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Wyświetlanie 1-15 z 57
Tytuł:
Examination of steam gasification of coal with physically mixed catalysts
Autorzy:
Śpiewak, Katarzyna
Czerski, Grzegorz
Sopata, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/779131.pdf
Data publikacji:
2019
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
coal gasification
kinetics
catalysts
Opis:
The aim of this study was to analyse the steam gasification process of ‘Janina’ coal with and without Na-, K- and Ca-catalysts. The catalysts were physically mixed with the coal due to the simplicity of this method, short time of execution and certainty that the amount of catalyst is exactly as the adopted one. The isothermal measurements were performed at 800, 900 and 950°C and a pressure of 1 MPa using thermovolumetric method. The obtained results enabled assessment of the effect of analysed catalysts on the process at various temperatures by determination of: i) carbon conversion degree; ii) yield and composition of the resulting gas; and iii) kinetics of formation reactions of main gas components – CO and H2. The addition of catalysts, as well as an increase in operating temperature, had a positive effect on the coal gasification process – reactions rates increased, and the process time was reduced.
Źródło:
Polish Journal of Chemical Technology; 2019, 21, 4; 51-57
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ca-Modified Co/SBA-15 Catalysts for Hydrogen Production through Ethanol Steam Reforming
Autorzy:
Chiou, J. Y. Z.
Liu, S. W.
Ho, K. F.
Huang, H. H.
Tang, Ch. W.
Wang, Ch. B.
Powiązania:
https://bibliotekanauki.pl/articles/411682.pdf
Data publikacji:
2014
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
cobalt catalysts
ethanol
steam reforming
Opis:
Hydrogen production through steam reforming of ethanol (SRE) over the Ca-modified Co/SBA-15 catalysts was studied herein to evaluate the catalytic activity, stability andthebehavior of coke deposition.The Ca-modified SBA-15 supports were prepared from the Ca(NO3)2•4H2O (10 wt%) which was incorporated to SBA-15 by incipient wetness impregnation (assigned as Ca/SBA-15) and direct hydrothermal (assigned as Ca-SBA-15) method. The active cobalt species from the Co(NO3)2•6H2O (10 wt%) was loaded to SiO2, SBA-15 and modified-SBA-15 supports with incipient wetness impregnation method to obtain the cobalt catalysts (named as Co/SiO2, Co/SBA-15, Co-Ca/SBA-15 and Co/Ca-SBA-15, respectively). The prepared catalysts were characterized by using X-ray diffraction (XRD), temperature programmed reduction (TPR), transmission electron microscopy (TEM) and BET.The catalytic performance of the SRE reaction was evaluated in a fixed-bed reactor.The results indicated that the Co/Ca-SBA-15 catalystwas preferential among these catalysts and the ethanol can be converted completely at 375 °C. The hydrogen yield (YH2) approached 4.76 at 500 °C and less coke deposited. Further, the long-term stabilitytest of this catalyst approached100h at 500 °C and did not deactivate.
Źródło:
International Letters of Chemistry, Physics and Astronomy; 2014, 5; 1-16
2299-3843
Pojawia się w:
International Letters of Chemistry, Physics and Astronomy
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Polysiloxanes as supports for transition metal catalysts
Polisiloksany jako nośniki katalizatorów na bazie metali przejściowych
Autorzy:
Cypryk, M.
Pospiech, P.
Powiązania:
https://bibliotekanauki.pl/articles/947463.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Chemii Przemysłowej
Tematy:
polysiloxanes
polymer-supported catalysts
palladium
rhodium
immobilized catalysts
polisiloksany
polimerowe nośniki katalizatorów
pallad
rod
katalizatory immobilizowane
Opis:
This article reviews the potential applicability of polysiloxanes as supports for transition metal catalysts. Unique physicochemical properties of polysiloxanes suggest their usefulness as catalyst supports. Polysiloxanes of various macromolecular topologies – linear and star-shaped and hyperbranched – with the functional side groups capable of binding transition metals were prepared. These polymers were used as carriers for palladium and rhodium complexes. The activities of so-immobilized complexes of transition metals in model reactions were comparable to that of the corresponding homogeneous complexes of these metals.
Przedstawiono przegląd potencjalnych zastosowań polisiloksanów jako nośników katalizatorów opartych na metalach przejściowych. Unikatowe właściwości fizykochemiczne polisiloksanów wskazują na ich przydatność w charakterze nośników katalizatorów. Otrzymano polisiloksany o różnych topologiach makrocząsteczek – liniowych, gwiaździstych i hiperrozgałęzionych – zawierających boczne grupy funkcyjne zdolne do wiązania metali przejściowych. Polimery te wykorzystano jako nośniki kompleksów palladu i rodu. Immobilizowane kompleksy metali przejściowych w modelowych reakcjach wykazały aktywność porównywalną z aktywnością katalizatorów homogenicznych.
Źródło:
Polimery; 2016, 61, 6; 407-412
0032-2725
Pojawia się w:
Polimery
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dissolution of Metal Supported Spent Auto Catalysts in Acids
Autorzy:
Fornalczyk, A.
Kraszewski, M.
Willner, J.
Kaduková, J.
Mrážiková, A.
Marcinčáková, R.
Velgosová, O.
Powiązania:
https://bibliotekanauki.pl/articles/353228.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
dissolution
metal supported auto catalysts
metal substrate
Opis:
Metal supported auto catalysts, have been used in sports and racing cars initially, but nowadays their application systematically increases. In Metal Substrate (supported) Converters (MSC), catalytic functions are performed by the Platinum Group Metals (PGM): Pt, Pd, Rh, similarly to the catalysts on ceramic carriers. The contents of these metals make that spent catalytic converters are valuable source of precious metals. All over the world there are many methods for the metals recovery from the ceramic carriers, however, the issue of platinum recovery from metal supported catalysts has not been studied sufficiently yet. The paper presents preliminary results of dissolution of spent automotive catalyst on a metal carrier by means of acids: H2SO4, HCl, HNO3, H3PO4. The main assumption of the research was the dissolution of base metals (Fe, Cr, Al) from metallic carrier of catalyst, avoiding dissolution of PGMs. Dissolution was the most effective when concentrated hydrochloric acid, and 2M sulfuric acid (VI) was used. It was observed that the dust, remaining after leaching, contained platinum in the level of 0.8% and 0.7%, respectively.
Źródło:
Archives of Metallurgy and Materials; 2016, 61, 1; 233-236
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of heating rate and solvent on Ni-based catalysts prepared by solution combustion method for syngas methanation
Autorzy:
Zeng, Yan
Ma, Hongfang
Zhang, Haitao
Ying, Weiyong
Fang, Dingye
Powiązania:
https://bibliotekanauki.pl/articles/779390.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
nickel catalysts
syngas methanation
solution combustion method
Opis:
Ni-Al2O3 catalysts prepared by solution combustion method for syngas methanation were enhanced by employing various heating rate and different solvent. The catalytic properties were tested in syngas methanation. The result indicates that both of heating rate and solvent remarkably affect Ni particle size, which is a key factor to the catalytic activity of Ni-Al2O3 catalysts for syngas methanation. Moreover, the relationship between Ni particle size and the production rate of methane per unit mass was correlated. The optimal Ni-Al2O3 catalyst prepared in ethanol at 2°C/min, achieves a maximum production rate of methane at the mean size of 20.8 nm.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 4; 95-100
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characteristics of titanium silicalite TS-1, Ti-Beta and Ti-MWW catalysts
Autorzy:
Wróblewska, A.
Fajdek, A.
Milchert, E.
Powiązania:
https://bibliotekanauki.pl/articles/779396.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
TS-1
Ti-Beta
Ti-MWW
titanium-silicalite catalysts
Opis:
The synthesis methods of the following titanium-silicalite catalysts: TS-1, Ti-Beta and Ti-MWW were presented. The results of the analyses of the catalysts by XRD, SEM and IR, UV-vis methods were also shown. A brief description of the catalytic performances of these catalysts in the oxidation process of olefins, alkenes, alcohols and aromatic compounds was presented.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 1; 64-71
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Methanol as a High Purity Hydrogen Source for Fuel Cells: A Brief Review of Catalysts and Rate Expressions
Autorzy:
Madej-Lachowska, M.
Kulawska, M.
Słoczyński, J.
Powiązania:
https://bibliotekanauki.pl/articles/185394.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
copper catalysts
noble metal catalysts
fuel cell
hydrogen production
CO-PROX
katalizatory miedziowe
katalizatory z metalu szlachetnego
ogniwo paliwowe
produkcja wodoru
Opis:
Hydrogen is the fuel of the future, therefore many hydrogen production methods are developed. At present, fuel cells are of great interest due to their energy efficiency and environmental benefits. A brief review of effective formation methods of hydrogen was conducted. It seems that hydrogen from steam reforming of methanol process is the best fuel source to be applied in fuel cells. In this process Cu-based complex catalysts proved to be the best. In presented work kinetic equations from available literature and catalysts are reported. However, hydrogen produced even in the presence of the most selective catalysts in this process is not pure enough for fuel cells and should be purified from CO. Currently, catalysts for hydrogen production are not sufficiently active in oxidation of carbon monoxide. A simple and effective method to lower CO level and obtain clean H2 is the preferential oxidation of monoxide carbon (CO-PROX). Over new CO-PROX catalysts the level of carbon monoxide can be lowered to a sufficient level of 10 ppm.
Źródło:
Chemical and Process Engineering; 2017, 38, 1; 147-162
0208-6425
2300-1925
Pojawia się w:
Chemical and Process Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Factors Affecting of Porous Properties of Carbon Gel Microsphere
Autorzy:
Elsayed, M. A.
Powiązania:
https://bibliotekanauki.pl/articles/1194052.pdf
Data publikacji:
2015
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
base catalysts
carbon microsphere
nitrogen adsorption
sol-gel polycondensation
Opis:
Carbon microsphere with high porosity and surface area were synthesized via the sol-gel polycondensation of resorcinol with formaldehyde in a slightly basic medium and followed by drying and pyrolysis. The effects of different parameters during synthesis were investigated. The porous properties of carbon microsphere were evaluated by nitrogen adsorption method and scanning electron microscopy (SEM). By changing both the catalyst species and resorcinol to catalyst ratio (R/C), it was possible to prepare ultramicroporous carbon sphere with pore size about 1.8 nm. The samples evolve from micro-mesoporous solid (RF-Na2CO3: combination of types I and IV isotherms) with 24.2% micropore to an exclusively microporous material (RF-NH4HCO3: type I isotherm) with 98.7% micropore. The results show that it is possible to tailor the morphology of these materials by varying the initial pH of the precursor’s solution in a narrow range and that the micropore surface area and micropore volume are independent from the initial pH, while the BET surface area vary from 582 m2/g (pH = 3.2) to 680 m2/g (pH = 6). However, as the pH increases over pH = 6 the surface area is decreases. These materials can be used as packing for separation columns or as catalysts supports.
Źródło:
World Scientific News; 2015, 13; 80-94
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalysts preparation and investigation: laboratory exercise for students
Autorzy:
Zawadzki, Witold
Powiązania:
https://bibliotekanauki.pl/articles/2079940.pdf
Data publikacji:
2019
Wydawca:
Uniwersytet Marii Curie-Skłodowskiej. Wydawnictwo Uniwersytetu Marii Curie-Skłodowskiej
Tematy:
laboratory course
catalysts preparation
TPR
TG
CO2 methanation
Opis:
Catalysts preparation, investigation its basic properties, activity and selectivity measurements in carbon dioxide methanation reaction was proposed as laboratory course for international students doing a period of study at Maria Curie-Sklodowska University within the frame of the Erasmus mobility programme.
Źródło:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia; 2019, 74, 1; 31-40
2083-358X
Pojawia się w:
Annales Universitatis Mariae Curie-Skłodowska, sectio AA – Chemia
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of vanadium, potassium and iron from spent vanadium catalyst by leaching with citric acid at atmospheric pressure
Autorzy:
Mazurek, K.
Powiązania:
https://bibliotekanauki.pl/articles/778659.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
citric acid
sulphur oxide
spent vanadium catalysts
leaching
recovery
Opis:
The effect of time, temperature, the catalyst particle size and the ratio of the catalyst weight to the leaching solution volume (S:L) on the treatment of spent vanadium catalyst components was determined using citric acid solutions at atmospheric pressure. The optimal parameters of catalyst leaching in 10% acid solutions at atmospheric pressure are: T = 323 K, t = 4 h, the particle size of less than 0.160 mm, the S:L ratio below 0.1. Under these conditions it was possible to dissolve about 90% of vanadium and potassium compounds and more than 60% of iron compounds contained in the catalyst. These results fall within the scope of research on a comprehensive method for recovering spent vanadium catalyst components.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 1; 59-62
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the exchanged metal ions (Cu, Co, Ni and Mn) on the selective catalytic reduction of NO with hydrocarbons over modified ferrierite
Autorzy:
Ćwikła-Bundyra, W.
Powiązania:
https://bibliotekanauki.pl/articles/778840.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
catalytic reduction
nitrogen oxides
ferrierite
selective catalysts
ion exchanged
Opis:
This article presents the research results concerning the possibilities of natural zeolite-ferrierite application for the reduction of nitrogen oxide. H-FER forms were modified by Cu+2, Co+2, Mn+2, Ni+2 using an ion exchange procedure. The effect of metal contents was shown for the ferrierite matrices and related to their catalytic properties. The catalytic properties of Cu-, Co-Ni-, and Mn- were compared for NO reduction with methane. High NO conversion was observed for copper and cobalt-ferrierite catalysts, especially in the temperature range 400 and 500oC. It was found that copper- and cobalt-ferrierite catalysts have higher activity and N2 selectivity than the catalysts composed of nickel and manganese doped on ferrierite. Moreover, the nickel and manganese containing catalysts produced more nitrous oxide than nitrogen. The presence of both copper and cobalt species seems to be an indispensable condition for a large activity and selectivity in the NO reduction.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 2; 10-15
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Ionic liquid assisted olefin reactions
Autorzy:
Thirunarayanan, G.
Muthuvel, I.
Sathiyendiran, V.
Powiązania:
https://bibliotekanauki.pl/articles/1075429.pdf
Data publikacji:
2019
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Ionic liquids
Metal complexes
Nano catalysts
alkene reactions
olefin reactions
Opis:
In this review article the authors studied the ionic liquid assisted various alkene reactions with various metal complex catalysts such as Isomerization, Hydrogenation, Hydroformylation, Metathesis-Oligomerization, Dimerization, Arylation, Cyclization, Polymerization, Epoxidation, Michael addition and Tandem Cross-coupling reactions.
Źródło:
World Scientific News; 2019, 126; 36-64
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrocarbon Synthesis During Methane Pyrolysis
Synteza węglowodorów podczas pirolizy metanu
Autorzy:
Pavlenko, Anatoliy
Klas, Engvall
Powiązania:
https://bibliotekanauki.pl/articles/1811601.pdf
Data publikacji:
2020
Wydawca:
Politechnika Koszalińska. Wydawnictwo Uczelniane
Tematy:
methane pyrolysis
modified catalysts
hydrocarbons
piroliza metanu
modyfikowane katalizatory
węglowodory
Opis:
The catalyzed conversion of acetylene to higher hydrocarbons has been studied by many researchers. The importance of these processes is determined by the fact that a successful conversion of this type will create technologies for obtaining cheap alternative synthetic fuel. Acetylene can be obtained in large quantities from coal and methane, which opens up the possibility of obtaining the specified synthetic fuel. However, the lack of an effective catalyst for continuous conversion has not allowed the development of this alternative fuel route. Features of hydrocarbon synthesis during methane pyrolysis, based on modified catalysts, are presented in the paper. It is demonstrated that production of hydrocarbons from pyrolysis gas using modified catalysts can be intensified.
Katalityczna konwersja acetylenu do wyższych węglowodorów była przedmiotem badań wielu badaczy. Znaczenie tych procesów determinuje fakt, że udana konwersja tego typu pozwoli nam opracować nowe technologie pozyskiwania taniego alternatywnego paliwa syntetycznego. Acetylen można uzyskać w dużych ilościach z węgla i metanu, co otwiera możliwość uzyskania określonego paliwa syntetycznego. Jednak brak skutecznego katalizatora do ciągłej konwersji nie pozwolił na opracowanie tej alternatywnej drogi paliwowej. W artykule przedstawiono cechy syntezy węglowodorów podczas pirolizy metanu na modyfikowanych katalizatorach. Wykazano, że można zwiększyć produkcję węglowodorów z gazu pirolitycznego na modyfikowanych Со-katalizatorach.
Źródło:
Rocznik Ochrona Środowiska; 2020, Tom 22, cz. 1; 196-202
1506-218X
Pojawia się w:
Rocznik Ochrona Środowiska
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation and characterization of multi-walled carbon nanotubes grown on transition metal catalysts
Autorzy:
Pełech, I.
Narkiewicz, U.
Kaczmarek, A.
Jędrzejewska, A.
Powiązania:
https://bibliotekanauki.pl/articles/779825.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
catalysts
carbon nanotubes
chemical vapor deposition
X-ray diffraction
thermogravimetry
Opis:
Transition metal catalysts (mainly: iron, cobalt and nickel) on various supports are successfully used in a largescale production of carbon nanotubes (CNTs), but after the synthesis it is necessary to perform very aggressive purification treatments that cause damages of CNTs and are not always effective. In this work a preparation of unsupported catalysts and their application to the multi-walled carbon nanotubes synthesis is presented. Iron, cobalt and bimetallic iron-cobalt catalysts were obtained by co-precipitation of iron and cobalt ions followed by solid state reactions. Although metal particles were not supported on the hard-to-reduce oxides, these catalysts showed nanometric dimensions. The catalysts were used for the growth of multi-walled carbon nanotubes by the chemical vapor deposition method. The syntheses were conducted under ethylene - argon atmosphere at 700°C. The obtained catalysts and carbon materials after the synthesis were characterized using transmission electron microscopy (TEM), X-ray diffraction method (XRD), Raman spectroscopy and thermogravimetric analysis (TG). The effect of the kind of catalyst on the properties of the obtained carbon material has been described.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 1; 117-122
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fe-modified activated carbon obtained from biomass as a catalyst for α-pinene autoxidation
Autorzy:
Kamińska, Adrianna
Maciejewska, Nikola
Miądlicki, Piotr
Kiełbasa, Karolina
Sreńscek-Nazzal, Joanna
Michalkiewicz, Beata
Powiązania:
https://bibliotekanauki.pl/articles/1849280.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
activated carbon
carbonaceous catalysts
autoxidation
alpha-pinene
iron particles
biomass
Opis:
The presented work describes the autoxidation of alpha-pinene for the first time using a catalyst based on activated carbon from biomass with introduced Fe. The raw material for the preparation of the carbon material was waste orange peel, which was activated with a KOH solution. The following instrumental methods characterized the obtained catalyst (Fe/O_AC):N2 adsorption at 77 K, XRD, UV, SEM, TEM, X-ray microanalysis, and catalytic studies. It was shown that the Fe/O_AC catalyst was very active in the autoxidation of alpha-pinene. The main reaction products were: alpha-pinene oxide, verbenone, verbenol, and campholenic aldehyde.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 73-80
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 57

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