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Tytuł:
Extraction of rubidium ion from brine solutions by dicyclohexano-18-crown-6 / ionic liquid system
Autorzy:
Huang, Dongfang
Ma, Guixiang
Lv, Peng
Zhou, Quanbao
Powiązania:
https://bibliotekanauki.pl/articles/2204138.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Rubidium
Ionic liquid
Dicyclohexano-18-crown-6
Solvent extraction
Opis:
Separation among rubidium and potassium ions from salt lake brines remains challenging. In this work, a typical room temperature ionic liquid 1-ethyl-3-metyhlimidazaolium bis(trifluoromethylsulfonyl)imide ([C2mim+][NTf2-]) was used as diluent and synergistic extractant, dicyclohexano-18-crown-6 (DCH18C6) was used as extractant to extract rubidium ions from brine solutions which contain high concentrations of potassium ions was investigated. Under the optimal conditions, the single extraction efficiency of rubidium ions was up 93.63%. The thermodynamic parameters of the rubidium ion extraction were obtained. Based on the slope analysis method, the extracted species in the organic phase were ascertained as 1:1 complex. UV-visible has been performed to investigate the ion concentration of ionic liquid before and after the interaction of metal ions and ligands. Rubidium ions in [Rb · DCH18C6]+ complex were stripped by 2.5 mol · L–1 NH4NO3. The extraction system offers high efficiency, simplicity and environmentally friendly application prospect to separate rubidium from brine solutions.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 1; 61--68
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Extraction of rubidium and cesium from brine solutions using a room temperature ionic liquid system containing 18-crown-6
Autorzy:
Huang, D.
Zheng, H.
Liu, Z.
Bao, A.
Li, B.
Powiązania:
https://bibliotekanauki.pl/articles/779994.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Rubidium
Cesium
Ionic liquid
18-crown-6
Solvent extraction
Opis:
Application of 1-butyl-3-metyhlimidazaolium hexafl uorophosphate ([C4mim][PF6 ]), in the extraction of rubidium and cesium from brine solutions using 1,4,7,10,13,16-hexaoxacyclooctadecane (18C6) as extractant was investigated. Parameters that affect the extraction including pH of aqueous phase, equilibration time, dosage of the ionic liquid, phase ratio, concentration of 18C6 were studied. Under the optimal conditions, the single extraction effi ciency of rubidium ions and cesium ions were up 84.11% and 94.99%, respectively. The stripping of alkali metal ions from the loaded organic phase with different stripping agents and concentrations were also investigated. The initial value of the K/Cs and K/Rb ratios were 93.0 and 104.3, respectively, which have dropped 91.21% and 88.01%, respectively, after the extraction and stripping experiments. It was taken a big step in the separation and enrichment of cesium (rubidium) ion and potassium ion. The extraction mechanism was revealed most likely to be a cation exchange mode in this system.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 2; 40-46
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Excitations and Decays of Rubidium Rydberg States Induced by Blackbody Radiation
Autorzy:
Glukhov, I.
Chernushkin, V.
Powiązania:
https://bibliotekanauki.pl/articles/1791217.pdf
Data publikacji:
2009-10
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Opis:
The rates of excitations and decays induced by blackbody radiation were calculated in the single-electron Fues' model potential approach for states up to n = 100 in rubidium s-, p- and d-series. On the basis of the calculations, general regularities for maxima rates of blackbody radiation induced decays and excitations were ascertained and a simple polynomial-based approximation formula was proposed for blackbody radiation induced decay and excitation rates of Rydberg states. A temperature parameterization for T = 50-1500 K was also proposed and respective matrices of coefficients were calculated.
Źródło:
Acta Physica Polonica A; 2009, 116, 4; 532-534
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Temperature-and-Spectral Deformations of the Optical Indicatrix of Rubidium Sulphate Single Crystal
Autorzy:
Gaba, V.
Powiązania:
https://bibliotekanauki.pl/articles/1550356.pdf
Data publikacji:
2010-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
77.84.Fa
78.20.Ci
77.80.Bh
Opis:
The paper deals with newly investigated temperature-and-spectrum dependences of principal birefringences (Δ $n_{i}$(λ,T)-i=X, Y, Z; λ=250÷850 nm; T = 4.2-1100 K), and temperature dependence of the optic-axial angle (2V(T) - T=4.2-1100 K) for two laser lines 632.8 nm and 441.1 nm of $Rb_{2}SO_{4}$ crystals. Based on the temperature dependence of the optic-axial angle, the second point of birefringence sign inversion has been found. Newly obtained is the temperature-and-spectrum diagram of the uniaxial state of the optical indicatrix at the "isotropic points" and in the hexagonal phase of $Rb_{2}SO_{4}$. Based on the temperature behavior of the birefringence and optic-axial angle it was supposed that hexagonal-orthorhombic phase transition in rubidium sulfate can be a second-order phase transition. Found is the inversion of birefringence dispersion in the X and Y directions at 400 K and 620 K, respectively.
Źródło:
Acta Physica Polonica A; 2010, 117, 1; 129-132
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Three-Colour Excitation of D$\text{}_{1}$ Transition in Cold Rubidium Atoms
Autorzy:
Alhasan, A. M.
Powiązania:
https://bibliotekanauki.pl/articles/2047289.pdf
Data publikacji:
2007-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
42.50.Gy
42.50.Hz
42.65.-k
Opis:
We analyse the three-colour electromagnetically induced transparency for the D$\text{}_{1}$ transition in cold $\text{}^{87}$Rb atoms. We report an enhancement of the electromagnetically induced emission of a drive field as an exclusive enhancement of the third- and fourth-rank components of the density matrix. Moreover, the gain experienced by the drive field is attributed to the influence of the quantum switching effect on the increased absorption of the probe field. The electromagnetically induced emission effect is employed to generate slow light Gaussian-wave trains with shape preserving. These soliton trains were not only generated in the drive channel as has been designated but also in the switch channel which reveals multiple-light storage phenomenon.
Źródło:
Acta Physica Polonica A; 2007, 111, 3; 299-321
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The SW-MSA calculation of self-diffusion coefficients in liquid lithium and rubidium
Autorzy:
Dubinin, N.
Powiązania:
https://bibliotekanauki.pl/articles/1075357.pdf
Data publikacji:
2016-03
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.20.Gy
61.20.Ne
61.25.Mv
66.10.C-
Opis:
Successfully used recently for liquid Na and K the approach combined the linear trajectory approximation with the square-well model in the semi-analytical representation of the mean spherical approximation to calculate the self-diffusion coefficients is applied here to liquid Li and Rb. As well as earlier for Na and K, the results obtained are found to be in reasonable agreement with the available experimental data and confirm previous conclusion that the square-well model within the mean spherical approximation is quite useful for description of diffusion properties in liquid alkali metals.
Źródło:
Acta Physica Polonica A; 2016, 129, 3; 310-312
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Transmission characteristics of 85Rb and 87Rb laser-induced dichroism atomic filters at 795 nm
Autorzy:
Peng, Y F
Zhang, W J
Powiązania:
https://bibliotekanauki.pl/articles/173843.pdf
Data publikacji:
2014
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
atomic filter
optical anisotropy
narrowband
rubidium
Opis:
The transmission characteristics for 85Rb and 87Rb laser-induced dichroism atomic filters operating on rubidium D1 lines (795 nm) transitions are analyzed. By means of semiclassical density matrix equations of motion, a three-level model for the transmission characteristics of the ground state laser-induced dichroism atomic filter is presented. Calculative results show that this filter, using two counterpropagating pump and probe beams, can obtain higher transmission, narrower bandwidth and larger tuning capability than that using two copropagating pump and probe beams; with the aid of counterpropagating pump, the 85Rb ground state laser-induced dichroism atomic filter can be more effective to achieve higher peak transmission (>34%) and larger tunability (>1 GHz) than the 87Rb ground state laser-induced dichroism atomic filter in the same operation parameters. This result may be helpful for improving peak transmission (14.6%) of Rb ground state laser-induced dichroism atomic filter reported (CERÈ A. et al., Opt. Lett. 34(7), 2009, pp. 1012–1014).
Źródło:
Optica Applicata; 2014, 44, 1; 55-67
0078-5466
1899-7015
Pojawia się w:
Optica Applicata
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of altered homeostasis on mammary gland rubidium concentrations in dogs
Wpływ zaburzonej homeostazy na zawartość rubidu w gruczole sutkowym suk
Autorzy:
Skibniewska, E.M.
Skibniewski, M.
Kosla, T.
Powiązania:
https://bibliotekanauki.pl/articles/15079.pdf
Data publikacji:
2013
Wydawca:
Uniwersytet Warmińsko-Mazurski w Olsztynie / Polskie Towarzystwo Magnezologiczne im. Prof. Juliana Aleksandrowicza
Opis:
Rubidium is an alkaline metal with exceptional chemical activity. Together with lithium, sodium, potassium and cesium, it belongs to group I of the periodic table of elements. The aim of this study was to provide data on the rubidium content in normal mammary gland tissue and adenocarcinomas and to elucidate the effects of altered homeostasis on this element in the course of mammary gland neoplastic disease in dogs. The investigation was performed to confirm the hypothesis put forward in human research that this metal is cumulated in neoplastic tumours of the mammary gland. The research material included post mortem collected healthy mammary glands of bitches and mammary gland neoplastic tumours obtained during routine surgical treatments as well as during necropsies. The content of rubidium was determined by the inductively coupled plasma mass spectrometry (ICP-MS) method. The highest rubidium content was observed in the tissues with neoplastic lesions, where it averaged 10.72 mg kg–1 wet mass. In the healthy tissues, the content of this metal was on a much lower level. The mean rubidium concentration in mammary glands without pathological changes was 1.91 m kg–1 wet mass. The statistical analysis showed a significant difference (P=0.01) in the rubidium content between the investigated groups. Higher rubidium concentrations were observed in the tissues with neoplastic lesions. This phenomenon is similar to disturbances of the ionic balance observed in the case of breast cancer in women.
Źródło:
Journal of Elementology; 2013, 18, 4
1644-2296
Pojawia się w:
Journal of Elementology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of Uniaxial Pressure on the Refractive Properties of Rubidium Tetrachlorine Zincanate Crystals
Autorzy:
Stadnyk, V.
Gaba, V.
Kohut, Z.
Popel, O.
Powiązania:
https://bibliotekanauki.pl/articles/1550379.pdf
Data publikacji:
2010-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.44.Fw
77.84.Fa
78.20.Ci
Opis:
The effect of uniaxial pressure ($σ_m$ ≤ 200 bar) on the spectral (300-800 nm) and temperature (77-300 K) dependences of the refractive indices of $Rb_{2}ZnCl_{4}$ crystals are investigated. The baric dependences of the electron polarizability, specific refraction and the parameters involved in the Sellmeier formula are calculated.
Źródło:
Acta Physica Polonica A; 2010, 117, 1; 136-138
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Target preparation of RbCl on a copper substrate by sedimentation method for the cyclotron production of no-carrier-added 85Sr for endotherapy
Autorzy:
Sadeghi, M.
Alipoor, Z.
Kakavand, T.
Powiązania:
https://bibliotekanauki.pl/articles/148632.pdf
Data publikacji:
2010
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
rubidium chloride
target
sedimentation
radionuclide
Opis:
85Sr was produced via the 85Rb(p,n)85Sr reaction. Rubidium chloride deposition on copper substrate was carried out via the sedimentation method in order to produce strontium-85. Optimum conditions were achieved as a result of several repeated experiments with different amount of ethyl cellulose (EC) and acetone. 520 mg of RbCl, 208 mg of EC 4 mL of acetone were used to prepare a layer of enriched rubidium chloride of 11.69 cm2 area and 62.2 mg/cm2 thickness. Target quality control was done by a SEM photomicrograph and a thermal shock test. The deposited target was irradiated at a 20 ěA current and a 15 MeV proton beam for 30 min. No degradation was observed. The RbCl surface following bombardment was white, except the central area that was light brown and also without any crack or peeling off.
Źródło:
Nukleonika; 2010, 55, 3; 303-306
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Zeeman Coherences Narrowing due to Ramsey Effects Induced by Thermal Motion of Rubidium Atoms
Autorzy:
Grujić, Z.
Mijailović, M.
Panić, B.
Minić, M.
Kovačević, A.
Obradović, M.
Jelenković, B.
Cartaleva, S.
Powiązania:
https://bibliotekanauki.pl/articles/1814392.pdf
Data publikacji:
2007-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
42.50.Gy
32.70.Jz
Opis:
We investigated effects of spatially separated laser fields on amplitudes and widths of electromagnetically induced transparency in M-type atomic system. We have shown narrowing of the electromagnetically induced transmission resonance and therefore enhancement of medium non-linearities that can be explained by diffusion-induced Ramsey narrowing. Depending on the polarization of two laser beams, narrow probe Hanle transmission resonance changes its sign in respect of the profile obtained when the pump laser beam is off.
Źródło:
Acta Physica Polonica A; 2007, 112, 5; 799-803
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Production, quality control and initial imaging studies of [82mRb]RbCl for PET studies
Autorzy:
Rowshanfarzad, P.
Jalilian, A.
Kiyomarsi, M.
Sabet, M.
Karimian, A.
Moradkhani, S.
Mirzaii, M.
Powiązania:
https://bibliotekanauki.pl/articles/146165.pdf
Data publikacji:
2006
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
rubidium-82m
quality control
animal study
cyclotron
Opis:
Rubidium-82m was prepared via 15.4 MeV proton irradiation of a krypton-82 gaseous target (30% enrichment). Washing the target chamber with hot water yielded a Rb-82m containing solution, which was further purified using short column chromatography in order to remove organic/inorganic impurities. The flowthrough was formulated in normal saline for injection. Radionuclide, radiochemical and chemical purity tests were performed prior to administration to rats for imaging (radiochemical yield: 95-97%, radiochemical purity > 97%). Preliminary dual-head coincidence studies were performed to determine the distribution of [82mRb]Rb in normal rats. For biodistribution studies, Rb-81 was injected to rats and tracer accumulation in heart, GI and bladder was determined after sacrification in time intervals. A yield of 1.3 GBq at EOB, 235.7 MBq/mAh was obtained.
Źródło:
Nukleonika; 2006, 51, 4; 209-215
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
All-Optical Magnetometer Based on Resonant Excitation of Rubidium Atoms by Frequency Modulated Diode Laser Light
Autorzy:
Cartaleva, S.
Karaulanov, T.
Petrov, N.
Slavov, D.
Vaseva, K.
Yanev, A.
Mijailovic, M.
Grujic, Z.
Jelenkovic, B. M.
Powiązania:
https://bibliotekanauki.pl/articles/2047842.pdf
Data publikacji:
2007-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
42.50.Gy
07.55.Ge
Opis:
Magnetic field and its gradient measurements based on coherent population trapping resonances at the D$\text{}_{1}$ line of $\text{}^{87}$Rb are performed by means of coupling two ground-state Zeeman sublevels belonging to different hyperfine levels to a common excited state. Two coherent laser fields with frequency difference of 6.8 GHz are used. They are produced by direct current modulation of a diode laser. The resonance splitting and broadening caused by the applied magnetic field is measured by scanning the laser modulation frequency around the ground-state hyperfine frequency.
Źródło:
Acta Physica Polonica A; 2007, 112, 5; 871-876
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High pure, carrier free 85Sr and 83Rb tracers obtained with AIC-144 cyclotron
Autorzy:
Misiak, R.
Gaca, P.
Bartyzel, M.
Mietelski, J.
Powiązania:
https://bibliotekanauki.pl/articles/148437.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
AIC-144 cyclotron
carrier free tracers
environmental radioactivity
ion-exchange chromatography
rubidium-83
strontium-82
strontium-85
Opis:
The method of obtaining carrier free tracers, 85Sr and 83Rb from proton-irradiated natRbCl target is described. The separation of the radionuclides was done using Sr-Resin, the resin based on a crown ether. Current and some other possible applications of the tracers are discussed.
Źródło:
Nukleonika; 2003, 48, 3; 151-153
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural, Mechanical and Thermodynamic Properties Under Pressure Effect of Rubidium Telluride: First Principle Calculations
Autorzy:
Bidai, K.
Ameri, M.
Ameri, I.
Bensaid, D
Slamani, A.
Zaoui, A.
Al-Douri, Y.
Powiązania:
https://bibliotekanauki.pl/articles/354182.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Anti-fluorite: Rb2Te; FP-LAPW; GGA
structural properties
thermodynamics properties
elastic constants
Opis:
First-principles density functional theory calculations have been performed to investigate the structural, elastic and thermodynamic properties of rubidium telluride in cubic anti-fluorite (anti-CaF2-type) structure. The calculated ground-state properties of Rb2Te compound such as equilibrium lattice parameter and bulk moduli are investigated by generalized gradient approximation (GGA-PBE) that are based on the optimization of total energy. The elastic constants, Young’s and shear modulus, Poisson ratio, have also been calculated. Our results are in reasonable agreement with the available theoretical and experimental data. The pressure dependence of elastic constant and thermodynamic quantities under high pressure are also calculated and discussed.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2A; 865-871
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 19

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