywności.
The experimental results of carbon dioxide and nitrogen separation on ceramic membranes impregnated with ionic liquid [Emim][Ac] (1-ethyl-3-methylimidazolium acetate) are presented. Ceramic membranes made by Pervatech BV were investigated in 20-60°C and in the pressure range 1-7 bar. The ionic liquid was introduced into ceramic support by coating and soaking. It was found, that prepared SILMs are characterized by small mass fluxes and high selectivities.
Źródło:
Prace Naukowe Instytutu Inżynierii Chemicznej Polskiej Akademii Nauk; 2019, 23; 55-67
1509-0760
Pojawia się w:
Prace Naukowe Instytutu Inżynierii Chemicznej Polskiej Akademii Nauk
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Alternative Solutions to Optimalisation of the Gassing-up Operation After Tanks Inerting Using Pressure Swing Adsorption (PSA) and Membrane Techniques
Alternatywne rozwiązania dla optymalizacji procesu zagazowania zbiorników ładunkowych po inertowaniu w odniesieniu do PSA (Pressure Swing Adsorption) i technologii membranowej
Autorzy:
Wieczorek, A.
Powiązania:
https://bibliotekanauki.pl/articles/342015.pdf
Data publikacji:
2018
Wydawca:
Uniwersytet Morski w Gdyni. Wydawnictwo Uniwersytetu Morskiego w Gdyni
Tematy:
gas separation
pressure swing adsorption
membrane technology
nitrogenethylene composition
separacja gazów
technologia membranowa
mieszanina azot-etylen
Opis:
The article constitutes the introduction to finding a solution to a problem concerning carrying gassing-up operation in a more efficient way in terms of loosing ethylene cargo. To begin with, the impact of nitrogen presence on ethylene cascade cycle’s technical work and cooling capacity has been described. Further, the results of investigation into methods of nitrogen removing from cargo tanks after gassing-up have been presented. Possibility of pressure swing adsorption (PSA) and membrane techniques use has been analyzed with reference to ethylene carriers.
Artykuł stanowi wprowadzenie do rozwiązania problemu przeprowadzenia operacji gassing-up w sposób bardziej efektywny w odniesieniu do znacznych ilości „traconego” ładunku. W pierwszej kolejności opisano wpływ obecności azotu na pracę obiegu. W dalszej części przeanalizowano dostępne metody usunięcia azotu podczas operacji gassing-up. Opisano metody PSA (Pressure Swing Adsorption) oraz membrany i przeanalizowano je w odniesieniu do etylenowców.
Źródło:
Zeszyty Naukowe Akademii Morskiej w Gdyni; 2018, 105; 136-144
1644-1818
2451-2486
Pojawia się w:
Zeszyty Naukowe Akademii Morskiej w Gdyni
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of gas holdup on the efficiency of cyclonic-static microbubble flotation column for oily wastewater treatment
Autorzy:
Ning, K.
Huang, G.
Xu, H.
Wu, L.
Li, X.
Wang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/208139.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
bubble columns
efficiency
flotation
wastewater treatment
oil water separation
kolumna flotacyjna
efektywność
flotacja
oczyszczanie ścieków
separacja wody
Opis:
A cyclonic-static microbubble flotation column of a novel construction was used in oil-water separation fields and has high efficiency for oil-water separation. The gas holdup is a key parameter for the evaluation of the performance of a flotation column. The gas holdup, closely related to the bubble size, bubble velocity and superficial gas velocity, is one of the most important parameters characterizing the hydrodynamics of a bubble column. The effect of gas holdup in a cyclonic-static microbubble flotation column was investigated. In addition, several operating parameters such as the circulating pressure, superficial gas velocity, and frother consumption were also investigated. The gas holdup was positively correlated to the superficial gas velocity. The gas holdup of clean water and oil wastewater increased along with the increase of the frother consumption. The separation mechanism of cyclonic-static microbubble flotation column was analyzed.
Źródło:
Environment Protection Engineering; 2018, 44, 2; 5-17
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of the absorbing pervaporation technique for ammonia recovery after the haber process
Autorzy:
Atlaskin, A.
Petukhov, A. N.
Yanbikov, N. R.
Salnikova, M.E.
Sergeeva, M. S.
Vorotyntsev, V. M.
Vorotyntsev, I. V.
Powiązania:
https://bibliotekanauki.pl/articles/184857.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
gas separation
absorbing pervaporation
ammonia
process intensification
membrane
separacja gazów
amoniak
intensyfikacja procesu
membrana
Opis:
A novel absorbing pervaporation hybrid technique has been evaluated experimentally for the recovery of ammonia from the gas mixture in a recycle loop of synthesis plants. This process of hybridization brings together the combination of energy-efficient membrane gas separation based on poly(dimethylsiloxane) poly(diphenylsilsesquioxane) with a high selective sorption technique where a water solution with polyethylene glycol 400 (PEG-400) was used as the liquid absorbent. Process efficiency was studied using the pure and mixed gases. The influence of PEG-400 content in aqueous solutions on process selectivity and separation efficiency was studied. The ammonia recovery efficiency evaluation of an absorbing pervaporation technique was performed and compared with the conventional membrane gas separation. It was shown that the absorbing pervaporation technique outperforms the conventional membrane method in the whole range of productivity, producing the ammonia with a purity of 99.93 vol.% using the PEG 80 wt.% solution. The proposed method may be considered as an attractive solution in the optimization of the Haber process.
Źródło:
Chemical and Process Engineering; 2018, 39, 3; 323--333
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Metodyka rozdzielania i oznaczania lotnych inhibitorów fermentacji w brzeczkach fermentacyjnych ciemnej fermentacji, techniką GC-MS
Method for the separation and determination of volatile fermentation inhibitors in broths from dark fermentation, using GC-MS
Autorzy:
Makoś, P.
Słupek, E.
Kamiński, M.
Powiązania:
https://bibliotekanauki.pl/articles/92212.pdf
Data publikacji:
2018
Wydawca:
Uniwersytet Przyrodniczo-Humanistyczny w Siedlcach
Tematy:
biomasa lignocelulozowa
fermentacja ciemna
inhibitory fermentacji
ekstrakcja ciecz-ciecz
chromatografia gazowa
spektrometria mas
GC-MS
fermentation inhibitors
lignocellulosic biomass
dark fermentation
liquid-liquid extraction
gas chromatography-mass spectrometry (GC-MS)
Opis:
W pracy przedstawiono opracowaną w wyniku badań metodykę identyfikacji i oznaczania inhibitorów fermentacji w brzeczkach fermentacji ciemnej z biomasy ligno-celulozowej, z wykorzystaniem ekstrakcji ciecz-ciecz w sprzężeniu z chromatografią gazową ze spektrometrem mas (LLE-GC-MS). W ramach badań dokonano doboru korzystnych warunków ekstrakcji ciecz-ciecz, w tym: pH, objętości rozpuszczalnika ekstrakcyjnego, czasu ekstrakcji oraz warunków wirowania. Opracowana metodyka charakteryzuje się niskimi wartościami granicy wykrywalności (0,0086 – 3,75 mg/L) i oznaczalności, dobrą powtarzalnością i szerokim zakresem liniowości. W próbkach brzeczek fermentacyjnych, zidentyfikowano trzy inhibitory fermentacji (furfural, gwajakol i syringol) w stężeniach w zakresie od 0,04 do 2,45 mg/L. Dodatkowo, osiem innych inhibitorów, w tym głównie lotne kwasy tłuszczowe w stężeniach od 2,86 do 956 mg/L zidentyfikowano w brzeczkach, w trybie SCAN. Wyniki badań, wskazują na konieczność monitorowania przebiegu procesu fermentacji ciemnej w zakresie powstawania inhibitorów fermentacji, których obecność wpływa toksycznie na mikroorganizmy wytwarzające biowodór.
The paper presents the method for the qualitative and quantitative determination of fermentation inhibitors in fermentation broths for bio-hydrogen, using liquid-liquid extraction and gas chromatography with mass spectrometry (LLE-GC-MS). Initially, the extraction parameters were optimized. These included: pH, volume of extraction solvent, pH, extraction time as well as speed of centrifugation. The developed method has low detection limits (0,0086 – 3,75 mg/L), and determination, good repeatability and a wide range of linearity. In fermentation broth samples, three fermentation inhibitors (furfural, guaiacol and syringol) were identified in concentrations ranging from 0.04 to 2.45 mg/L. In addition, eight more inhibitors, mainly volatile fatty acids in concentrations from 2.86 to 956 mg/L, were identified in fermentation broth, using the SCAN mode. The paper demonstrates the need for monitoring inhibitors in fermentation broth during dark fermentation process, due to the fermentation inhibitors are toxic to biohydrogen-producing microorganisms.
Źródło:
Camera Separatoria; 2018, 10, 2; 64-80
2083-6392
2299-6265
Pojawia się w:
Camera Separatoria
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 78

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