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Wyszukujesz frazę "solid-state synthesis" wg kryterium: Temat


Wyświetlanie 1-3 z 3
Tytuł:
Solid State Synthesis of Europium Zirconate Based Material
Autorzy:
Mikuśkiewicz, M.
Moskal, G.
Powiązania:
https://bibliotekanauki.pl/articles/353816.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
europium zirconates
solid-state synthesis
pyrochlores
TBC
Opis:
In the article, the characterization of the microstructure, phase composition and distribution of elements in the Eu2 O3 -ZrO2 sintered materials obtained by four different ways of powders’ homogenization (mixing) process and different temperature of sintering process is shown. The feedstock powders with an average mole ratio of ZrO2 to Eu2 O3 equal 74% to 26% were used as an initial material. The principal aim of the investigation was characterization of differences in the microstructure of the same type of ceramics, however, prepared via different mixing and manufacturing processes. The range of the investigation covered a characterization of these materials via phase identification of all samples by XRD (X-ray diffraction) and characterization of internal morphology of the specimens with detailed analysis of elements distributions by SEM (scanning electron microscopy) and EDS (energy dispersive spectrometry). The aim of the following investigation is to characterize the possibilities of the solid state synthesis of the europium zirconate based materials, dedicated for TBC applications.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 4; 1343-1352
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structure, Morphology and Electrical Properties of CaTiO3 Ceramics Synthesized by the Solid-State Reaction Method
Autorzy:
Rocha-Rangel, E.
López-Hernández, J.
Castillo-Martínez, J. A.
Osorio-Ramos, J. J.
Calles-Arriaga, C. A.
Estrada-Guel, I.
Martínez-Sánchez, R.
Powiązania:
https://bibliotekanauki.pl/articles/352238.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
CaTiO3
solid state synthesis
electrical properties
insulating ceramics
Opis:
In this paper, explain the preparation of CaTiO3 ceramics synthesized by the solid-state reaction method. Calcium carbonate and titanium dioxide were high energy mixed in stoichiometric amounts, and the obtained mixture was calcined at different temperatures (800, 900, 1000 and 1300ºC) for 2h. The obtained samples were characterized by measurement of particle size, Energy Dispersive X-Ray (EDX) Analysis; differential thermal analysis, X-ray diffraction and SEM images. XRD patterns indicated that CaTiO3 ceramics with the structure of perovskite is obtained from calcined powders at 1,300°C for 2h. SEM images show the formation of a very fine and homogeneous morphology. The measured values of electrical resistivity were within the typical range of insulating materials and approach values corresponding to insulating ceramics.
Źródło:
Archives of Metallurgy and Materials; 2018, 63, 4; 1749-1753
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Reaction Kinetics and Morphological Study of TiNb2O7 Synthesized by Solid-State Reaction
Autorzy:
Choi, S. H.
Ali, B.
Choi, K. S.
Hyun, S. K.
Sim, J. J.
Choi, W. J.
Joo, W.
Lim, J. H.
Lee, T. H.
Kim, T. S.
Park, K. T.
Powiązania:
https://bibliotekanauki.pl/articles/355326.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
solid state reaction
kinetic analysis
quantitative phase analysis
TiNb2O7 synthesis
Opis:
Although TiNb2O7 is regarded as a material with high application potential in lithium-ion batteries (LIBs) and solid-oxide fuel cells (SOFCs), it has been difficult to find suitable cost-effective conditions for synthesizing it on a commercial scale. In this study, TiNb2O7 compounds were synthesized by a solid state synthesis process. For stoichiometrically precise synthesis of the TiNb2O7 phase, the starting materials, TiO2 and Nb2O5 were taken in a 1:1 molar ratio. Activation energy and reaction kinetics of the system were investigated at various synthesis temperatures (800,1000,1200, and 1400°C) and for various holding durations (1,5,10, and 20 h). Furthermore, change in the product morphology and particle size distribution were also evaluated as a function of synthesis temperature and duration. Additionally, quantitative phase analysis was conducted using the Rietveld refinement method. It was found that increases in the synthesis temperature and holding time lead to increase in the mean particle size from 1 to 4.5 μm. The reaction rate constant for the synthesis reaction was also calculated.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1051-1056
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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