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Wyszukujesz frazę "RuCl2(PPh3)3" wg kryterium: Wszystkie pola


Wyświetlanie 1-1 z 1
Tytuł:
A study of ruthenium-based catalysts used in homogeneous transfer hydrogenation of acetophenone
Autorzy:
Mikołajczyk, Filip
Kamiński, Kamil
Powiązania:
https://bibliotekanauki.pl/articles/185307.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ruthenium-based catalysts
transfer hydrogenation
ketones
catalysis
RuCl2(PPh3)3
katalizatory na bazie rutenu
przeniesienie uwodornienia
ketony
kataliza
RuCl2 (PPh3) 3
Opis:
A detailed comparison of catalytic properties of two different ruthenium-based catalysts in the reaction of homogeneous hydrogenation of acetophenone was performed. Additionally, methods of synthesis of both catalysts were tested and optimized in order to achieve the best possible quality and purity of the final catalysts. NMR analysis was used to analyze and identify the composition of ruthenium compounds and gas chromatography was used to analyze the conversion rate of hydrogenation reactions. It was determined that RuCl2(PPh3)3 obtained with a modified method described by Shaw’s group (Shawet al., 2007) had the best catalytic properties in the reaction performed under conditions described in Liang Wang’s publication (Wang et al., 2014). It was also determined that for concentration ratio of substrate to RuCl2(PPh3)3 amounting to 250:1 the conversion rate was much higher than that of the reaction performed with a double dose of the catalyst. Results of experiments also show that samples of the post-reaction solution should be analyzed right after the reaction, because even if they are stored in low temperature the amount of product can change up to 3–5% compared to the base sample and this change is not predictable. These findings have significant implications for further research of the reaction of homogeneous transfer hydrogenation of ketones. With the right catalysts and methods of their synthesis other parameters of this reaction can be optimized. The most important one is a change of solvent from isopropyl alcohol to a less toxic substance like water. This may increase the value of the reaction in green chemistry and chemical industry.
Źródło:
Chemical and Process Engineering; 2019, 40, 2; 213--222
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-1 z 1

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