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Tytuł:
Global transcriptome analysis reveals genes associated with seedling advance growth traits in a selfed family of Chinese fir (Cunninghamia lanceolata)
Autorzy:
Deng, H.
Hu, D.
Wei, R.
Yan, S.
Wang, R.
Zheng, H.
Powiązania:
https://bibliotekanauki.pl/articles/2130183.pdf
Data publikacji:
2022
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
Chinese fir
selfing
RNA-Seq
growth trait
hub gene
Opis:
Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.) is a major timber conifer species in southern China. In this study, we aimed to capture the rarely advanced phenomenon for selfing in this species and illustrated the underlying molecular mechanism, especially the hub gene-regulated networks and pathways, by global transcriptome analysis assays (RNA-Seq). Self-pollination trials revealed a wide variation of selfing effects among parents. Parent cx569 produced a selfed family with the best growth performance at the seedling stage. The growth-based extremely advanced (AD) (n=3) and depressed (DE) variants (n=3; different types) were then subjected to comparative RNA-Seq. The transcriptome data revealed more than 5000 differentially expressed genes (DEGs) for each comparison group (AD versus DE). Weighted gene co-expression network analysis (WGCNA) further identified more than 80 important DEGs that were significantly associated with growth traits in each comparison group. A subsequent enrichment analysis showed that the identified DEGs belonged to six main types, including xylem metabolism-related, sugar and energy metabolism-related, plant hormone signal transduction-related, stress response-related, cytochrome-related, and transcription factor genes. Ten hub genes represented by the ERF071, MYB-relate 305, WRKY6, WRKY31, PER3, LAC4, CESA8, CESA9, GID1, and PR1 genes were co-identified between AD and DE variants. These genes exhibited rather different expression patterns between AD and DE variants, especially of the transcription factor ERF071 gene that presented a low transcript level in the AD seedlings with only 4.45% activity compared to DE's. While, the plant hormone signal transduction GID1 gene was significantly upregulated in AD by about 20-fold when compared to DE's, and fold change of the lignin biosynthesis-related PER3, CESA9 and LAC4 gene expression parallel reached to 10–15 times in an upregulation pattern in AD seedlings. The set of hub gene-linked interaction networks and pathways revealed in this study may be responsible for the rarely advanced phenomenon for selfing at the seedling stage in Chinese fir.
Źródło:
Dendrobiology; 2022, 87; 27-46
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fatigue life prediction for Ni-based superalloy GH4169 considering machined surface roughness and residual stress effects
Autorzy:
Wu, Z. R.
Wang, S. Q.
Yang, X.
Pan, L.
Song, Y. D.
Powiązania:
https://bibliotekanauki.pl/articles/1839712.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Mechaniki Teoretycznej i Stosowanej
Tematy:
surface roughness
residual stress
fatigue crack
life prediction
GH4169
Opis:
Establishing a fatigue life prediction model considering the machined surface state is of great significance to improve fatigue life prediction accuracy. Fatigue tests with different machined surface states of GH4169 alloy were conducted firstly. The influence of surface state parameters on the fatigue life was analyzed. Then, the machined surface stress concentration factor and residual stress were introduced into the fatigue crack initiation and propagation models. Finally, the fatigue life prediction model of GH4169 material considering the surface states was established. The prediction results based on the proposed model are almost within a factor of two scatter band of the test results.
Źródło:
Journal of Theoretical and Applied Mechanics; 2021, 59, 2; 215-226
1429-2955
Pojawia się w:
Journal of Theoretical and Applied Mechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Revealing the core transcriptome modulating plant growth phase in Arabidopsis thalianaby RNA sequencingand coexpression analysis of the FHY3 FAR1 mutant
Autorzy:
Wang, W.
Zhao, G.
Wu, S.
Hua, W.
Zhang, T.
Ruan, R.
Cheng, Y.
Powiązania:
https://bibliotekanauki.pl/articles/2130692.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Botaniczne
Tematy:
weekly transcriptome analysis
plant development
different expression genes
(DEGs)
immune response
Opis:
Plants must continually calibrate their growth in response to the environment throughout their whole life cycle. Revealing the regularity of plant early growth and development is of great significance to plant genetic modification. It was previously demonstrated that loss of two key light signaling transcription factors, FHY3 and FAR1, can cause a stunted stature in the plant adult stage, and numerous defense response genes can be continuously activated. In this study, we performed a time-course transcriptome analysis of the early 4 weeks of leaf samples from wild plants and their fhy3 and far1 transcription factors. By comparative transcriptome analysis, we found that during the early 4 weeks of plant growth, plants primarily promoted morphogenesis by organizing their microtubules in the second week. In the third week, plants began to trigger large- scale defense responses to resist various external stresses. In the fourth week, increased photosynthetic efficiency promoted rapid biomass accumulation. Weighted gene coexpression network analysis of FHY3 and FAR1 revealed that the two light signaling transcription factors may be originally involved in the regulation of genes during embryonic development, and in the later growth stage, they might regulate gene expression of some defense-related genes to balance plant growth and immunity. Remarkably, our yeast two-hybrid and bimolecular fluorescence complementation experiments showed that FAR1 interacts with the immune signaling factor EDS1. Taken together, this study demonstrates the major biological processes occurring during the early 4 weeks of plant growth. The light signaling transcription factors, FHY3 and FAR1, may integrate light signals with immune signals to widely regulate plant growth by directly interacting with EDS1.
Źródło:
Acta Societatis Botanicorum Poloniae; 2020, 89, 2
0001-6977
2083-9480
Pojawia się w:
Acta Societatis Botanicorum Poloniae
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Climate response of Salix oritrepha growth along a latitudinal gradient on the northeastern Tibetan Plateau
Autorzy:
Lu, X.
Sigdel, S.R.
Dawadi, B.
Wang, Y.
Powiązania:
https://bibliotekanauki.pl/articles/2077745.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
shrub
radial growth
climate sensitivity
dendrochronology
summer temperature
Opis:
Shrubs are widespread at higher altitudes and latitudes. Dendrochronology of shrub growth has been intensively studied in the circumpolar Arctic, Mediterranean and Patagonia. However, relatively little is known about shrub growth responses to climate change on the Tibetan Plateau. Herein, we investigate climate sensitivity of Salix oritrepha growth along a north–south (35–39° N) latitudinal gradient on the north- eastern Tibetan Plateau. Four S. oritrepha shrub sites were selected for dendrochronology study. Pearson and partial correlation analyses were used to estimate strength of the climate sensitivity of the growth time series at each site. We found that not all of the site chronologies show consistent variations. Despite of this, its ra- dial growth was primarily limited by the July mean temperature across the latitudinal gradient, and warming summer climate tends to increase the growth of S. oritrepha on the northeastern Tibetan Plateau.
Źródło:
Dendrobiology; 2019, 81; 14-21
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Isolation and sequence analysis of the complete VP2 gene of canine parvovirus from Chinese domestic pets and determination of the pathogenesis of these circulating strains in beagles
Autorzy:
Chen, M.R.
Guo, X.Y.
Wang, Z.Y.
Jiang, Y.T.
Yuan, W.F.
Xin, T.
Hou, S.H.
Song, T.Q.
Lin, W.D.
Zhu, H.F.
Jia, H.
Powiązania:
https://bibliotekanauki.pl/articles/2087542.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
canine parvovirus
molecular epidemiology
phylogenetic analysis
pathogenesis
Źródło:
Polish Journal of Veterinary Sciences; 2019, 2; 287-296
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Development of a rapid immunochromatographic assay for detection of antibodies against porcine epidemic diarrhea virus
Autorzy:
Li, R.
Ma, J.
Tian, X.
Yu, Y.
Qiao, S.
Wang, Z.
Powiązania:
https://bibliotekanauki.pl/articles/2087760.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
porcine epidemic diarrhea virus
immunochromatographic test strip
nucleocapsid protein
diagnosis
Źródło:
Polish Journal of Veterinary Sciences; 2018, 21, 1; 139-147
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Expression analysis of multifunctional RNA-binding protein hnRNP K during development of mammalian testis
Autorzy:
Xu, H.
Zhang, P.
Li, R.
Wu, W.
Wang, S.
Xu, Y.
Powiązania:
https://bibliotekanauki.pl/articles/2087724.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
hnRNP K
testis development
spermatogenesis
pig
rat
Źródło:
Polish Journal of Veterinary Sciences; 2018, 21, 2; 343-352
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modeling the ecosystem response to summer coastal upwelling in the Northern South China Sea
Autorzy:
Jiang, R.
Wang, Y.-S.
Powiązania:
https://bibliotekanauki.pl/articles/47804.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Instytut Oceanologii PAN
Tematy:
nutrient
phytoplankton
zooplankton
ecosystem model
coastal upwelling
hydrographic condition
seasonal change
sea surface temperature
South China Sea
Opis:
A coupled three-dimensional physical model and a nitrogen-based nutrient, phytoplankton, zooplankton, and detritus (NPZD) ecosystem model were applied to simulate the summer coastal upwelling system over the continental shelf of northern South China Sea (NSCS) and its impact on hydrographic conditions and ecosystem. The simulated results were comprehensively validated against field and satellite measurements. The model results show that the near shore ecosystem of NSCS has significant responses to the summer coastal upwelling system. The Shantou Coast to the Nanri Islands of Fujian province (YD) and the east of the Leizhou Peninsula (QD) are two main regions affected by NSCS summer coast upwelling. During summer, these two coastal areas are characterized by nearshore cold and high salinity upwelling current. Further, the summer coastal upwelling serves as a perfect nutrient pump, which lifts up and advects nutrient-rich current from deep to surface, from inner shelf to about 30 km outer shelf. This nutrient source reaches its maximum in the middle of July and then begins to decrease. However, the maximum phytoplankton and chlorophyll a do not coincide with the maximum nutrients and delay for about 10 days. Because of the intensive seasonal thermocline and the complicated current transporting through Qiongzhou strait, the ecological responding of QD is less pronounced than YD. This study has a better understanding of the physically modulated ecological responses to the NSCS summer coastal upwelling system.
Źródło:
Oceanologia; 2018, 60, 1
0078-3234
Pojawia się w:
Oceanologia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Monte Carlo based angular analysis of multiple scattered photons for underwater optical imaging
Autorzy:
Li, S.
Wang, R.
Chen, G.
Powiązania:
https://bibliotekanauki.pl/articles/173322.pdf
Data publikacji:
2018
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
underwater imaging
turbid media
Monte Carlo method
multiple scattering
Opis:
Image contrast and visibility associated with underwater optical imaging systems are usually degraded by the absorbing and scattering effects of turbid waters. To improve the image contrast, laser-range-gate has been widely applied to underwater optical imaging systems. The work of Katsev et al. (Appl.Opt. 38(33), 1999, pp. 6849–6858) shows that the contrast of a shadow image is greater than that of the object image. The present paper outlines a Monte Carlo based simulation method of image formation for underwater optical imaging. It is found that the contrast of a shadow image varies with gate starting depths. The angular distribution of multiply scattered photons is obtained via semi-analytical models (Shengfu Li et al., Opt.Commun. 381, 2016, pp. 43–47). The simulated results show that increasing the gate starting depth can reduce the highly backscattered photons, thus can improve the image contrast.
Źródło:
Optica Applicata; 2018, 48, 2; 237-247
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Acer truncatum seedlings are more plastic than Quercus variabilis seedlings in response to different light regimes
Autorzy:
Guo, X.
Wang, R.-Q.
Wang, C.D.
Xu, F.
Zhao, S.
Guo, W.-H.
Powiązania:
https://bibliotekanauki.pl/articles/41339.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
Acer truncatum
seedling
Quercus variabilis
Chinese cork oak
plant response
light regime
irradiance acclimation
chlorophyll fluorescence
morphology
photoinhibition
Opis:
In this study, we investigated responses of the mid-successional species Acer truncatum Bunge and the late-successional species Quercus variabilis Blume to three solar illumination conditions: (1) constant low light (CL), (2) constant high light (CH) and (3) low light first and high light afterwards (LH). The last treatment was to simulate a canopy opening. Both species exhibited increases in biomass, totally and in part, and decreases in leaf water content, specific leaf area and chlorophyll concentrations in LH treatment compared to CL treatment. For A. truncatum, exposure to high light condition (LH) increased crown area, and decreased root to shoot ratio, stem mass ratio and leaf perimeter. However, for Q. variabilis, LH treatment increased stem diameter at ground height, effective quantum yield, photochemical quenching and decreased maximum photosystem II quantum yield. The biomass allocation pattern did not change in Q. variabilis among three light conditions. With respect to newly developed leaves, no significant differences were found in leaf size of Q. variabilis between LH treatment and CH treatment while that of A. truncatum decreased in LH treatment. All chlorophyll fluorescence parameters in newly developed oak leaves in LH treatment increased compared to those of CH treatment while no difference was found for A. truncatum between LH and CH treatment. A. truncatum displayed a greater overall plasticity than Q. variabilis although the oak seedlings have a greater plasticity with respect to chlorophyll concentration and chlorophyll fluorescence parameters. A. truncatum should be a better candidate for vegetation recovery, especially in places with heterogeneous light conditions.
Źródło:
Dendrobiology; 2016, 76
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Neuromedin S on the proliferation of splenic lymphocytes and the cytokine secretion by pulmonary alveolar macrophages in pigs in vitro
Autorzy:
Lin, R.
Wang, Q.
Qi, B.
Huang, Y.
Yang, G.
Powiązania:
https://bibliotekanauki.pl/articles/30295.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Opis:
Neuromedin S (NMS), a 36-amino acid neuropeptide, has been found to be involved in the regulation of the endocrine activity. It has been also detected in immune tissues in mammals, what suggests that NMS may play an important role in the regulation of immune response. The aim of this study was to demonstrate the presence of NMS receptor 1 (NMU1R) and effect of NMS in pig splenic lymphocytes (SPLs) and pulmonary alveolar macrophages (PAMs). The presence of NMU1R in pig SPLs and PAMs was respectively confirmed by reverse transcription-polymerase chain reaction (RT-PCR), western blot analysis and immunocytochemical methods. Furthermore, SPL proliferation was analyzed using the 3-(4,5)-dimethyl-thiahiazo-(-2-yl)-3,5-di-phenytetrazoliumromide (MTT) method. Additionally, the secretion of interleukin (IL)-1β, IL-6 and tumor necrosis factor-α (TNF-α) in PAMs was all measured by enzyme-linked immunosorbent assay (ELISA) kits. In the present study, the results of RT-PCR and western blot analysis revealed that NMU1R mRNA and protein were both expressed in pig SPLs and PAMs, and the immunocytochemical investigations further revealed that the positive signal of NMU1R immunoreactivity was observed in plasma membranes of both SPLs and PAMs. In the in vitro study, we found that at concentrations of 0.001-1000 nM NMS alone or combined with lipopolysaccharide or phytohemagglutinin significantly increased SPL proliferation. Application of ELISA method showed that NMS could induce the secretion of the pro-inflammatory cytokines IL-1β, IL-6 and TNF-α in PAMs. These results suggest that NMS can act as a potently positive pro-inflammatory factor and immunomodulatory agent that affects the immune response of immune cells by combining with its receptor NMU1R.
Źródło:
Polish Journal of Veterinary Sciences; 2016, 19, 3
1505-1773
Pojawia się w:
Polish Journal of Veterinary Sciences
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Software Startups – A Research Agenda
Autorzy:
Unterkalmsteiner, M.
Abrahamsson, P.
Wang, X. F.
Nguyen-Duc, A.
Shah, S.
Bajwa, S. S.
Baltes, G. H.
Conboy, K.
Cullina, E.
Dennehy, D.
Edison, H.
Fernandez-Sanchez, C
Garbajosa, J.
Gorschek, T.
Klotins, E.
Hokkanen, L.
Kon, F.
Lunesu, I.
Marchesi, M.
Morgan, L.
Oivo, M.
Selig, C.
Seppänen, P.
Sweetman, R.
Tyrväinen, P.
Ungerer, C.
Yagüe, A.
Powiązania:
https://bibliotekanauki.pl/articles/953060.pdf
Data publikacji:
2016
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
software startup
research agenda
software-intensive systems
Opis:
Software startup companies develop innovative, software-intensive products within limited time frames and with few resources, searching for sustainable and scalable business models. Software startups are quite distinct from traditional mature software companies, but also from micro-, small-, and medium-sized enterprises, introducing new challenges relevant for software engineering research. This paper’s research agenda focuses on software engineering in startups, identifying, in particular, 70+ research questions in the areas of supporting startup engineering activities, startup evolution models and patterns, ecosystems and innovation hubs, human aspects in software startups, applying startup concepts in non-startup environments, and methodologies and theories for startup research. We connect and motivate this research agenda with past studies in software startup research, while pointing out possible future directions. While all authors of this research agenda have their main background in Software Engineering or Computer Science, their interestin software startups broadens the perspective to the challenges, but also to the opportunities that emerge from multi-disciplinary research. Our audience is therefore primarily software engineering researchers, even though we aim at stimulating collaborations and research that crosses disciplinary boundaries. We believe that with this research agenda we cover a wide spectrum of the software startup industry current needs.
Źródło:
e-Informatica Software Engineering Journal; 2016, 10, 1; 89-123
1897-7979
Pojawia się w:
e-Informatica Software Engineering Journal
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Vibrational Properties of Sundatang Soundboard
Autorzy:
Batahong, R. Y.
Dayou, J.
Wang, S.
Lee, J.
Powiązania:
https://bibliotekanauki.pl/articles/176904.pdf
Data publikacji:
2014
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sundatang
frequency response function
impact testing
mode shape
Opis:
This paper presents the measurement of vibrational properties of sundatang soundboard. Sundatang is a plucked stringed traditional musical instrument that is popular among the Kadazandusun communities in Sabah, Malaysia. The vibrational properties of the soundboard are measured using CADA-X impact hammering system in a condition where the instrument is without any string. There are two types of sundatang used in this study; one made from acacia and the other from vitex wood. In this measurement, frequency response functions (FRFs) and modal parameters of the top plate and back plate of this instrument are obtained. It is found that in free edge, fundamental frequency of both plates of acacia sundatang is greater than the vitex sundatang in a range of 112 Hz to 230 Hz. However, in clamped edge (attached to its ribs), it was modified to a lower frequency and closer to each other in the range of 55 Hz to 59 Hz. Another finding is the detection of the excitation of similar mode shape at different resonance frequencies. This phenomenon is termed as Different State of Mode (DSM) which is observed may be because the number of testing points is not enough. Findings of this study provide important information to the study of quality development of this instrument.
Źródło:
Archives of Acoustics; 2014, 39, 2; 177-187
0137-5075
Pojawia się w:
Archives of Acoustics
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of CCHP in deep mine thermal hazard control
Zastosowanie systemu trójgeneracji w systemie kontroli zagrożeń termicznych w kopalni głębinowej
Autorzy:
Yang, D. D.
Wang, B. S.
Zhou, S. G.
Qin, R. X.
Powiązania:
https://bibliotekanauki.pl/articles/348684.pdf
Data publikacji:
2012
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
Tematy:
system trójgeneracji
kopalnia o wysokiej metanowości
kontrola zagrożeń cieplnych
chłodzenie absorpcyjne
CCHP
high gas mine
thermal hazard control
absorption refrigeration
Opis:
Due to the characteristics of high gas, high geothermal temperature and high strength development in Huainan mine area, thermal hazard problem has become more and more serious and also affects safety and productivity in coal mine. The CCHP (combined cooling heating and power), as a new mode to control thermal hazard, is put forward after advantages and disadvantages of all kinds of cooling methods are investigated. The CCHP method not only takes full advantage of gas but also reduces the greenhouse gas emission. At the same time, the application of CCHP remits the pressure of the power supply in summer, providing guarantee for safe and high efficiency exploitation.
W związku z wysoką gazonośnością, wysoką temperaturą pierwotną górotworu i wysokimi wartościami zawartości metanu w kopalni Huainan zaobserwowano zagrożenia natury cieplnej, wpływające również na bezpieczeństwo i wydajność produkcji w kopalni. Po zbadaniu wad i zalet różnych metod klimatyzacji podjęto decyzję o wprowadzeniu systemu trójgeneracji jako nowego sposobu kontroli zagrożeń natury cieplnej. Metoda trójgeneracji nie tylko wykorzystuje pełen potencjał ujętego gazu, ale również pozwala obniżyć emisję gazów cieplarnianych. Zastosowanie tego systemu zmniejsza ponadto pobór energii zasilającej w porze letniej, dając gwarancję bezpiecznej i wydajnej eksploatacji kopalni.
Źródło:
AGH Journal of Mining and Geoengineering; 2012, 36, 3; 443-451
1732-6702
Pojawia się w:
AGH Journal of Mining and Geoengineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Oxidation of a lignin model compound of benzyl-ether type linkage in water with H2O2 under an oxygen atmosphere catalyzed by Co(Salen)
Utlenianie modelowego związku ligniny z typem wiązania benzylowo-eterowego w wodzie z H2O2 w atmosferze tlenu katalizowane Co(Salen)
Autorzy:
Zhou, X.F.
Qin, J.X.
Wang, S.R.
Powiązania:
https://bibliotekanauki.pl/articles/52363.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Technologii Drewna
Tematy:
oxidation
lignin model compound
benzyl-ether type
linkage
water
oxygen atmosphere
cobalt salen complex
catalytic property
analytical technique
veratrylglycerol-beta-guaiacyl-alpha,gamma-dimethylether
Opis:
The catalytic properties of Cobalt salen? complex in the oxidation of a lignin model compound [veratrylglycerol-β-guaiacyl-α,γ-dimethylether, VGD] have been investigated in order to obtain the mechanistic aspects of the reaction between Co(salen) and VGD under an oxygen atmosphere using hydrogen peroxide as an oxidant. VGD was found to undergo structural changes in response to the catalytic reaction as characterised by different analytical techniques (FT-IR, H-1 NMR and GC-MS), yielding 2-methoxy phenol and biphenyl. A mechanism for the oxidation of VGD was postulated.
Zbadano katalityczne właściwości kompleksu Co(Salen) w utlenianiu modelowego związku ligniny (veratrylglycerol-β-guaiacyl-α,γ-dimetyleter, VGD) w celu określenia mechanicznych aspektów reakcji pomiędzy Co(salen) i VGD w atmosferze tlenu przy zastosowaniu nadtlenku wodoru jako utleniacza. Zaobserwowano, że w VGD zaszły zmiany strukturalne w odpowiedzi na reakcję katalityczną, co przedstawiono za pomocą różnych technik analitycznych (FTIR, H-1 NMR oraz GC-MS). W efekcie otrzymano 2-metoksy fenol i bifenyl.
Źródło:
Drewno. Prace Naukowe. Doniesienia. Komunikaty; 2011, 54, 186
1644-3985
Pojawia się w:
Drewno. Prace Naukowe. Doniesienia. Komunikaty
Dostawca treści:
Biblioteka Nauki
Artykuł
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