Wszystkie pola: WO3/TiO2 - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Effect of WO3 on the morphology and photodegradation of dimethyl phthalate of TiO2 nanotube array photoelectrode
Autorzy:: Xin, Y.
Wang, G.
Liu, Y.
Zang, Z.
Gao, M.
Powiązania:: https://bibliotekanauki.pl/articles/206886.pdf
Data publikacji:: 2018
Wydawca:: Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:: degradation
esters
morphology
scanning electron microscopy
tungsten
water treatment
degradacja
estry
morfologia
skaningowa mikroskopia elektronowa
wolfram
oczyszczalnia ścieków
Opis:: WO₃ modified TiO₂ nanotube array (WO₃/TNAs) photoelectrodes were fabricated via electrochemical deposition on TNAs/Ti photoelectrodes. The morphology and structure of WO₃/TNAs photoelectrodes were investigated by scanning electron microscopy (SEM) and X-ray diffractometer (XRD). The effects of deposition potential, deposition duration, NaWO₄ concentration, and calcination temperature on the morphology and the photocatalytic activity were investigated. The results showed that suitable amounts of WO₃ promoted the photocatalytic activity of TNAs photoelectrodes for the degradation of dimethyl phthalate (DMP). The optimal conditions for the fabrication of WO₃/TNAs photoelectrodes were as follows: deposition voltage 3.0 V, 10 min deposition duration, 0.01 mol/dm³ Na₂WO₄ concentration, 1.5 cm electrode gap, and 550 °C annealing temperature. The degradation rate of DMP reached 77% after 60 min of illumination by WO₃/TNAs photoelectrode. Additionally, WO₃/TNA photoelectrodes possessed superb stability for maintaining a high DMP degradation efficiency at more than 75% after 10 times of successive use with 60 min irradiation for each cycle. The enhancement of photocatalytic performance by the efficient combination of WO₃ with TNAs would provide a theoretical basis for the practical application of WO₃/TNA photoelectrodes in water treatment.
Źródło:: Environment Protection Engineering; 2018, 44, 3; 129-139
0324-8828
Pojawia się w:: Environment Protection Engineering
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 2.

Tytuł:: Photocatalytic mineralisation of humic acids using TiO2 modified by tungsten dioxide/ hydrogen peroxide
Autorzy:: Tryba, B.
Piszcz, M.
Borowiak-Paleń, E.
Grzmil, B.
Morawski, A. W.
Powiązania:: https://bibliotekanauki.pl/articles/779747.pdf
Data publikacji:: 2012
Wydawca:: Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:: kwasy humusowe
WO3/TiO2
powstawanie rodników
humic acids photodecomposition
OH radicals formation
Opis:: TiO2 of anatase structure was modified by tungsten dioxide and H2O2 in order to obtain WO3-TiO2 photocatalyst with enhanced photocatalytic activity under both, UV and artificial solar light irradiations. WO2 was dissolved in 30% H2O2 and mixed with TiO2 in a vacuum evaporator at 70°C. Such modified TiO2 was dried and then calcinated at 400 and 600°C.The prepared samples and unmodified TiO2 were used for the photocatalytic decomposition of humic acids (Leonardite standard IHSS) in the aqueous solution under irradiations of both, UV and artificial solar light. Modification of TiO2 with tungsten dioxide and H2O2 improved separation of free carriers in TiO2 which resulted in the increase of OH radicals formation. Calcination caused an increase of anatase crystals and higher yield in OH radicals. The uncalcined samples showed high abilities for the adsorption of HA. Combination of adsorption abilities and photocatalytic activity of photocatalyst caused that the uncalcined TiO2 modified with WO2/H2O2 showed the shortest time of HA mineralisation. The mineralisation of HA under the artificial solar light was much lower than under the UV. It was proved that, although OH radicals are powerful in the decomposition of HA, adsorption can facilitate the contact of the adsorbed molecules with the photocatalyst surface and accelerate their photocatalytic decomposition.
Źródło:: Polish Journal of Chemical Technology; 2012, 14, 2; 54-61
1509-8117
1899-4741
Pojawia się w:: Polish Journal of Chemical Technology
Dostawca treści:: Biblioteka Nauki

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Skocz do pozycji: 3.

Tytuł:: Natural sun-light assisted photocatalytic and electrocatalytic activity of WO3-TiO2 novel nanomaterial
Autorzy:: Kamalakkannan, J.
Balraj, N.
Powiązania:: https://bibliotekanauki.pl/articles/1157041.pdf
Data publikacji:: 2018
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: Photocatalysis
Reusability
Sun light
Opis:: The WO3-TiO2 novel nanomaterial was synthesized by precipitation method and sonication technique. The nanomaterial for the degradation of malachite green (MAG) dye under natural sun light irradiation. The synthesized nanomaterial is characterized by HR-SEM with EDX, PL and UV-Vis DRS analysis. The photodegradation of MAG at various parameters are reported. The mechanisms of dye degradation in natural sun light explain the higher photocatalytic activity of the catalyst. The result indicates the advantage of wastewater treatment by it. The electrochemical study from DSSC analysis showed increased current by WO3-TiO2 nanomaterial. It was proposed that the catalyst was found to be stable and reusable.
Źródło:: World Scientific News; 2018, 94, 2; 276-286
2392-2192
Pojawia się w:: World Scientific News
Dostawca treści:: Biblioteka Nauki

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