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Wyszukujesz frazę "82.65.+r" wg kryterium: Wszystkie pola


Tytuł:
Chemisorption Theory at Submonolayer Coverages: Influence of the Dynamic Hopping on the Electronic Characteristics
Autorzy:
Cardenas, R.
Taranko, E.
Taranko, R.
Fedyanin, V.
Powiązania:
https://bibliotekanauki.pl/articles/1891892.pdf
Data publikacji:
1991-11
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
73.20.-r
82.65.My
Opis:
The influence of the dynamic hopping term included in the Newns-Anderson Hamiltonian on the electronic structure of the chemisorbed layer at different coverages rates is investigated. It is shown that this additional interaction can destroy the initial symmetry of the Newns-Anderson model or restore this symmetry in the initial negative asymmetric case. The coverage dependence of the adatom electron charge is also studied for the case of hydrogen chemisorption on a model transition metal surface.
Źródło:
Acta Physica Polonica A; 1991, 80, 5; 731-743
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Negatively and Positively Polarized Hydrogen Adspecies on Thin Platinum Films
Autorzy:
Nowicka, L.
Wolfram, Z.
Duś, R.
Powiązania:
https://bibliotekanauki.pl/articles/1892305.pdf
Data publikacji:
1992-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.65.-i
73.60.Aq
Opis:
Hydrogen adsorption on thin platinum films under isothermal conditions within the temperature and pressure intervals 78-298 K and 10$\text{}^{-10}$-10$\text{}^{-2}$ Torr has been studied measuring simultaneously surface potential (SP) and pressure (P), by means of a sensitive, short response time apparatus. Two forms of hydrogen deposit of different electrical character have been distinguished. The first one arising at the beginning of adsorption decreases the surface potential, the second one following it increases the SP due to positively polarized adspecies formation. This positively polarized form is inhomogeneous as concerns binding energy. Hydrogen uptake associated with the decrease of SP becomes larger with increase of temperature. It seems that this β¯ form of the adsorbate stabilizes the positively polarized adspecies on the surface.
Źródło:
Acta Physica Polonica A; 1992, 81, 1; 117-124
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemisorption Isotherms for Ising Anderson Hamiltonian
Autorzy:
Taranko, E.
Cardenas, R.
Taranko, R.
Fedyanin, V. K.
Powiązania:
https://bibliotekanauki.pl/articles/1931807.pdf
Data publikacji:
1994-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
68.45.-v
82.65.My
Opis:
The adsorption isotherms for Ising-Anderson type model Hamiltonian describing the chemisorbed system was calculated. The submonolayer coverage of the substrate surface was considered on the equal footing together with the electronic characteristics of the chemisorbed adatoms in a self-consisting manner. The resulting adsorption isotherms depend in explicit way on the electronic parameters describing the chemisorbed adatoms and substrate metal.
Źródło:
Acta Physica Polonica A; 1994, 86, 6; 917-927
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Atomic Force Microscopy of Instabilities and Reorganization of Langmuir-Blodgett Films
Autorzy:
Takamoto, D. Y.
Ter-Ovanesyan, E.
Schwartz, D. K.
Viswanathan, R.
Chiruvolu, S.
Zasadzinski, J. A.
Powiązania:
https://bibliotekanauki.pl/articles/1968761.pdf
Data publikacji:
1998-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
82.65.Dp
Opis:
The atomic force microscope was used to show that Langmuir-Blodgett films are unstable to reorganization via a folding mechanism by which uniformly thick films spontaneously form holes and multilayer steps. These bilayer step defects originate at isolated sites and quickly spread to cover the entire film. The defects retain the sixfold symmetry of the underlying molecular lattice; after sufficient time, straight edges begin to form and the entire film is comprised of high islands with straight edges aligned with sixfold symmetry. The kinetics of the reorganization depend strongly on the chain length of the fatty acid used and the nature of the substrate. The results suggest that the reorganization is driven by an interconversion of strained, asymmetric monolayers to unstrained, centrosymmetric bilayers.
Źródło:
Acta Physica Polonica A; 1998, 93, 2; 373-382
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Interaction of Hydrogen with Vanadium Layers Preadsorbed on Tungsten Field Emitter Tip
Autorzy:
Błaszczyszyn, R.
Wachowicz, E.
Błaszczyszynowa, M.
Powiązania:
https://bibliotekanauki.pl/articles/1968928.pdf
Data publikacji:
1998-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
79.70.+q
82.65.My
Opis:
Interaction of hydrogen with vanadium layers preadsorbed on a thermally cleaned tungsten field emitter was studied at room temperature and 78 K through measurements of the total work function changes. An increase in the work function followed by its slight decrease at higher exposure can be understood taking into account the possibility of negatively (β$\text{}^{-}$) and positively (β$\text{}^{+}$) polarized adspecies formation on thin vanadium layer. This process leads to vanadium hydride formation. The work function results suggest that hydrogen diffusion into the vanadium layer is meaningful at room temperature. Thermal desorption of hydrogen adsorbate carried out within the temperature range 409-461 K from thin vanadium layer (Θ$\text{}_{V}$ = 40) provided a value of 127 ± 6 kJ/mol for the activation energy for desorption.
Źródło:
Acta Physica Polonica A; 1998, 93, 5-6; 763-773
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spatially Resolved Chemistry on Bimetallic Surfaces
Autorzy:
Behm, R. J.
Powiązania:
https://bibliotekanauki.pl/articles/1968689.pdf
Data publikacji:
1998-02
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.16.Ch
68.10.Jy
82.65.-i
Opis:
The local chemical properties of bimetallic surfaces, which are often drastically different from those of each of the components, will be discussed. Using CO adsorption as a probe molecule it will be shown for two model systems, Au/Pd(111) and Pt/Ru(0001), that their chemical properties depend decisively on the local surface structure and that the correct interpretation of area integrating spectroscopic and kinetic data obtained from such surfaces requires detailed knowledge of their (defect) structure and of the distribution of the different components in the surface layer. It will further be shown that information on the local chemical properties of specific structural elements such as monolayer islands and monolayer island edges, and specific surface ensembles can be gained by applying high resolution scanning tunneling microscopy imaging and area integrating spectroscopic techniques in combination to bimetallic surfaces whose morphology and composition is varied in a systematic and controlled way. Based on experimental results adsorption on a monolayer A / substrate B system is suggested as a model for gaining information on the modifications in chemical properties of AB alloy surfaces due to metal-metal interactions.
Źródło:
Acta Physica Polonica A; 1998, 93, 2; 259-272
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Charge Transfer Dynamics in Atom-Metal Surface Collisions
Autorzy:
Wiertel, M.
Taranko, R.
Taranko, E.
Powiązania:
https://bibliotekanauki.pl/articles/2011189.pdf
Data publikacji:
1999-12
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
79.20.Rf
78.70.-g
82.65.Pa
Opis:
We study the charge exchange in atom-metal collisions in the framework of the generalized time-dependent Anderson-Newns model. The electron correlations and correlated hopping are treated within the mean-field approximation. The resulting one-particle model with an effective spin-dependent atom-surface coupling is used to study the charge transfer in scattering of Na and Li atoms on metal surfaces. It is shown that the effective occupation dependent atom-surface coupling influences mainly the expectation values for producing positive, neutral, and negative particles for small work functions and high atom velocities. It is also shown that the temperature dependence of these expectation values is more visible, especially for magnetic solutions.
Źródło:
Acta Physica Polonica A; 1999, 96, 6; 769-783
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Steering and Locking of Discrete Solitons in Optical Waveguide Arrays
Autorzy:
Peschel, U.
Lederer, F.
Morandotti, R.
Aitchison, J. S.
Eisenberg, H.
Silberberg, Y.
Powiązania:
https://bibliotekanauki.pl/articles/2015072.pdf
Data publikacji:
2001-01
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
42.65.Tg
42.65.Wi
42.82.Et
Opis:
By operating an AlGaAs waveguide array at the half band gap, we experimentally demonstrate basic features of discrete systems, which do not appear in the corresponding continuous counterpart - the slab waveguide. Under selected initial conditions, we observed nonlinearly induced locking of an initially moving soliton to the input waveguide. If the power is even higher, originally locked beams start to move again, but in a direction opposite to the initial tilt.
Źródło:
Acta Physica Polonica A; 2001, 99, 1; 57-65
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Resonant Charge Exchange in Atom Scattering on Atoms Adsorbed on Metal Surfaces
Autorzy:
Wiertel, M.
Taranko, E.
Taranko, R.
Powiązania:
https://bibliotekanauki.pl/articles/2030724.pdf
Data publikacji:
2002-06
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
79.20.-m
82.65.+r
34.70.+e
Opis:
The ionization probability of an atom scattered from an atom adsorbed on a metal surface has been studied theoretically within the time-dependent Anderson-Newns model. The effect of the metal electron density of states, the band filling as well as the relative position of the scattered atom and adsorbed atom energy levels have been considered and the comparison with the results obtained for clean surfaces has been made.
Źródło:
Acta Physica Polonica A; 2002, 101, 6; 837-855
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of an Adsorbed Atom on Resonant Charge Exchange in Atom Scattering on Metal Surfaces
Autorzy:
Taranko, R.
Taranko, E.
Wiertel, M.
Powiązania:
https://bibliotekanauki.pl/articles/2035749.pdf
Data publikacji:
2003-05
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
79.20.-m
82.65.+r
34.70.+e
Opis:
A simple model describing resonant charge transfer between the free-electron metal surface and an atom colliding with it at some distance from another adsorbed atom is presented. The negative ionization probability of a scattered atom is studied within the time-dependent Anderson-Newns model and the time-evolution operator approach. With appropriate models for the considered system, the ionization probability is shown to oscillate with the distance between the adsorbed atom and the collision point of the scattered atom with the metal surface. These oscillations are results of the indirect interaction between the adsorbed and the scattered atoms due to the coupling of both atoms with the metal energy band.
Źródło:
Acta Physica Polonica A; 2003, 103, 5; 483-497
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure Characterization and Catalytic Properties of Cr$\text{}_{2}$O$\text{}_{3}$ Doped with MgO Supported on MgF$\text{}_{2}$
Autorzy:
Goslar, J.
Wojciechowska, M.
Zieliński, M.
Tomska-Foralewska, I.
Przystajko, W.
Powiązania:
https://bibliotekanauki.pl/articles/2043607.pdf
Data publikacji:
2005-08
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
76.30.Fc
68.43.Fg
82.65.+r
Opis:
A characterization of double oxide systems containing Cr$\text{}_{2}$O$\text{}_{3}$ doped with MgO and supported on MgF$\text{}_{2}$ was carried out. The catalysts were prepared by impregnation and co-impregnation methods and characterized by the Brunauer-Emmett-Teller method, EPR, and temperature programmed reduction. The results proved the interactions between supported oxides and the presence of spinel-like phase after treatment at 400ºC. Magnesium oxide clearly influences the catalytic activity as well as selectivity of chromium catalysts supported on MgF$\text{}_{2}$. The MgO-Cr$\text{}_{2}$O$\text{}_{3}$/MgF$\text{}_{2}$ systems were active and selective in the reaction of CO oxidation at the room temperature and in the dehydrogenation of cyclohexene.
Źródło:
Acta Physica Polonica A; 2005, 108, 2; 323-330
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Subdiffusion with External Time Modulation
Autorzy:
Wojnar, R.
Powiązania:
https://bibliotekanauki.pl/articles/1812233.pdf
Data publikacji:
2008-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
05.40.Jc
05.70.Ln
82.39.Rt
87.18.Hf
89.65.Gh
89.65.Lm
Opis:
A subdiffusion process, similar to a Zeldovich-Kompaneets heat conduction process, is defined by a nonlinear diffusion equation in which the diffusion coefficient takes the form D=a(t)f^n, where a=a(t) is an external time modulation, n is a positive constant, and f=f(x, t) is a solution to the nonlinear diffusive equation. It is shown that a Zeldovich-Kompaneets solution satisfies the subdiffusion equation if a=a(t) is replaced by the mean value of a. Also, a solution to the subdiffusion equation is constructed that may be useful in description of biological, social, and financial processes.
Źródło:
Acta Physica Polonica A; 2008, 114, 3; 607-611
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis, Characterization and Application οf Al,Fe-Pillared Clays
Autorzy:
Banković, P.
Milutinović-Nikolić, A.
Jović-Jovičić, N.
Dostanić, J.
Čupić, Ž.
Lončarević, D.
Jovanović, D.
Powiązania:
https://bibliotekanauki.pl/articles/1808061.pdf
Data publikacji:
2009-04
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.05.C-
61.43.Gt
61.46.-w
68.43.-h
82.65.+r
Opis:
Al,Fe-pillared clay was synthesized from domestic clay from Bogovina according to a common procedure: grinding, sieving, Na exchange, pillaring, drying and calcination. Two synthesized samples differing only in calcining conditions were prepared. Phase composition and textural properties of the starting clay and synthesized pillared clays were characterized using X-ray diffraction and physisorption of nitrogen. Catalytic tests were performed using sample with better textural properties being the one submitted to milder calcining conditions. Catalytic wet peroxide oxidative degradation of aromatic compounds phenol and tartrazine on the synthesized catalyst was confirmed showing better efficiency in the case of tartrazine.
Źródło:
Acta Physica Polonica A; 2009, 115, 4; 811-815
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Carbonaceous Materials Obtained from Sewage Sludge for $NO_2$ Removal under Wet Conditions at Room Temperature
Autorzy:
Pietrzak, R.
Powiązania:
https://bibliotekanauki.pl/articles/1536471.pdf
Data publikacji:
2010-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
61.66.Fn
81.05.-t
81.05.Rm
82.65.+r
89.60.-k
Opis:
The effect of the processes of carbonisation and activation on adsorbents obtained from sewage sludge and their sorption properties towards $NO_2$ were studied. Carbonaceous adsorbents were obtained by carbonisation of sewage sludge at 600°C for four different times 30, 60, 90 and 120 min followed by activation of the carbonisates by $CO_2$ at 800°C for 60 min. Adsorption of $NO_2$ was carried out in wet air. It has been shown that by appropriate thermal and chemical treatment of sludge, mesoporous adsorbents capable of $NO_2$ removal can be obtained. The sorption abilities of the carbonised and activated samples to adsorb $NO_2$ have been shown to increase with increased time of carbonisation and reach maximum for the carbonisation maintained for 90 min. Further increase in this time causes a decrease in the adsorption abilities of the samples. The sorption properties of the carbonisates have been proved to be determined by the chemical character of the surface, while those of the activated samples - by the porous structure.
Źródło:
Acta Physica Polonica A; 2010, 118, 3; 487-492
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemically Modified Activated Carbons as Catalysts of Oxidative Dehydrogenation of n-Butane
Autorzy:
Malaika, A.
Wower, K.
Kozłowski, M.
Powiązania:
https://bibliotekanauki.pl/articles/1535911.pdf
Data publikacji:
2010-09
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
81.05.Rm
81.65.Mq
81.40.Gh
82.65.+r
Opis:
Commercial availability and low price of light alkanes make them very attractive in many branches of industry. Potentially interesting is their use in the process of oxidative dehydrogenation leading to production of olefins. This study was undertaken to characterise the oxidative dehydrogenation of n-butane to 1,3-butadiene (important substrate in production of synthetic rubber and polyamides) taking place over the modified carbon catalysts obtained from peach stones precursor. The catalytic tests were performed in the temperature range 250-450°C at oxygen/n-butane ratio of 1:1. For the majority of the activated carbon samples studied at the lowest temperature the only product was $CO_2$. At 300°C the products of dehydrogenation of n-butane and side products appeared. With increasing temperature the amount of compounds generated increased and in the group of C4 hydrocarbons the dominant were 1-butene and 1,3-butadiene. The most effective catalyst was the sample oxidised with air, the least effective was the sample modified with ammonium peroxydisulphate.
Źródło:
Acta Physica Polonica A; 2010, 118, 3; 459-464
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł

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