- Tytuł:
- New thermoplastic poly(carbonate-urethane) elastomers
- Autorzy:
-
Kultys, A.
Rogulska, M. - Powiązania:
- https://bibliotekanauki.pl/articles/779306.pdf
- Data publikacji:
- 2011
- Wydawca:
- Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
- Tematy:
-
elastomery termoplastyczne
elastomery poliuretanowe
diole
diizocyjanian 4,4'-difenylometanu
diizocyjanian heksano-1,6-diylu
właściwości termiczne
właściwości mechaniczne
mikroskopia sił atomowych
thermoplastic polyurethane elastomers
poly(hexane-1,6-diyl carbonate) diol
4,4'-diphenylmethane diisocyanate
thermal properties
mechanical properties
atomic force microscopy (AFM) - Opis:
- Two series of novel thermoplastic poly(carbonate-urethane) elastomers, with different hard-segment content (30 - 60 wt %), were synthesized by melt polymerization from poly(hexane-1,6-diyl carbonate) diol of Mn = 2000 as a soft segment, 4,4'-diphenylmethane diisocyanate (MDI) or hexane-1,6-diyl diisocyanate (HDI) and 6,6'-[methylenebis(1,4-phenylenemethylenethio)]dihexan-1-ol as a chain extender. The structure and basic properties of the polymers were examined by Fourier transform infrared spectroscopy, X-ray diffraction analysis, atomic force microscopy, differential scanning calorimetry, thermogravimetric analysis, Shore hardness and tensile tests. The resulting TPUs were colorless polymers, showing almost amorphous structures. The MDI-based TPUs showed higher tensile strengths (up to 21.3 MPa vs. 15.8 MPa) and elongations at break (up to 550% vs. 425%), but poorer low-temperature properties than the HDI-based analogs.
- Źródło:
-
Polish Journal of Chemical Technology; 2011, 13, 1; 23-30
1509-8117
1899-4741 - Pojawia się w:
- Polish Journal of Chemical Technology
- Dostawca treści:
- Biblioteka Nauki
Artykuł