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Tytuł:
Adsorption of Methyl Orange Dye by Modified Fly Ash-Based Geopolymer – Characterization, Performance, Kinetics and Isotherm Studies
Autorzy:
Purbasari, Aprilina
Ariyanti, Dessy
Fitriani, Evi
Powiązania:
https://bibliotekanauki.pl/articles/24201617.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
adsorption
methyl orange
modified fly ash-based geopolymer
CTAB surfactant
cetyltrimethylammonium bromide
Opis:
Geopolymer has been widely used as adsorbent for heavy metals and dyes. Modification on geopolymer surface with cationic surfactant can improve the anion exchange capacity of geopolymer. In this paper, fly ash-based geopolymer had been modified with cetyltrimethylammonium bromide (CTAB) which is cationic surfactant and applied as adsorbent of methyl orange (MO) anionic dye. Modified geopolymer had shown better performance as MO dye adsorbent compared to unmodified geopolymer. The adsorption of MO dye showed the best result at low pH and reached equilibrium after 90 minutes. On the basis of kinetics and isotherm studies, MO dye adsorption by modified geopolymer followed pseudo-second-order model and Langmuir model with maximum adsorption capacity of 19.231 mg∙g-1.
Źródło:
Journal of Ecological Engineering; 2023, 24, 3; 90--98
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical Reduction of Gold(III) Bromide Complexes Using Sodium Nitrite - Kinetic Aspects
Autorzy:
Pacławski, K.
Powiązania:
https://bibliotekanauki.pl/articles/354755.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
kinetics
mechanism
redox
gold complexes
sodium nitrite
Opis:
In this work, the spectrophotometric studies on the kinetics of redox reaction between gold(III) bromide complexes and sodium nitrite, were carried out. From the kinetic curves collected under different conditions of reactants concentration, addition of bromide ions, temperature, pH and ionic strength, corresponding rate constants have been determined. The obtained results suggest the complex path of the [AuBr4]- reduction consisting of two parallel, bimolecular reactions where different reductant species (HNO2 and NO2-) take place and consecutive step with the metallic gold production. The second-order rate constants at 20°C are equal to 2.948 and 0.191 M-1·s-1, respectively. The values of activation enthalpy and activation entropy for the first and the second parallel step of the reaction were found to be ΔH = 29.18 kJ·mol-1 and ΔS = –13.95 J·mol-1·K, and ΔH‡ = 40.75 kJ·mol-1 and ΔS‡ = –31.06 J·mol-1·K, respectively. It was found that the reaction accelerates significantly with the increase of pH and is inhibited with the increase of Br- concentration. The substitutive, inner-sphere mechanism of electron transfer in the studied system was also suggested.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 2; 667-675
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Crystalline structures of Rb2UBr6 ionic conductor determined by neutron diffraction
Autorzy:
Małetka, Krzysztof
Ressouche, Eric
Rundlof, Hakan
Tellgren, Rolland
Szczepaniak, Włodzimierz
Zabłocka-Malicka, Monika
Powiązania:
https://bibliotekanauki.pl/articles/146364.pdf
Data publikacji:
2020
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
neutron diffraction
Ionic conductivity
solid electrolyte
phase transitions
crystalline structure
uranium bromide
Opis:
The neutron powder diffraction technique has been used for structural studies of Rb2UBr6 solid electrolyte as a function of temperature. The low-, room-, and high-temperature structures have been determined. At the temperature range of 4.2–80 K, the compound crystallizes in a monoclinic unit cell in the P21/c space group. At 80 K and 853 K, the compound crystallizes in a tetragonal unit cell in the P4/mnc space group. At 300 K, the lattice constants are a = b = 7.745(1) and c = 11.064(1) Å. At the temperature range of 853–960 K, a trigonal phase is observed in the P–3ml space group.
Źródło:
Nukleonika; 2020, 65, 1; 3-11
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Selective arylation of phenol proteted propygyl bromide via pd-catalysed Suzuki coupling reaction: synthesis, mechanistic studies by DFT calculations and Their Pharmacological Aspects
Autorzy:
farooq, hira
rasool, nasir
Ansari, Muhammad T.
rizwan, komal
mahmood, tariq
israr, hira
Ayub, Khurshid
rasheed, tahir
Zareen, Seema
Akhtar, muhammad N.
iqbal, sarosh
Powiązania:
https://bibliotekanauki.pl/articles/895304.pdf
Data publikacji:
2018-08-31
Wydawca:
Polskie Towarzystwo Farmaceutyczne
Tematy:
biofilm
phenol
DFT
Suzuki coupling
organoboron
Biaryl
Opis:
Biaryls are the potential source of synthetic drugs. The present study describes the synthesis of a series of functionalized biphenyl derivatives (3a-3g) using Pd-catalyzed Suzuki coupling reaction. The experimental results revealed the facile synthesis of biphenyl derivatives (3a-3g) with notably high yield (80-88 %). Density functional theory (DFT) studies were performed by Gaussian 09 software in order to rationalize the selectivity of coupling at C-Br bond instead of C-Cl bond. In addition of synthesis, the biological activities (biofilm inhibition, hemolytic and anti-thrombolytic) of these novel compounds were investigated. These results exhibited good biofilm inhibition (5.86-65.8 %), hemolytic (1.32-30.1 %) and anti-thrombolytic activities (9.64-42.5 %), indicating the potential use of these compounds for pharmaceutical applications.
Źródło:
Acta Poloniae Pharmaceutica - Drug Research; 2018, 75, 4; 911-919
0001-6837
2353-5288
Pojawia się w:
Acta Poloniae Pharmaceutica - Drug Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Thermo-economic analysis and environmental aspects of absorption refrigeration unit operation onboard marine vehicles: RO- PAX vessel case study
Autorzy:
Ammar, N. R.
Sediek, I. S.
Powiązania:
https://bibliotekanauki.pl/articles/260242.pdf
Data publikacji:
2018
Wydawca:
Politechnika Gdańska. Wydział Inżynierii Mechanicznej i Okrętownictwa
Tematy:
ship emissions
IMO
lithium bromide-water ARU
thermodynamic analysis
economic and environmental analysis
Opis:
Marine diesel engines lose a huge amount of fuel heat content in the form of exhaust gas and jacket cooling water, especially onboard high-powered marine vehicles such as Ro-Pax ships. In this paper, the possibility of using the waste heat of marine diesel engines as a source of heat for air conditioning absorption system is investigated. The thermodynamic analysis, in addition to the environmental and economic analysis of the air condition absorption cycle operated with two heat sources using lithium bromide as absorbent, are performed using the Engineering Equation Solver (EES) software. The last 10 years have seen a steady growth in the passenger ferry and Ro-Pax market, with particularly strong growth in passenger numbers. As a case study, a Ro-Pax vessel operating in the Red Sea area is considered, regarding the profitability of using air conditioning absorption system. The results show specific economic benefits of the jacket cooling water operated absorption refrigeration unit (ARU) over the exhaust gas operated unit, with annual costs of capital money recovery of 51,870 $/year and 54,836 $/year, respectively. Environmentally, applying an ARU machine during cruising will reduce fuel consumption by 104 ton/year. This, in turn, will result in reducing NOx, SOx, and CO2 emissions with cost-effectiveness of 7.73 $/kg, 20.39 $/kg, and 0.13 $/kg, respectively.
Źródło:
Polish Maritime Research; 2018, 3; 94-103
1233-2585
Pojawia się w:
Polish Maritime Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Charakterystyka metod zapobiegania powstawaniu bromianów(V) w wodzie przeznaczonej do spożycia
Characteristics of bromate formation prevention methods in water intended for human consumption
Autorzy:
Olsińska, U.
Powiązania:
https://bibliotekanauki.pl/articles/236674.pdf
Data publikacji:
2017
Wydawca:
Polskie Zrzeszenie Inżynierów i Techników Sanitarnych
Tematy:
tap water
bromate formation control
bromide removal
ozonation optimization
water ammonification
H2O2 dosing
woda do spożycia
bromiany
zapobieganie
usuwanie bromków
optymalizacja ozonowania
amonizacja wody
dawkowanie H2O2
Opis:
Bromate content following ozonation of bromide-containing water may range from 0.4 to 60 mgBrO3–/m3. Based on toxicological studies, bromates are classified as potential human carcinogens and are subject to legal regulations in many countries. In Europe, since the 25th of December 2008 their maximum permissible content in water intended for human consumption must not exceed 10 mgBrO3–/m3. As bromates are stable compounds, difficult to remove using conventional water treatment technologies, novel techniques to control their formation in water need to be developed. Technologies meant to control the bromate content in water can be divided into two groups: (1) methods allowing limitation of bromate formation and (2) methods for bromate removal. Methods that may be applied to control the bromate formation in water intended for human consumption are briefly reviewed herein. Evaluation of progress in their development was performed as well as feasibility of their application in water treatment systems was assessed. The review outlines both the well-known methods (e.g. lowering of pH, water ammonification, bromide removal in conventional water treatment processes, operational parameter optimization, multi-stage ozonation, addition of OH radical scavengers, hydrogen peroxide dosing) and the novel ones (e.g. membrane processes for bromide removal, catalytic ozonation, strong oxidant dosing). Selection of an appropriate solution to the problem of increased bromate presence in water should always be preceded by pilot studies. The main reasons include a complex mechanism of bromate formation and simultaneous effect of various water quality indicators on the effectiveness of different bromate formation prevention methods.
Zawartość bromianów(V) po procesie ozonowania wody zawierającej bromki może sięgać od 0,4 mgBrO3–/m3 do 60 mgBrO3–/m3. Na podstawie wyników badań toksykologicznych bromiany(V) zostały zakwalifikowane do grupy potencjalnych kancerogenów i są przedmiotem regulacji prawnych w wielu krajach. W Europie, od 25 grudnia 2008 r., ich maksymalna dopuszczalna zawartość w wodzie przeznaczonej do spożycia nie może przekraczać 10 mgBrO3–/m3. Ponieważ bromiany(V) są związkami trwałymi i trudno usuwalnymi za pomocą konwencjonalnych procesów oczyszczania wody, dlatego niezbędne jest opracowanie nowych technik kontroli ich powstawania w wodzie. Technologie przydatne do kontroli zawartości bromianów(V) w wodzie można podzielić na dwie grupy: (1) metody umożliwiające ograniczenie powstawania bromianów(V), (2) metody usuwania bromianów(V). W pracy omówiono metody, które mogą być wykorzystane do kontroli powstawania bromianów(V) w wodzie przeznaczonej do spożycia przez ludzi. Dokonano także oceny postępu w ich opracowaniu, jak również możliwości ich stosowania w systemach oczyszczania wody. W rozważaniach uwzględniono zarówno metody dobrze znane (np. obniżenie wartości pH wody, amonizacja wody, usuwanie bromków w konwencjonalnych procesach oczyszczania wody, optymalizacja parametrów procesowych, ozonowanie wieloetapowe, dawkowanie akceptorów rodników OH, dawkowanie nadtlenku wodoru), jak i nowsze (zastosowanie technik membranowych do usuwania bromków, ozononowanie katalityczne oraz dawkowanie silnych utleniaczy). Wybór właściwego rozwiązania problemu zwiększonej obecności bromianów(V) w wodzie, ze względu na złożony mechanizm ich tworzenia i jednoczesny wpływ wielu wskaźników jakości wody na skuteczność poszczególnych metod zapobiegania ich powstawaniu, powinien być zawsze poprzedzony badaniami pilotowymi.
Źródło:
Ochrona Środowiska; 2017, 39, 2; 17-26
1230-6169
Pojawia się w:
Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of pH on adsorption and desorption of hexadecyl trimethyl ammonium bromide from silicate surface
Autorzy:
Karaguzel, C.
Xu, Z.
Powiązania:
https://bibliotekanauki.pl/articles/110257.pdf
Data publikacji:
2017
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
adsorption
silica sensor
hexadecyl trimethyl ammonium bromide
quartz crystal micro-balance with dissipation monitoring
Opis:
Hexadecyl trimethyl ammonium bromide (HTAB), a cationic surfactant, is physically adsorbed on negatively charged silicate surfaces due to electrostatic forces. This reversible adsorption process is important for surfactant regeneration in some industrial applications such as waste water treatment. Cationic surfactant adsorption and desorption from silica surfaces were studied using several methods such as UV, FTIR, XPS, and XRD. However, most of these methods are time independent and ex situ in nature. Quartz crystal microbalance with dissipation monitoring (QCM-D) is a power tool that can determine the amount and thickness of the deposited material on the surface in situ as a function of time. In this study, the adsorption and desorption characteristic of HTAB was studied on the silica sensor surface by using QCM-D. The adsorption and desorption tests were performed at a constant HTAB concentration (5·10-4 M, close to CMC of HTAB) at different pH values (3, 5.5, 6.5 and 10). The results obtained from these studies clearly showed that pH is a critical factor determining the adsorption and desorption processes.
Źródło:
Physicochemical Problems of Mineral Processing; 2017, 53, 2; 750-757
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Adsorptive performance of MCM-41 towards hg(II) in water. Adsorption and desorption studies
Autorzy:
Zhai, Q. Z.
Hu, W.-H.
Guo, X.-Y.
Powiązania:
https://bibliotekanauki.pl/articles/208154.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
electron microscopy
mesoporous silicates
cetyltrimethylammonium bromide
adsorption conditions
mikroskopia elektronowa
krzemiany mezoporowate
bromek cetyltrimethylammonium
warunki adsorpcyjne
Opis:
MCM-41 mesoporous material was prepared under a standard conditions by using cetyltrime-thylammonium bromide as a structure-directing agent and tetraethyl orthosilicate as silica source from the liquid phase at 80 °C. Powder X-ray diffraction and scanning electron microscopy used to characterize the product, showed that the MCM-41material had an average particle size of 110 nm. The synthesized material was used to investigate the effects of acidity, adsorption time, the concentration of Hg2+, adsorbent dosage and temperature on the adsorption of Hg2+. The results showed that the optimal adsorptive conditions were: pH 5.0, m(MCM-41):mHg2+ 6.67, temperature 20 °C and contact adsorption time 60 min, for the initial Hg2+concentration of 1.0 mg/cm3. The maximum adsorptive amount of Hg2+ was 56.48 mg Hg2+/g MCM-41. The results of the desorptive effect of three desorption agents such as HCl, HNO3 and HAc showed that the best desorbent was HCl at the concentration of 0.10 mol/dm3. The highest desorption efficiency was 77.21% for the desorption time 2 h.
Źródło:
Environment Protection Engineering; 2016, 42, 1; 5-15
0324-8828
Pojawia się w:
Environment Protection Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of oxidation process of 3-aminotoluene with ozone in presence of manganese bromide catalyst
Issledovanie processa okislenija 3-amino-toluola ozonom v prisutstvii marganec-bromidnogo katalizatora
Autorzy:
Galstyan, A.
Galstyan, G.
Timoshyna, L.
Powiązania:
https://bibliotekanauki.pl/articles/793180.pdf
Data publikacji:
2016
Wydawca:
Komisja Motoryzacji i Energetyki Rolnictwa
Tematy:
oxidation
3-aminotoluene
ozone
sulphuric acid
selectivity
potassium bromide
Źródło:
Teka Komisji Motoryzacji i Energetyki Rolnictwa; 2016, 16, 2
1641-7739
Pojawia się w:
Teka Komisji Motoryzacji i Energetyki Rolnictwa
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preg-robbing of gold in chloride-bromide solution
Autorzy:
Ahtiainen, R.
Lundstrom, M.
Powiązania:
https://bibliotekanauki.pl/articles/110931.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
gold
leaching
pre-robbing
hydrometallurgy
carbon
Opis:
One of the major issue in gold chloride leaching is a tendency of gold to either precipitate or adsorb on a carbonaceous matter in an ore, i.e. preg-robbing. This paper discusses issues related to a preg-robbing phenomenon in gold hydrometallurgy, specifically in gold chloride-bromide leaching. This phenomenon has been observed in the 1800s to decrease gold recovery during gold chlorination as well as the state-of-art of gold cyanidation processes. The experiments were conducted in order to study the preg-robbing phenomenon in chloride-bromide media. The tendency of preg-robbing was demonstrated by adding carbon in a non-preg-robbing ore. It was shown that the preg-robbing tendency in the chloride-bromide media was very strong. Addition of 0.01% w/w of carbon powder into the non-preg-robbing ore decreased gold recovery from 92 to 70% and addition 5% w/w of carbon decreased gold recovery to almost zero.
Źródło:
Physicochemical Problems of Mineral Processing; 2016, 52, 1; 244-251
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Research on solvent systems with tetra-n-butylammonium bromide for counter-current chromatography of betalains
Autorzy:
Spórna-Kucab, A.
Wysoczańska, J.
Bartel, A.
Świergosz, T.
Szot, D.
Wybraniec, S.
Powiązania:
https://bibliotekanauki.pl/articles/115657.pdf
Data publikacji:
2016
Wydawca:
Fundacja na Rzecz Młodych Naukowców
Tematy:
betanin
betalains
tetra-n-butylammonium bromide
high-speed counter-current chromatography
Beta vulgaris L.
betanina
betalainy
bromek tetra-n-butyloamoniowy
HSCCC
Opis:
In this study, new two-phase solvent systems for counter-current chromatography (CCC) consisting of n-butanol and water as well as various amounts of acetic acid, acetonitrile, ethanol, acetone or ethyl acetate were tested. Additionally, tetra-n-butylammonium bromide (TBAB) was introduced into the system in the form of aqueous solutions or phosphate-citrate buffer (pH 6.7) in order to form ion-pairs with betalains. The selection of buffer pH was based on their ability to create ion pairs by tetraalkylammonium salts, with selected betalains under these conditions. In this study, it is shown that the settling time of two phases is longer with the increase of acetic acid/acetonitrile/ethanol/acetone/ethyl acetate. For selected solvent systems with high amounts of acetonitrile, ethanol and acetone two phases were not observed. The systems with acetone have the largest increase of settling time. Ethyl acetate systems were characterized by a slow settling time increase. In systems containing additionally 2% aqueous TBAB, smaller changes in settling time than in similar systems without TBAB were observed. Addition of TBAB in the buffer resulted in a prolongation of settling time. Solvent systems in which the separation between the aqueous and organic phases was visually best, were selected from among all the tested systems and the betalain partition coefficients were measured by LC-DAD-ESI-MS. The best results were observed for systems: n-butanol-water-acetic acid (2:2.5:0.75, v/v/v), n-butanol-water-acetic acid (2:2.5:1, v/v/v) and n-butanol-TBAB in water-acetonitrile (2:2.5:0.5, v/v/v).
Źródło:
Challenges of Modern Technology; 2016, 7, 1; 12-16
2082-2863
2353-4419
Pojawia się w:
Challenges of Modern Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, spectral studies and insect antifeedant activities of some 4-substituted 1-naphthacyl bromide and its esters
Autorzy:
Thirunarayanan, Ganesamoorthy
Powiązania:
https://bibliotekanauki.pl/articles/763926.pdf
Data publikacji:
2016
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
4-substituted 1-naphthacylbromides, 4-substituted 1-naphthacylbenzoates, IR& NMR spectra, Correlation analysis, Insect antifeedant activities
Opis:
About nine 4-substituted 1-naphthacyl bromides and its esters have been synthesized by greener synthetic method using fly-ash catalyzed water mediated reaction.  These acyl bromides and esters have been characterized by their physical constants, Mass, IR and NMR spectral data.  These carbonyl frequencies(cm-1) of existed rotomers of these compounds have been assigned and correlated with Hammett substituent constants, F, R and Swain-Lupton’s parameters.  The insect antifeedant activities of the synthesized acyl bromide and esters have been evaluated using 4th instar larvae Achoea Janatha L.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2016, 71, 2
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ethanol behaviour at the solution-air interface in the presence of Triton X-100 and cetyltrimethylammonium bromide mixture
Autorzy:
Bielawska, Magdalena
Zdziennicka, Anna
Powiązania:
https://bibliotekanauki.pl/articles/764116.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Opis:
On the basis of the surface tension ( LV g ) data of the aqueous solutions of p-(1,1,3,3-tetramethylbutyl)phenoxypoly(ethylene glycol) (Triton X-100 or TX-100) and cetyltrimethylammonium bromide (CTAB) mixture with ethanol published in our previous paper, the process of ethanol adsorption was investigated. For that reason, the values of Gibbs surface excess concentration of ethanol at the solution-air interface and Gibbs standard free energy of its adsorption at that interface were calculated and compared with those determined for the aqueous solutions of ethanol. The surface excess concentration of ethanol at the solution-air interface was calculated with two different methods. The standard free energy of alcohol adsorption was determined from both the Gu and Zhu and Langmuir equations.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2015, 70, 1
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Wpływ stężenia salicylanu sodu na właściwości reologiczne wodnego roztworu bromku heksadecylotrimetyloamoniowego
Effect of sodium salicylate concentration on rheological properties of hexadecylotrimethylammonium bromide aqueous solution
Autorzy:
Kostrzewa, M.
Broniarz-Press, L.
Wierschem, A.
Powiązania:
https://bibliotekanauki.pl/articles/2073010.pdf
Data publikacji:
2014
Wydawca:
Stowarzyszenie Inżynierów i Techników Mechaników Polskich
Tematy:
micele robaczkowe
stężenie przeciwjonu
nieliniowa reologia
micellar solutions
counterion concentration
nonlinear rheology
Opis:
Przedstawiono wyniki badań właściwości reologicznych wodnego roztworu bromku heksadecylotrimetyloamoniowego, ukierunkowane na analizę krzywych lepkości i naprężenia ścinającego w funkcji stężenia dodatku salicylanu sodu. Badane roztwory wykazują silnie nienewtonowski charakter. Wykazano zmiany wewnątrz struktury spowodowane przepływem ścinającym. Również pomiary oscylacyjne wykazały wpływ stężenia przeciwjonu na strukturę i wielkość sieci micelarnych.
Studies on rheological properties of hexadecylotrimethylammonium bromide aqueous solutions with addition of sodium salicylate focused on flow and viscosity curves analysis are presented in the paper. The studied solutions revealed strong non-Newtonian properties. It was proven that shear flow caused structural changes in the micellar network. The dynamical measurements showed an influence of counterion concentration on the structure and size of micellar network.
Źródło:
Inżynieria i Aparatura Chemiczna; 2014, 5; 353--354
0368-0827
Pojawia się w:
Inżynieria i Aparatura Chemiczna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of Properties of Foaming Concentrates Containing Sodium Dodecyl Sulfate (SDS) and Cetyltrimethylammonium Bromide (CTAB) for Rescue and Decontamination Purposes
Porównanie właściwości koncentratów pianotwórczych zawierających dodecylosiarczan sodu (SDS) i bromek cetylotrimetyloamoniony (CTAB) stosowanych do celów ratowniczych i dekontaminacji
Autorzy:
Król, B.
Mizerski, A.
Powiązania:
https://bibliotekanauki.pl/articles/136550.pdf
Data publikacji:
2013
Wydawca:
Szkoła Główna Służby Pożarniczej
Tematy:
wetting
foamability
decontamination
zdolność zwilżania
zdolność pianotwórcza
trwałość pian
Opis:
The paper presents results of the research of two model and one typical foaming concentrates prepared for rescue operations connected with elimination of chemical and biological contamination. Concentrates include 20% (wt) of surfactants, 25% (wt) of solvent (ethylene glycol monobutyl ether), 2% (wt) of foam stabilizer (1-dodecanol) and 53% (wt) of water. Two surfactants were studed: SDS as the component of the K–1 concentrate and CTAB as the component of the K-2 concentrate. The course of surface tension isotherms, the wetting power and the properties of foams generated by use of the pure foaming solutions and by the same solutions with additions of acids (HCl, H2SO4, CH3COOH), bases (KOH, NaOH, Ca(OH)2) and oxidants (H2O2, ClO2) were tested. The K-1 concentrate (with SDS) had twice higher foaming power than the K-2 concentrate (with CTAB). However foam stability measured as the kinetic of solution drainage was much higher in case of foams generated from CTAB based concentrate. In each case foams showed good resistance to acids, bases and oxidants additives. The disadvantage of CTAB based solutions was their low wetting power.
W artykule przedstawiono wyniki badań dwóch modelowych (K-1, K-2) oraz jednego typowego handlowego preparatu pianotwórczego (S). Są one przeznaczone do działań związanych z usuwaniem zagrożeń chemicznych i biologicznych. Badano wpływ dodatków kwasów, zasad oraz utleniaczy na właściwości roztworów środków pianotwórczych (zdolność zwilżania, zdolność pianotwórcza, trwałość pian).
Źródło:
Zeszyty Naukowe SGSP / Szkoła Główna Służby Pożarniczej; 2013, 1, 45; 5-16
0239-5223
Pojawia się w:
Zeszyty Naukowe SGSP / Szkoła Główna Służby Pożarniczej
Dostawca treści:
Biblioteka Nauki
Artykuł

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