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Wyświetlanie 1-15 z 26
Tytuł:
Solid State Synthesis of Europium Zirconate Based Material
Autorzy:
Mikuśkiewicz, M.
Moskal, G.
Powiązania:
https://bibliotekanauki.pl/articles/353816.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
europium zirconates
solid-state synthesis
pyrochlores
TBC
Opis:
In the article, the characterization of the microstructure, phase composition and distribution of elements in the Eu2 O3 -ZrO2 sintered materials obtained by four different ways of powders’ homogenization (mixing) process and different temperature of sintering process is shown. The feedstock powders with an average mole ratio of ZrO2 to Eu2 O3 equal 74% to 26% were used as an initial material. The principal aim of the investigation was characterization of differences in the microstructure of the same type of ceramics, however, prepared via different mixing and manufacturing processes. The range of the investigation covered a characterization of these materials via phase identification of all samples by XRD (X-ray diffraction) and characterization of internal morphology of the specimens with detailed analysis of elements distributions by SEM (scanning electron microscopy) and EDS (energy dispersive spectrometry). The aim of the following investigation is to characterize the possibilities of the solid state synthesis of the europium zirconate based materials, dedicated for TBC applications.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 4; 1343-1352
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorption of strontium, europium and americium(III) ions on a novel adsorbent Apatite II
Autorzy:
Krejzler, J.
Narbutt, J.
Powiązania:
https://bibliotekanauki.pl/articles/148382.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
adsorption
americium
Apatite II
europium
hydroxyapatite
nuclear waste
strontium
Opis:
A novel material, Apatite II, obtained from a natural source, has been determined to be a good adsorbent for radionuclides of strontium, europium and trivalent actinides, but not caesium, from neutral aqueous solutions containing common chelating agents and inorganic salts at moderate concentrations. This inexpensive, easily available material seems to be a promising backfill for engineered barriers in nuclear waste repositories. However, encapsulation of the sorbent grains loaded with radiostrontium in the Portland cement matrix results in undesirably high leaching rate for this particular radionuclide.
Źródło:
Nukleonika; 2003, 48, 4; 171-175
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Recovery of Yttrium and Europium Compounds from Waste Materials
Odzysk związków itru i europu z surowców odpadowych
Autorzy:
Góralczyk, S.
Uzunow, E.
Powiązania:
https://bibliotekanauki.pl/articles/204909.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
recovery
yttrium
europium
waste materials
odzysk
ITR
europ
odpady
Opis:
Rare earth metals including yttrium and europium are one of several critical raw materials, the use of which ensures the development of the so-called high technology. The possibility of their recovery in Europe is limited practically only to secondary materials such as phosphogypsum and electronic waste. The article presents the results of our research concerning the development of recovery technology of yttrium and europium from luminophore CRT used lamps. It describes the principle of separation of elements and the test results of cleaning the concentrate. It was shown that the costs of preparing the concentrate according to the proposed technology are lower than the phosphogypsum processing technology and the composition of the resulting product does not contain hazardous substances.
Metale ziem rzadkich, w tym itr i europ należą do tej grupy kilkunastu surowców krytycznych, których stosowanie zapewnia rozwój w obszarze tzw. wysokich technologii. Możliwość ich pozyskiwania w Europie ogranicza się praktycznie do surowców wtórnych, np. fosfogipsów oraz zużytego sprzętu elektronicznego. W artykule przedstawiono wyniki badań autorów dot. opracowania technologii odzysku itru i europu z luminoforu zużytych lamp kineskopowych. Opisano zasady wydzielania pierwiastków i wyniki badań oczyszczania koncentratu. Wykazano, że koszty otrzymywania koncentratu wg proponowanej technologii są niższe od technologii przeróbki fosfogipsów, a otrzymany produkt nie zawiera substancji niebezpiecznych.
Źródło:
Archives of Environmental Protection; 2013, 39, 3; 107-114
2083-4772
2083-4810
Pojawia się w:
Archives of Environmental Protection
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Migration of strontium, cesium, europium and uranium from poly(methyl styrene)- and polystyrene - phosphate composites prepared using gamma radiation
Autorzy:
Alhassanieh, O.
Ajji, Z.
Powiązania:
https://bibliotekanauki.pl/articles/146616.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
poly(methyl styrene)
polystyrene
composites
distribution
radionuclide
europium
strontium
cesium
uranium
Opis:
Composites consisting of natural phosphate powder and two monomers (styrene or methyl styrene) have been prepared by means of gamma irradiation. The polymerization reaction was followed up using a thermogravimetric analyzer (TGA) to determine the conversion of the polymerization. Differential scanning calorimeter (DSC) was used to locate and determine the glass transition temperature (Tg) of the prepared samples. The distribution of 137Cs, 152Eu, 85Sr and 238U in a solid-aqueous system, composites of phosphate-poly(methyl styrene) and of phosphate-polystyrene in contact with groundwater, was investigated using alfa-spectrometry and fluorometry. The effects of contact time, pH, and the concentration of concurrent element (Ca) were studied. The results were compared with earlier results with phosphate alone in the solid phase. The ability of the produced composites to keep the studied radioisotopes in the solid phase is much higher than in the mineral phosphate. This improvement is more remarkable for strontium and cesium than for europium and uranium, due to their high element ratio in the solid phase in phosphate experiments.
Źródło:
Nukleonika; 2012, 57, 3; 369-374
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Thermal Properties of Europium-Cerium Oxide as a New Fluorite-Type Ceramic Material for Thermal Barrier Coatings Applications
Autorzy:
Mikuśkiewicz, M.
Stopyra, M.
Moskal, G.
Powiązania:
https://bibliotekanauki.pl/articles/352272.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
TBC
cerium oxide
europium oxide
thermal properties
Opis:
In the present paper the structure and thermal properties of europium cerium oxides were investigated. The material for the research was obtained via solid state synthesis. The initial powders: ceria CeO2 and europia Eu2O3 were mixed in 1:1 mass ratio (non-stoichiometric proportion with the excess of CeO2) and milled. The sintering process was performed using high temperature vacuum press at 1350°C. Calorimetric analysis was conducted both for initial powders and milled mixture. The structure, phase composition and thermal diffusivity of obtained material were investigated in as-sintered condition. It was revealed that the obtained material was multi-phase. Non-stoichiometric phases including Ce0.5Eu0.5O1.75 with fluorite type structure and different lattice parameters were present. Thermal diffusivity decreased in the range from 25 to 900°C from 1.49 to 0.57 mm2 /s and then increased to 0.70 mm2 /s at 1400°C.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 4; 2089-2093
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The use of gadolinium and europium concentrations as contaminant tracers in the Nida River watershed in south-central Poland
Autorzy:
Migaszewski, Z. M.
Gałuszka, A.
Powiązania:
https://bibliotekanauki.pl/articles/2060198.pdf
Data publikacji:
2016
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
are earth elements
wastewater effluent
Nida River drainage system
anthropogenic gadolinium
geogenic europium
Opis:
This paper presents the results of rare earth element (REE) determinations in the Nowiny wastewater treatment plant (NWWTP) effluents and Nida River system waters of the southeastern Kielce Region (south-central Poland). Of the REE examined, gadolinium and europium turned out to be very useful for pinpointing anthropogenic and geogenic sources. Anthropogenic gadolinium (Gdanth), used as a contrasting agent in magnetic resonance imaging (MRI), is released from the NWWTP into the river drainage system. This micropollutant is traced downstream over the distance of about 15 km. This river stretch is characterized by a strong positive NASC-normalized Gdanth anomaly with the GdNASC/GdNASC* ratio above 1.1 (1.80–15.57) and the Gdanth input varying from 44 to 94%. Two additional positive Gdanth anomalies recorded in the rivers Bobrza and Nida point out to mixing of effluents derived from the NWWTP and other local wastewater treatment plants. In contrast, the Gdanth-uncontaminated waters upstream, or downstream far away from the NWWTP display a distinct positive NASC-normalized Eu anomaly highlighted by a high Eu/Eu* ratio in the range of 2.87 to 29.70. The lack of Gdanth anomaly upstream from the NWWTP also indicates that there is no leakage of municipal sewage from the sanitary collector sewer into the Silnica River. Thus Gd as a contaminant may be effectively used as a tracer in similar pollution studies because it is relatively simple and cost-effective to discriminate between contaminant concentrations and normal background concentrations.
Źródło:
Geological Quarterly; 2016, 60, 1; 67--76
1641-7291
Pojawia się w:
Geological Quarterly
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of metal surfaces coated with europium-doped titanium dioxide by laser induced breakdown spectroscopy
Autorzy:
Głogocka, D.
Noculak, A.
Pucińska, J.
Jopek, W.
Podbielska, H.
Langner, M.
Przybyło, M.
Powiązania:
https://bibliotekanauki.pl/articles/306866.pdf
Data publikacji:
2015
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
europ
tytan
LIBS
jakość
kompozycja
cienkie warstwy
europium
titanum
quality
composition
thin layers
Opis:
The surface passivation with titanium sol-gel coatings is a frequently used technique to control the adsorption of selected biological macromolecules and to reduce the exposure of the bulk material to biological matter. Due to the increasing number of new coating-preparation methods and new gel compositions with various types of additives, the quality and homogeneity determination of the surface covering is a critical factor affecting performance of any implanted material. While coating thickness is easy to determine, the homogeneity of the surface distribution of coating materials requires more elaborate methodologies. In the paper, the laser induced breakdown spectroscopy (LIBS) based method, capable to quantitate the homogeneity and uniformity of the europium in titanium dioxide sol-gel coatings on stainless steel surfaces prepared with two different procedures: spin-coating and dip-coating, is presented. The emission intensity of titanium has been used to determine the coating thickness whereas the relative values of europium and titanium emission intensities provide data on the coating homogeneity. The obtained results show that the spin-coating technique provides better surface coverage with titanium dioxide. However, when the surface coating compositions were compared the dip-coating technique was more reliable.
Źródło:
Acta of Bioengineering and Biomechanics; 2015, 17, 3; 33-40
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Scattering of Spin Polarized Positrons from Heavy Atoms: Europium and Bismuth
Autorzy:
Sharma, Kapil
Powiązania:
https://bibliotekanauki.pl/articles/1203962.pdf
Data publikacji:
2014-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
34.80.Bm
34.80.Uv
Opis:
We present calculations of differential, integrated elastic, total momentum transfer cross-sections and spin polarization parameters S for scattering of positron from Eu and Bi atoms in the energy range 2.0 to 500.0 eV using relativistic approach. The target projectile interaction is represented both by real and complex parameter-free optical potentials in the solution of the Dirac equation for the scattered positrons. The theoretical results are obtained from relativistic approach based on solving the Dirac equation using Hartree-Fock and Dirac-Fock wave functions to calculate cross-sections at all the energies considered.
Źródło:
Acta Physica Polonica A; 2014, 126, 3; 688-693
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sorption and migration of Cs, Sr, and Eu in gypsum - groundwater system
Autorzy:
Alhassanieh, O.
Mrad, O.
Ajji, Z.
Powiązania:
https://bibliotekanauki.pl/articles/147892.pdf
Data publikacji:
2012
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
distribution
cesium
europium
strontium
gypsum
groundwater
Opis:
The distribution of 137Cs, 152Eu, and 85Sr in a solid/aqueous system, gypsum in contact with groundwater, was investigated using gamma-spectrometry. The sorption and migration of the radionuclides were investigated. The aqueous phase was characterized using instrumental neutron activation analysis (INAA) and high performance liquid chromatography (HPLC). The solid phases were characterized using X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The investigations included three kinds of gypsum: mineral, commercial, and own prepared gypsum. The influence of some parameters on sorption/migration of the radionuclides were studied, such as contact time, pH, and concentrations of concurrent elements. The effect of element concentration was also investigated. The results show the ability of gypsum to keep Sr and Eu in the solid phase in all three cases. The incorporation of Cs in the solid phase depends on the conditions and used materials, and varies between 93 and 97%.
Źródło:
Nukleonika; 2012, 57, 1; 125-131
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Optical Spectra of Neodymium and Europium Tungstates and Molybdates
Autorzy:
Macalik, L.
Hanuza, J.
Legendziewicz, J.
Powiązania:
https://bibliotekanauki.pl/articles/1929790.pdf
Data publikacji:
1993-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
33.60.Cv
33.50.Dq
33.70.Ca
78.20.Dj
Opis:
Absorption and excitation spectra of lanthanides molybdates and tungstates were measured and analyzed. Probabilities of electronic transitions were analysed on the basis of the Judd-Ofelt theory. The significant differences of intensities were observed. Those differences could result from the symmetry changes, cooperative effects and electron-phonon interaction. The elucidation of intensities given by separate mechanisms needs further investigation.
Źródło:
Acta Physica Polonica A; 1993, 84, 5; 909-916
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Rare-Earth Elements Recovery on the Example of Europium (III) from Lean Technogenic Raw Materials
Autorzy:
Lobacheva, O.
Dzhevaga, N.
Powiązania:
https://bibliotekanauki.pl/articles/123060.pdf
Data publikacji:
2017
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
recovery
separation
extraction
rare-earth element
distribution coefficients
Opis:
Europium (III) recovery from nitrate solutions in a form of dodecyl sulfates using extraction methods was studied. Distribution and recovery coefficients as a function of equilibrium aqueous phase рН value were received. Conclusions on the effectiveness of presented method depending on the assigned task were drawn. The aims of this study were the development of rare-earth elements recovery and separation methods by using extraction with surfactant and distribution coefficients separation as well as recovery coefficient experimental validation with their subsequent introduction for poor mineral raw materials industrial processing. The authors study the rare-earth metals distribution and recovery coefficients during the extraction processes as a function of aqueous phase pH value with recovered compound form determination and thermodynamical justification.
Źródło:
Journal of Ecological Engineering; 2017, 18, 6; 122-126
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and Characterization of Thermal Properties of Type Eu2O3-ZrO2 Sinters
Autorzy:
Jucha, S.
Moskal, G.
Mikuśkiewicz, M.
Powiązania:
https://bibliotekanauki.pl/articles/352258.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
pyrochlores
europium zirconates
thermal diffusivity
TBC
Opis:
The oxides with pyrochlore or defected fluorite structure are a potential alternative ceramic materials for now widely used yttria-stabilized zirconia 8YSZ in the application for the insulation layer of thermal barrier coatings systems. This paper presents a procedure of synthesis of europium zirconate of Eu2Zr2O7 type, by the method of high temperature sintering under pressure. The analysis of the effect of the powders` homogenization methods on homogeneity of final sintered material showed that the highest homogeneity can be obtained after mechanical mixing in alcohol. Moreover, the DSC investigation carried out on a mixture of powders before the sintering process and on the material after high temperature sintering under pressure, suggest the synthesis of a new phase an europium zirconate Eu2Zr2O7 with the pyrochlore structure. Obtained phase was characterized by stability over the entire range of tested temperature, i.e. to 1450°C. The resulting material based on europium zirconate has a lower coefficient of thermal diffusivity than the now widely used 8YSZ.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 2B; 1121-1128
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fabrication of fluoride nanocrystals and their spectroscopic properties
Autorzy:
Pawlik, N.
Szpikowska-Sroka, B.
Goryczka, T.
Pisarski, W. A.
Powiązania:
https://bibliotekanauki.pl/articles/173278.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
sol-gel method
glass-ceramics
fluoride nanocrystals
europium ions
Opis:
In this work, the fabrication of glass-ceramic materials containing MF3:Eu3++ (M = La, Gd) nanocrystals dispersed in silica sol-gel hosts has been presented. The transformation from liquid sols towards bulk samples was also examined based on IR measurements. The crystallization temperatures and formation of MF3 phases were verified based on TG/DSC analysis and XRD measurements. The optical properties of prepared Eu3+5D05D0 → 7FJ (J = 1–4) emission bands, which were recorded within the reddish-orange spectral area under near-UV illumination (λexc = 393 nm). Recorded luminescence spectra and double-exponential character of decay curves for prepared glass-ceramic samples indicated the successful migration of Eu3+ dopant ions from amorphous silica framework to low-phonon energy MF3 nanocrystal phases.
Źródło:
Optica Applicata; 2019, 49, 3; 415-426
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Luminescence Properties of Europium in Sorbates of the Complexes with Naphthoic Acid on Zeolite
Autorzy:
Beltyukova, S. V.
Egorova, A. V.
Tselic, E. I.
Teslyuk, O. I.
Powiązania:
https://bibliotekanauki.pl/articles/2010950.pdf
Data publikacji:
1999-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.55.Cr
Opis:
A study of luminescence properties of sorbates of the europium(III) complexes with naphthoic acid and 1,10-phenanthroline on the zeolite of CaA-type that may be used as luminophores of the red color luminosity, has been performed. It was shown that the highest luminescence intensity in sorbate is observed upon the preliminary sorption of Eu(III) ion on zeolite following the treatment of naphthoic acid and 1,10-phenanthroline. The stability of sorbates to the temperature action was established (100°C, 2 h).
Źródło:
Acta Physica Polonica A; 1999, 95, 6; 977-982
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spectroscopic Studies of Neodymium and Europium Phosphoro-azo β-Diketonates
Autorzy:
Amirkhanov, V.
Ovchinnikov, V.
Legendziewicz, J.
Graczyk, A.
Hanuza, J.
Macalik, L.
Powiązania:
https://bibliotekanauki.pl/articles/1945685.pdf
Data publikacji:
1996-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
78.20.Wc
78.55.Hx
78.20.Dj
Opis:
New complexes of lanthanides (Nd, Eu) with phosphoro-azo derivatives of β-diketones were synthesized. Optical properties of these compounds were investigated and confronted with the structure and single crystal spectra of different types of earlier reported lanthanide phosphoro-azo-β-diketonates. The exchange of the N-P-O-Me ligand group by the N-P-NR$\text{}_{2}$ one plays only a minor role in binding character of lanthanide ions but strongly affects biological functions and properties of lanthanide systems. In vitro experiment on cytotoxicity of the samples was performed using 10T$\text{}_{1}\text{}_{/}\text{}_{2}$ , L$\text{}_{1}$, MCF, DETA and Meω-132 cell lines.
Źródło:
Acta Physica Polonica A; 1996, 90, 2; 455-460
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 26

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