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Wyświetlanie 1-15 z 15
Tytuł:
A new basal actinopterygian fish from the Anisian (Middle Triassic) of Luoping, Yunnan Province, Southwest China
Autorzy:
Wen, W.
Zhang, Q.-Y.
Hu, S.-X.
Zhou, C.-Y.
Xie, T.
Huang, J.-Y.
Chen, Z.Q.
Benton, M.J.
Powiązania:
https://bibliotekanauki.pl/articles/21811.pdf
Data publikacji:
2012
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Tematy:
actinopterygian fish
fish
Anisian
Middle Triassic
Luoping
Yunnan Province
China
Actinopterygii
Halecomorphi
Triassic
Opis:
The new neopterygian fish taxon Luoxiongichthys hyperdorsalis gen. et sp. nov. is established on the basis of five specimens from the second member of the Guanling Formation (Anisian, Middle Triassic) from Daaozi Quarry, Luoping, Yunnan Province, Southwest China. The new taxon is characterized by the following characters: triangular body outline with a distinct apex located between skull and dorsal fin; free maxilla; slender preopercular almost vertical; three suborbitals; at least eight strong branchiostegals with tubercles and comb−like ornamentation on the anterior margin; clavicles present; two postcleithra; ganoid scales covered by tubercles and pectinate ornamentation on the posterior margin with peg−and−socket structure; hemiheterocercal tail slightly forked. Comparison with basal actinopterygians reveals that the new taxon has parasemionotid−like triangular symplectics, but a semionotid opercular system. Cladistic analysis suggests that this new genus is a holostean, and either a basal halecomorph or basal semionotiform.
Źródło:
Acta Palaeontologica Polonica; 2012, 57, 1
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A novel polypeptide from Cervus nippon Temminck proliferation of epidermal cells and NIH3T3 cell line
Autorzy:
Guan, Shu-Wen
Duan, Leng-Xin
Li, Yuan-Yuan
Wang, Ben-Xiang
Zhou, Qiu-Li
Powiązania:
https://bibliotekanauki.pl/articles/1041255.pdf
Data publikacji:
2006
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
polypeptide
velvet antler
promoting cell proliferation
Opis:
A novel polypeptide, velvet antler polypeptide (VAPPs), having a stimulary effect on proliferation of some cell was isolated from the velvet antler of sika deer (Cervus nippon Temminck). This polypeptide consists of a single chain of 32 amino-acid residues VLSAT DKTNV LAAWG KVGGN APAFG AEALE RM. VAPPs showed marked stimulary effect on rat epidermal cells and NIH3T3 cell line (dose range from 10-40 mg·L-1 and 5-80 mg·L-1, respectively).
Źródło:
Acta Biochimica Polonica; 2006, 53, 2; 395-397
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of diethylenetriaminepenta pentasodium salt as an eco-friendly depressant to effectively improve the flotation separation of scheelite and calcite
Autorzy:
Zhou, Hepeng
Wu, Handan
Guo, Jiangfeng
Tang, Xuekun
Huang, Wen
Luo, Xianping
Powiązania:
https://bibliotekanauki.pl/articles/27323649.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
flotation
scheelite
calcite
diethylenetriaminepenta pentasodium salt
depressant
adsorption
Opis:
Diethylenetriaminepenta (methylene-phosphonic acid) pentasodium salt (DTPMPA), an eco-friendly reagent, was tried for the first time as a depressant for flotation separation of scheelite from calcite. Micro-flotation tests show that DTPMPA can selectively depress the floatability of calcite. In contrast, DTPMPA barely affects the flotation behavior of scheelite. Based on the selective depress effect, floatation separation of scheelite and calcite can be effectively achieved by using DTPMPA as depressant in artificially mixed minerals flotation tests. Based on a series of measurements, it found the surface of calcite was positively charged due to the existence of Ca ion site, which can be chelated with –PO3H- functional group on the surface of DTPMPA. In the flotation process, DTPMPA can be chemically absorbed on the surface of calcite to inhibit further collector adsorption. On contrast, little DTPMPA was adsorbed on the surface of scheelite due to the spatial site resistance and electrostatic repulsion induced by surface WO42+. All in all, these results exhibit DTPMPA has excellent selective depression ability on calcite, which can be potentially applied in the actual scheelite flotation process.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174718
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Coelacanths from the Middle Triassic Luoping Biota, Yunnan, South China, with the earliest evidence of ovoviviparity
Autorzy:
Wen, W.
Zhang, Q.-Y.
Hu, S.-X.
Benton, M.J.
Zhou, C.-Y.
Tao, X.
Huang, J.-Y.
Chen, Z.-Q.
Powiązania:
https://bibliotekanauki.pl/articles/23008.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Instytut Paleobiologii PAN
Tematy:
coelacanth
Middle Triassic
Triassic
Yunnan province
South China
China
evidence
ovoviviparity
Anisian
Actinistia
Coelacanthoidei
Latimerioidei
Opis:
The fossil record of coelacanths is patchy, with very few taxa known from the Triassic of Asia. We report here two new genera and species of coelacanths from the Luoping Biota, a recently found site of exceptional fossil preservation from Yunnan, South China. The first new taxon, Luopingcoelacanthus eurylacrimalis, is based on four specimens, which to− gether show most aspects of the anatomy. One specimen shows two small coelacanths inside the ventral portion of the ab− dominal cavity, and these are interpreted as intrauterine embryos, close to birth size, based on comparisons with previ− ously reported embryos of the fossil coelacanths Rhabdoderma and Undina, and the extant genus Latimeria. Our new find extends the evidence for ovoviviparity in coelacanths back from the Late Jurassic to the Middle Triassic. The second new taxon, Yunnancoelacanthus acrotuberculatus, is based on one specimen, and differs from Luopingcoelacanthus in the dentary, lachrymojugal, number of rays of the first dorsal fin, and especially in the ornament on dermal bones and scales. Acladistic analysis shows that the new taxa are closest relatives to the derived clade Latimerioidei. The relatively high di− versity of coelacanths in the Early Triassic, and adaptations of living Latimeria to low−oxygen conditions, suggests that the group may have included ‘disaster taxa’ that benefited from anoxic and dysoxic ocean conditions in the aftermath of the end−Permian mass extinction.
Źródło:
Acta Palaeontologica Polonica; 2013, 58, 1
0567-7920
Pojawia się w:
Acta Palaeontologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comprehensive Evaluation Cloud Model for Ship Navigation Adaptability
Autorzy:
Zhu, M.
Wen, Y.
Zhou, C.
Xiao, C.
Powiązania:
https://bibliotekanauki.pl/articles/115973.pdf
Data publikacji:
2014
Wydawca:
Uniwersytet Morski w Gdyni. Wydział Nawigacyjny
Tematy:
cloud computing
Cloud Model
marine navigation
Delphi
Qualitative Description
Quantitative Transformation
Cloud Algorithm
Fuzzy Comprehensive Evaluation Method
Opis:
In this paper, using cloud model and Delphi, we build a comprehensive evaluation cloud model to solve the problems of qualitative description and quantitative transformation in ship navigation adaptability comprehensive evaluation. In the model, the normal cloud generator is used to find optimal cloud models of reviews and evaluation factors. The weight of each evaluation factor is determined by cloud model and Delphi. The floating cloud algorithm is applied to aggregate the bottom level’s evaluation factors, and comprehensive cloud algorithm is used to aggregate the highest level’s evaluation factors to get comprehensive evaluation cloud model. Finally, evaluation result is got by matching comprehensive evaluation cloud model and optimal cloud model of reviews. As case study, the model is applied to the small LNG ship’s navigation adaptability in Southeast Asia. Compared with the fuzzy comprehensive evaluation method, the model proposed in this paper is more intuitive and reliable in comprehensive evaluation of the small LNG ship’s navigation adaptability.
Źródło:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation; 2014, 8, 3; 331-336
2083-6473
2083-6481
Pojawia się w:
TransNav : International Journal on Marine Navigation and Safety of Sea Transportation
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Design wave calculation of a passenger catamaran under multiple load control parameters
Autorzy:
Ge, Shenwei
Ji, Zeng
Jin, Bowen
Zhou, Wen
Qin, Xiaolong
Powiązania:
https://bibliotekanauki.pl/articles/32898725.pdf
Data publikacji:
2022
Wydawca:
Politechnika Gdańska. Wydział Inżynierii Mechanicznej i Okrętownictwa
Tematy:
catamaran
load prediction
equivalent design wave
multiple load control parameters
Opis:
To determine the loading conditions considering the action of both bending and torque moment for a passenger catamaran moving among waves, a method for calculating equivalent design waves under multiple load control parameters was derived based on wave load prediction results using three-dimensional potential flow theory. The method was developed by defining the wave amplitude discrepancy factors between the primary and second load of the combined bending and torquing equivalent design wave. The primary goal was to find a reasonable design wave. Finally, the design waves of a target passenger catamaran ship were calculated using the proposed method, and each load component of every design wave for the target hull was recalculated. The average error compared with the object load component was less than 1%, which verifies the effectiveness of the method and offers an effective engineering evaluation method for a catamaran.
Źródło:
Polish Maritime Research; 2022, 2; 3-11
1233-2585
Pojawia się w:
Polish Maritime Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Diffraction mechanism of five-port transmission gratings
Autorzy:
Gao, Chenhao
Wang, Bo
Wen, Kunhua
Meng, Ziming
Wang, Qu
Nie, Zhaogang
Xing, Xiangjun
Chen, Li
Lei, Liang
Zhou, Jinyun
Powiązania:
https://bibliotekanauki.pl/articles/1835817.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
1 × 5 splitting
single-groove grating
normal incidence
Opis:
This paper designs a five-port transmission grating under normal incidence. Rigorous coupled-wave approach is used to optimize the grating parameters. The energy of the grating is mainly dispersed to the 0th, ±1st and ±2nd orders. The efficiency of each diffraction order under both polarizations is close to 20%. The modal method is used to describe the propagation mechanism of the two polarized lights in the grating, and the diffraction behavior of the grating is analyzed. In addition, the grating has a wide range of incident characteristics and a large process tolerance. Therefore, this five-port beam splitter with a connecting layer will be a good polarization-independent beam splitting device.
Źródło:
Optica Applicata; 2020, 50, 4; 609-618
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effective flotation separation of scheelite and calcite by applying methylene phosphonic acid sodium as a novel and green depressant
Autorzy:
Zhou, Hepeng
Wu, Handan
Guo, Jiangfeng
Tang, Xuekun
Huang, Wen
Luo, Xianping
Powiązania:
https://bibliotekanauki.pl/articles/24086193.pdf
Data publikacji:
2023
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
scheelite
calcite
inhibition mechanism
flotation separation
Opis:
It is known that the flotation separation of scheelite and calcite is quite difficult due to their similar surface properites. To slove the problem, ethylenediaminetetra (methylene phosphonic acid) sodium (EDTMPS), an environmentally friendly reagent, was employed as an efficient depressant for flotation separation of calcite for the first time. In flotation experiments, it demonstrates that EDTMPS could strongly inhibit the flotation of calcite but barely affect the flotaiton behavior of scheelite, showing excellent dpress ability and selectivity. Based on a series of measurements including contact angle analysis, zeta potential, and XPS analysis, it was found that large amout of EDTMPS could be absorbed on the surface of calcite through strong chemical chelation reaction and thus inhibiting the further adsorption of NaOL. On the contrary, little EDTMPS was absorbed on that of scheelite owing to the negatively charged tungstate ions on the surface in relative terms. All in all, these results exhibit EDTMPS has excellent selective inhibition ability on calcite, which can be potentially applied in actual scheelite and calcite flotation separation process.
Źródło:
Physicochemical Problems of Mineral Processing; 2023, 59, 3; art. no. 168517
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Generation of three-port splitter by double-layer grating in second-order Littrow configuration
Autorzy:
Gao, Chenhao
Wang, Bo
Fu, Chen
Fang, Jimin
Wen, Kunhua
Meng, Ziming
Nie, Zhaogang
Xing, Xiangjun
Chen, Li
Lei, Liang
Zhou, Jinyun
Powiązania:
https://bibliotekanauki.pl/articles/174662.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
three-port splitter
second-order Littrow
double-layer grating
Opis:
In this paper, a novel double-layer three-port grating is described. The incident grating structure is in the second-order Littrow configuration. The grating region is composed of fused silica and Ta2O5.The designed grating beam splitter has high efficiency under TE polarization and TM polarization, respectively. The efficiency of two polarizations is more than 90%. In addition, compared with a single-layer three-port grating, this new beam splitter has good fabrication tolerance and incident bandwidth. Therefore, the optimized structure has a good application value.
Źródło:
Optica Applicata; 2020, 50, 2; 271-280
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Observation and Modelling on the Shipping Noise in Shallow Waters with Complex Islands and Reefs of the East China Sea
Autorzy:
Peng, Zilong
Zhou, Fulin
Fan, Jun
Wang, Bin
Wen, Huabing
Powiązania:
https://bibliotekanauki.pl/articles/1953475.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czasopisma i Monografie PAN
Tematy:
shipping noise
spectral source level
noise mapping
shallow water
merchant ship
Opis:
The impact of the noise radiated from merchant ships on marine life has become an active area of research. In this paper, a methodology integrating observation at a single location and modelling the whole noise field in shallow waters is presented. Specifically, underwater radiated noise data of opportunistic merchant ships in the waters of Zhoushan Archipelago were collected at least one day in each month from January 2015 to November 2016. The noise data were analyzed and a modified empirical spectral source level (SSL) model of merchant ships was proposed inspired by the RANDI-3 model (Research Ambient Noise Directionality) methodology. Then combining the modified model with the realistic geoacoustic parameters and AIS data of observed merchant ships, the noise mappings in this area were performed with N × 2D of Normal Mode calculations, in which the SSL of each ship was estimated using the modified model. The sound propagation at different receiving positions is different due to the shielding effect of islands and bottom topography. The methodology proposed in this paper may provide a reference for modelling shipping noise in shallow waters with islands and reefs.
Źródło:
Archives of Acoustics; 2021, 46, 2; 301-311
0137-5075
Pojawia się w:
Archives of Acoustics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polyamine plays a role in subculture growth of in vitro callus of indica rice
Autorzy:
Tan, Yanping
Hu, Wen
Xu, Xin
Zhou, Jie
Wang, Chuntai
Liu, Xuequn
Cheng, Gang
Powiązania:
https://bibliotekanauki.pl/articles/952026.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
browning
callus
gene expression
indica rice
polyamine
Opis:
In vitro embryogenic callus is a critical factor for genetic transformation of rice, especially for indica varieties. In this study, we investigated the relationship between polyamines, including putrescine (Put), spermidine (Spd) and spermine (Spm), and callus browning, and we studied the effect of exogenous Put on callus regeneration and on the content of endogenous polyamines. In addition, the expression levels of arginine decarboxylase gene (Adc1) and S-adenosylmethionine decarboxylase gene (Samdc) in embryogenic callus were studied by quantitative Real-time PCR analysis. The results showed that the contents of endogenous Put and Spd in the browning callus were significantly lower than those in normal callus. Exogenous Put could effectively improve the growing state of callus of indica rice and enhance the development of embryogenic callus. The content of endogenous polyamines in embryogenic callus, especially Spd and Spm, was increased after addition of exogenous Put. Additionally, exogenous Put also had an obvious impact on the expression levels of Adc1 but partial effect on the expression levels of Samdc gene. This study could increase the knowledge of both embryogenic callus induction and polyamine catabolism in callus in indica rice.
Źródło:
Acta Biologica Cracoviensia. Series Botanica; 2017, 59, 1
0001-5296
Pojawia się w:
Acta Biologica Cracoviensia. Series Botanica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Protective effects of cassia seed ethanol extract against carbon tetrachloride-induced liver injury in mice
Autorzy:
Xie, Qing
Guo, Fang-Fang
Zhou, Wen
Powiązania:
https://bibliotekanauki.pl/articles/1039746.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Biochemiczne
Tematy:
carbon tetrachloride
cassia seed extract
antioxidant
CYP2E1
hepatoprotective effects
Opis:
Oxidative stress has been recognized as a critical pathogenetic mechanism for the initiation and the progression of hepatic injury in a variety of liver disorders. Antioxidants, including many natural compounds or extracts, have been used to cope with liver disorders. The present study was designed to investigate the hepatoprotective effects of cassia seed ethanol extract (CSE) in carbon tetrachloride (CCl4)-induced liver injury in mice. The animals were pre-treated with different doses of CSE (0.5, 1.0, 2.0 g/kg body weight) or distilled water for 5 days, then were injected intraperitoneally with CCl4 (0.1% in corn oil, v/v, 20 ml/kg body weight), and sacrificed at 16 hours after CCl4 exposure. The serum aminotransferase activities, histopathological changes, hepatic and mitochondrial antioxidant indexes, and cytochrome P450 2E1 (CYP2E1) activities were examined. Consistent with previous studies, acute CCl4 administration caused great lesion to the liver, shown by the elevation of the serum aminotransferase activities, mitochondria membrane permeability transition (MPT), and the ballooning degeneration of hepatocytes. However, these adverse effects were all significantly inhibited by CSE pretreatment. CCl4-induced decrease of the CYP2E1 activity was dose-dependently inhibited by CSE pretreatment. Furthermore, CSE dramatically decreased the hepatic and mitochondrial malondialdehyde (MDA) levels, increased the hepatic and mitochondrial glutathione (GSH) levels, and restored the activities of superoxide dismutase (SOD), glutathione reductase (GR), and glutathione S-transferase (GST). These results suggested that CSE could protect mice against CCl4-induced liver injury via enhancement of the antioxidant capacity.
Źródło:
Acta Biochimica Polonica; 2012, 59, 2; 265-270
0001-527X
Pojawia się w:
Acta Biochimica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sperm quality and DNA integrity of coke oven workers exposed to polycyclic aromatic hydrocarbons
Autorzy:
Jeng, Hueiwang Anna
Pan, Chih-Hong
Chao, Mu-Rong
Chiu, Chien-Chih
Zhou, Guodong
Chou, Chon-Kit
Lin, Wen-Yi
Powiązania:
https://bibliotekanauki.pl/articles/2168377.pdf
Data publikacji:
2016-11-18
Wydawca:
Instytut Medycyny Pracy im. prof. dra Jerzego Nofera w Łodzi
Tematy:
DNA damage
semen quality
sperm
DNA integrity
DNA fragmentation
bulky DNA adducts
Opis:
Objectives The objective of this study was to assess sperm quality and deoxyribonucleic acid (DNA) integrity of coke oven workers exposed to polycyclic aromatic hydrocarbons (PAHs) as compared to control subjects. Material and methods The coke oven workers (N = 52) and administrative staff (N = 35) of a steel plant served as the exposed and control groups, respectively. Exposure to PAHs was assessed by measuring 1-hydroxypyren. Analysis of sperm quality (concentration, motility, vitality, and morphology) was performed simultaneously with sperm DNA integrity analysis, including DNA fragmentation, denaturation, bulky DNA adducts, and 8-oxo-7,8-dihydro-2’-deoxyguanosine (8-oxo-dGuo). A questionnaire was conducted to collect demographic and potential confounding data. Results The coke oven workers had lower percentages of sperm motility, vitality and normal morphology than the control group, but the difference was not significant. For DNA integrity, the coke oven workers had significantly higher concentrations of bulky DNA adducts and 8-oxo-dGuo than the control subjects (p = 0.009 and p = 0.048, respectively). However, DNA fragmentation percentages did not significantly increase as compared to those in the subjects from the control group (p = 0.232). There was no correlation between sperm quality parameters and DNA integrity indicators. Conclusions Occupational exposure of the coke oven workers to PAHs was associated with decreased sperm DNA integrity. Int J Occup Med Environ Health 2016;29(6):915–926
Źródło:
International Journal of Occupational Medicine and Environmental Health; 2016, 29, 6; 915-926
1232-1087
1896-494X
Pojawia się w:
International Journal of Occupational Medicine and Environmental Health
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on recovery of iron and sulfur from high-sulfur magnetite ore
Autorzy:
Zhao, Yongqiang
Zhou, Wen-tao
Sun, Tichang
Ahmadzai, Asadullah
Powiązania:
https://bibliotekanauki.pl/articles/2146914.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
high-sulfur magnetite
pyrrhotite flotation
magnetic separation
mixed collectors
Opis:
In this paper, to produce a saleable magnetite concentrate with a sulfur level below 0.20% and recover sulfur concentrate, flotation and magnetic separation tests were undertaken. Results showed that the optimum conditions of flotation were established as follows: grinding fineness of 90% particles passing 0.074mm, pH 6, 400 g/t of CuSO4, and 400 g/t of combined collectors. Under these conditions and magnetic separation, S grade of the magnetite concentrate was reduced from 3.20% to 0.18%, and the Fe grade improved from 57.29% to 71.17%. At the same time a sulfur concentrate with S grade of 38.05% and recovery of 91.32% was also obtained. The XPS results showed that the addition of CuSO4 benefited the formation of hydrophobic Sn2-/S0 and Cu+-xanthate, enhancing pyrrhotite floatability. The flotation separation efficiency could be enhanced using a mixture of collectors, and collector mixture demonstrated three synergetic effects, namely enhanced S recovery, improved adsorption behavior of the collectors and enhanced hydrophobicity of pyrrhotite surface.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 4; art. no. 150889
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on safe disposal of cephalosporins based on kinetic pyrolysis mechanism
Autorzy:
Fan, Jiangxue
Zhang, Meng
Hou, Xiaofei
Wang, Fang
Bai, Mengyuan
Jiao, Ruoxi
Yang, Zhongyu
Duan, Erhong
Cheng, Fengfei
Zhou, Wen
Powiązania:
https://bibliotekanauki.pl/articles/27315672.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Distillation residues
Thermal analysis kinetics
Template “3-2-2”
Template “1+1”
Pyrolysis mechanism
Opis:
Based on the global goals for cleaner production and sustainable development, the pyrolysis behavior of cephalosporin residues was studied by TG-MS method. The influence of full temperature window on the safe disposal of residues was analyzed based on the “3-2-2” and “1+1” of thermal analysis kinetics, and the gas by-products of thermal degradation were monitored. Results showed that the pyrolysis of distillation residues were divided into low and high-temperature zones, including six stages. Maximum error rate (8.55%) by multiple scan rate was presented based on “3-2-2” pattern and maximum total fluctuation (33.7) by single scan rate was presented based on “1+1” pattern, which implied that the comprehensive multi-level comparison method was very reliable. The E value “E” of six stages showed an increasing trend ranging 166.8 to 872.8 kJ/mol. LgA(mean) was 27.28. Most mechanism function of stage 1, 2 were Z-L-T equation (3D), stage 3, 4, 6 were Avrami-Erofeev equation (AE3, AE4, AE2/3) and stage 5 was Reaction Order (O2). In addition, various small molecular micromolecule substances were detected such as C2H4O, C2H6, NH3, CH4, CO2 under full temperature windows and a possible pyrolysis path of residues was provided.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 4; 52--60
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-15 z 15

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