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Wyświetlanie 1-13 z 13
Tytuł:
Study On The Electro-Refining Of Tin In Acid Solution From Electronic Waste
Badanie elektrorafinacji cyny w roztworze kwasu z e-odpadów
Autorzy:
Son, S. H.
Park, S. C.
Kim, J. H.
Kim, Y. H.
Lee, M. S.
Ahn, J.-W.
Powiązania:
https://bibliotekanauki.pl/articles/352665.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
electrorefining
tin
electronic waste
recycling
high purity
elektrorafinacja
cyna
odpady elektroniczne
recykling
Opis:
The tin metal could be retractable from wasted tin scrap, sludge, and wasted electroplated solution hydrometallurgical treatment, and purification process. In order to be used as resource of electronic devices, the retracted crude metal should be purified to the extent of higher than 99.9%. In this study, tin electro-refining process was performed to purify the casted tin crude metal at various experimental conditions: at the current density of 3, 5A/dm2, and in various electrolytes such as hydrochloric acid, sulfuric acid and methansulfonic acid. Additional experiment was conducted using Rotating Disk Electrode (RDE) in order to investigate the rate determining step of tin electro-refining process. The current efficiency, 65.6%, was achievable at the condition of current density, 5A/dm2, and in the electrolyte of Hydrochloric acid. During tin electro-refining process, impurity dissolved from tin crude metal into the electrolyte was analyzed using Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES), and the result showed the concentration of impurity metal gradually increased. Quantitative analysis on casted tin crude metal showed that it consists of tin with 93.9 wt.% and several impurity metals of Ag, Bi, Pb, Cu, and etc. After tin electro-refining process, the purity of tin increased up to 99.985 wt.%.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1217-1220
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Hafnium and Zirconium to Glass Forming Ability, Thermal Stability, Plasticity Deformation and Crystallization of Ni-Free Pentabasic Ti-Based Bulk Metallic Glasses
Autorzy:
Oak, J.-J.
Kim, Y. H.
Bae, K.-C.
Park, Y. H.
Powiązania:
https://bibliotekanauki.pl/articles/352087.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Ti-based alloy
metallic glass
Ti fiber
glass formability
plastic deformation
Opis:
The newly designed Ti-based bulk metallic glass (BMG) in which case of fracture behavior was observed 1990MPa to compressive strength with a wide plastic deformation around 7% after process of elastic deformation. This phenomenon can be compared with those of Ti-based alloys and other Ti-based BMGs and indicates high potential to be applied in use. It was evaluated the Ti-based BMG for thermal stability that the reduced glass parameters, ΔTx, Trg and γ, are 79K, 0.50 and 0.38, respectively. In addition, it reveals high activation energies for crystallization in which are estimated to Ex1 = 291.77 ±9.71 kJ/mol, Ex2 = 588.77 ±28.88 kJ/mol and Ex3 = 330.26 ±3.61 kJ/mol on kissinger plotting in this study.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1081-1087
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Fe Content on the Microstructure and Mechanical Properties of Ti-Al-Mo-V-Cr-Fe Alloys
Autorzy:
Bae, K.-C.
Oak, J.-J.
Kim, Y. H.
Park, Y. H.
Powiązania:
https://bibliotekanauki.pl/articles/351896.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Ti alloy
near-β titanium alloy
aircraft applications
structural material
landing gear
Opis:
To investigate the effect of Fe content on the correlation between the microstructure and mechanical properties in near-b titanium alloys, the Ti-5Al-5Mo-5V-1Cr-xFe alloy system has been characterized in this study. As the Fe content increased, the number of nucleation sites and the volume fraction of the α phase decreased. We observed a significant difference in the shape and size of the α phase in the matrix before and after Fe addition. In addition, these morphological deformations were accompanied by a change in the shape of the α phase, which became increasingly discontinuous, and changed into globular-type α phase in the matrix. These phenomena affected the microstructure and mechanical properties of Ti alloys. Specimen #2 exhibited a high ultimate tensile strength (1071 MPa), which decreased with further addition of Fe.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1105-1108
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
High-temperature Oxidation Behavior and Kinetics of Forged 12Cr-MoVW Steel
Autorzy:
Kim, Y. H.
Oak, J.-J.
Bae, K.-C.
Lee, W-J.
Park, Y. H.
Powiązania:
https://bibliotekanauki.pl/articles/351450.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
ferritic/martensitic stainless steels
forging
oxidation kinetics
oxide layer
Opis:
The oxidation kinetics of forged 12Cr-MoVW steel was investigated in an air (N2+O2) atmosphere at 873-1073 K (Δ50 K) using thermogravimetric analysis. The oxidized samples were characterized using X-ray diffraction, and the surface and cross-sectional morphologies were examined using scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy. The forged 12Cr-MoVW steel samples exhibited parabolic behavior and a low oxidation rate compared with their as-cast counterparts. A protective oxide layer was uniformly formed at relatively low temperature (≤973 K) for the forged samples, which thus exhibited better oxidation resistance than the as-cast ones. These oxides are considered solid-solution compounds such as (Fe, Cr)2O3.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1099-1104
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recovery Of Valuable Metals In Tin-Based Anodic Slimes By Carbothermic Reaction
Odzysk cennych metali ze szlamów anodowych na bazie Sn metodą reakcji karbotermicznej
Autorzy:
Han, C.
Kim, Y.-M.
Son, S. H.
Choi, H.
Kim, T. B.
Kim, Y. H.
Powiązania:
https://bibliotekanauki.pl/articles/352796.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
tin
anodic slime
carbothermic reduction
carbon
recovery
cyna
szlam anodowy
reakcja karbotermiczna
węgiel
odzysk metali
Opis:
This study investigated the recovery of anodic slimes by carbothermic reaction in the temperature range of 973~1,273K and amount of carbon as a function of time. Tin anodic slime samples were collected from the bottom of the electrolytic cells during the electro-refining of tin. The anodic slimes are consisted of high concentrated tin, silver, copper and lead oxides. The kinetics of reduction were determined by means of the weight-loss measurement technique. In order to understand in detail of carbothermic reaction, thermodynamic calculation was carried out and compared with experiments. From thermodynamic calculation and experiment, it was confirmed that Sn-based anodic slime could be reduced by controlling temperature and amount of carbon. However, any tendency between the reduction temperature and carbon content for the reduction reaction was not observed.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1213-1216
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Recovery Of Electrodic Powder From Spent Nickel-Metal Hydride Batteries (NiMH)
Odzyskiwanie proszku elektrodowego ze zużytych akumulatorów niklowo-wodorkowych (NiMH)
Autorzy:
Shin, S. M.
Shin, D. J.
Jung, G. J.
Kim, Y. H.
Wang, J. P.
Powiązania:
https://bibliotekanauki.pl/articles/356110.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
nickel-metal hybride (NiMH)
electrodic powder
nickel
rare earth elements (REE)
thermal treatment
akumulator niklowo-wodorkowy
proszek elektrodowy
nikiel
pierwiastki ziem rzadkich
obróbka termiczna
Opis:
This study was focused on recycling process newly proposed to recover electrodic powder enriched in nickel (Ni) and rare earth elements (La and Ce) from spent nickel-metal hydride batteries (NiMH). In addition, this new process was designed to prevent explosion of batteries during thermal treatment under inert atmosphere. Spent nickel metal hydride batteries were heated over range of 300°C to 600°C for 2 hours and each component was completely separated inside reactor after experiment. Electrodic powder was successfully recovered from bulk components containing several pieces of metals through sieving operation. The electrodic powder obtained was examined by X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX) and image of the powder was taken by scanning electron microscopy (SEM). It was finally found that nickel and rare earth elements were mainly recovered to about 45 wt.% and 12 wt.% in electrodic powder, respectively.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1139-1143
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Spontaneous Formation of Titanium Nitride on the Surface of a Ti Rod Induced by Electro-Discharge-Heat-Treatment in an N2 Atmosphere
Autorzy:
Lee, W. H.
Yoon, Y. H.
Kim, Y. H.
Lee, Y. K.
Kim, J. Y.
Chang, S. Y.
Powiązania:
https://bibliotekanauki.pl/articles/352477.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium
surface modification
diffusion
heat treatment
XPS
Opis:
A single pulse of 2.0 to 3.5 kJ of input energy from a 450 mF capacitor was applied to a commercially pure Ti rod in a N2 atmosphere. The surface of the Ti rod transformed from TiO2 into titanium nitride in times as short as 159 msec, providing a bimodal morphology of the cross-section. A much higher value of hardness that was observed at the edge of the cross-section was attributed to nitrogen-induced solid-solution hardening that occurred during the electrical discharge process. The activation energy (Ea) for the diffusion process was estimated to be approximately 86.9 kJ/mol. Results show that the electrical discharge process is a possible potential method for the nitriding of Ti; advantages include a short processing time and control of the nitrided layer without dimensional changes.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1281-1285
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation and Surface Modification of Mechanical Alloyed Ti-25.0 at.% Al Powder Mixture by Using an Electro-Discharge Technique
Autorzy:
Chang, S. Y.
Jang, H. S.
Yoon, Y. H.
Kim, Y. H.
Kim, J. Y.
Lee, Y. K.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/354212.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sintering
mechanical alloying
powder consolidation
intermetallic compounds
titanium aluminides
Opis:
Electrical discharges using a capacitance of 450 μF at 0.5, 1.0, and 1.5 kJ input energies were applied in a N2 atmosphere to obtain the mechanical alloyed Ti3Al powder without applying any external pressure. A solid bulk of nanostructured Ti3Al was obtained as short as 160 μsec by the Electrical discharge. At the same time, the surface has been modified into the form of Ti and Al nitrides due to the diffusion process of nitrogen to the surface. The input energy was found to be the most important parameter to affect the formation of a solid core and surface chemistry of the compact.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1293-1297
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation Mechanism of Ti5Si3 Compact Obtained by Electro-Discharge-Sintering Directly from Physically Blended Ti-37.5 At.% Si Powder Mixture
Autorzy:
Chang, S. Y.
Cheon, Y. W.
Yoon, Y. H.
Kim, Y. H.
Kim, J. Y.
Lee, Y. K.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/353022.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
sintering
mechanical alloying
powder consolidation
intermetallic compounds
titanium silicide
Opis:
Characteristics of electro-discharge-sintering of the Ti-37.5at.% Si powder mixture was investigated as a function of the input energy, capacitance, and discharge time without applying any external pressure. A solid bulk of Ti5Si3 was obtained only after in less than 129 μsec by the EDS process. During a discharge, the heat is generated to liquefy and alloy the particles, and which enhances the pinch pressure can condensate them without allowing a formation of pores. Three step processes for the self-consolidation mechanism during EDS are proposed; (a) a physical breakdown of oxide film on elemental as-received powder particles, (b) alloying and densifying the consolidation of powder particles by the pinch pressure, and (c) diffusion of impurities into the consolidated surface.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1299-1302
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Trace Elements (Co, Cr) on the Microstructure and Physical Properties of Al-Si-Cu-Mg-Fe Extruded Alloy
Autorzy:
Ahn, S. S.
Sharief, P.
Lee, C. H.
Son, H. T.
Kim, Y. H.
Kim, Y. C.
Hong, S.
Hong, S. J.
Powiązania:
https://bibliotekanauki.pl/articles/352787.pdf
Data publikacji:
2019
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Al-Si alloy
microstructure
extrusion
coefficient of thermal expansion
trace elements
Opis:
Trace elements Co, Cr were added to investigate their influence on the microstructure and physical properties of Al-Si extruded alloy. The Co, Cr elements were randomly distributed in the matrix, forms intermetallic phase and their existence wereconfirmed by XRD, EDS and SEM analysis. With addition of trace elements, the microstructure was modified, Si particle size was reduced and the growth rate of β-(Al5 FeSi) phase limited. Compared to parent alloy, hardness and tensile strength were enhanced while the linear coefficient of thermal expansion (CTE) was significantly reduced by 42.4% and 16.05% with Co and Cr addition respectively. It is considered that the low CTE occurs with addition of Co was due to the formation of intermetallic compound having low coefficient of thermal expansion. The results suggested that Co acts as an effective element in improving the mechanical properties of Al-Si alloy.
Źródło:
Archives of Metallurgy and Materials; 2019, 64, 3; 857-862
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization Of The Graded Microstructure In Powder Sintered Porous Titanium
Charakterystyka gradientowej mikrostruktury porowatego tytanu spiekanego z proszku
Autorzy:
Oak, J.-J.
Bang, J. I.
Bae, K.-C.
Kim, Y. H.
Lee, Y. C.
Chun, H. H.
Park, Y. H.
Powiązania:
https://bibliotekanauki.pl/articles/356239.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium
powder metallurgy
porous structure
sintering
biomaterial
tytan
metalurgia proszków
struktura porowata
spiekanie
biomateriał
Opis:
The proposed sintering process produce porosity and functional graded microstructure in the sinterd titanium powders. Titanium powders with different micro sizes were sintered at the proposed temperature region at 1200 and 1300°C for 2h. The apatite-forming on the graded microstructure is observed by immersion test in Hanks balanced salt soluion at 37°C. Sintering condition of titanium powders is estimated by thermogravitmetry-differential thermal analysis (TG-DTA). The synthersied surface structures and apatite-forming ability were characterized by a field emission scanning electron microscopy (FE-SEM) observation and energy dispersive X-ray spectroscopy (EDS) analysis. As results, these graded microstructure of sintered porous titanium powders reveals apatite-forming ability as osseointegration by calcification in Hanks balanced salt soluion(HBSS) at 37°C.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1265-1269
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Surface Modification of Self-Consolidated Microporous Ti Implant Compacts Fabricated by Electro-Discharge-Sintering in Air
Autorzy:
Jo, Y. J.
Yoon, Y. H.
Kim, Y. H.
Chang, S. Y.
Kim, J. Y.
Lee, Y. K.
Van Tyne, C. J.
Lee, W. H.
Powiązania:
https://bibliotekanauki.pl/articles/356790.pdf
Data publikacji:
2017
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
titanium
implant
porous
sintering
X-ray photoelectron spectroscopy (XPS)
Opis:
A single pulse of 0.75-2.0 kJ/0.7g of atomized spherical Ti powders from 300 mF capacitor was applied to produce a microporous Ti implant compact by electro-discharge-sintering (EDS). A solid core in the middle of the compact surrounded by a microporous layer was found. X-ray photoelectron spectroscopy was employed to study the surface characteristics of the EDS Ti compact and it revealed that Ti, C and O were the main constituents on the surface with a smaller amount of N. The surface was lightly oxidized and was primarily in the form of TiO2 resulting from the air oxidation during EDS processing. The lightly oxidized surface of the EDS compact also exhibited Ti nitrides such as TiN and TiON, which revealed that the reaction between air constituents and the Ti powders even in times as short as 128 msec.
Źródło:
Archives of Metallurgy and Materials; 2017, 62, 2B; 1287-1291
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Self-Consolidation Mechanism Of Porous Ti-6Al-4V Implant Prototypes Produced By Electro-Discharge-Sintering Of Spherical Ti-6Al-4V Powders
Mechanizm autokonsolidacji prototypów porowatych implantów wytworzonych przez spiekanie sferycznych proszków Ti-6Al-4V
Autorzy:
Lee, W. H.
Jo, Y. J.
Kim, Y. H.
Jo, Y. H.
Seong, J. G.
Van Tyne, C. J.
Chang, S. Y.
Powiązania:
https://bibliotekanauki.pl/articles/356277.pdf
Data publikacji:
2015
Wydawca:
Polska Akademia Nauk. Czytelnia Czasopism PAN
Tematy:
Ti-6Al-4V
implant
porous
sintering
electrodischarge
porowatość
spiekanie
proszki spiekane
Opis:
Electro-Discharge-Sintering (EDS) was employed to fabricate Ti-6Al-4V porous implant prototypes from atomized powders (100 – 150 μm), that were subjected to discharges of 0.75 to 2.0 kJ/0.7g-powder from 150, 300, and 450 μF capacitors. Both fully porous and porous-surfaced Ti-6Al-4V compacts with various solid core sizes were self-consolidated in less than 86 – 155 μsec. It is known that EDS can simultaneously produce the pinch pressure to squeeze and deform powder particles and the heat to weld them together. The formation of a solid core in these prototypes depends on the amounts of both the pinch pressure and heat generated during a discharge. The size of the solid core and the thickness of the porous layer can be successfully controlled by manipulating the discharge conditions such as input energy and capacitance.
Źródło:
Archives of Metallurgy and Materials; 2015, 60, 2B; 1185-1189
1733-3490
Pojawia się w:
Archives of Metallurgy and Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-13 z 13

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