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Tytuł:
Hydrogen effect on the electronic and structural properties of Nb-Fe alloys
Autorzy:
Brzeska-Michalak, B.
Ostrasz, A.
Powiązania:
https://bibliotekanauki.pl/articles/148793.pdf
Data publikacji:
2003
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
Mössbauer spectroscopy of 57Fe
iron-niobium alloys
niobium hydrides
Opis:
The influence of hydrogen on the electronic and structural properties of Nb1-yFey alloys has been studied with 57Fe Mössbauer spectroscopy and X-ray diffraction. No ability of hydrogen to creation of the ferromagnetic properties has been observed in this system. The results clearly indicate the ß-NbH0.85÷0.77 hydride formation in place of ?-Nb phase. The quadrupole splitting and the isomer shift of the ß-NbHx subspectrum have been considered in terms of interaction between the interstitials and the Mössbauer atoms within the hydride phase.
Źródło:
Nukleonika; 2003, 48,suppl.1; 53-57
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Effects of Niobium on the Bioactivity of Ni-Ti-Al-Nb Shape Memory Alloys
Autorzy:
Teixeira, Ricardo Luiz Perez
de Lacerda, José Carlos
Conceição, Isabella Carolina
da Silva, Sidney Nicodemos
Siqueira, Guilherme O.
Moura, Francisco
Powiązania:
https://bibliotekanauki.pl/articles/2049692.pdf
Data publikacji:
2021
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
nitinol
niobium
aluminum
bioactivity
cytotoxicity
Opis:
This work aims to analyze the effects of niobium on the bioactivity of a titanium, nickel, aluminum, and niobium alloy obtained by the Plasma Skull Push Pull process (PSPP). Titanium alloys, such as NiTinol (NiTi), are metallic biomaterials that have wide application in health and surgical prostheses. In this work the microstructural and bioactivity characteristics of the alloys are evaluated. The addition of aluminum improves alloy ductility and reduces its cost. The addition of niobium favors the hydroxyapatite nucleation. Therefore, the addition of the combination of the two elements contributes to lower cost and better alloy bioactivity.
Źródło:
Archives of Metallurgy and Materials; 2021, 66, 2; 437-442
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High Versatility of Niobium Alloyed AHSS
Autorzy:
Kučerová, L.
Opatová, K.
Káňa, J.
Jirková, H.
Powiązania:
https://bibliotekanauki.pl/articles/958202.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
TRIP steel
niobium
heat treatment
thermomechanical treatment
Opis:
The effect of processing parameters on the final microstructure and properties of advanced high strength CMnSiNb steel was investigated. Several processing strategies with various numbers of deformation steps and various cooling schedules were carried out, namely heat treatment without deformation, conventional quenching and TRIP steel processing with bainitic hold or continuous cooling. Obtained multiphase microstructures consisted of the mixture of ferrite, bainite, retained austenite and M-A constituent. They possessed ultimate tensile strength in the range of 780-970 MPa with high ductility A5 mm above 30%. Volume fraction of retained austenite was for all the samples around 13%. The only exception was reference quenched sample with the highest strength 1186 MPa, lowest ductility A5 mm = 20% and only 4% of retained austenite.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 3; 1485-1491
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preconcentration of a low-grade betafite ore by dense medium cyclone
Autorzy:
Lv, Zihu
Wei, Min
Zhao, Dengkui
Wu, Dongyin
Liu, Changmiao
Cheng, Hongwei
Powiązania:
https://bibliotekanauki.pl/articles/2146943.pdf
Data publikacji:
2022
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
preconcentration
betafite
dense medium cyclone
uranium
niobium
Opis:
In order to find an economical and feasible short process for betafite preconcentrating and to provide a reference for the development of similar low-grade uranium deposits, preconcentration of the betafite ore was investigated based on mineralogical characterization study, float-sink tests, and dense medium cyclone (DMC) separation experiments. The float-sink test results revealed that the gravity separation of the betafite ore was feasible, and the expected particle size range was chosen to be 3~0.3 mm. The effect of important parameters of the DMC experiment such as particle size, grade of the feed, separation density, and inlet pressure on the separation performance of betafite ore was studied. Under the optimal experimental conditions, the expanded experiments were performed and the heavy minerals contained 4557 ppm U and 5200 ppm Nb2O5 with a recovery of 88.86% and 79.73%, respectively, were obtained. Besides, the enrichment ratio (E) values of U and Nb2O5 were 14.24 and 12.78 severally, and the tailings discarding ratio (R) value was 93.76%. The results demonstrate that the preconcentration of low-grade betafite by DMC can remove a large number of tailings and obtain a high-grade uranium concentrate.
Źródło:
Physicochemical Problems of Mineral Processing; 2022, 58, 1; 1--14
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of Adding Niobium and Vanadium to Fe-Based Oxide Dispersion Strengthened Alloy
Autorzy:
Park, Chun Woong
Choi, Won June
Byun, Jong Min
Kim, Young Do
Powiązania:
https://bibliotekanauki.pl/articles/353024.pdf
Data publikacji:
2020
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Fe-based ODS
vanadium
niobium
superalloy
hardness
Opis:
In this study, the effects of adding niobium and vanadium to Fe-based oxide dispersion strengthened alloys are confirmed. The composition of alloys are Fe-20Cr-1Al-0.5Ti-0.5Y2 O3 and Fe-20Cr-1Al-0.5Ti-0.3V-0.2Nb-0.5Y2 O3. The alloy powders are manufactured by using a planetary mill, and these powders are molded by using a magnetic pulsed compaction. Thereafter, the powders are sintered in a tube furnace to obtain sintered specimens. The added elements exist in the form of a solid solution in the Fe matrix and suppress the grain growth. These results are confirmed via X-ray diffraction and scanning electron microscopy analyses of the phase and microstructure of alloys. In addition, it was confirmed that the addition of elements, improved the hardness property of Fe-based oxide dispersion strengthened alloys.
Źródło:
Archives of Metallurgy and Materials; 2020, 65, 4; 1265-1268
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The alternative, novel technology for improvement of surface finish of SRF niobium cavities
Autorzy:
Rokicki, Ryszard
Hryniewicz, Tadeusz
Konarski, Piotr
Rokosz, Krzysztof
Powiązania:
https://bibliotekanauki.pl/articles/1179599.pdf
Data publikacji:
2017
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
SRF niobium cavities
electrochemical polishing
hydrogen content
surface roughness
Opis:
Pure niobium is used for making superconducting radio frequency (SRF) cavities. These cavities need to have a good surface finish to achieve maximum performance. The high smoothness, lack of subsurface hydrogen content and sulfur contamination removal of SRF niobium cavities are the three most important factors to achieving a high accelerating gradient. For finishing niobium surface, electropolishing (EP) in hydrofluoric/sulfuric acid electrolyte is commonly used as a final process. Unfortunately this process had been considered to cause hydrogen absorption that could result in hydrogen Q-disease in niobium SRF cavities. This is why a new electrolyte was compounded to substitute the one presently used. Moreover, the additional imposition of a magnetic field during the electropolishing process (magnetoelectropolishing MEP) not only increases hydrogen removal, but also results in reduction of surface roughness when compared to the roughness achieved by the electropolishing process alone (Rz much over 300 nm). This effect of sharp decrease in hydrogen content was found previously in our experiments with titanium and stainless steels after MEP processing. Our present studies, with the electrolyte consisting of a mixture of 70% methanesulfonic acid with 49% hydrofluoric acid by volume in 3:1 ratio, resulted in intensifying and speeding-up the electrochemical processes of dissolution and polishing niobium surface. It was found that the imposition of a magnetic field of ≈ 100 mT upon the EP process is able to reduce niobium surface roughness of up to 50% (Rz below 200 nm) compared to the roughness achieved by conventional electropolishing.
Źródło:
World Scientific News; 2017, 74; 152-163
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and structural characterization of niobium-doped hydroxyapatite ceramics
Autorzy:
Korzeniewski, Wojciech
Witkowska, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/284989.pdf
Data publikacji:
2019
Wydawca:
Akademia Górniczo-Hutnicza im. Stanisława Staszica w Krakowie. Polskie Towarzystwo Biominerałów
Tematy:
structure
nanoceramics
sol-gel method
hydroxyapatite
niobium
mechano-chemical synthesis
Opis:
Hydroxyapatite (HAp) ceramic materials are consi-dered as one of the most promising implant materials in bone surgery and in dentistry. They exhibit unique biocompatibility, bioactivity, and osteoconductivity, which are the most desirable biomaterial features. However, HAp itself is brittle, has low strength, high degree of crystallinity and low solubility at physiological pH. Doping synthetic HAp with metal ions plays an important role in improving its structural and physico--chemical properties. HAp doped with niobium ions has not been widely investigated so far. However, the results of studies available in the literature show that the synthesized CaO-P2O5-Nb2O5 compounds still show good biocompatibility, very low cytotoxicity and, additionally, they stimulate osteoblast proliferation. Therefore, this study is dedicated to the niobium--doped HAp ceramics obtained by two methods: mechano-chemical synthesis and sol-gel method. Bioceramics chemical composition, morphology, and structure were characterized by means of scanning electron microscopy imaging, BET method, X-ray diffraction, Fourier transform infrared spectroscopy and X-ray photoelectron spectroscopy. The results indicate that nanoceramics of non-stoichiometric HAp with a clear Ca deficiency on the nanograin surface were obtained. Moreover, it has been observed that the presence of Nb dopants and the synthesis method directly affect unit cell parameters, crystallinity degree, crystallites size, porosity and distribution of niobium in the grain structure. Mechano-chemical synthesis has allowed effective niobium incorporation into the HAp structure, leading to the quite homogeneous Nb distribution in the grain volume. Whereas, Nb-doping by sol-gel method has led to dopants location mainly on the grain surface.
Źródło:
Engineering of Biomaterials; 2019, 22, 150; 10-15
1429-7248
Pojawia się w:
Engineering of Biomaterials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Physical and chemical processes of Abu Rusheid cataclastic rocks for recovering niobium, zirconium and uranium compounds
Autorzy:
Abdellah, Walid Mahmoud
Khalafalla, Mahmoud Sayed
Abu Khoziem, Hanaa Abdelaal
El Hussain, Omneya Mouhamed
Powiązania:
https://bibliotekanauki.pl/articles/2146869.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
physical processes
chemical processes
cataclastic rocks
separation
niobium
zirconium
uraniom
Opis:
Cataclastic rocks of Abu Rushied area (South Eastern Desert, Egypt) characterized by the presence of niobium, tantalum, zirconium minerals as well as uranium-thorium minerals. Physical upgrading process was applied using gravity and magnetic separation techniques to concentrate these economic minerals mainly to obtain the magnetic niobium concentrate at 0.2- 0.5 ampere, beside the non-magnetic Zr and U at 1.5 ampere. The chemical processing upon niobium concentrate was performed using NH4F roasting process at 250ºC followed by selective precipitation of Nb as Nb-sulfide. An alkaline fusion using NaOH was applied upon zirconium concentrate at the optimum conditions of: zircon concentrate/ NaOH mass ratio 1/2, fusion temperature of 650ºC and 2.5h fusion time followed by selective precipitation of Zr as Zr- tartrate. Finally, two flowsheets were drawn summarizing the whole recovery processes.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 5; 137--152
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Leakage Current Degradation Due to Ion Drift and Diffusion in Tantalum and Niobium Oxide Capacitors
Autorzy:
Kuparowitz, M.
Sedlakova, V.
Grmela, L.
Powiązania:
https://bibliotekanauki.pl/articles/221515.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
niobium oxide capacitors
tantalum capacitors
leakage current
ion diffusion
ion drift
Opis:
High temperature and high electric field applications in tantalum and niobium capacitors are limited by the mechanism of ion migration and field crystallization in a tantalum or niobium pentoxide insulating layer. The study of leakage current (DCL) variation in time as a result of increasing temperature and electric field might provide information about the physical mechanism of degradation. The experiments were performed on tantalum and niobium oxide capacitors at temperatures of about 125°C and applied voltages ranging up to rated voltages of 35 V and 16 V for tantalum and niobium oxide capacitors, respectively. Homogeneous distribution of oxygen vacancies acting as positive ions within the pentoxide layer was assumed before the experiments. DCL vs. time characteristics at a fixed temperature have several phases. At the beginning of ageing the DCL increases exponentially with time. In this period ions in the insulating layer are being moved in the electric field by drift only. Due to that the concentration of ions near the cathode increases producing a positively charged region near the cathode. The electric field near the cathode increases and the potential barrier between the cathode and insulating layer decreases which results in increasing DCL. However, redistribution of positive ions in the insulator layer leads to creation of a ion concentration gradient which results in a gradual increase of the ion diffusion current in the direction opposite to the ion drift current component. The equilibrium between the two for a given temperature and electric field results in saturation of the leakage current value. DCL vs. time characteristics are described by the exponential stretched law. We found that during the initial part of ageing an exponent n = 1 applies. That corresponds to the ion drift motion only. After long-time application of the electric field at a high temperature the DCL vs. time characteristics are described by the exponential stretched law with an exponent n = 0.5. Here, the equilibrium between the ion drift and diffusion is achieved. The process of leakage current degradation is therefore partially reversible. When the external electric field is lowered, or the samples are shortened, the leakage current for a given voltage decreases with time and the DCL vs. time characteristics are described by the exponential stretched law with an exponent n = 0.5, thus the ion redistribution by diffusion becomes dominant.
Źródło:
Metrology and Measurement Systems; 2017, 24, 2; 255-264
0860-8229
Pojawia się w:
Metrology and Measurement Systems
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High temperature oxidation behaviour of TiAl8Nb alloy
Badania wysokotemperaturowego utleniania stopu TiAl8Nb
Autorzy:
Przybylski, K.
Prażuch, J.
Brylewski, T.
Durda, E.
Powiązania:
https://bibliotekanauki.pl/articles/353677.pdf
Data publikacji:
2013
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
intermetallics
titanium aluminides
niobium
oxidation
związki międzymetaliczne
Ti-Al
niob
utlenianie
Opis:
The goal of this work is to determine the effect of niobium on the kinetics and mechanism of Ti-Al oxidation in air. In order to compare the oxidation kinetics of Ti-Al and Ti-Al with the addition of niobium, isothermal oxidation was performed on Ti-48Al and Ti-46Al-8Nb (in at.%) alloys at 1073 K in synthetic air. Cyclic oxidation of Ti-46Al and Ti-46Al-8Nb alloys was carried out in laboratory air for 42 cycles (1 cycle, 24 hrs). The morphology, as well as chemical and phase composition of the oxidation products were investigated using X-ray Diffraction (XRD) and Scanning Electron Microscopy combined with Energy Dispersive Spectroscopy (SEM-EDS). From these investigations it can be concluded that niobium addition increases the corrosion resistance of TiAl and, furthermore, improves the adherence between the metallic substrate and the oxide scale. The oxidation mechanism of Ti-46Al-8Nb was studied via secondary neutral mass spectroscopy (SNMS) after two-stage isothermal oxidation (24 hrs in 16O2 followed by 24 hrs in 18O2) at 1073 K. From this analysis it can be assumed that the oxidation mechanism of Ti-46Al-8Nb alloy consists of simultaneous outward titanium and aluminum diffusion and inward oxygen transport.
Celem pracy jest określenie wpływu dodatku niobu na kinetykę i mechanizm utleniania stopu TiAl w powietrzu. Dla porównania kinetyk utleniania stopu Ti-Al oraz stopu z dodatkiem niobu zostały przeprowadzone badania izotermicznego utleniania stopów o składach Ti-48Al i Ti-46Al-8Nb (w at.%) w powietrzu syntetycznym w 1073 K. Stopy Ti-48Al i Ti-46Al-8Nb poddano cyklicznemu utlenianiu w powietrzu laboratoryjnym w 1073 K obejmującym 42 cykle 24-godzinne. Morfologie oraz skład fazowy i chemiczny produktów utleniania badanych próbek przeprowadzono metodą dyfrakcji promieniowania rentgenowskiego (XRD) oraz skaningowej mikroskopii elektronowej (SEM) w połączeniu z metodą dyspersji energii promieniowania rentgenowskiego (EDS). Na podstawie tych badań stwierdzono, że dodatek niobu w stopie TiAl podwyzsza jego odporność korozyjną a ponadto polepszą przyczepność zgorzeliny do rdzenia metalicznego. Mechanizm utleniania stopu Ti-46Al-8Nb badano metodą spektrometrii masowej rozpylonych cząstek neutralnych (SNMS) po dwuetapowym izotermicznym utlenianiu (pierwszy etap w 16O2 przez 24 godz., kolejny w 18O2 przez 24 godz.) w 1073 K. Na podstawie tej analizy postuluje się, że mechanizm utleniania stopu Ti-46Al-8Nb odbywa się w wyniku równoczesnej odrdzeniowej dyfuzji tytanu i glinu oraz dordzeniowego transportu tlenu.
Źródło:
Archives of Metallurgy and Materials; 2013, 58, 2; 477-480
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Activation mechanism of tantalum niobium flotation by lead ions in a combined collector flotation system
Autorzy:
He, Mingfei
Li, Shuangke
Cao, Miao
Gao, Yude
Bu, Hao
Meng, Qingbo
Powiązania:
https://bibliotekanauki.pl/articles/1448361.pdf
Data publikacji:
2021
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
tantalum niobium ore
Pb2+ ions activation
ammonium dibutyl dithiophosphate
coadsorption
Opis:
The effect of lead ions on the flotation activation of tantalum niobium ore (TNO) was studied by micro-flotation, adsorption capacity experiments, solution chemical composition calculations, and infrared spectral analysis. The experimental demonstrated that the combined collector of salicylhydroxamic acid (SHA) and ammonium dibutyl dithiophosphate (ADDP) resulted in a strong collection capacity for TNO in the presence of lead ions. The solution chemistry calculations determined that the dominant source of lead ions in the aqueous solution was $Pb(OH)^+$ at a pH of 8, which was conducive to the adsorption and interaction of SHA and ADDP anions. In the lead ion activation system, the combined reagent co-adsorbed onto the TNO surface, causing a large negative shift in the zeta potential. The co-adsorption mechanism of the combined collector consisted of complex chemisorption between SHA and the TNO surface active particles, while the main adsorption of ADDP is physisorption.
Źródło:
Physicochemical Problems of Mineral Processing; 2021, 57, 1; 29-38
1643-1049
2084-4735
Pojawia się w:
Physicochemical Problems of Mineral Processing
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Critical Raw Materials – What´s the Crux of the Matter?
Lista pierwiastków krytycznych – jakie są kryteria zaliczenia pierwiastków?
Autorzy:
Dvoracek, Jaroslav
Sousedikova, Radmila
Jurekova, Zdenka
Matyasova, Zuzana
Powiązania:
https://bibliotekanauki.pl/articles/318251.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
surowce krytyczne
wolfram
fluoryt
niob
grafit
critical raw materials
tungsten
fluorspar
niobium
graphite
Opis:
The paper takes into account mineral commodities that have been listed as critical by the EU Commission. It concentrates attention on the issue of global demand/supply balances, and summarizes causes for critical listing of these commodities.
W artykule przedstawiono surowce mineralne wymienione przez Komisję Europejską jako krytyczne. Koncentruje uwagę na globalnym popycie i podsumowuje przyczyny zestawienia listy pierwiastków krytycznych.
Źródło:
Inżynieria Mineralna; 2019, 21, 1/2; 97-99
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Plasma Electrolytic Oxidation as a modern method to form porous coatings enriched in phosphorus and copper on biomaterials
Autorzy:
Rokosz, Krzysztof
Hryniewicz, Tadeusz
Powiązania:
https://bibliotekanauki.pl/articles/1190116.pdf
Data publikacji:
2016
Wydawca:
Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:
Plasma Electrolytic Oxidation (PEO)
Niobium
Ti6Al4V
TNZ
Porous coatings
Opis:
In the paper, the porous coatings obtained on niobium and two titanium alloys (Ti6Al4V, and TNZ) after Plasma Electrolytic Oxidation (PEO), known also as Micro Arc Oxidation, were studied. The samples were treated at the voltage of 450 V for 3 minutes in the electrolyte consisting of 300 g and 600 g of copper nitrate Cu(NO3)2 in 1 litre of concentrated phosphoric acid H3PO4, consecutively. SEM and EDS studies were performed on the samples. Based on the obtained results it may be concluded that enriched in copper porous coatings on all studied materials were created in the electrolyte within copper nitrate amounting for 600 g. The proposed by the Authors factor to evaluate the obtained coatings, i.e. copper-to-phosphorus ratio, which for the studied materials amounted to 0.21, clearly indicates that the performed electrochemical PEO treatment for surface modification especially of bioimplants may be advised.
Źródło:
World Scientific News; 2016, 35; 44-61
2392-2192
Pojawia się w:
World Scientific News
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Market for Critical Raw Materials and its Influence on Mineral Prices
Rynek surowców krytycznych i jego wpływ na ceny minerałów
Autorzy:
Dvoracek, J.
Sousedikova, R.
Kudelova, Z.
Jurekova, Z.
Powiązania:
https://bibliotekanauki.pl/articles/318765.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Przeróbki Kopalin
Tematy:
krytyczne surowce
rynek
cena
wolfram
lit
niob
grafit
critical raw materials
market
price
tungsten
lithium
niobium
graphite
Opis:
The paper has focused on market for critical raw materials and its influence on mineral prices. Usually ores and ore products are deemed critical raw materials if they mostly or totally come from foreign countries, have difficult replacement, and are vital for the Nation’s economy, especially for defence issues. Tungsten, niobium, graphite and lithium were chosen for analysis from the critical mineral commodities declared by the European Commission and the Government of the Czech Republic. An analysis of these mineral commodity market conditions has been made, and their impacts on particular mineral availability and price have been assessed. As regards tungsten supplies, there are relatively many producer countries with the existing or developing extraction structures, but China has at its disposal 60% of the deposits. Lithium reserves are sufficient, but supplies are highly concentrated – four producer companies deliver about 90% of lithium in the world. Also niobium supplies are extremely concentrated, in the period, 2009–2012, two Brazilian mines and a single Canadian one produced 99% of niobium in the world. The biggest world producer of natural graphite is China that dominates 70% of the market. Natural resources of the above mentioned mineral commodities are not critical. The Earth’s crust deposits are sufficient for long-term exploitation, and what’s more, a technology has been patented for lithium recycling. What rather matters is the issue of the free play of market forces. The theoretical preconditions for the free play of market forces and balanced price convergence – market presence of many various producers and many customers – are disturbed by producer structure, high concentration of mining companies and countries. Free market interference is implied in dominance of individual producer countries or production companies, and their ability to decide about production levels and related prices. Nevertheless, the inevitable rise of mineral commodity prices will mean that exploitation of some sources, which are currently deemed uneconomical, may become interesting.
W artykule skoncentrowano się na rynku surowców krytycznych i ich wpływie na ceny surowców mineralnych. Zazwyczaj rudy i produkty wzbogacania uznane za surowce krytyczne surowce jeśli w większości lub w całości pochodzą z innych krajów, mają trudno zastępowalne i są niezbędne w gospodarce narodowej, zwłaszcza dla przemysłu obronnego. Jako przedmiot analizy wybrano wolfram, niob, grafit i lit będące surowcami krytycznymi w dokumentach opublikowanych przez Komisję Europejską i rząd Republiki Czeskiej. Przeprowadzono analizę rynku surowców oraz jego wpływ na dostępność i cenę minerałów. Zasobywolframu zostały zidentyfikowane w kilku krajach natomiast 60% złóż znajduje się w Chinach. Rezerwy litu są wystarczające, ale podaż jest bardzo skoncentrowana cztery firmy producenckie dostarczają około 90% litu. Również podaż niobu jest niezwykle skoncentrowana, w latach 2009-2012 dwie kopalnie brazylijskie i jedna kanadyjska wyprodukowały 99% niobu na świecie. Największym światowym producentem grafitu naturalnego są Chiny, które obejmują 70% rynku światowego. Zasoby naturalne wymienionych surowców mineralnych nie są krytyczne. Złoża skorupy ziemskiej są wystarczające dla długotrwałej eksploatacji, a ponadto opatentowano technologie recyklingu np. litu. Isotny jest problem gry wolnorynkowej. Teoretyczne warunki wstępne dla swobodnej gry sił rynkowych i zrównoważonej konwergencji cen – rynek to obecność wielu różnych producentów i wielu klientów – warunki są zakłócane przez strukturę producentów, dużą koncentrację firm górniczych. Zakłócenia wolnego rynku są implikowane przez dominację poszczególnych krajów producenckich lub przedsiębiorstw produkcyjnych, oraz ich zdolność do decydowania o poziomach produkcji i cenach. Niemniej jednak nieunikniony wzrost cen surowców mineralnych może oznaczać, że wykorzystanie niektórych źródeł, które obecnie uważa się za nieekonomiczne, może stać się interesujące.
Źródło:
Inżynieria Mineralna; 2018, R. 19, nr 1, 1; 43-46
1640-4920
Pojawia się w:
Inżynieria Mineralna
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Investigation of mechanical and physicochemical properties of clinically retrieved titanium-niobium orthodontic archwires
Autorzy:
Stoyanova-Ivanova, Angelina
Cherneva, Sabina
Petrunov, Vladimir
Petrova, Violeta
Ilievska, Ivana
Mikli, Valdek
Iankov, Roumen
Powiązania:
https://bibliotekanauki.pl/articles/306480.pdf
Data publikacji:
2020
Wydawca:
Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
Tematy:
właściwości mechaniczne
morfologia
struktura
skład chemiczny
Ni-free orthodontic wires
titanium-niobium
mechanical properties
morphology
chemical composition
structure
Opis:
Most of the orthodontic archwires used in the clinical practice nowadays contain nickel (Ni), however, many patients, especially kids, are allergic to Ni. One possible Ni-free alternative is the Titanium-Niobium (Ti-Nb) archwire. Unfortunately, there is not enough information about its mechanical properties in the literature, especially after clinical usage. Therefore, the aim of this work was to investigate and compare the mechanical properties, chemical composition, structure and morphology of as received and used in clinical practice Ti-Nb orthodontic archwires. Materials and methods: We investigated and compared as received and clinically retrieved after 4 and 6 weeks respectively Ti-Nb archwires with dimensions 0.43 × 0.64 mm (0.017 in. × 0.025 in.). The following methods were used: instrumented indentation testing (nanoindentation), X-ray diffraction, scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. Results: The nanoindentation investigations of as received and used Ti-Nb archwires revealed a decreasing in their indentation hardness with increased periods of use in the patient’s mouth. Moreover, an increasing of the concentration of Ti in the content of the TiNb alloy was associated with an increased period of use in the oral cavity. The SEM analysis showed changes in surface morphology with increasing the period of use of the archwires. Conclusions: The results showed that there are slight changes in the mechanical and physicochemical properties of the investigated wires after their use in the patient’s mouth. That is why we do not recommend them for recycling.
Źródło:
Acta of Bioengineering and Biomechanics; 2020, 22, 1; 31-39
1509-409X
2450-6303
Pojawia się w:
Acta of Bioengineering and Biomechanics
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 24

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