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Wyświetlanie 1-3 z 3
Tytuł:
Synthesis of the cross-linked humic acid supporting palladium catalyst and its catalytic properties for Heck reaction
Autorzy:
Xu, Q.
Shi, W.
Cui, Y.
Powiązania:
https://bibliotekanauki.pl/articles/779729.pdf
Data publikacji:
2012
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
kwasy humusowe
epichlorohydryna
reakcja Hecka
humic acid
epichlorohydrin
supporting palladium catalyst
Heck reaction
Opis:
Cross-linked humic acid supporting palladium (CL-HA-Pd) catalyst was prepared readily and characterized by infrared analysis (IR) and thermogravimetric analysis (TG). The catalyst could catalyze the Heck reaction of aryl halide or substituted aryl halide with vinyl compounds in N2 atmosphere; the yields were above 95%. The catalyst could be recovered and reused 7 times with the Heck reaction of iodobenzene with acrylic acid, and the yield was above 75.6%. The results showed that the catalyst had high catalytic activity even at low temperature of 62°C or with a small amount of the catalyst.
Źródło:
Polish Journal of Chemical Technology; 2012, 14, 2; 75-79
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalytic performances of cross-linking humic acids supported Pd/Ni bimetallic catalyst for heck reaction
Autorzy:
Xu, Q.
Zhang, L.
Shi, W.
Cui, Y.
Powiązania:
https://bibliotekanauki.pl/articles/778727.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
kwas humusowy
epichlorohydryna
katalizator bimetaliczny Pd/Ni
katalizator nośnikowy
reakcja Hecka
cross-linking humic acid
epichlorohydrin
Pd/Ni bimetallic catalyst
supported catalyst
Heck reaction
Opis:
The cross-linking humic acids (CL-HAs), epichlorohydrin as the cross-linking reagent and the supported Pd/Ni bimetallic catalysts (CL-HAs-Pd/Ni) were prepared and characterized by IR, AAS, XPS, TEM. The effects of reaction time, temperature, base, solvent and the amount of catalyst on the properties of the catalyst were studied. These catalysts could catalyze the Heck reaction of aryl halides and substituted aryl halides with acrylic acids or styrene successfully; the yields were all above 95%.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 3; 22-26
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Biomass partition and carbon storage of Cunninghamia lanceolata chronosequence plantations in Dabie Mountains in East China
Autorzy:
Xie, X.
Cui, J.
Shi, W.
Liu, X.
Tao, X.
Wang, Q.
Xu, X.N.
Powiązania:
https://bibliotekanauki.pl/articles/41359.pdf
Data publikacji:
2016
Wydawca:
Polska Akademia Nauk. Instytut Dendrologii PAN
Tematy:
biomass
carbon storage
Cunninghamia lanceolata
Chinese fir
chronosequence
plantation forest
Dabie Mountains
China
Opis:
The quantification of biomass carbon pools is important for understanding carbon cycling in forest ecosystems. This study was designed to reveal the effects of stand age on biomass partitioning and carbon storage of Chinese fir plantation stands in Dabie Mountains of Anhui, East China. A total of six even-aged Chinese fir plantation stands along an age-sequence from 10 to 50 years were selected. To quantify the biomass of different tree components, 18 trees with diameter at breast height (D1.3) from 6.5 to 35.2 cm were harvested from the different aged stands. Biomasses of understory vegetation, forest floor and standing dead trees were also investigated. Total biomass carbon storages ranged from 57.6 to 211.4 Mg ha–1 in the different aged stands. Tree layer comprised from 93.7% to 96.4% of the total biomass C pools in the different aged stands. The C pools of the necromass were from 1.8 to 6.2 Mg ha–1. Stand age had a significant effect on tree biomass partitioning, with an increase in proportion of root biomass. The root/shoot ratios were from 0.187 to 0.312, which was significantly positively correlated to stand age. The existing plantation stands are still developing and have somewhat high rate of biomass and carbon accumulations beyond the normal rotation period (usually 25–30 years) even over an age of 50 years. Appropriate prolongation of the rotation period of Chinese fir plantation will be effective in maintaining long-term productivity and providing large carbon sink. The measurements provide valuable data for modelling productivity of Chinese fir plantation forest.
Źródło:
Dendrobiology; 2016, 76
1641-1307
Pojawia się w:
Dendrobiology
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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