- Tytuł:
- The Microstructural Evolution in HMX Based Plastic-bonded Explosive During Heating and Cooling Process: an in situ Small-angle Scattering Study
- Autorzy:
-
Yan, G.
Tian, Q.
Liu, J.
Fan, Z.
Sun, G.
Zhang, C.
Wang, Y.
Chen, B.
Gong, J.
Zhou, X.
Yang, Z.
Nie, F.
Li, J.
Li, X. - Powiązania:
- https://bibliotekanauki.pl/articles/358618.pdf
- Data publikacji:
- 2016
- Wydawca:
- Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
- Tematy:
-
SANS
SAXS
HMX-PBX
thermal damages
phase transition - Opis:
- The thermal damage in octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) based plastic-bonded explosive (PBX) was investigated using in situ small-angle neutron and X-ray scattering techniques. The microstructural evolution was quantitatively characterized by the model fitting parameters of total interfacial surface area (Sv) and void volume distribution. The Sv of HMX-PBX decreased markedly above 100 °C, indicating the movement of binder into the voids. After subsequent cooling to room temperature, the scattering intensity increased significantly with increasing storage time, and a new population of voids with average diameter of 20 nm was observed, accompanied by the gradual phase transition of HMX from δ- to β-phase. The experimental results implied that serious damage within the HMX-PBX was developed during storage after heating.
- Źródło:
-
Central European Journal of Energetic Materials; 2016, 13, 4; 916-926
1733-7178 - Pojawia się w:
- Central European Journal of Energetic Materials
- Dostawca treści:
- Biblioteka Nauki