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    Wyświetlanie 1-2 z 2
    Tytuł:
    Effects of Metal Oxides on the Thermal Decomposition Kinetics and Mechanisms of HAN/PVA Based Propellants
    Autorzy:
    Hu, Song-qi
    Liu, Xue-li
    Liu, Lin-Lin
    Kang, Bo
    Zhang, Yan
    Powiązania:
    https://bibliotekanauki.pl/articles/27787991.pdf
    Data publikacji:
    2021
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    HAN/PVA-based propellant
    metal oxides
    catalytic behaviour
    kinetic parameters
    Opis:
    The thermal decomposition processes of HAN/PVA-based propellants have been investigated using a simultaneous thermogravimetric analysis (TGA) – differential scanning calorimetry (DSC), coupled with Fourier-Transform Infrared Spectroscopy (FTIR) and Mass Spectrometry (MS) system. The activation energy (Ea), pre-exponential factor A and reaction mechanism function f(α) of the decomposition processes have been determined by non-isothermal and Malek methods. The results showed that the decomposition process of an HAN/PVA sample occurs mainly in the temperature range 202.2~220.1 °C, with a mass loss, heat release and Ea of about 84.8%, 1474.18 and 88.76 kJ·mol–1, respectively. Of the seven metal oxides studied as catalysts, Al2O3, V2O5 and Fe2O3 have significant catalytic effects on an HAN/PVA-based propellant, in lowering the decomposition temperature, with Ea changing from 88.8 to 83.7, 85.6 and 113.6 kJ·mol–1, respectively. The f(α) of both HAN/PVA and HAN/PVA/Al2O3 samples can be expressed as f(α) = (1 – α)2, whereas f(α) = α or f(α) = α/2 fit well for the HAN/PVA/V2O5 and HAN/PVA/Fe2O3 samples.
    Źródło:
    Central European Journal of Energetic Materials; 2021, 18, 3; 322-338
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Simulation of start-up behaviour of a passive autocatalytic hydrogen recombiner
    Autorzy:
    Rożeń, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/146233.pdf
    Data publikacji:
    2018
    Wydawca:
    Instytut Chemii i Techniki Jądrowej
    Tematy:
    catalytic recombination
    computational fluid dynamics
    hydrogen safety
    natural convection
    rekombinacja katalityczna
    obliczeniowa dynamika płynów
    naturalna konwekcja
    Opis:
    Heterogeneous catalytic recombination of hydrogen with oxygen is one of the methods used to remove hydrogen from the containment of a light-water nuclear reactor (LWR). Inside a passive autocatalytic recombiner (PAR), hydrogen and oxygen molecules are adsorbed at catalyst active spots and they recombine to yield water. Heat released in this exothermic reaction creates natural convection of gas in the spaces between the elements supporting a catalyst. Hot and humid gas fl ows upwards into the PAR chimney, while fresh, hydrogen-rich gas enters the PAR from below. Catalytic recombination should start spontaneously at room temperature and low hydrogen concentration. Computational fl uid dynamics (CFD) has been used to study the dynamic behaviour of a plate-type Areva FR-380 recombiner in a quiescent environment for several test scenarios, including different rates of increase in hydrogen concentration and temporary catalyst deactivation. A method for the determination of pressure boundary conditions at the PAR exits was proposed and implemented into a CFD code. In this way, transient operation of PAR could be simulated without the need to model gas circulation outside the device. It was found that fi rst a slow downward fl ow of gas is developed, which may persist until the temperature of the catalyst foils rises. As soon as the gas inside the PAR absorbs enough heat to become lighter than the gas outside the PAR, it starts to fl ow upwards. Criteria for determining the start-up time of PAR were proposed. Model predictions were also compared with experimental data obtained in tests conducted at the THAI facility.
    Źródło:
    Nukleonika; 2018, 63, 2; 27-41
    0029-5922
    1508-5791
    Pojawia się w:
    Nukleonika
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-2 z 2

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