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Wyświetlanie 1-2 z 2
Tytuł:
Considering the influence of calcium on EAF dust acid leaching
Autorzy:
Havlik, Tomas
Miskufova, Andrea
Turek, Peter
Urban Kobialkova, Ivana
Powiązania:
https://bibliotekanauki.pl/articles/110605.pdf
Data publikacji:
2019
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
EAF-dust
leaching
sulphuric acid
industrial waste
zinc
iron
calcium
hydrometallurgy
Opis:
This work focuses on the hydrometallurgical processing of EAF steelmaking dust in laboratory conditions. The behavior of calcium under the influence of sulphuric acid as the leaching agent is discussed. Due to calcium presence the acid is continuously consumed, gradually leaching the calcium phase from EAF dust as well as other zinc- and iron-containing phases. A thorough composition analysis of the input sample of EAF dust was performed. A kinetic study of calcium showed that its leaching is a very fast process, but most of the calcium reacting with sulphuric acid is precipitated from the solution in the form of CaSO4∙2H2O. This causes greater sulphuric acid consumption, and therefore it is necessary to study the calcium behavior during processing of EAF dust. This work is narrowed with calcium behavior during leaching of EAF dust in sulphuric acid and effect of calcium to extraction other metals into solution.
Źródło:
Physicochemical Problems of Mineral Processing; 2019, 55, 2; 528-536
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Sustainable development in the tinplate industry: refining tinplate leachate with cementation
Autorzy:
Klimko, Jakub
Urban, Kobialkova Ivana
Piroskova, Jana
Orac, Dusan
Havlik, Tomas
Klein, Dusan
Powiązania:
https://bibliotekanauki.pl/articles/1449632.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
tin sludge
recycling
hydrometallurgy
cementation
electrolysis
Opis:
Tin sludge produced during tin electroplating of steel sheet is an interesting secondary source of tin. Dried sludge usually contains more than 50% tin. Hydrometallurgical sludge treatment consists of several steps, including leaching in hydrochloric acid and electrolytic recovery of tin. The electrowinning process is negatively affected by the presence of impurities such as antimony and bismuth, which can cut overall current efficiency to 11% as well as reducing the quality of recovered tin. It is appropriate therefore to remove these impurities from the leachate before the electrowinning steps. This work studies the refining of leachate using cementation. The experiments were carried out at temperatures of 20, 40 and 60 °C at solid to liquid ratios of 1:60, 2:60, 3:60 and 4:60 using tin and iron dust as cementing metals. The leachates were mixed at a constant rate of 400 rpm during all cementation experiments. Effective removal of impurities was achieved in the case of iron powder cementation at s/l ratio 2:60 and temperature 20 °C. This cementation removed 98.49% bismuth and 99.14% antimony from the leachate solution. Electrolysis efficiency was increased from 11 to 71% after leachate refining. Antimony and bismuth were not detected in the final product obtained from refined electrolyte by means of electrolysis.
Źródło:
Physicochemical Problems of Mineral Processing; 2020, 56, 1; 219-227
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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