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Wyświetlanie 1-6 z 6
Tytuł:
Origin of natural gases in the autochthonous Miocene strata of the Polish Carpathian Foredeep
Autorzy:
Kotarba, M. J.
Powiązania:
https://bibliotekanauki.pl/articles/191377.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
microbial methane
stable carbon isotopes
thermogenic hydrocarbon gases
carbon dioxide
nitrogen
sulphide hydrogen
autochthonous Miocene strata
Polish Carpathian Foredeep
Opis:
Methane concentrations in natural gases accumulated in the autochthonous Miocene strata of the Polish Carpathian Foredeep (between Kraków and Przemyśl) usually exceeded 90 vol%. Methane and part of the ethane were generated during microbial reduction of carbon dioxide in the marine environment, mainly during the sedimentation of Miocene clays and muds. It is possible that this microbial process has continued even recently. Higher light hydrocarbons (mainly propane, butanes and pentanes) were generated during the diagenesis and the initial stage of the low-temperature thermogenic process. Very small changes in the values of geochemical hydrocarbon indices and stable isotope ratios of methane, ethane and propane with depth are evidence for similar gas generation conditions within the whole Badenian and Lower Sarmatian successions. Only in a few natural gas accumulations within the Upper Badenian and Lower Sarmatian reservoirs are thermogenic gases or thermogenic components present, both generated from mixed, type III/II kerogen. These thermogenic gases, now accumulated mainly in the bottom part of Miocene strata, probably resulted from thermogenic processes in the Palaeozoic– Mesozoic basement and then migrated to the Miocene strata along the fault zones. The presence of low hydrogen concentrations (from 0.00 to 0.26 vol%) within the Miocene strata is related to recent microbial processes. Carbon dioxide and nitrogen, which are common minor constituents, were generated in both microbial and low-temperature thermogenic processes. However, CO2 has also undergone secondary processes, mainly dissolution in water during migration. Hydrogen sulphide, which occurs in natural gases of Lower Badenian strata, was most probably generated during microbial sulphate reduction of the Lower Badenian gypsum and anhydrites.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 409-424
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Origin of natural gases in the autochthonous Miocene strata of the Ukrainian Carpathian Foredeep and its Mesozoic basement
Autorzy:
Kotarba, M. J.
Koltun, Y. V.
Powiązania:
https://bibliotekanauki.pl/articles/191381.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
microbial gases
thermogenic gases
stable carbon isotopes
stable hydrogen isotopes
carbon dioxide
nitrogen
Miocene strata
Mesozoic strata
Opis:
Methane concentrations in natural gases accumulated in the Lower and Upper Badenian and Lower Sarmatian reservoirs of the Bilche-Volytsia Unit in the western part of the Ukrainian Carpathian Foredeep usually exceed 96 vol%. Methane was generated by microbial reduction of carbon dioxide in the marine environment. Microbial methane and ethane were produced mainly during sedimentation of Miocene clays and muds. It is possible that this microbial process continues today. Higher light hydrocarbons (ethane in part, and mainly propane, butanes and pentanes) were generated during the diagenesis and the initial stage of the low-temperature, thermogenic processes from Type III and III/II kerogen deposited in Miocene strata and/or Middle and Upper Jurassic basement rocks. Limited variations in the values of geochemical hydrocarbon indices and stable isotope ratios of methane, ethane and propane with the depth indicate similar gas generation conditions within the whole Miocene succession. The microbial gases (methane and partly ethane) generated during microbial processes within the Miocene strata later migrated to the Upper Jurassic and the Upper Cretaceous (Cenomanian) reservoirs of the Mesozoic basement, and to the bottommost Lower Badenian reservoirs of the analysed Letnia, Orkhovychi, Rudky and Vereshchytsia fields. The low hydrogen concentrations within the Miocene strata as well as within the Upper Jurassic and the Upper Cretaceous (Cenomanian) reservoirs of the Mesozoic basement, and within the bottommost Lower Badenian reservoirs are also related to microbial processes. Carbon dioxide and nitrogen, which are common minor constituents, were generated by both microbial and low-temperature thermogenic processes. Moreover, CO2 also underwent secondary processes, mainly dissolution in water, during migration. At least part of the nitrogen accumulated in the Rudky field, which is remarkably high in N2 (96.9 vol%), is probably of atmospheric origin and was introduced to the reservoir by secondary recovery methods.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 425-441
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of hydrocarbon potential of the autochthonous Miocene strata in the NW part of the Ukrainian Carpathian Foredeep
Autorzy:
Kotarba, M. J.
Więcław, D.
Kosakowski, P.
Koltun, Y. V.
Kowalski, A.
Powiązania:
https://bibliotekanauki.pl/articles/191375.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
source rocks
hydrocarbon potential
organic geochemistry
Miocene
Bilche-Volytsia Unit
Ukrainian Carpathian Foredeep
Opis:
The quantity, genetic type, maturity and hydrocarbon potential of dispersed organic matter were determined for the complete sequence of the autochthonous Miocene ranging from the Lower Badenian Sandy-Calcareous Series to the Lower Sarmatian Upper Dashava Formation of the Bilche-Volytsia Unit. Geochemical analyses were conducted on 78 core samples collected from 11 wells in the Ukrainian Carpathian Foredeep between the Ukrainian-Polish state border and the Stryi River. The most favourable source-rock parameters characterize the Upper Badenian Kosiv Formation where the highest TOC contents, from 0.44 to 2.01 wt% (median 0.76 wt%), were found. Only slightly lower values were obtained for the Lower and the Upper Dashava formations – from 0.01 to 1.45 wt% (median 0.72 wt%) and from 0.62 to 0.77 wt% (median 0.71 wt%), respectively. In the Lower Badenian Sandy-Calcareous Series, the Lower Badenian Baraniv beds, and the Upper Badenian Tyras Formation, the TOC content is lower and varies from 0.00 to 0.77 wt%. Immature type III (terrestrial) kerogen dominates the analysed sections of the Kosiv and Dashava formations. Marine organic matter was detected sporadically, and only in the Upper Badenian Kosiv Formation in the vicinity of Kokhanivka, and in the Upper Badenian Kosiv and Tyras formations.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 395-407
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sekwencje depozycyjne w utworach miocenu autochtonicznego w rejonie Brzeska
Depositional sequences of autochthonous Miocene strata in the Brzesko area
Autorzy:
Drozd, A.
Powiązania:
https://bibliotekanauki.pl/articles/1835325.pdf
Data publikacji:
2017
Wydawca:
Instytut Nafty i Gazu - Państwowy Instytut Badawczy
Tematy:
zapadlisko przedkarpackie
miocen autochtoniczny
stratygrafia sekwencji
elementy szelfowej architektury depozycyjnej
Carpathian Foreland Basin
Miocene
sequence stratigraphy
shelf-margin delta
Opis:
Stratygrafia sekwencji jest multikompontentowym narzędziem służącym do odwzorowywania architektury depozycyjnej, środowisk sedymentacji, litofacji i ich przestrzennego rozmieszczenia. Podstawową jednostką wyróżnianą w tej metodzie jest sekwencja depozycyjna, definiowana jako genetyczne następstwo powiązanych ze sobą warstw, ograniczone w spągu i stropie poprzez subaeralne niezgodności lub ich korelatywne zgodności (granic sekwencji), które są wynikiem zmian względnego poziomu morza, towarzyszących wypełnianiu basenów sedymentacyjnych. Przedstawiona próba interpretacji materiałów sejsmicznych, obejmująca mioceńską sukcesję nadewaporatową w rejonie Brzeska, na podstawie założeń tej metodyki i przy wykorzystaniu pomiarów geofizyki otworowej i ich wzajemnym dowiązaniu, pozwoliła na zidentyfikowanie 11 granic sekwencji (SB) i 9 powierzchni maksimum zalewu (MFS). W obrębie tych sekwencji, w zapisie sejsmicznym, karotażowym i w oparciu o dane literaturowe, zinterpretowano elementy architektury depozycyjnej zdominowane litofacją piaskowcową, deponowaną głównie w trakcie niskiego stanu WMP. Zostały one zinterpretowane jako nasypy przyujściowe/bary piaszczyste oraz fragmenty wciętych dolin w strefie szelfu.
Sequence stratigraphy is a multi-component tool for mapping the depositional architecture, sedimentary environments, lithofacies and their spatial distribution. The basic unit of distinction in this method is a depositional sequence, defined as a genetic consequence of interconnected layers, limited in the bottom and top by unconformities or corelative conformities (sequences borders). They are the result of changes in relative sea level that accompanies filling sedimentary basins. The study area included upper Badenian-lower Sarmatian (Miocen) strata in the region of Brzesko. Methodology used in conjunction with well logs and geological data allowed identification in the seismic 11 sequence boundaries (SB) and 9 of the maximum flooding surface (MFS). Within the sequence the elements of depositional architecture were interpreted. They were dominated by sandstone facies that had been deposited mainly during the low state of relative sea level.
Źródło:
Nafta-Gaz; 2017, 73, 12; 928-934
0867-8871
Pojawia się w:
Nafta-Gaz
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Microbial gas system and prospectives of hydrocarbon exploration in Miocene strata of the Polish and Ukrainian Carpathian Foredeep
Autorzy:
Kotarba, M. J.
Peryt, T. M.
Koltun, Y. V.
Powiązania:
https://bibliotekanauki.pl/articles/191552.pdf
Data publikacji:
2011
Wydawca:
Polskie Towarzystwo Geologiczne
Tematy:
microbial gas
thermogenic gas
source rocks
hydrocarbon potential
organic geochemistry
prospectives of hydrocarbon exploration
autochthonous Miocene strata
Bilche-Volytsia Unit
Carpathian Foredeep
SW Poland
Western Ukraine
Opis:
Molecular composition of natural gases accumulated in autochthonous Miocene strata of the Polish and Ukrainian Carpathian Foredeep is dominated by methane, which usually constitutes over 98 vol%. Methane was generated by the carbon dioxide reduction pathway of microbial processes. Ethane was generated both during microbial and thermogenic processes ("oil window") and propane at the initial stage of the low-temperature thermogenic processes, and also by the microbial processes. The rhythmic and cyclic deposition of Miocene clays and sands as well as the vigorous generation of microbial methane caused that the gas produced in claystone beds was accumulated in the overlaying sandstones, and capped, in turn, by the succeeding claystones. Such generation and accumulation system of microbial gases gave rise to the formation of multi-horizontal gas fields. Analysis of the distribution of immature humic dispersed organic matter in the Upper Badenian and Lower Sarmatian sequences indicates that it is practically homogeneous. A migration range of microbial gases was insignificant and locations of their accumulations would depend only on the existence of proper type of traps (compactional anticlines situated above basement uplifts, sealed by the Carpathian Overthrust and/or by faults; stratigraphic pinching out and stratigraphic traps related to unconformities). Another situation is encountered in the south, beneath the Carpathian Overthrust. The thickness of the autochthonous Miocene strata in this area is more than 1,500 metres. Geochemical studies reveal that from a depth of 2,500 metres starts the process of low-temperature thermogenic hydrocarbon generation (“oil window”). At greater depths, more than 7,500 metres, within the autochthonous Lower Miocene basin only the high-temperature methane ("gas window") could be produced and accumulated.
Źródło:
Annales Societatis Geologorum Poloniae; 2011, 81, No 3; 523-548
0208-9068
Pojawia się w:
Annales Societatis Geologorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Potencjał węglowodorowy skał macierzystych i geneza gazu ziemnego akumulowanego w utworach miocenu zapadliska przedkarpackiego w strefie Rzeszowa
Hydrocarbon potential of source rocks and origin of natural gases accumulated in Miocene strata of the Carpathian Foredeep in Rzeszów area
Autorzy:
Kotarba, M. J.
Więcław, D.
Kosakowski, P.
Kowalski, A.
Powiązania:
https://bibliotekanauki.pl/articles/2074398.pdf
Data publikacji:
2005
Wydawca:
Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
Tematy:
zapadlisko przedkarpackie
miocen autochtoniczny
kopalna substancja organiczna
geochemia
potencjał węglowodorowy
gaz ziemny
izotopy trwałe
Carpathian Foredeep
autochthonous Miocene
organic matter
hydrocarbon potential
methane
gas origin
microbial processes
organic geochemistry
stable isotopes
Opis:
In the autochthonous Upper Badenian and Lower Sarmatian strata of the Carpathian Foredeep in the Rzeszów area the total organic carbon (TOC) contents vary from 0.02 to 1.26 wt. %(average 0.64 wt. %). Geochemical studies on the dispersed organic matter demonstrated the presence of gas-prone type III (humic) kerogen with small admixtures of algal type II kerogen. At depths less than 2,500 metres the organic matter is immature, thus microbial processes predominated. Methane concentration in natural gases accumulated within Miocene strata usually exceeded 94 vol. %and was generated by microbial reduction of carbon dioxide. Microbial methane was generated mainly during deposition of autochthonous Miocene sediments, but it is possible that this process continues today on a small scale. Higher gaseous hydrocarbons (mainly ethane and propane), which are usually minor constituents (concentrations less than 0.4 vol. %), were generated during diagenetic processes and at the initial stage of the low-temperature thermogenic processes. The slight changes in the geochemical indices of dispersed organic matter and isotope ratios of natural gases with depth are evidence of the homogeneity of deposition of humic organic matter in shallow marine basin during the Late Badenian and the Early Sarmatian and the fact that similar gas generation conditions can be found in the Miocene sequence. Generation and accumulation of microbial methane and the formation and charging multiple stacked reservoirs within the autochthonous Miocene strata, e.g., Palikówka, Jasionka, Stobierna and Terliczka deposits, was facilitated by rhythmic and cyclic deposition of clays and sands and their very high sedimentation rate.
Źródło:
Przegląd Geologiczny; 2005, 53, 1; 67--76
0033-2151
Pojawia się w:
Przegląd Geologiczny
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-6 z 6

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