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Wyświetlanie 1-2 z 2
Tytuł:
The Optimization of Antioxidant Properties of Herbal Bathing Salts
Autorzy:
Zawada, K.
Makarova, K.
Kowalska, D.
Wawer, I.
Powiązania:
https://bibliotekanauki.pl/articles/1032383.pdf
Data publikacji:
2017-07
Wydawca:
Polska Akademia Nauk. Instytut Fizyki PAN
Tematy:
87.64.kh
87.80.Lg
Opis:
The antioxidant properties 4 herbal infusions (of lavender flower, melissa leaf, verbena herb, and birch leaf), 2 salts (Dead Sea and Bochnia Mine salts) and 8 herbal salts (combination of herbal extract and salt) have been evaluated by 2,2-diphenyl-1-picrylhydrazyl-ESR (DPPH-ESR) test, ferric reducing antioxidant power and spin trap ESR using the Fenton reaction. The influence of herbal extracts and herbal salts on lipid membrane permeability has been studied with the spin probe ESR in the range of 293-323 K. The highest antioxidant activity was determined for melissa leaf preparations followed by birch leaf preparations in DPPH and ferric reducing antioxidant power assays whereas in the Fenton reaction the highest radical scavenging was observed for verbena herb and melissa leaf preparations. The lowest membrane permeability was observed in the presence of infusions of melissa and birch leaves, followed by corresponding herbal salts based on Bochnia Mine salt, and it was lower than in the reference system. On the other hand, lavender infusion increased the permeability of the model membrane, whereas the lavender salts decreased it. Therefore, the antioxidant activity of herbal infusions and salts towards skin could be inhibited by a lowered permeability. Thus, the combination of permeability studies with antioxidant studies in the presence of model lipids could be potentially used for optimization of other types of herbal bath salts.
Źródło:
Acta Physica Polonica A; 2017, 132, 1; 56-61
0587-4246
1898-794X
Pojawia się w:
Acta Physica Polonica A
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spin trapping studies of essential oils in lipid systems
Autorzy:
Makarova, K.
Drązikowska, K.
Suska, B.
Zawada, K.
Wawer, I.
Powiązania:
https://bibliotekanauki.pl/articles/147786.pdf
Data publikacji:
2015
Wydawca:
Instytut Chemii i Techniki Jądrowej
Tematy:
spin trapping ESR
essential oils
DFT calculations
lipids
Opis:
In the present work, we report the results of a spin trapping ESR study of four essential oils widely used for skin care products such as creams and bath salts. The studied essential oils are Rosmarini aetheroleum (rosemary), Menthae piperitae aetheroleum (mint), Lavandulae aetheroleum (lavender), and Thymi aetheroleum (thyme). Fenton reaction in the presence of ethanol was used to generate free radicals. The N-tert- -butyl-α-phenylnitrone (PBN) was used as a spin trap. In the Fenton reaction, the rosemary oil had the lowest effect on radical adduct formation as compared to the reference Fenton system. Since essential oils are known to be lipid soluble, we also conducted studies of essential oils in Fenton reaction in the presence of lipids. Two model lipids were used, namely 1,2-dioleoyl-sn-glycero-3-phosphocholine (DOPC) and 1,2-dipalmitoyl-sn- -glycero-3-phosphocholine (DPPC). The obtained results suggested that in the presence of DOPC lipids, the •OH and PBN/•CHCH3(OH) radicals are formed in both phases, that is, water and lipids, and all the studied essential oils affected the Fenton reaction in a similar way. Whereas, in the DPPC system, the additional type of PBN/X (aN = 16.1 G, aH = 2.9 G) radical adduct was generated. DFT calculations of hyperfi ne splittings were performed at B3LYP/6-311+G(d,p)/EPR-II level of theory for the set of c-centered PBN adducts in order to identify PBN/X radical.
Źródło:
Nukleonika; 2015, 60, No. 3, part 1; 461-468
0029-5922
1508-5791
Pojawia się w:
Nukleonika
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-2 z 2

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