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Tytuł:
Effective separation of specularite and aegirite using chitosan as a novel depressant
Autorzy:
Li, Mingyang
Zhang, Pengpeng
Gao, Xiangpeng
Tong, Xiong
Xie, Xian
Powiązania:
https://bibliotekanauki.pl/articles/2175424.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
iron-bearing silicates
aegirite
specularite
chitosan
depressant
Opis:
As a typical iron-bearing silicate gangue, aegirite often associates with specularite. Due to the iron element contained in aegirite, it has similar surface properties to specularite. Flotation is by far one of the most efficient methods of processing this kind of iron ore. But the traditional depressants unable to take action in the separation of specularite and aegirite. Chitosan was used as a novel depressant to attempt to separate specularite from aegirite through microflotation tests, adsorption tests, contact angle measurements, Zeta potential measurements, and XPS analysis. The flotation results indicate that chitosan show more strong depression effect on specularite than aegirite. Zeta potential measurements, contact angle measurements and adsorption tests demonstrate that chitosan is more inclined to adsorb on the specularite surface than aegirite, which hinders the subsequent adsorption of collector sodium oleate and increases difference in hydrophobicity between the two minerals. The XPS results of specularite validate the adsorption of chitosan on specularite, and illustrate that electrons of chitosan were partially transferred to oxygen and iron atoms in specularite during the adsorption process.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 6; art. no. 151692
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect and mechanism of depressant CK102 on flotation separation of fluorite and dolomite
Autorzy:
Li, Zhengyao
Wang, Xuewen
Xu, Chengyan
Sun, Tichang
Liu, Weiran
Wei, Jinzhi
Powiązania:
https://bibliotekanauki.pl/articles/2146904.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
fluorite
dolomite
flotation
depressant CK102
adsorption
Opis:
For a low grade dolomite type fluorite ore in the Hebei province, it was observed that the depressant CK102, a mixture of sulfuric acid, sodium silicate and aluminum sulfate, can effectively inhibit the gangue mineral dolomite in the flotation of fluorite. However, the inhibition mechanism of the depressant is still unclear. In this paper, the flotation separation performance and underlying mechanism of CK102 inhibiting dolomite were investigated through mineral flotation tests, adsorption measurements, infrared spectroscopy, and X-ray photoelectron spectroscopy (XPS). The flotation results showed that the inhibition effect of CK102 on dolomite flotation was much more remarkable than that of fluorite flotation under optimum conditions. Adsorption measurements revealed that there was competitive adsorption between the depressant and collector and that the adsorption of the depressant CK102 prevented the collector modified sodium oleate from adsorbing onto the surface of minerals. The FT-IR and XPS results showed that the co-oxygen cross-linked component of the depressant CK102 chemisorbed on the surface of dolomite; the CaSiO3 precipitation was generated from the reaction of CK102 with Ca2+ groups on the surface of the dolomite; Al2MgO8Si2 precipitation was also generated from Mg2+ reacting with the sodium silicate and aluminum sulfate of CK102. The above adsorptions and reactions enhanced the hydrophilicity of the dolomite surface and the dolomite was effectively depressed.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 3; art. no. 145796
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigations on soluble starch as the depressant of hematite during flotation separation of apatite
Autorzy:
Bai, Shaojun
Ding, Zhan
Fu, Xianyu
Li, Chunlong
Lv, Chao
Wen, Chao
Powiązania:
https://bibliotekanauki.pl/articles/110115.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
soluble starch
depressant
hematite
apatite
FTIR
XPS
Opis:
In this paper, soluble starch was studied as a depressant of hematite during flotation separation of apatite using sodium oleate as a collector. Surface charge measurement, soluble starch adsorptions, Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) were used to understand the interaction mechanisms between minerals (hematite and apatite) and soluble starch. The results indicated that chemical interaction between hematite and soluble starch was present, and supported the bonding of hydroxyl, while physical adsorption of soluble starch molecules with apatite occurred. Results of micro-flotation studies suggested that soluble starch was considered as a selective depressant for hematite. The maximum recovery difference between hematite and apatite of 77.5% was obtained with 40 mg/dm3 soluble starch. The flotation experiment results of natural iron ore showed that flotation indexes with 59.73% Fe, iron recovery of 81.5% and 75.68% of dephosphorization ratio were achieved at a soluble starch dosage of 60 mg/dm3. However, a higher dosage of soluble starch addition caused the difficulty for flotation separation of apatite from hematite. Our results provided theoretical basis for the flotation separation of apatite from iron oxide ores.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 38-48
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Use of PASP and ZnSO4 mixture as depressant in the flotation separation of chalcopyrite from Cu-activated marmatite
Autorzy:
Wei, Qian
Jiao, Fen
Qin, Wenqing
Dong, Liuyang
Feng, Liqin
Powiązania:
https://bibliotekanauki.pl/articles/109451.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
chalcopyrite
marmatite
polyaspartic acid
mixed depressant
adsorption
Opis:
In this study, the synergistic depressive effect of polyaspartic acid (PASP) and zinc sulfate (ZnSO4) in the flotation separation of chalcopyrite from Cu-activated marmatite was investigated by micro-flotation experiments and ore sample flotation tests, and the possible depressive mechanism was proposed from contact angle measurements, fourier transform infrared (FT-IR) analysis, inductively coupled plasma (ICP) measurements and X-ray photoelectron spectroscopy (XPS) analysis. Microflotation tests indicated that the mixed depressant PASP/ZnSO4 (PZ) exerted strong depressive effect on Cu-activated marmatite in the pH range of 9~12, but it had little effect on chalcopyrite flotation. The ore sample flotation experiments indicated the PZ system decreased the grade of Zn in Cu concentrate by 4.18%, and the depressant consumption was reduced by more than a half. The results from contact angle measurement demonstrated that the hydrophobicity of Cu activated-marmatite surface was higher than that of chalcopyrite surface in presence of PZ. FT-IR analysis demonstrated the more intensive chemisorption of PZ on Cu-activated marmatite surface. ICP measurements showed that PASP had an excellent complexing ability with Cu2+ and Zn2+, which not only reduced the activation of Cu species, but also generated Zn-PASP complex on marmatite surface. XPS analysis indicated a stronger interaction between PZ and Cu-activated marmatite surface, and the depressant PZ may mainly react with Cu-activated marmatite surface through the copper atoms.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 5; 1192-1208
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of a novel depressant on the separation of talc and copper –nickel sulfide ore
Autorzy:
Gu, Guohua
Chen, Zhixiang
Zhao, Kaile
Song, Siyu
Li, Shuangke
Wang, Chongqing
Powiązania:
https://bibliotekanauki.pl/articles/110492.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
Sodium alginate
talc
copper–nickel sulfide
polysaccharide depressant
flotation
Opis:
This paper researched the influence of the polysaccharide polymer sodium alginate (SAG) on the depression of talc at a fixed room temperature about 25 °C through micro flotation and batch flotation experiments, zeta potential and contact angle measurements as well as infrared spectroscopy analysis. The flotation results displayed that the SAG had a significant influence on the flotation of talc but less influence on sulphide flotation. Compared with the depressant carboxymethyl cellulose (CMC) and guar gum, using of the SAG gave the highest copper recovery. It could not only eliminate a talc removal step, but also significantly decrease in the depressant consumption by half at least. Sodium alginate apparently adsorbs on the talc surface and promotes hydrophilization, as revealed by contact angle tests (contact angle decreased from 75 to 33° after treating with SAG). It is demonstrated that the SAG obviously absorbed at the surface of talc but rarely for chalcopyrite through the results of zeta potential measurements and infrared spectroscopy analysis.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 116-127
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of diethylenetriaminepenta pentasodium salt as an eco-friendly depressant to effectively improve the flotation separation of scheelite and calcite
Autorzy:
Zhou, Hepeng
Wu, Handan
Guo, Jiangfeng
Tang, Xuekun
Huang, Wen
Luo, Xianping
Powiązania:
https://bibliotekanauki.pl/articles/27323649.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
scheelite
calcite
diethylenetriaminepenta pentasodium salt
depressant
adsorption
Opis:
Diethylenetriaminepenta (methylene-phosphonic acid) pentasodium salt (DTPMPA), an eco-friendly reagent, was tried for the first time as a depressant for flotation separation of scheelite from calcite. Micro-flotation tests show that DTPMPA can selectively depress the floatability of calcite. In contrast, DTPMPA barely affects the flotation behavior of scheelite. Based on the selective depress effect, floatation separation of scheelite and calcite can be effectively achieved by using DTPMPA as depressant in artificially mixed minerals flotation tests. Based on a series of measurements, it found the surface of calcite was positively charged due to the existence of Ca ion site, which can be chelated with –PO3H- functional group on the surface of DTPMPA. In the flotation process, DTPMPA can be chemically absorbed on the surface of calcite to inhibit further collector adsorption. On contrast, little DTPMPA was adsorbed on the surface of scheelite due to the spatial site resistance and electrostatic repulsion induced by surface WO42+. All in all, these results exhibit DTPMPA has excellent selective depression ability on calcite, which can be potentially applied in the actual scheelite flotation process.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174718
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cellulase as a new phosphate depressant in dolomite-phosphate flotation
Autorzy:
Yehia, A.
Khalek, M. A.
Ammar, M.
Powiązania:
https://bibliotekanauki.pl/articles/110349.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
cellulose
cellophane
dolomite
oleic acid
Opis:
Recently, many research efforts have been made to reduce the magnesium content in the phosphate concentrate to meet the requirement for phosphoric acid production and other applications. A bioprocessing technique is among these efforts. However, this paper was devoted to study the use of cellulase enzyme as a new phosphate depressant during fatty acid flotation of a calcareous phosphate rock. The flotation behavior of collophane and dolomite as single minerals using oleic acid as a collector and cellulase enzyme as the phosphate depressant was investigated in details. The results from single mineral flotation tests were discussed based on FTIR and zeta potential measurements to find out the mechanism of cellulase depression of phosphate. The findings from the single minerals tests were used to develop a selective flotation process for recovery of phosphate minerals from the natural phosphate ore. The flotation experiments were carried out to apply this new process using the calcareous phosphate ore. Under the optimum flotation conditions, 0.04% cellulase and 0.5 mM oleic acid, a phosphate concentrate containing 0.89% MgO with a P2O5 recovery of 75% was obtained from the phosphate ore containing 2.2% MgO.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1092-1104
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective separation of chalcopyrite from jamesonite with guar gum
Autorzy:
Chen, Xiong
Gu, Guohua
Zhu, Renfeng
Wang, Chongqing
Powiązania:
https://bibliotekanauki.pl/articles/110473.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
guar gum
chalcopyrite
jamesonite
flotation depressant
Opis:
A novel reagent, guar gum (GG), is investigated as the depressant on the depression of chalcopyrite and jamesonite, when mixed aerofloat (CSU11) is used as the collector in flotation tests. Kinetics, dynamic potential, adsorption and infrared spectra analysis are performed to study the interaction mechanism between GG and minerals. The flotation results display that selective flotation separation of chalcopyrite from jamesonite is achieved under conditions of depressant GG 2.5 mg/dm3, collector CSU11 10 mg/dm3 and frother MIBC (Methyl isobutyl carbinol) 10 mg/dm3 at pH 5.3. As to mixed minerals flotation, the Cu grade and recovery in the concentrate is 21.35 % and 85.12 %, respectively, indicating that GG has a selective depression effect on jamesonite. Flotation kinetics shows that the addition of GG can dramatically reduce the floatability of jamesonite but hardly influences that of chalcopyrite. The zeta potential and adsorption reveal that the depressant GG adsorbs strongly on the surface of jamesonite. Infrared spectra reveal a dominant chemisorption between GG and jamesonite, while GG occurs weak chemisorption on chalcopyrite surface. This is the reason why GG has excellent selectivity for jamesonite and less effect on chalcopyrite.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 237-247
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation separation of chalcopyrite from talc using carboxymethyl chitosan as depressant
Autorzy:
Qian, G.
Bo, F.
Danping, Z.
Jujie, G.
Powiązania:
https://bibliotekanauki.pl/articles/110249.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
talc
chalcopyrite
flotation
separation
carboxymethyl chitosan
Opis:
Flotation separation of chalcopyrite from talc using carboxymethyl chitosan as a depressant was studied. Flotation tests indicated that carboxymethyl chitosan had a selective depression effect on talc and the use of carboxymethyl chitosan as the depressant could achieve flotation separation of chalcopyrite from talc at pH 7. Adsorption studies showed that carboxymethyl chitosan only adsorbed on the surface of talc. This was the reason why carboxymethyl chitosan had high depression selectivity for talc. The zeta potential measurements and XPS analysis indicated that carboxymethyl chitosan adsorbed on the talc surface mainly through physical interaction and hydrophobic interaction may be the main driving force.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1255-1263
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of depressants in the selective flotation of smithsonite and calcite using cationic collector
Autorzy:
Liu, Hongjiang
Zhang, Guofan
Luo, Yuanjia
Powiązania:
https://bibliotekanauki.pl/articles/1449481.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
smithsonite
calcite
selective separation
depressant
Opis:
This work studied the effects of sodium hexametaphosphate (SHMP), tanning extract, water glass (WG) and calcium lignosulfonate (CLS) as depressants for the separation of smithsonite from calcite by using a cationic collector called octadecylamine acetate (ODA). Micro-flotation experimental tests showed that CLS can greatly and selectively depress calcite. When the dosages of CLS used were 20 and 40 mg/L, a concentrate with Zn grades of 42.54% and 49.32% and Zn recoveries of 81.66% and 68.00% was achieved in the flotation separation of mixed mineral (1:1 smithsonite:calcite). Zeta potential and adsorption measurements revealed that the adsorption of CLS on calcite’s surface was greater than that on smithsonite’s surface. When CLS was added, the adsorption of ODA was hindered greatly on the calcite’s surface but slightly on the smithsonite’s surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 1; 1-10
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
New method of electrostatic separation of the oxidized iron ore
Autorzy:
Idres, A.
Bouhedja, A.
Bounouala, M.
Benselhoub, A.
Powiązania:
https://bibliotekanauki.pl/articles/89112.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Wydział Geoinżynierii, Górnictwa i Geologii. Instytut Górnictwa
Tematy:
iron ore
electrostatic separation
reagent-collector
reagent–depressant
efficiency
Opis:
The complexity of the mineralogical, chemical and exogenous parameters generates a low efficiency of electrical separation of oxidized iron ore. For this purpose, a study was conducted to provide a method for electrostatic separation and to select the chemical reagents. And this, for increasing the contrast of the dielectric separating minerals in the corona discharge field. The reagent-collector used is the auramine with a specific consumption of 0.3 kg/t. Whereas, the reagent depressants is carboxymethyl cellulose mixture with a specific consumption of 0.25 kg/t. From the obtained test results electrical treatment of oxidized iron ore are satisfied for proposed process.
Źródło:
Mining Science; 2016, 23; 33-41
2300-9586
2353-5423
Pojawia się w:
Mining Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ligandy receptora NMDA w leczeniu zaburzeń depresyjnych
The NMDA receptor ligands in anti-depressant therapy
Autorzy:
Stasiuk, Weronika
Warchulińska, Joanna
Olszewska, Anna
Poleszak, Ewa
Powiązania:
https://bibliotekanauki.pl/articles/943323.pdf
Data publikacji:
2016
Wydawca:
Instytut Medycyny Wsi
Tematy:
depresja
receptor nmda
terapia przeciwdepresyjna
Opis:
Wprowadzenie. Nowy kierunek badań nad zaburzeniami depresyjnymi koncentruje się na hamowaniu aktywności receptora NMDA, co stwarza nowe możliwości leczenia chorób wywołanych nadmierną aktywacją układu glutaminianergicznego. Cel pracy. Celem prezentowanej pracy jest przegląd ligandów (w szczególności antagonistów) receptora NMDA działających na jego ekspresję i funkcje oraz ich wpływ na działanie klasycznych leków przeciwdepresyjnych. Opis stanu wiedzy. Skuteczność obecnie stosowanych metod leczenia zaburzeń depresyjnych jest niezadowalająca i obarczona wieloma skutkami ubocznymi. Niepokojący jest również fakt, iż u wielu pacjentów rozwija się lekooporność. Dlatego też opracowuje się nowsze, skuteczniejsze metody leczenia. Wykazano, że jednym z istotnych mechanizmów działania przeciwdepresyjnego jest blokowanie receptora NMDA. Podsumowanie. Wprowadzenie do lecznictwa antagonistów receptora NMDA stwarza nowe możliwości terapeutyczne zaburzeń depresyjnych, a także wydaje się być interesującą alternatywą w leczeniu depresji lekoopornych.
A new direction in research on depressive disorders focuses on reducing the activity of the NMDA receptor, which opens up new possibilities for the treatment of diseases caused by the excessive activity of the glutamatergic system. The aim of this work is the study of ligands (especially antagonists) of the NMDA receptor, which influence its expression and function as well as their impact on the action of classic anti-depressant medications. The effectiveness of currently utilized depressive disorder treatment methods is unsatisfactory and linked to many sideeffects. It is also a worrying fact that many patients develop drug resistance. This is why there is a continued effort for the development of newer, more effective treatment methods. It has been shown that one of the key anti-depressant mechanisms of action is through the blockage of the NMDA receptor. The introduction into the treatment regime of antagonists of the NMDA receptor opens new therapeutic possibilities in the treatment of depressive disorders, as well as being a potential alternative in the treatment of drug resistant forms of the disease.
Źródło:
Medycyna Ogólna i Nauki o Zdrowiu; 2016, 22(51), 3
2083-4543
Pojawia się w:
Medycyna Ogólna i Nauki o Zdrowiu
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of depressants in the selective flotation of smithsonite and calcite using potassium lauryl phosphate as collector
Autorzy:
Sun, Qing
Feng, Qiming
Shi, Qing
Powiązania:
https://bibliotekanauki.pl/articles/110635.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
smithsonite
calcite
flotation
depressant
separation
Opis:
In order to selectively separate smithsonite and calcite using potassium lauryl phosphate as collector and reveal the depression mechanism, the approaches of micro-flotation and zeta potential measurements were adopted. The effects of sodium hexametaphosphate (SHMP), water glass (WG), carboxymethyl cellulose (CMC) and lignosulfonate calcium (LSC) as depressants on smithsonite and calcite have been studied through micro-flotation. The single mineral flotation tests show that LSC can depress calcite, but it has little effect on smithsonite flotation. Flotation separation of a mixture of smithsonite and calcite can be completed to obtain a zinc concentrate grade up to 33.85% Zn with a recovery of 70.06%. The zeta potential results illustrate that LSC has higher tendency to be adsorbed on the surface of calcite. However, there is little adsorption of LSC on smithsonite.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 1; 89-96
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Flotation separation of scheelite from calcite using sodium polyacrylate as depressant
Autorzy:
Zhang, Y.
Chen, R.
Li, Y.
Wang, Y.
Luo, X.
Powiązania:
https://bibliotekanauki.pl/articles/110896.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
scheelite
calcite
flotation
sodium polyacrylate
selective depression
Opis:
The depressing properties of sodium polyacrylate (PA-Na) for calcite from scheelite were studied by microflotation experiments, zeta potentials, X-ray photoelectron spectroscopy (XPS) and density functional theory (DFT) calculation. Flotation results revealed that the selective depression effect of PA-Na was better than that of sodium silicate (Na2SiO3), and PA-Na can depress calcite more effectively than scheelite. The flotation recovery of scheelite and calcite kept at about 75% and 15% respectively at the pulp pH 9.3~9.6 and PA-Na concentration from 37.5 mg/dm3 to 50 mg/dm3. The zeta potentials of the minerals were significantly altered and the zeta potential of calcite became more negative than scheelite. XPS analysis deduced the occurrence of chemisorption between PA-Na and mineral surfaces, and the chemisorption of PA-Na on calcite was stronger than on scheelite. The results from DFT calculation demonstrated that the absolute value of the adsorption energy in the presence of PA-Na on the surface of calcite {104} was larger than on the surface of scheelite {111}. With the combination of the analysis, it could be concluded that calcite was more easily depressed than scheelite, and this finding remarkably matched with the microflotation experimental results. Furthermore, by using PA-Na as depressant, the flotation separation of scheelite from calcite can be achieved by controlling the flotation pH and PA-Na dosage.
Źródło:
Physicochemical Problems of Mineral Processing; 2018, 54, 2; 505-516
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Quinic acid as a novel depressant for efficient flotation separation of scheelite from calcite
Autorzy:
Huang, Zheyu
Kuang, Jingzhong
Yu, Mingming
Ding, Dan
Powiązania:
https://bibliotekanauki.pl/articles/24085979.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
quinic acid
scheelite
calcite
depression
selective adsorption
Opis:
There are difficulties to the conventional depressant for achieving separation of scheelite from calcite for the sake of their similar surface properties. The paper reported that a new depressant quinic acid (QA) was used for separating scheelite from calcite. The adsorption experiments, zeta potential experiment, contact angle, FTIR, XPS analysis and crystal chemistry analysis were utilized to known the depression mechanism of selectivity. The results showed that the recovery of calcite decreased drastically after QA added, whereas hardly influenced on scheelite. The tungsten concentrate could reach 66.24% WO3 grade and 89.46% recovery with 1.5×10-4 mol•L-1 QA at pH=9. The surface adsorption quantity of the QA on calcite was much greater than scheelite, which enhanced significantly the hydrophilicity of calcite surface. Due to its negative charge, QA could be adsorbed on the surface of calcite which had positive charge instead of that of scheelite with negative charge. Subsequently, free carboxyl groups of QA could chelated with Ca2+ species on the calcite surface to form stable chemical adsorption in order to prevent the Pb-BHA to form further adsorption on that, so there was no increase significantly on hydrophobicity. However, QA was obviously weak for adsorbing while Pb-BHA which could still be chemically adsorbed on scheelite surface of pre-treated with QA.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 2; art. no. 166008
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 29

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