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    Wyświetlanie 1-9 z 9
    Tytuł:
    Polish scientists in studies of extraterrestrial matter; past, present, reminiscences
    Autorzy:
    Manecki, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/2059311.pdf
    Data publikacji:
    2001
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    meteorites
    structures of chondrules
    chondrules
    cosmic dusts
    cosmic glass
    cosmic graphite
    Opis:
    The contributions of Polish scientists to studies of extraterrestrial matter are described, and a history of investigations into the Pułtusk, Łowicz, Morasko and Baszkówka meteorites is given. Opinions expressed in Polish journals on the structure and genesis of chondrules are discussed, together with the results of X-ray structural research of graphites. Polish papers devoted to the studies of cosmic dusts, particularly of their aluminosilicate glass, are summarized. In this context the use of the infrared method in distinguishing terrestrial and cosmic glasses is stressed.
    Źródło:
    Geological Quarterly; 2001, 45, 3; 211-218
    1641-7291
    Pojawia się w:
    Geological Quarterly
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    The Baklia Fault Zone – a regional strike-slip zone splitting Prins Karls Foreland (Svalbard
    Autorzy:
    Ziemniak, G.
    Czerny, J.
    Manecki, M.
    Kośmińska, K.
    Powiązania:
    https://bibliotekanauki.pl/articles/184582.pdf
    Data publikacji:
    2016
    Wydawca:
    Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
    Tematy:
    metasediments
    geological structure
    lithostratigraphy
    Opis:
    Prins Karls Foreland (PKF) is a westernmost island of Svalbard Archipelago belonging to the Southwestern Basement Province. The island consists of low-metamorphic facies probably Neoproterozoic metasediments, divided into two, northern and southern parts. Both parts are characterized by similar geological structures but different stratigraphy. New discoveries presented here result from joint, Norwegian Polar Institute and AGH UST Krakow expeditions in 2013 and 2014. Thorough characteristics of the location and character of a strike-slip fault splitting PKF (the Baklia Fault Zone) is presented here for the first time. To date, one succession has been distinguished in the lithostratigraphy of PKF’s basement. The northern part of the island consists of two groups: the Scotiafjellet Group and Grampianfjella Group (Dallmann et al. 2015). They comprise low-metamorphic metasediments (chlorite zone of greenschist facies), mostly slates, metapsamites and carbonates. Stratigraphic units of the southern part represent slightly higher, biotite metamorphic zone, and have been considered to be conformably underlying Scotiafjellet Group. The uppermost Peachflya Group and Geikiebreen Group (mostly phyllites with metavolcanics and carbonates) are in thrust contact with underlying Ferrierpiggen Group, comprising schistose diamictites. The Ferrierpiggen Group is a tectonic unit stratigraphically discontinuous at top and bottom. Isolated klippe of the Ferrierpiggen Group separated from Scotiafjellet Group by tectonic boundary is present in the northern part of PKF (Harland et al. 1979, 1993). These complexes have undergone the Caledonian metamorphism followed by D 1 deformation producing SE directed folding and thrusts. D 2 deformation was coaxial, but not coplanar with D 1. D 2 deformation occurred probably in Mid-Cenozoic and resulted in refolding and thrusting, followed by formation of a dextral shear zone along Scotiadalen (Morris 1989). D 3 deformation is connected with transtensional formation of the Forlandsundet Graben along NNW-SSE faults finishing the West Spitsbergen Orogeny (WSO) (Manby 1986). Distinct difference in the stratigraphy of southern and northern parts of PKF is apparent. The presence of the fault dividing the island was indicated before (Hjelle et al. 1979), but no single fault has been recognized during detailed mapping later on (Harland et al. 1979, Morris 1982, Manby 1986, Morris 1989). Mapping and structural measurements conducted by the authors in the area of Selvågen led to the discovery of the major fault zone (the Baklia Fault Zone – BFZ) dividing PKF into two terrains. The BKF have N-S trend from Haukebukta in the west coast, through the slopes of Alasdairhornet (where it trapped few hundred meters long slab of the Ferrierpiggen Group rocks), to the southern Scotiadalen. Approaching Selvågen, the fault zone bends slightly to the NNE-SSW. The zone is filled with breccias and mixture of different lithologies with slabs of rocks derived from both limbs of the fault zone. The width of the zone measures approximately 100–250 meters. To the east, it is accompanied by at least three narrow subparallel faults. The age of the BFZ is unknown. A brittle character of deformation may suggest that it is Cenozoic in age. En échelon normal faults with a drop to the north, which associate BFZ may be considered as a Riedel shears R 1 formed at the beginning of a strike-slip movement. Structural measurements on slickensides as kinematic indicators revealed that normal faulting was associated with both, dextral and sinistral shear (not simultaneous). A main movement connected with dextral shearing occurred probably earlier, during late stages of the early Cenozoic crustal shortening. The extended width of the fault zone and the presence of a mixture of rock material from both terranes suggest the significant lateral displacement that might reach tens of kilometers. The BFZ cuts through the boundary faults of the Forlandsundet Graben displacing them sinistrally by approximately one kilometer. This suggests that sinistral movement was probably associated with rejuvenation of the fault during late stages or after the Forlandsundet Graben formation. There are several regional implications of BFZ. The stratigraphic relationship of southern and northern terranes is unclear. The presence of BFZ at the boundary of the Scotiafjellet and Peachflya groups does not exclude their stratigraphic succession but makes it impossible to define. The field observations suggest that BFZ may be Cenozoic in age. It has similar tectonic style and orientation to other strike-slip zones present along western Svalbard coast. Strong tectonic deformation suggests displacement of the northern terrain of PKF by tens of kilometers. Even though southern terrain can be directly correlated with Oscar II Land, more research is needed to correlate more exotic northern terrain of PKF with the basement rocks in the southern parts of Spitsbergen. Ongoing research towards dating and detail structural characterization of this regional fault zone will allow for reconstruction of pre-Tertiary position of this part of Archipelago.
    Źródło:
    Geology, Geophysics and Environment; 2016, 42, 1; 142-143
    2299-8004
    2353-0790
    Pojawia się w:
    Geology, Geophysics and Environment
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Weathering in a regolith on the Werenskioldbreen forefield (SW Spitsbergen) : modelling of pore water chemistry
    Autorzy:
    Kwaśniak-Kominek, M.
    Manecki, M.
    Rzepa, G.
    Płonka, A. M.
    Górniak, D.
    Powiązania:
    https://bibliotekanauki.pl/articles/191820.pdf
    Data publikacji:
    2016
    Wydawca:
    Polskie Towarzystwo Geologiczne
    Tematy:
    retreating glaciers
    chronosequence
    hydrochemistry
    Werenskioldbreen
    Spitsbergen
    Opis:
    The mineral framework and pore waters of glacial sediments exposed in the foreland of Weren- skioldbreen in SW Spitsbergen were sampled and analyzed to model the evolution of pore water chemistry, representing the advancement of weathering in a chronosequence. Three samples were taken at distances representing snapshots of approximately 5, 45 and 70 years of exposure. Complementary mineralogical analyses of the mineral framework and chemical analyses of pore waters, coupled with thermodynamic modelling of mineral-water interactions were applied. Recently uncovered sediments of the bottom moraine underwent very little weathering underneath the glacier cover; both the sediments and pore waters in the forefield of the Werenskioldbreen represent a very immature system. Poorly sorted sediments were deposited by the glacier and not reworked by fluvioglacial waters. The ratio of ‘amorphous iron’ to ‘free iron’ Feo/Fed increases with distance from the glacier terminus from 0.30 through 0.36 to 0.49, typical for fresh glacial till. The increase in saturation with CO2 (from p(CO2) –3.8 to –2.4) and the concentration of all major ions in pore waters (from 123 to 748 mg/L total dissolved solids, TDS) was observed in this young chronosequence. The waters evolved from carbonate- dominated to sulphate-dominated, indicating that with progress in weathering the dominating processes are equilibration with carbonates, oxidation of sulphides and the influence of gypsum precipitation by seasonal freeze-thaw cycles. Mass balance calculations and inverse modelling of the composition of pore waters, verified by microscopic observations of alteration on the surfaces of mineral grains, allowed thermodynamic confirmation of the fact that the relative significance of carbonate weathering decreases and that of sulphate increases down the chronosequence. The participation of silicate minerals in weathering is low, indicating a relatively immature stage of weathering within this particular chronosequence. It is significant that the morphology of etch pits and the formation of secondary phases apparent on mineral surfaces were identical, regardless of the distance from the glacier terminus. This might indicate that the mechanisms of particular weathering processes at the mineral-water interface are the same at the initial as well as at the more mature stages and do not change at least within ca. 70 years of exposure.
    Źródło:
    Annales Societatis Geologorum Poloniae; 2016, 86, 3; 249-264
    0208-9068
    Pojawia się w:
    Annales Societatis Geologorum Poloniae
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Characteristics of soil of “Józefka” deposit overlay, Kielce District
    Autorzy:
    Pawlikowski, M.
    Manecki, M.
    Kozień, D.
    Waluś, E.
    Borecka, A.
    Stanisz, J.
    Pękala, M.
    Kiecana, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/184183.pdf
    Data publikacji:
    2016
    Wydawca:
    Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
    Tematy:
    mine
    mineral composition
    geotechnics
    Opis:
    The aim of this article is to describe and characterize the properties of the overburden overlying rocks of “Józefka” mine, with an attempt to demonstrate a dependence of diversified mineral composition on geotechnical characteristics of the tested material. The article presents previously obtained unpublished data necessary for the evaluation of the physical characteristics of the overlying rocks. The research was conducted in the mining area of the “Józefka” mine, located in Górno – ca. 10 km eastwards from Kielce. Dolomite and calcareous rocks, estimated to be Givetian in age (Czarnocki 1938), are exploited in the mine. The obtained material is used as road aggregate. The deposit is located in the southern part of the Świętokrzyskie Mountains, in the so-called Kielce zone being a part of Małopolska Province Massif (Stupnicka 1997). Silty soils occur there as pockets and interbeds. An attempt to describe them precisely has not been undertaken as yet. Three samples with intact structure and natural moisture were collected during field work. The deposit investigations were carried out at two stages: 1) mineralogical and petrographic, and 2) geotechnical. At the first stage, the analysis included optical microscopy of thin sections, X-ray diffractometry and thermal differential analysis DTA. Clay fraction (below 2 μm) was separated by settling in water. Oriented specimens, glikoled and heated to 550°C were analyzed. The rock contains up to 70 wt% of detrital quartz. The second stage of the research programme was conducted in accordance with the engineering practice and standards (PKN-CEN ISO/TS 17892-2:20 09). Basic physical parameters were established: - natural moisture – w n [%], - bulk density – ρ [g/cm 3 ], - density – ρ s [g /cm 3 ], - granulometric composition, - plasticity – w P [%] and liquidity limits – w L [%], - swelling index – p [%]. The results of the mineralogical and petrographical tests revealed that kaolinite is the main fraction of clay minerals in all three samples. The content of clay fraction was determined with the use of two methods: - water separation – 50 g of material was prepared; the clay material in sample 1 constitutes 55% of the whole material, in sample 2–40%, and in sample 3–39%; - areometric – 35g of material was prepared; the results show that the proportions of the clay material amount to: sample 1–48%, sample 2–33%, sample 3–29%. The concurrence of results of both methods is evident. The maximum difference of clay fraction content was 10%. It indicates the difference in selecting equally representative samples. During the geotechnical determination the tested soil was classified as: sample 1 – clay (Cl), sample 2 – sandy clay (saCl), sample 3 – silty sandy clay (sasiCl) (PN-EN ISO 14688-2:2006). Moreover the following physical properties of the samples were determined: - sample 1: w n = 22.34%, w P = 22.16%, w L = 40.5%, p = 15.42%, ρ = 2.01g/cm 3, ρ s = 2.68 g/cm 3 ; - sample 2: w n = 22.97%, w P = 23.47%, w L = 52%, p = 11.97%, ρ = 2.04g/cm 3, ρ s = 2.66 g/cm 3 ; - sample 3: w n = 20.21%, w P = 21.3%, w L = 43%, p = 21.5%, ρ = 2.05 g/cm 3, ρ s = 2.68 g/cm 3. Sample 3 was classified as highly swelling, which confirms a significant content of smectite in the mineral composition. Other samples were classified as medium swelling, correspondingly sample 1: 15.42%, and sample 2: 11.97% (Niedzielski 1993). The lowest value of bulk density of sample 1 indicates increased content of clay fraction. This is confirmed by the mineralogical and petrographical tests. Soils present in “Józefka” deposit overburden may be used as an addition to vegetable fertilizers. Their use will increase sorption of cations and water in soil. This material should be mined in a selective way due to its variability.
    Źródło:
    Geology, Geophysics and Environment; 2016, 42, 1; 116-117
    2299-8004
    2353-0790
    Pojawia się w:
    Geology, Geophysics and Environment
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Preservation of magmatic signals in metavolcanics from Wedel Jarlsberg Land, SW Svalbard
    Autorzy:
    Gołuchowska, K.
    Barker, A. K.
    Majka, J.
    Manecki, M.
    Czerny, J.
    Bazarnik, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/2086518.pdf
    Data publikacji:
    2012
    Wydawca:
    Polskie Towarzystwo Mineralogiczne
    Tematy:
    Neoproterozic
    Svalbard
    metavolcanics
    Factor Analysis
    Opis:
    The purpose of this study is to determine the role of metamorphism and thereby identify the preserved magmatic signature in metavolcanics from Wedel Jarlsberg Land in southwestern Svalbard. Samples have been collected from late Precambrian metavolcanics occurring within metasedimentary rocks of the Sofiebogen Group, as well as dikes cutting older metasedimentary rocks of the Deilegga Group. The volcanic rocks were metamorphosed under greenschist facies conditions during the Caledonian Orogeny. To investigate the role of metamorphism, we present petrography, major and trace element geochemistry, and use factor analysis as a tool to identify correlations that correspond to primary magmatic signals. The metavolcanics are classified as subalkaline basalt to basaltic andesite and they contain relicts of primary clinopyroxene and plagioclase. The metamorphic minerals are actinolite, secondary plagioclase, chlorite and minerals belonging to the epidote group. Major element variations are highly scattered with no obvious trends observed. The HFSE and REE show strong trends attributed to fractional crystallization. The LILE, Th and La show elevated contents in some samples. Factor analysis shows that the HFSE and REE are well correlated. The LILE form a separate well correlated group, while the major elements are not correlated, except for Na2O, Fe2O3 and CaO. The lack of correlation for major elements, as well as the lack of observed fractional crystallization trends between these elements suggests that they were modified by metamorphism. The strong correlation of HFSE and REE reflects the original geochemical signal generated by magmatic processes. The correlation of the LILE is consistent with their elevated composition implying the influence of crustal contamination processes, and though some variability is likely superimposed due to metamorphism, the primary magmatic record is not completely destroyed. We conclude that the HFSE and REE are not influenced by metamorphic processes and therefore provide robust records of magmatic processes.
    Źródło:
    Mineralogia; 2012, 43, 3/4; 179--197
    1899-8291
    1899-8526
    Pojawia się w:
    Mineralogia
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    CO2-brine-rock interactions as a result of long term experiment onto rock samples from Chabowo anticline, Poland
    Autorzy:
    Wdowin, M.
    Tarkowski, R.
    Manecki, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/184769.pdf
    Data publikacji:
    2013
    Wydawca:
    Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Wydawnictwo AGH
    Tematy:
    CO2 brine-rock interactions
    CO2 sequestration
    petrophysical investigation
    petrology-mineralogical characteristics
    Chabowo anticline
    Opis:
    The presented work concerns investigations of CO2-brine-rock interactions conducted over a period of 20-months. Experiments were carried out at laboratory scale with the use of equipment specifically designed for this purpose. Research materials (reservoir and cap rocks) were taken from the Chabowo 3 well located within Chabowo anticline. The experiments were carried out at room temperature (about 25°C) and pressure about 6 MPa. For samples before and after the experiment a numerous investigations were carried out i.e. petrophysical (porosity, surface area, threshold diameter, average capillary, framework and bulk densities) and petrological-mineralogical characteristics. Also brine used for examination before and after experiment was analyzed (chemical analysis). Petrophysical results have shown a significant decrease of porosity (from 17.0% to 7.5%) and surface area (from 0.395 m2/g to 0.196 m2/g) in case of sandstone. These changes are caused probably by crystallization of halite in pore spaces, because mineralogical analysis (XRD) has shown the presence of halite (3-5% vol. in the rock) after experiment. More detailed results were obtained during mineralogical analyses of thin sections. These results have shown in sandstone samples a small increase of porosity and a small decrease of feldspar and cements (carbonate and clay) as well as matrix which suggests dissolution of these constituents. For clay stone - after experiment XRD clay fraction has shown absence of clay minerals such as montmorillonite, which may also be caused by interaction between the rock, CO2 and brine. Dissolution of some minerals is evidenced by chemical analysis of brine where amounts of most tested ions increase after experiment for both sandstone and clay stone.
    Źródło:
    Geology, Geophysics and Environment; 2013, 39, 4; 385-400
    2299-8004
    2353-0790
    Pojawia się w:
    Geology, Geophysics and Environment
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Weathering in a regolith on the Werenskioldbreen Glacier forefield (SW Spitsbergen). 2. Speciation of Fe, Mn, Pb, Cu and Zn in the chronosequence
    Autorzy:
    Rzepa, Grzegorz
    Manecki, Maciej
    Jakubski, Grzegorz
    Kwaśniak-Kominek, Monika
    Czerny, Jerzy
    Górniak, Dorota
    Powiązania:
    https://bibliotekanauki.pl/articles/191866.pdf
    Data publikacji:
    2019
    Wydawca:
    Polskie Towarzystwo Geologiczne
    Tematy:
    retreating glaciers
    incongruent dissolution
    sequential chemical extraction
    global warming
    Opis:
    The evolution of chemical speciation of Fe, Mn, Pb, Cu, and Zn was investigated in the chronosequence of young sediments, exposed by a currently retreating Arctic glacier on Spitsbergen. Werenskioldbreen is a 27 km2 subpolar, land-terminated, polythermal glacier in recession, located near the SW coast of West Spitsbergen. Three samples of structureless till were collected at locations exposed for 5, 45 and 70 years. Four grain-size fractions were separated: > 63, 20–63, 2–20, and < 2 µm. Speciation of Fe, Mn, Pb, Cu, and Zn was determined using a 6-step sequential chemical extraction method: 1) 1 M sodium acetate, 2) 1 M hydroxylamine hydrochloride in acetic acid, 3) sodium dithionite in buffer, 4) acid ammonium oxalate, 5) boiling HCl, 6) residuum. The weathering in the proglacial area of the retreating glacier is very fast. The geochemical fates of the metals in question correlate with each other, reflecting a) the geochemical similarities between them, b) the similarities of their primary mineral sources, c) the significant role of incongruent dissolution. The weathering processes dominating the system are redox reactions and incongruent dissolution, followed by precipitation of secondary phases and partial sorption of aqueous species. As a result, the elements released from weathering minerals are only partially transported away from the system. The remaining part transforms by weathering from the coarse-grained fraction (dominated by fragments of primary minerals) into the fine-grained fraction (in the form of secondary, authigenic minerals or as species sorbed onto a mineral skeleton). This is very strongly pronounced within the chronosequence: the content of each of the metals studied correlates identically with the grain size, despite the differences in their chemical character and affinities. The microscope study presented herein indicates that the role of incongruent dissolution previously was underestimated. Also, the formation of coatings of secondary phases on primary mineral surfaces was observed. All these rapid weathering processes affect the mineral speciation of initial soils as well as the composition of mineral suspensions transported away by rivers to the nearby ocean.
    Źródło:
    Annales Societatis Geologorum Poloniae; 2019, 89, 3; 317-341
    0208-9068
    Pojawia się w:
    Annales Societatis Geologorum Poloniae
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Petrographic-mineralogical and textural changes in reservoir and sealing rocks (Zaosie anticline) as a result of a long-term experiment in CO2-brine-rock interactions
    Zmiany petrograficzno-mineralogiczne i teksturalne w skałach zbiornikowych i nadkładu (antyklina Zaosia) w wyniku długoterminowego eksperymentu oddziaływania CO2-skała-solanka
    Autorzy:
    Wdowin, M.
    Tarkowski, R.
    Manecki, M.
    Powiązania:
    https://bibliotekanauki.pl/articles/216920.pdf
    Data publikacji:
    2013
    Wydawca:
    Polska Akademia Nauk. Instytut Gospodarki Surowcami Mineralnymi i Energią PAN
    Tematy:
    CCS
    badania petrograficzne
    badania mineralogiczne
    analiza teksturalna
    antyklina Zaosia
    petrographic research
    mineralogical research
    textural analysis
    Zaosie anticline
    Opis:
    Artykuł przedstawia wyniki badań mineralogiczno-petrograficznych oraz teksturalnych na próbkach skalnych ze skał zbiornikowych i uszczelniających (piaskowce, iłowce, mułowce) z utworów dolnej jury z antykliny Zaosia (środkowa Polska), z otworów wiertniczych Zaosie 2 i Buków 2. Próbki poddano eksperymentowi oddziaływania CO2-solanka-skała celem określenia ich przydatności pod kątem geologicznej sekwestracji CO2. Eksperyment polegał na zamknięciu próbek skalnych na 20 miesięcy w zbudowanym reaktorze, gdzie były one poddane oddziaływaniu solanki i dwutlenku węgla w temperaturze pokojowej (20–25°C), przy ciśnieniu otrzymanym z butli z CO2 (ok. 6MPa). Analizy mineralogiczno petrograficzne obejmowały obserwacje w świetle przechodzącym (planimetria), SEM-EDS, XRD próbek skalnych. Dodatkowo dla skał uszczelniających wykonano XRD z frakcji ilastej. Badania te pozwoliły określić skład mineralny oraz morfologię ziaren jak również strukturę i teksturę skały. W przypadku analiz teksturalnych określona została powierzchnia właściwa BET oraz rozkład i wielkość porów. Miały na celu określenie zmian w matrycy skalnej i spoiwie badanych skał w wyniku eksperymentu oddziaływania pomiędzy solanką-skałą-CO2. Eksperyment nie wpłynął znacząco na badane parametry. W przypadku każdej z analizowanych skał obserwuje się nieznaczne zmiany w porowatości przed i po eksperymencie, co związane jest z rozpuszczaniem się matrycy skalnej i spoiwa oraz wytrącaniem niektórych faz mineralnych. Zmiany zaobserwowane w piaskowcach (skały zbiornikowe) są zmianami, które nie wpływają negatywnie na proces składowania CO2. W przypadku mułowców i iłowców (skał uszczelniających) wyniki badań pokazały, że eksperyment nieznacznie wpłynął na analizowane skały. Wskazywać to może na dobre właściwości uszczelniające tych skał. Niemniej jednak wyniki powinny zostać zweryfikowane i potwierdzone w uzupełnieniu o dalsze badania petrofizyczne (porowatość, przepuszczalność), analizy solanek przed i po eksperymencie, jak również modelowanie geochemiczne oddziaływania CO2 na skały w obecności solanki.
    This article presents the petrographic-mineralogical and textural test results from rock samples from the reservoir and sealing rocks (sandstones, claystone, mudstone) of the Lower Jurassic formation of the Zaosie anticline (central Poland), from boreholes Zaosie 2 and Buków 2. Samples were subjected to an experiment involving CO2-brine-rock interactions in order to determine their suitability for the geological sequestration of CO2. The experiment consisted of closing the rock samples for 20 months in constructed autoclaves where they were subjected to the influences of brine and carbon dioxide at room temperature (20–25°C) and under pressure (about 6 MPa). Mineralogical and petrographic analyses included observations under transmitted light (planimetric analysis), and SEM-EDS and XRD of rock samples were carried out. Additionally, XRD analysis of the clay fraction was conducted to examine the sealing characteristics of the rock. These studies allowed for the determination of the mineral composition and morphology of the grains as well as the structure and texture of the rocks. For the textural analysis, the BET specific surface area and pore size distribution were identified. The study aimed to determine the changes in the rock matrix and cement of the rocks caused by the brine-rock-CO2 interactions experiment. The experimentation did not significantly affect the analyzed parameters. For each of the examined rocks, little change in the porosity before and after the experiment was observed, which was associated with the dissolution of the rock matrix and cement as well as the precipitation of some mineral phases. The changes observed in the sandstones (reservoir rocks) are differences that do not affect the process of CO2 storage. In the case of mudstone and claystone (sealing rocks), the experiment had some slight effect on the analyzed rocks. This study nevertheless indicates good sealing properties of these rocks, though the results should be verified and proven by petrophysical (porosity, permeability) examination, the analysis of brines before and after the experiment, as well as geochemical modeling of the impact of CO2 on a rock in the presence of brine.
    Źródło:
    Gospodarka Surowcami Mineralnymi; 2013, 29, 4; 137-153
    0860-0953
    Pojawia się w:
    Gospodarka Surowcami Mineralnymi
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Pochodzenie i zagrożenia siarkowodorem i wysokociśnieniowym gazem ziemnym w złożu kopalń rud miedzi Polkowice-Sieroszowice i Rudna – wstępne badania izotopowe i mineralogiczne
    Origin and hazards of hydrogen sulphide and high-pressure natural gas in deposits of Polkowice-Sieroszowice and Rudna copper ore mines: preliminary isotopic and mineralogical studies
    Autorzy:
    Kotarba, M. J.
    Bilkiewicz, E.
    Manecki, M.
    Pawlik, W.
    Ciesielczyk, A.
    Selerowicz, T.
    Powiązania:
    https://bibliotekanauki.pl/articles/2061828.pdf
    Data publikacji:
    2017
    Wydawca:
    Państwowy Instytut Geologiczny – Państwowy Instytut Badawczy
    Tematy:
    siarkowodór
    gaz ziemny
    geneza
    zagrożenia gazowe
    badania izotopowe
    badania mineralogiczne
    kopalnia miedzi Polkowice-Sieroszowice
    kopalnia miedzi Rudna
    hydrogen sulphide
    natural gas origin
    gas hazards
    isotopic analyses
    mineralogical study
    Polkowice-Sieroszowice copper mine
    Rudna copper mine
    Opis:
    Wyniki badań składu cząsteczkowego i izotopowego (13C/12C w CH4, C2H6, C3H8, iC4H10, nC4H10 i CO2, 2H/1H w CH4 i 15N/14N w N2) dwóch próbek gazu ziemnego występującego w utworach wapienia cechsztyńskiego (Ca1) kopalni Rudna porównano z gazem ziemnym akumulowanym w utworach karbonu, czerwonego spągowca i wapienia cechsztyńskiego (Ca1) monokliny przedsudeckiej oraz gazu wytworzonego podczas pirolizy wodnej z kopalnej materii organicznej utworów dolomitu głównego (Ca2). Badany gaz ziemny charakteryzuje się normalnym składem izotopowym w układzie metan–etan–propan, co świadczy o tym, że powstał w jednej fazie generowania z tej samej skały macierzystej, zawierającej kerogen mieszanego typu II/III, prawdopodobnie w obrębie utworów karbońskich. Na podstawie badań mineralogicznych i izotopowych 13C/12C 12 próbek węglanowych i 34S/35S 14 próbek siarczanowych, pobranych w strefie głębokości eksploatacji rud miedzi od 900 do ok. 1200 m ZG Polkowice-Sieroszowice i Rudna w zakresie współczesnych temperatur od 35 do 45°C, wykazano, że w dwóch próbkach węglanów i w dwóch próbkach siarczanów pobranych z jednego rdzenia zachodzą procesy mikrobialnej redukcji anhydrytu dolnego (Ad1) cyklu PZ1 prowadzące do powstawania siarkowodoru.
    Composition of natural gas from the Zechstein Limestone (Ca1) strata of Rudna mine has been compared with the natural gas from Carboniferous, Rotliegend strata of the Fore-Sudetic Monocline and with gas generated from the organic matter of the Main Dolomite during hydrous pyrolysis experiments. The gas from Rudna mine is characterized by the normal methane–ethane–propane isotopic system which indicates formation in one stage from a single source rock probably of the Carboniferous age containing kerogen of mixed II/III type. Generation of the hydrogen sulphide resulted from the microbial sulphate reduction processes of the basal anhydrite has been proven by mineralogical and isotopic 13C/12C analyses of 12 carbonate and 34S/35S analyses of 14 sulphate samples. These samples were collected in the mine at the depth of about 900–1200 m at temperature range of 35–45°C and two samples of carbonates were taken from one core.
    Źródło:
    Biuletyn Państwowego Instytutu Geologicznego; 2017, 469; 9--33
    0867-6143
    Pojawia się w:
    Biuletyn Państwowego Instytutu Geologicznego
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
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