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Tytuł:
Agricultural biogas plants as a future in agricultural waste management
Autorzy:
Żukowski, Emil
Powiązania:
https://bibliotekanauki.pl/articles/1046527.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Biogas
Biogas plants
Macronutrients
Organic fertilization
Post-fermentation mass
Waste
Opis:
The demand for energy increases with the development of civilization. According to popular opinion, traditional energy resources, mainly fossil fuels (coal, oil, natural gas), are depleted and their use causes an increase in environmental pollution, mainly greenhouse gases. Therefore, renewable energy sources (RES), such as agricultural biogas plants, which are harmless to the world around us, are gaining importance. The European Union pays great attention to environmental protection and soil protection (organic fertilization with digestate, biogas plants) and energy issues. It emphasizes the increase in the share of energy from renewable energy in the total energy consumption. In EU countries, energy issues are regulated by relevant directives and the so-called Green and White Paper [1].
Źródło:
World Scientific News; 2019, 136; 95-107
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Use of HPLC, Py-GCMS, FTIR methods in the studies of the composition of soil dissolved organic matter
Wykorzystanie HPLC, Py-GCMS i FTIR w badaniach składu rozpuszczalnej materii organicznej gleb
Autorzy:
Rosa, E.
Debska, B.
Banach-Szott, M.
Tobiasova, E.
Powiązania:
https://bibliotekanauki.pl/articles/905677.pdf
Data publikacji:
2015
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
soil
organic matter
soil composition
analysis method
high performance liquid chromatography
Py-GCMS zob.pyrolysis gas chromatography mass spectrometry
dissolved organic matter
FTIR method
pyrolysis gas chromatography mass spectrometry
Opis:
The study has determined the composition of dissolved organic matter in Luvisols, Fluvisols and Histosols using spectroscopic (FTIR) and chromatographic (HPLC and Py-GCMS) methods. It has been found that aliphatic hydrocarbons (linear) containing from 4 to 12 atoms of carbon constitute the dominant group of compounds included in the dissolved organic matter (DOC). The preparations isolated from Histosols and Luvisols demonstrated a higher proportion of hydrophobic fraction with a longer retention time probably containing more compounds with long-chain aliphatic and simple aromatic structure than the DOC of Fluvisols. The differences in infrared spectra are evident particularly in the wave number between 1650–1030 cm⁻¹. The DOC of Histosols is richer in aromatic compounds (range 1620 cm⁻¹) but the DOC of Luvisols and Fluvisols is richer in alkene chains and hydroxyl (OH) and methoxy (OCH₃) groups. The results showed differences in the composition of the DOM across the soils, caused their genesis.
W pracy badano skład rozpuszczalnej materii organicznej (RMO) gleb (Luvisols, Fluvisols and Histosols) przy zastosowaniu metod spektroskopowych (FTIR) oraz chromatograficznych (HPLC i Py-GCMS). Stwierdzono, że dominującą grupą związków wchodzących w skład RMO są węglowodory alifatyczne (łańcuchowe) zawierające od 4 do 12 atomów węgla. Preparaty RMO wyizolowane z torfu i gleby płowej charakteryzujące się wyższym udziałem frakcji hydrofobowych o najdłuższym czasie retencji, zawierały najprawdopodobniej więcej związków o długich łańcuchach alifatycznych oraz proste struktury aromatyczne w porównaniu z RMO mady. Przebieg widm w podczerwieni wyraźnie wskazał różnicę w składzie badanych preparatów RMO, szczególnie w zakresie liczb falowych między 1650-1030 cm⁻¹. Preparaty RMO wyizolowane z torfu były bogatsze w związki aromatyczne (pasmo 1620 cm⁻¹) a frakcja RMO wyizolowana z gleby płowej i mady ciężkiej była bogatsza w łańcuchy alkenowe i grupy hydroksylowe (OH) i metoksylowe (OCH₃). Otrzymane wyniki badań wykazały różnice w składzie RMO pomiędzy glebami, wynikające z ich genezy.
Źródło:
Polish Journal of Soil Science; 2015, 48, 1
0079-2985
Pojawia się w:
Polish Journal of Soil Science
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Is it possible to detect lung cancer by trained dogs?
Autorzy:
Rudnicka, J.
Walczak, M.
Jezierski, T.
Buszewski, B.
Powiązania:
https://bibliotekanauki.pl/articles/2052420.pdf
Data publikacji:
2015
Wydawca:
Akademia Bialska Nauk Stosowanych im. Jana Pawła II w Białej Podlaskiej
Tematy:
breath samples
volatile organic compounds
solid phase microextraction
gas chromatography-mass spectometry
canine olfactory
Opis:
During the illness are released volatile organic compounds with specific smell which could have in diagnosis of diseases. The first aim of the study was qualitative and quantitative analysis of exhaled breath samples obtained from patients with lung cancer, healthy volunteers and people with other lung diseases by gas chromatography-mass spectrometry. This study showed that twenty compounds propane, ethanol, isobutane, butane, propanal, 1-propanol, 2-propanol, 2-methylfuran, 2-butanone, benzene, 2-pentanone, pentanal, hexanal, cyclohexanone, 4-heptanone, 2,4-dimethylheptane, 2,3,4-trimethylhexane, 2,3,5-trimethylhexane, 4-methyloctane, α-pinene separated two research groups of patients and healthy controls. The second goal was to evaluate the sensitivity and specificity of canine scent detection using 5 station scent lineup. Among lung cancer patients and complementary samples, overall sensitivity of canine scent detection was 85.54%, while specificity was 71.84%.
Źródło:
Health Problems of Civilization; 2015, 09, 2; 19-26
2353-6942
2354-0265
Pojawia się w:
Health Problems of Civilization
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of gas chromatography to evaluate the quality of rapeseed oil
Autorzy:
Lubinska, Martyna
Namieśnik, Jacek
Powiązania:
https://bibliotekanauki.pl/articles/1179570.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
edible oils
mass spectrometry
quality markers
thermal degradation
two-dimensional gas chromatography
volatile organic compounds
Opis:
Two-dimensional gas chromatography is an analytical technique, which is increasingly being used in food research. Through the analysis of volatile fraction, it is possible to determine the quality of food products. One of the reasons for the deterioration of food is thermal degradation. Products that are often subject to degradation reactions due to temperatures are edible oils. In the thesis, the results of edible oils with different botanical origin are presented. The samples of oil were heated at temperatures of 20 °C, 60 °C, 100 °C, 140 °C and 180 °C. Based on the results of the chromatographic analysis, potential indicators of thermal degradation of edible oils were selected. The last step was to quantify the selected compounds to confirm that the typed chemical compounds are the markers of thermal decomposition of cooking oils. To calibrate, the method of standard additions was chosen
Źródło:
World Scientific News; 2017, 75; 96-105
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Levels of bacterial endotoxin in air of animal houses determined with the use of gas chromatography - mass spectrometry and Limulus test
Autorzy:
Pomorska, D
Larsson, L.
Skorska, C.
Sitkowska, J.
Dutkiewicz, J.
Powiązania:
https://bibliotekanauki.pl/articles/51583.pdf
Data publikacji:
2007
Wydawca:
Instytut Medycyny Wsi
Tematy:
animal house
determination
gas chromatography
veterinary medicine
mass spectrometry
air
organic dust
Limulus test
endotoxin
Opis:
Air samples were collected on glass fi bre fi lters in 22 animal houses and 3 hay storage barns and examined for the presence of bacterial endotoxin with the Limulus (LAL) test and the gas chromatography – tandem mass spectrometry (GC-MSMS) technique, based on detection of 3-hydroxy fatty acids (3-OH-FAs) as chemical markers of the endotoxin lipopolysaccharide. The median concentrations of airborne endotoxin determined with LAL test in poultry houses, sheep sheds, piggeries, cow barns, and horse stables were respectively 62.49 μg/m3, 26.2 μg/m3, 3.8 μg/m3, 1.65 μg/m3, and 1.14 μg/m3, while those determined with the GC-MSMS technique were respectively 1.06 μg/m3, 7.91 μg/m3, 0.2 μg/m3, 0.31 μg/m3, and 1.42 μg/m3. The median concentrations of airborne endotoxin determined with LAL test and GC-MSMS technique in hay storage barns were much smaller, 0.09 μg/m3 and 0.03 μg/m3, respectively. The concentrations of airborne endotoxin (LPS) detected with GC-MSMS method in the air of sheep sheds were signifi cantly greater than in all other examined facilities, while those detected in hay storage barns were signifi cantly smaller than in all other examined facilities (p<0.05). The concentrations of airborne endotoxin determined with LAL test and GC-MSMS analysis exceeded in most of animal houses examined (91% by each method) the threshold limit value for airborne endotoxin of 0.1 μg/m3 proposed by various authors. A signifi cant correlation (p<0.05) between the concentrations of endotoxin determined with the LAL and GC-MSMS techniques was found in the air samples collected in poultry houses and sheep sheds, but not in other examined facilities. 3-OH FAs with C14-C18 chains were predominant in the air of the facilities under study. A signifi cant correlation (p<0.05) was found between the concentrations of endotoxin determined with LAL test and the amounts of 3-OH FAs with C14-C16 chains. In conclusion, endotoxin in the concentrations detected in this study may present a respiratory hazard to both humans and livestock animals.
Źródło:
Annals of Agricultural and Environmental Medicine; 2007, 14, 2
1232-1966
Pojawia się w:
Annals of Agricultural and Environmental Medicine
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation of a solid product with high water content and water retention properties
Autorzy:
Cvijić, Marko
Golob, Janvit
Powiązania:
https://bibliotekanauki.pl/articles/778509.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
water in organic phase emulsion
phase equilibrium
mass transfer
Luikov’s parameters
theory of drying
Opis:
This work presents the development of a solid product with a high water content (99.08%) and water retention properties. Water was chosen as a potential carrier of a volatile active substance and water retaining properties of material were studied at a temperatures and relative air humidity values with the support of the theory of drying. The study first confirmed the role of Gibbs’ phase rule in the research of solid-gas phase equilibrium, and second presented drying kinetics developed from Fick’s second law and expressed with the first term of the Fourier equation. Solutions of equations for phase equilibrium and mass transfer enabled the calculation of Luikov’s parameters, which are important for equilibrium relations and for the diffusivity of water in a solid for mass transfer prediction. The obtained thermodynamic and kinetic parameters enabled product characterisation that may be important for the prediction of retention times.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 3; 17-23
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of Selected Technical and Technological Parameters of the Sewage Sludge Stability Process
Autorzy:
Bartkowska, I.
Wawrentowicz, D.
Powiązania:
https://bibliotekanauki.pl/articles/123847.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
autothermal thermophilic stabilization
sewage sludge
dry mass
organic substances
sewage sludge hygienization
sewage sludge in agriculture
Opis:
The article presents the results of the analysis, which was carried out in 2015-2017 on the example of autothermal installation of thermophilic sludge stabilization (ATAD) in a sewage treatment plant in Giżycko. The installation was created in 2003 as the first of its kind and still remains operational. The purpose of the conducted research was to assess the suitability of the analyzed technological parameters as tools that can be used by operators to determine the actual possibilities of changing the operating conditions of the installation or to develop an optimization strategy to reduce the energy demand. The dry mass content and organic dry mass content was used as the assessment indicators. In the analysed period, the sludge from the process contained from 47.47% to 60.80% of organic matter in the dry mass of the sludge. The organic dry matter decrease due to the process was also calculated, and it ranged from 26.4% to 48.7%. The amount of sludge undergoing the process and the amount of electricity consumption were also analysed. On this basis, the energy consumption indicators in the ATAD process were calculated.
Źródło:
Journal of Ecological Engineering; 2018, 19, 4; 69-74
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Antifungal activity of Trichoderma VOCs against Pyrenophora teres, the causal agent of barley net blotch
Autorzy:
Moya, P.
Girotti, J.R.
Toledo, A.V.
Sisterna, M.N.
Powiązania:
https://bibliotekanauki.pl/articles/65288.pdf
Data publikacji:
2018
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
biological control
biopesticide
fungi
gas chromatography
mass spectrometry
pathogen
Pyrenophora teres
Trichoderma
antifungal activity
volatile organic compound
Opis:
Many species of Trichoderma produce secondary metabolites such as volatile organic compounds (VOCs) that reduce plant diseases and promote their growth. In this work we evaluated the antagonistic effects of VOCs released by eight strains of two Trichoderma species against Pyrenophora teres Drechsler, the causal agent of barley net blotch. Antagonism was estimated based on the percentage of mycelial growth inhibition according to the confronted cultures method. VOCs extraction and identification were performed by gas chromatography and mass spectrometry, through different methodologies for VOCs emitted by antagonists and pathogens alone or when confronted. VOCs produced by all Trichoderma strains inhibited mycelial growth of the pathogen in a range of 3 to 32%, showing weak and unpigmented mycelia with vacuolization. In addition, P. teres stimulated the release of VOCs by both Trichoderma species. The major groups of VOCs detected were sesquiterpenes, followed by diterpenes, terpenoids and eight-carbon compounds. This is the first report about characterization of volatiles emitted by Trichoderma in the presence of P. teres.
Źródło:
Journal of Plant Protection Research; 2018, 58, 1
1427-4345
Pojawia się w:
Journal of Plant Protection Research
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The influence of selected plant polyamines on feeding and survival of grain aphid (Sitobion avenae F.)
Autorzy:
Sempruch, C.
Leszczynski, B.
Kozik, A.
Chrzanowski, G.
Powiązania:
https://bibliotekanauki.pl/articles/55382.pdf
Data publikacji:
2010
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
plant polyamine
Sitobion avenae
body mass
aphid
survival
polyamine
grain aphid
Hemiptera
Aphididae
feeding
organic compound
biological modulator
insect
Opis:
The influence of common plant polyamines on feeding behaviour and survival of grain aphid (Sitobion avenae F., Hemiptera: Aphididae) has been studied. Laboratory tests showed that wingless females of S. avenae assimilated higher quantities of food from triticale seedlings placed in 0.01% solutions of agmatine and cadaverine, and lower in case of spermidine and spermine. Increase in the polyamines concentrations up to 0.10% caused strong decrease in food assimilation, especially under the agmatine, cadaverine and putrescine treatment. Moreover, 0.10% concentration of the all analyzed polyamines decreased body mass and reduced survival of grain aphid wingless females. The 0.01% concentration of the polyamines were not affecting survival and body mass of S. avenae with exception of spermidine. Importance of the polyamines as potential natural biopesticides to the grain aphid is discussed.
Źródło:
Pestycydy; 2010, 1-4
0208-8703
Pojawia się w:
Pestycydy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of the productivity of cereals with undersown serradella grown for green mass
Porównanie produkcyjności zbóż z wsiewką seradeli uprawianych na zieloną masę
Autorzy:
Bojarszczuk, J.
Księżak, J.
Staniak, M.
Powiązania:
https://bibliotekanauki.pl/articles/335859.pdf
Data publikacji:
2015
Wydawca:
Sieć Badawcza Łukasiewicz - Przemysłowy Instytut Maszyn Rolniczych
Tematy:
green mass
organic farm
spring cereals
undersown serradella
winter cereals
rolnictwo ekologiczne
wsiewka seradeli
zboża jare
zboża ozime
zielona masa
Opis:
The aim of the study was to assess the yielding of four cereal species harvested at milky-dough maturity stage for green mass, cultivated in pure sowing and with undersown serradella in organic farm. Field experiment was carried out in the years 2011-2013, in a split-plot design, in four replications. The experiment included two factors. Four species of cereals, winter cereals: rye, spelt wheat and spring cereals: barley and oats were the first factor. A second factor involved the method of cereal cultivation: pure sowing, or sowing with undersown serradella. The studies showed that yield level of cereals grown with undersown serradella depended on weather conditions, which varied during the experiments. Among the tested species of cereal, the highest grain yields were obtained with oats, grown both with undersown serradella, and in pure stands. The yield of green mass of serradella depended on the species of cereal, which was used as a protective crop. Higher yields of serradella were recorded when it was undersown into spring cereals, compared to its undersowing into winter cereals. It yielded highest when cultivated with barley, slightly lower - with winter rye and the lowest - with oats. Undersowing serradella into barley and winter wheat had a little impact on the contents of total N., and Corg in the soil, compared to pure sowings of cereals, while undersowing it into oats caused a decrease in their amounts.
Celem przeprowadzonych badań była ocena poziomu plonowania czterech gatunków zbóż zbieranych w dojrzałości mleczno-woskowej uprawianych w siewie czystym oraz z wsiewką seradeli w warunkach gospodarowania ekologicznego. Doświadczenie polowe przeprowadzono w latach 2011-2013, w układzie losowanych podbloków (split-plot), w czterech powtórzeniach. W doświadczeniu uwzględniono cztery gatunki zbóż: żyto ozime, pszenica orkisz, jęczmień jary, owies. Drugim czynnikiem był sposób uprawy zbóż: siew czysty lub z wsiewką seradeli. W badaniach wykazano, że poziom plonowania zbóż uprawianych z wsiewką seradeli zależał od przebiegu warunków pogodowych, które były zróżnicowane w czasię prowadzenia doświadczeń. Spośród badanych gatunków zbóż najwyższe plony uzyskano z owsa, uprawianego zarówno z wsiewką seradeli jak w siewie czystym. Plon zielonej masy seradeli uzależniony był od gatunku zboża, jako rośliny ochronnej. Większe plony seradeli zebrano, gdy była wsiewana w zboża jare niż w ozime. Najlepiej plonowała w uprawie z jęczmieniem, nieco mniej z żytem ozimym, zaś najniżej z owsem. Wsiewanie seradeli w jęczmień oraz zboża ozime miało niewielki wpływ na zawartość Ncałk. i Corg w glebie w porównaniu do siewu czystego zbóż, natomiast wsiewanie w owies powodowało zwiększenie ich zawartości.
Źródło:
Journal of Research and Applications in Agricultural Engineering; 2015, 60, 3; 16-20
1642-686X
2719-423X
Pojawia się w:
Journal of Research and Applications in Agricultural Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Emission of volatile organic compounds (VOC) from waterborne lacquers with different content of solids
Emisja lotnych związków organicznych (VOC) z wodorozcieńczalnych wyrobów lakierowych o zróżnicowanej zawartości ciał stałych
Autorzy:
Stachowiak-Wencek, A.
Pradzynski, W.
Powiązania:
https://bibliotekanauki.pl/articles/52642.pdf
Data publikacji:
2011
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Technologii Drewna
Tematy:
emission
volatile organic compound
lacquer
solid content
water-borne lacquer
gas chromatography-mass spectrometry
thermal desorption
wood-based material
wood
Opis:
This paper presents the results of investigations on the emission of volatile organic compounds (VOC) from oak wood surfaces finished with acrylic waterborne lacquers. The lacquers selected for the experiments were characterised by a different content of solids, fluctuating between 32 and 38%. The volatile organic compounds were analysed using a gas chromatography technique combined with mass spectrometry and thermal desorption (GC/MS/TD). Tenax TA was employed as an adsorption medium. The obtained results indicate that volatile organic compound emissions from the experimental waterborne lacquers varied widely from 388 to 1794 μg/m3. The most important constituents of emissions included compounds that belonged mainly to glycol ethers as well as aliphatic and aromatic hydrocarbons.
Przedstawiono wyniki badań emisji lotnych związków organicznych z powierzchni drewna dębowego, uszlachetnionego akrylowymi lakierami wodorozcieńczalnymi. Użyte wyroby lakierowe charakteryzowały się różną zawartością ciał stałych, która zmieniała się w zakresie od 32 do 38%. Lotne związki organiczne analizowano techniką chromatografii gazowej połączonej ze spektrometrią mas i termiczną desorpcją (GC/MS/TD). Jako medium adsorpcyjne zastosowano Tenax TA. Uzyskane rezultaty wskazują, iż emisja lotnych związków organicznych z wyrobów wodorozcieńczalnych zmieniała się w szerokim zakresie, od 388 do 1794 μg/m3. Głównymi składnikami emisji były związki należące w większości do eteroglikoli, węglowodorów alifatycznych oraz aromatycznych.
Źródło:
Drewno. Prace Naukowe. Doniesienia. Komunikaty; 2011, 54, 186
1644-3985
Pojawia się w:
Drewno. Prace Naukowe. Doniesienia. Komunikaty
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Proton transfer reaction mass spectrometry approach to monitor monoterpenes emission from Aleppo pine (Pinus halepensis) woods growing in different locations
Autorzy:
Sandak, J.
Sandak, A.
Boschetti, A.
Dimauro, M.
Negri, M.
Powiązania:
https://bibliotekanauki.pl/articles/29887.pdf
Data publikacji:
2010
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
proton transfer reaction mass spectrometry
monoterpene
monoterpene emission
Aleppo pine
Pinus halepensis
wood
tree location
wood provenience
volatile organic compound
detection
France
Algeria
Źródło:
Folia Forestalia Polonica. Series B - Drzewnictwo; 2010, 41
0071-6685
Pojawia się w:
Folia Forestalia Polonica. Series B - Drzewnictwo
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Organic geochemistry of Upper Carboniferous bituminous coals and clastic sediments from the Lublin Coal Basin (Poland)
Autorzy:
Karger, M.
Gazda, L.
Grafka, O.
Powiązania:
https://bibliotekanauki.pl/articles/139223.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Lublin Coal Basin
bituminous coal
gas chromatography-mass spectrometry
biomarkers
terrigenous organic matter
Lubelskie Zagłębie Węglowe
chromatografia gazowa ze spektrometrią mas
biomarkery
materia organiczna
Opis:
Bituminous coals and clastic rocks from the Lublin Formation (Pennsylvanian, Westphalian B) were subjected to detailed biomarker and Rock-Eval analyses. The investigation of aliphatic and aromatic fractions and Rock-Eval Tmax suggests that the Carboniferous deposits attained relatively low levels of thermal maturity, at the end of the microbial processes/initial phase of the oil window. Somewhat higher values of maturity in the clastic sediments were caused by postdiagenetic biodegradation of organic matter. The dominance of the odd carbon-numbered n-alkanes in the range n-C25 to n-C31 , high concentrations of moretanes and a predominance of C28 and C29 steranes are indicative of a terrigenous origin of the organic matter in the study material. This is supported by the presence of eudesmane, bisabolane, dihydro-ar-curcumene and cadalene, found mainly in the coal samples. In addition, tri- and tetracyclic diterpanes, e. g. 16β(H)-kaurane, 16β(H)-phyllocladane, 16α(H)-kaurane and norisopimarane, were identified, suggesting an admixture of conifer ancestors among the deposited higher plants. Parameters Pr/n-C17and Rdit in the coal samples show deposition of organic matter from peat swamp environments, with the water levels varying from high (water-logged swamp) to very low (ephemeral swamp). Clastic deposits were accumulated in a flood plain environment with local small ponds/lakes. In pond/lake sediments, apart from the dominant terrigenous organic matter, research also revealed a certain quantity of algal matter, indicated, i.a., by the presence of tricyclic triterpanes C28 and C29 and elevated concentrations of steranes. The Paq parameter can prove to be a useful tool in the identification of organic matter, but the processes of organic matter biodegradation observed in clastic rocks most likely influence the value of the parameter, at the same time lowering the interpretation potential of these compounds. The value of Pr/Ph varies from 0.93 to 5.24 and from 3.49 to 22.57 in the clastic sediments and coals respectively. The microbial degradation of organic matter in both type of rocks and during early stages of diagenesis is confirmed by a high concentration of hopanes, the presence of drimane homologues, bicyclic alkanes and benzohopanes. Moreover, bacteria could also have been connected with the primary input of organic matter, which is shown by the presence of e.g. C30 neohop-13(18)-ene.
Źródło:
Acta Geologica Polonica; 2013, 63, 3; 425-442
0001-5709
Pojawia się w:
Acta Geologica Polonica
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Chemical footprint of the solvent soluble extraterrestrial organic matter occluded in Sołtmany ordinary chondrite
Autorzy:
Schmitt-Kopplin, P.
Harir, M.
Kanawati, B.
Tziozis, D.
Hertkorn, N.
Gabelica, Z.
Powiązania:
https://bibliotekanauki.pl/articles/411511.pdf
Data publikacji:
2012
Wydawca:
Polskie Towarzystwo Meteorytowe
Tematy:
ordinary chondrite
extraterrestrial organic matter
carbon
nitrogen
sulphur
meteorite
Sołtmany
nuclear magnetic
resonance spectroscopy (NMR)
Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR-MS)
Opis:
By characterizing organic molecules of extra-terrestrial origin included in the Sołtmany meteorite, we also present the first results of the non-targeted chemical analysis of the methanol soluble organic matter present in an L6 ordinary chondrite. The structural characterization by means of ultrahigh resolution Fourier transform ion cyclotron mass spectrometry (FT-ICR-MS) with electrospray ionization (ESI) in negative and positive modes demonstrated an unexpected and astonishing chemical diversity with several thousand mass peaks that could be converted into C, H, N, O, S, and P elemental compositions. Molecular signatures were typically those of considerably oxygenated CHO and CHOS molecular series of primarily aliphatic character. 1H nuclear magnetic resonance (NMR) spectroscopy confirmed the prevalent existence of pure and functionalized aliphatic spin systems of intermediate chain length (C3-4 units), oxygenated aliphatics and a considerable diversity of oxygenated aromatics in the proton-based abundance ratio near 24 : 2 : 1. Although only residual organic matter allegedly survives in highly thermally altered L6 chondrites, the physical protection of organic matter in microcavities and traps between mineral surfaces might have supported and governed the chemistry with an apparent recalcitrance of extraterrestrial organic matter (EOM). Future studies of the organic matter in ordinary chondrites and its composition and structure in various regimes of (e.g.) temperature, radiation, pressure, and water content could shed light on these meteorites’ formation and evolution.
Źródło:
Meteorites; 2012, 2, No. 1-2; 79-92
2299-0313
2299-1220
Pojawia się w:
Meteorites
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Concentration of volatile organic compounds in the production halls of a selected furniture manufacturing plant
Stężenie lotnych związków organicznych na terenie hal produkcyjnych w wybranym zakładzie przemysłu meblarskiego
Autorzy:
Stachowiak-Wencek, A.
Pradzynski, W.
Powiązania:
https://bibliotekanauki.pl/articles/52520.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Technologii Drewna
Tematy:
compound concentration
volatile organic compound
production hall
furniture industry
manufacturing plant
air pollution
gas chromatography-mass spectrometry
dust
pollen
fungal spore
mould
chemical pollutant
human disease
Opis:
The aim of this study was to determine the concentrations of volatile organic compounds found in the air in five production halls at a furniture manufacturing plant. Tests were performed in production halls, where machining operations were performed both on wood and wood-based materials, in shop halls in which surface-finishing operations were performed, as well as a finished goods warehouse.A Tenax TA synthetic sorbent was used to adsorb compounds found in the air.Volatile substances were analysed by gas chromatography combined with mass spectrometry and thermal desorption. It was found that the microclimate in the examined production halls varied. Differences were observed not only in the type of compounds detected in the shop halls, but also in their amounts. The analysed air contained a broad spectrum of volatile compounds, mainly alcohols, glycols, aromatic hydrocarbons, aldehydes, esters and terpenes. The total concentrationof volatile organic compounds (TVOC) found in the air in the examined production halls varied within a very broad range from 795 to 5113 μg/m3. The concentrations of volatile organic compounds identified in the production halls were markedly lower than those specified by Polish legal regulations - the Ordinance of the Minister of Labour and Social Policy of 2002 (with later amendments).
Celem pracy było określenie stężenia lotnych związków organicznych występujących w powietrzu na terenie pięciu hal produkcyjnych w zakładzie przemysłu meblarskiego. Badaniu poddano hale, w których przeprowadzano zarówno obróbkę mechaniczną drewna i tworzyw drzewnych, jak i hale, w których wykonywano operacje uszlachetniania powierzchni oraz magazyn wyrobów gotowych. Adsorpcję związków obecnych w powietrzu przeprowadzano na sorbencie syntetycznym Tenax TA. Lotne substancje analizowano techniką chromatografii gazowej w połączeniu ze spektrometrią mas i termiczną desorpcją. Stwierdzono, że mikroklimat badanych hal produkcyjnych był zróżnicowany, tak pod względem rodzaju, jak ilości występujących w nich związków. Całkowite stężenie lotnych związków organicznych zmieniało się w bardzo szerokim zakresie, od 795 do 5113 μg/m3. W badanym powietrzu występowały głównie związki należące do alkoholi, glikoli, węglowodorów aromatycznych, aldehydów estrów i terpenów. Stężenie zidentyfikowanych w halach produkcyjnych lotnych związków organicznych kształtowało się na zdecydowanie niższym poziomie niż to regulują polskie przepisy prawne, rozporządzenie Ministra Pracy i Polityki Socjalnej z 2002 roku (z późniejszymi zmianami).
Źródło:
Drewno. Prace Naukowe. Doniesienia. Komunikaty; 2013, 56, 190
1644-3985
Pojawia się w:
Drewno. Prace Naukowe. Doniesienia. Komunikaty
Dostawca treści:
Biblioteka Nauki
Artykuł

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