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    Wyświetlanie 1-9 z 9
    Tytuł:
    Removal of Ni(II) Ions by Citric Acid-Functionalised Aloe vera Leaf Powder – Characterisation, Kinetics, and Isotherm Studies
    Autorzy:
    Al-Amrani, Waheeba Ahmed
    Abdullah, Rohaizan
    Megat Hanafiah, Megat Ahmad Kamal
    Suah, Faiz Bukhari Mohd
    Powiązania:
    https://bibliotekanauki.pl/articles/24201761.pdf
    Data publikacji:
    2023
    Wydawca:
    Polskie Towarzystwo Inżynierii Ekologicznej
    Tematy:
    Aloe vera
    biosorption
    isotherm
    nickel
    wastewater
    Opis:
    Aloe vera leaves (AVL), a by-product of agricultural waste, have been applied as a biosorbent for reducing Ni(II) ions in aqueous solutions. The biosorption capability of AVL powder was enhanced through chemical treatment with 0.10 M citric acid solution. Fourier-transform infrared (FTIR) spectrophotometer, scanning electron microscope coupled with energy dispersive X-ray (SEM-EDX), pH of point-zero-charge (pHPZC), and pHslurry analyses were used to study the surface, and chemical properties of citric acid-treated Aloe vera leaf powder (CAAVLP). The setting for experiments such as pH solution, CAAVLP dose, initial concentration, and biosorption time was investigated. Maximum Ni(II) ion biosorption capability was determined to be 48.65 mg/g based on the Langmuir model at pH 6, a CAAVLP dose of 0.02 g, initial Ni(II) concentrations of 5 to 50 mg/L and biosorption time of 120 min. The data for the isotherm and kinetics were well matched with the Freundlich and pseudo-second-order models, respectively, with high regression correlation (R2) and low chi-square (χ2) values. The presence of more-COOH groups after treating AVL with citric acid resulted in more Ni(II) ions being able to be removed.
    Źródło:
    Journal of Ecological Engineering; 2023, 24, 4; 217--227
    2299-8993
    Pojawia się w:
    Journal of Ecological Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Removal of Ni(II) ions from aqueous solutions using manganese oxide nanoparticles from buffelgrass, Cenchrus ciliaris L., as green adsorbent. Kinetics and thermodynamic studies
    Autorzy:
    Kiruba, Dunston Angeline
    Muthukumaran, Karpagasundaram
    Thamarai, Perumal
    Powiązania:
    https://bibliotekanauki.pl/articles/2057616.pdf
    Data publikacji:
    2022
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    Cenchrus ciliaris L.
    ecosystem
    Langmuir isotherm
    Freundlich isotherm
    heavy metals
    ekosystem
    izoterma Langmuira
    izoterma Freundlicha
    metale ciężkie
    Opis:
    Manganese oxide nanoparticles (MnONPs) synthesized from buffelgrass, Cenchrus ciliaris (L.), an invasive weed posing threats to ecosystems, are used in this study to remove nickel(II) ions from aqueous solutions. As a biosorbent, the synthesized MnONPs were put to the test. MnONPs were studied for their surface morphology and functional properties. A variety of adsorbent dosages and contact times were tested in batch experiments to see how they affected adsorption rates. At pH 6.0 and room temperature, MnONPs had an 87.1% removal efficiency for Ni(II) ions. Pseudo-second order correlations had a higher R2 value (0.988). In the Langmuir plot, a maximum adsorption capacity of 4.78 mg/g was observed. However, the experimental data fitted well with both Langmuir and Freundlich isotherm models (R2 = 0.99). Spontaneous and exothermic was the nature of the adsorption process. To remove heavy metal ions contaminants from aqueous solutions, these results suggested that MnONPs synthesized from buffelgrass extract could be used.
    Źródło:
    Environment Protection Engineering; 2022, 48, 1; 135--149
    0324-8828
    Pojawia się w:
    Environment Protection Engineering
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Separation of Co(II), Cu(II), Ni(II) and Mn(II) from synthetic hydrochloric acid leaching solution of spent lithium ion batteries by solvent extraction
    Autorzy:
    Nguyen, Viet Nhan Hoa
    Lee, Man Seung
    Powiązania:
    https://bibliotekanauki.pl/articles/1449331.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    spent lithium-ion batteries
    divalent metal ions
    solvent extraction
    separation
    Opis:
    Spent lithium ion batteries contain valuable critical metals such as cobalt, copper, lithium and nickel. In order to develop a process for the separation of the divalent metal ions from spent lithium ion batteries, solvent extraction experiments were performed by employing synthetic hydrochloric acid leaching solution. The synthetic solution contained Cu(II), Co(II), Mn(II) and Ni(II) and its acidity was 3 M HCl. Extraction with Aliquat 336 led to selective extraction of Cu(II) with a small amount of Co(II). After adding NaCl to the Cu(II) free raffinate to enhance the complex formation of Co(II), Co(II) was selectively extracted into Aliquat 336 together with Mn(II). The small amount of Mn(II) in the loaded Aliquat 336 was scrubbed by pure Co(II) solution. After adjusting the pH of the raffinate to 3, 91,3% of Mn(II) was selectively extracted over Ni(II) by the mixture of D2EHPA and Alamine 336. In this extraction, the mole fraction of D2EHPA in the mixture affected the extraction of Mn(II). McCabe-Thiele diagrams for the extraction of Cu(II) and Co(II) were constructed. Batch simulation experiments for the three stage counter-current extraction verified the selective extraction of the target metal ions in each extraction step. Namely, the total extraction percentage of Cu(II) and Co(II) was 71.6% and 98.8% respectively. Most metals in the loaded organic phase were stripped completely with the appropriate agents (1.0 M $H_2SO_4$ for Cu(II), 0.1 M H2SO4 for Co(II) and 0.3 M $HCl$ for Mn(II) stripping). A process was proposed to separate the metal ions by solvent extraction.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 4; 599-610
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Synthesis, characterization, biological activity of Schiff bases derived from 2-bromo-4-methyl aniline and its potentiometric studies with Cu(II), Co(II) and Ni(II) ions
    Autorzy:
    Upadhyay, Surbhi V.
    Zala, Raksha V.
    Bhatt, Keyur D.
    Powiązania:
    https://bibliotekanauki.pl/articles/1030767.pdf
    Data publikacji:
    2020
    Wydawca:
    Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
    Tematy:
    2-bromo-4-methyl aniline
    Antimicrobial activity
    Irving-Rossotti
    Potentiometric studies
    Schiff base
    Stability constant
    Opis:
    Schiff bases namely, 2-bromo-4-methyl-N-(2-nitrobenzylidene)aniline; 2-bromo-4-methyl-N-(2,4,5-trimethoxybenzylidene)aniline; 2-bromo-N-(4-methoxybenzylidene)-4-methylaniline and N-((1H-indol-3-yl)methylene-2-bromo-4-methylaniline have been synthesized and characterized by elemental analysis, FT-IR, Mass and 1H-NMR spectroscopy. Schiff bases have been screened for Antimicrobial activity against bacteria and fungi by using MIC determination. Binary complexes of Co(II), Ni(II) and Cu(II) with Schiff bases in solution have been studied potentiometrically in 60:40 % (V/V) 1,4-dioxane-water system at constant temperature 27 ±0.5 ºC and at an ionic strength of 0.1 M KNO3. The order of stability constant of formed binary complexes in solution was examined.
    Źródło:
    World Scientific News; 2020, 145; 1-15
    2392-2192
    Pojawia się w:
    World Scientific News
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) Schiff base complexes of 3-hydroxy-4-[N-(2-hydroxynaphthylidene)-amino]-naphthalene-1-sulfonic acid: Synthesis, Spectroscopic, thermal, and antimicrobial studies
    Autorzy:
    Bakare, Safyah B.
    Powiązania:
    https://bibliotekanauki.pl/articles/778830.pdf
    Data publikacji:
    2019
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    Schiff base
    hydroxynaphthalene-1-sulfonic acid
    hydroxy-1-naphthaldehyde
    transition metal ions
    morphology
    antimicrobial activity
    Opis:
    Five divalent transition metals Cu(II), Co(II), Ni(II), Mn(II) and Zn(II) complexes have been synthesized using 3-hydroxy-4-[N-(2-hydroxynaphthylidene)-amino]-naphthalene-1-sulfonic acid (H3L) Schiff base as a ligand derived from the condensation reaction between 4-amino-3-hydroxynaphthalene-1-sulfonic acid and 2-hydroxy-1-naphthalde-hyde. The synthesized complexes were characterized using microanalytical, conductivity, FTIR, electronic, magnetic, ESR, thermal, and SEM studies. The microanalytical values revealed that the metal-to-ligand stoichiometry is 1:1 with molecular formula [M2+(NaL)(H2O)x].nH2O (where x = 3 for all metal ions except of Zn(II) equal x = 1; n = 4, 10, 7, 4, and 6 for Cu(II), Co(II), Ni(II), Mn(II) and Zn(II), respectively). The molar conductivity result indicates that all these complexes are neutral in nature with non-electrolytic behavior. Dependently on the magnetic, electronic, and ESR spectral data, octahedral geometry is proposed for all the complexes except to zinc(II) complex is tetrahedral. Thermal assignments of the synthesized complexes indicates the coordinated and lattice water molecules are present in the complexes. SEM micrographs of the synthesized complexes have a different surface morphologies. The antimicrobial activity data show that metal complexes are more potent than the parent ligand.
    Źródło:
    Polish Journal of Chemical Technology; 2019, 21, 3; 26-34
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Inhibiting effect of citric acid on the floatability of serpentine activated by Cu(II) and Ni(II) ions
    Autorzy:
    Huang, Jun-wei
    Zhang, Cheng-qiang
    Powiązania:
    https://bibliotekanauki.pl/articles/110224.pdf
    Data publikacji:
    2019
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    copper ion
    nickel ion
    serpentine
    floatation
    activation
    inhibiting
    Opis:
    The laboratory researches about the inhibiting effect of citric acid on the flotation performance of serpentine activated by Cu2+ and Ni2+ were carried out through micro flotation tests, zeta potential measurements, collector adsorption capacity measurements and solution chemistry analysis. The flotation results showed that Cu2+ and Ni2+ could remarkably activate the flotation of serpentine when the pH value was more than 6, however, this activation could be effectively weakened by adding citric acid. Zeta potential measurement and adsorption capacity measurement indicated that the presence of citric acid could prevent the adsorption of Cu2+ and Ni2+, and therefore reduce the adsorption amount of potassium butyl xanthate on serpentine surface. Furthermore, solution chemical analysis of the flotation system showed that copper hydroxide Cu(OH)2(s) and the nickel hydroxide Ni(OH)2(s) were the main component in the pH range of 9 to 10, which adsorbed onto serpentine surface and made it activated; while the citric acid could effectively prohibit the formation of these metal hydroxide in slurry so as to inhibit the activation impact.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2019, 55, 4; 960-968
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Prediction of Co(II) and Ni(II) ions removal from wastewater using artificial neural network and multiple regression models
    Autorzy:
    Allahkarami, E.
    Igder, A.
    Fazlavi, A.
    Rezai, B.
    Powiązania:
    https://bibliotekanauki.pl/articles/109455.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    artificial neural network
    nonlinear multi-variable regression
    heavy metals
    adsorption
    Opis:
    In this research, carboxymethyl chitosan-bounded Fe3O4 nanoparticles were synthesized and used for removal of Co(II) and Ni(II) ion metals from wastewater. The capability of magnetic nanoparticles for metal ions removal was investigated under different conditions namely pH, initial concentration of metal ions and adsorbent mass. The assessment of adsorbent performance for metal ions removal under different conditions requires cost and time spending. In this regard, the capability of artificial neural network (ANN) and nonlinear multi-variable regression (MNLR) models were investigated for predicting metal ions removal. The values of operational parameters such as pH, contact time, initial concentration of metal ions and adsorbent mass were applied for simulation by means of ANN and MNLR. A back propagation feed forward neural network, with one hidden layer (4:8:2), was proposed. Two criteria, including mean square error (MSE) and coefficient of determination (R2) were used to evaluate the performance of models. The results showed that two models satisfactorily predicted the adsorbed amount of metal ions from wastewater. However, the ANN model with higher R2 and lower MSE than the MNLR model had better performance for predicting the adsorbed amount of metal ions from wastewater.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 2; 1105-1118
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Adsorption kinetic, equilibrium and thermodynamic investigations of Zn(II) and Ni(II) ions removal by poly(azomethinethioamide) resin with pendent chlorobenzylidine ring
    Autorzy:
    Kumar, P. S.
    Ethiraj, H.
    Venkat, A.
    Deepika, N.
    Nivedha, S.
    Vidhyadevi, T.
    Ravikumar, L.
    Sivanesan, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/780002.pdf
    Data publikacji:
    2015
    Wydawca:
    Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
    Tematy:
    adsorption
    models
    Ni(II) ions
    poly(azomethinethioamide)
    Zn(II) ions
    Opis:
    This paper reports the application of poly(azomethinethioamide) (PATA) resin having the pendent chlorobenzylidine ring for the removal of heavy metal ions such as Zn(II) and Ni(II) ions from the aqueous solutions by adsorption technology. Kinetic, equilibrium and thermodynamic models for Zn(II) and Ni(II) ions adsorption were applied by considering the effect of contact time, initial metal ion concentration and temperature data, respectively. The adsorption influencing parameters for the maximum removal of metal ions were optimized. Adsorption kinetic results followed the pseudo-second order kinetic model based on the correlation coefficient (R2) values and closed approach of experimental and calculated equilibrium adsorption capacity values. The removal mechanism of metal ions by PATA was explained with the Boyd kinetic model, Weber and Morris intraparticle diffusion model and Shrinking Core Model (SCM). Adsorption equilibrium results followed the Freundlich model based on the R2 values and error functions. The maximum monolayer adsorption capacity of PATA for Zn(II) and Ni(II) ions removal were found to be 105.4 mg/g and 97.3 mg/g, respectively. Thermodynamic study showed the adsorption process was feasible, spontaneous, and exothermic in nature.
    Źródło:
    Polish Journal of Chemical Technology; 2015, 17, 3; 100-109
    1509-8117
    1899-4741
    Pojawia się w:
    Polish Journal of Chemical Technology
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Absorption Spectrum of Ni(II) Ions Doped in Lithium Sodium Potassium Sulphate Single Crystal
    Autorzy:
    Rama Kumar, R.
    Venkata Reddy, B. C.
    Powiązania:
    https://bibliotekanauki.pl/articles/1933457.pdf
    Data publikacji:
    1995-06
    Wydawca:
    Polska Akademia Nauk. Instytut Fizyki PAN
    Tematy:
    78.40.-q
    78.50.-w
    Opis:
    The optical absorption spectra of lithium sodium potassium sulphate doped Ni$\text{}^{2+}$ ions at 300 and 77 K was recorded. The observed bands are assigned as transitions from the ground state $\text{}^{3}$A$\text{}_{2g}$(F) to various excited triplet and singlet states of the Ni$\text{}^{2+}$ ion in octahedral symmetry. The splittings observed for the bands $\text{}^{3}$T$\text{}_{1g}$(F) and $\text{}^{3}$T$\text{}_{2g}$(F) at liquid nitrogen temperature have been explained as due to spin-orbit interaction. The oscillator strengths of the transitions were computed from the area under the curves. From a detailed analysis of the bands of the spectrum, the crystal field parameters B, C, Dq and ξ are evaluated.
    Źródło:
    Acta Physica Polonica A; 1995, 87, 6; 1023-1029
    0587-4246
    1898-794X
    Pojawia się w:
    Acta Physica Polonica A
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-9 z 9

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