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Wyszukujesz frazę "synthesis" wg kryterium: Temat


Tytuł:
The activity of fused-iron catalyst doped with lithium oxide for ammonia synthesis
Autorzy:
Jedrzejewski, R.
Lendzion-Bieluń, Z.
Arabczyk, W.
Powiązania:
https://bibliotekanauki.pl/articles/779518.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
iron catalyst
ammonia synthesis
lithium oxide
Opis:
The iron catalyst precursor promoted with Al2O3, CaO, and Li2O was obtained applying the fusing method. Lithium oxide forms two phases in this iron catalyst: a chemical compound with iron oxide (Li2Fe3O4) and a solid solution with magnetite. The catalyst promoted with lithium oxide was not fully reduced at 773 K, while the catalyst containing potassium was easily reducible at the same conditions. After reduction at 873 K the activity of the catalyst promoted with lithium oxide was 41% higher per surface than the activity of the catalyst promoted with potassium oxide. The concentration of free active sites on the surface of the catalyst containing lithium oxide after full reduction was greater than the concentration of free active sites on the surface of the catalyst promoted with potassium oxide.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 2; 78-83
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
SCMNPs@Uridine/Zn: An efficient and reusable heterogeneous nanocatalyst for the rapid one-pot synthesis of tricyclic fused pyrazolopyranopyrimidine and 3-methyl carboxylate substituted pyrano[2,3-c]pyrazole derivatives under solvent-free conditions
Autorzy:
Wei, Jia
Gui, Wenjun
Cui, Yanjun
Zhang, Zhifang
Yousif, Qahtan A.
Powiązania:
https://bibliotekanauki.pl/articles/778587.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
nanocatalyst
synthesis of tricyclic
carboxylate
efficient heterogeneous
Opis:
SCMNPs@Uridine/Zn is utilized as an environmental-friendly and efficient heterogeneous nanocatalyst for two one-pot four-component condensation reactions, containing hydrazine hydrate, arylaldehyde, ethyl acetoacetate, and barbituric acid to yield tricyclic fused pyrazolopyranopyrimidine derivatives (5a-q), and hydrazine hydrate, arylaldehyde, malononitrile, and dimethyl acetylenedicarboxylate/diethyl acetylenedicarboxylate to yield 3-methyl carboxylate substituted pyrano[2,3-c]pyrazole derivatives (8a-y) under solvent-free conditions with high to excellent yields. The main advantages of this process are easy work-up, short reaction times, no chromatographic purifications, and recyclability of the catalyst for a minimum of six runs without any signifcant decrease in yields of the products. Also, the prepared catalyst SCMNPs@Uridine/Zn was synthesized and fully characterized by various techniques including Fourier transform infrared spectroscopy (FT-IR), energy dispersive X-ray (EDX), thermogravimetric analysis (TGA), X-ray diffraction (XRD), vibrating sample magnetometer (VSM) and Raman spectroscopy.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 2; 20-33
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of a novel environmental friendly plasticizer based on tung oil fatty acid for poly (vinyl chloride) blends
Autorzy:
Tong, H.
Hai, J.
Powiązania:
https://bibliotekanauki.pl/articles/778643.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Synthesis
plasticizer
migration resistance
poly (vinyl chloride)
Opis:
A novel environmental friendly plasticizer (TPE) derived from tung oil fatty acid with long fatty acid chain and high degree of branching was synthesized. Chemical structure of the obtained TPE was characterized with Fourier transform infrared spectroscopy (FT-IR) and  1H NMR. TPE was used to prepare plasticized PVC blends as main plasticizer. Thermal stability, mechanical properties and migration resistance of poly (vinyl chloride) plasticized with TPE were investigated. The results showed that torque data of plasticized PVC blends reached 12.4 N·m when the mass of the TPE was 50 wt.%. TPE improved the thermal stability of PVC blends obviously than dioctyl phthalate (DOP). The leaching tests showed that PVC plasticized with TPE were with higher migration resistance than that of DOP. The excellent thermal stability and high migration resistance of PVC blends showed high application value for TPE.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 2; 92-97
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Properties and activity of the cobalt catalysts for NH3 &enspsynthesis obtained by co-precipitation – the effect of lanthanum addition
Autorzy:
Zybert, M.
Karasińska, M.
Truszkiewicz, E.
Mierzwa, B.
Raróg-Pilecka, W.
Powiązania:
https://bibliotekanauki.pl/articles/778653.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ammonia synthesis
cobalt catalyst
promoter
lanthanum
coprecipitation
Opis:
In modern research on catalysts for NH3&enspsynthesis a lot of attention is paid to cobalt. In this work the new catalytic systems based on cobalt are presented. Unsupported cobalt catalysts singly promoted (La or Ba) and doubly promoted (La and Ba) were prepared and tested in NH3&enspsynthesis reaction under commercial synthesis conditions. Characterization studies revealed that lanthanum plays a role of a structural promoter, which improves the surface of catalyst precursors and prevents from sintering during calcination. However, lanthanum has a negative effect on the reduction of cobalt oxide, but the addition of barium promoter (Co/La/Ba catalyst) diminishes the negative impact of La. The co-promotion of cobalt with lanthanum and barium results in the increasing of the active phase surface and improvement of its activity in NH3&enspsynthesis.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 138-143
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Cobalt-lanthanum catalyst precursors for ammonia synthesis: determination of calcination temperature and storage conditions
Autorzy:
Zybert, M.
Tarka, A.
Mierzwa, B.
Raróg-Pilecka, W.
Powiązania:
https://bibliotekanauki.pl/articles/778044.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ammonia synthesis
catalyst precursor
cobalt
lanthanum
thermal analysis
Opis:
A thermal decomposition of a cobalt-lanthanum catalyst precursor containing a mixture of cobalt and lanthanum compounds obtained by co-precipitation were studied using thermal analysis coupled with mass spectrometry (TG-MS). Studies revealed that the calcination in air at 500°C is sufficient to transform the obtained cobalt precipitate into Co3 O4 , but it leads to only partial decomposition of lanthanum precipitate. In order to obtain Co/La catalyst precursor containing La2 O3  the calcination in air at the temperature about 800°C is required. However, it is unfavorable from the point of view of textural properties of the catalyst precursor. A strong effect of storage conditions on the phase composition of the studied cobalt-lanthanum catalyst precursor, caused by the formation of lanthanum hydroxide and lanthanum carbonates from La2 O3  when contacting with air, was observed.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 2; 61-66
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of the Content of Promoters in Magnetite and Wustite Phases in the Fused Iron Catalyst
Autorzy:
Lendzion-Bieluń, Z.
Jędrzejewski, R.
Powiązania:
https://bibliotekanauki.pl/articles/779352.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
iron catalyst
promoters
ammonia synthesis
selective etching
Opis:
Taking advantage of differences in etching rates of crystallographic phases, forming an oxidized form of the fused iron catalyst, a content of promoters in main phases, magnetite and wustite, was determined. A calcium oxide content in magnetite and wustite was 0.54 wt% and 3.59 wt%, respectively. Aluminum oxide was found in the magnetite phase, and its content was 4.5 wt%. The third promoter, potassium oxide, was almost completely located outside these phases. XRD and ICP-OES instrumental methods were used in the investigations.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 27-29
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Dehydrogenation of propane with CO2 - a new green process for propene and synthesis gas production
Autorzy:
Michorczyk, P.
Zeńczak, K.
Niekurzak, R.
Ogonowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/778939.pdf
Data publikacji:
2012
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
dehydrogenation with CO2
propene
synthesis gas
integrated processes
Opis:
Dehydrogenation of propane in the presence of CO2 was considered as an alternative to commercial dehydrogenation pathway of obtaining propene and the new sources of synthesis gas. Based on thermodynamic calculations and a catalytic tests it was shown that by controlling CO2 concentration in the feed the molar ratio of H2/CO (synthesis gas) in the products mixture can be regulated. Several different pathways of DHP-CO2 process integration with commercialized chemical processes utilized synthesis gas were proposed.
Źródło:
Polish Journal of Chemical Technology; 2012, 14, 4; 77-82
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis of silver nanoparticles by aqueous extract of Zingiber officinale and their antibacterial activities against selected species
Autorzy:
Hussain, Zawar
Jahangeer, Muhammad
ur Rahman, Shafiq
Ihsan, Tamanna
Sarwar, Abid
Ullah, Najeeb
Aziz, Tariq
Alharbi, Metab
Alshammari, Abdulrahman
Alasmari, Abdullah F.
Powiązania:
https://bibliotekanauki.pl/articles/27315653.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Nanotechnology
Antibacterial activity
Silver-nanoparticles
green synthesis
Ginger
Opis:
Silver nanoparticles have special plasmonic and antibacterial characteristics that make them efficient in a variety of commercial medical applications. According to recent research, chemically synthesized silver nanoparticles are harmful even in low concentrations. It was crucial to identify appropriate synthesis methods that may have low costs and be nontoxic to the environment. Zingiber officinale (ginger) extracts used to prepare silver nanoparticles were inexpensive and environmentally friendly, and the best physicochemical characteristics were analyzed. Silver nanoparticles were characterized by using UV-visible spectroscopy, Scanning electron microscopy (SEM), and X-ray diffraction (XRD). The surface Plasmon resonance peak at 425 nm was observed using UV-Visible spectroscopy. Scanning electron microscopy observed that the nanoparticles were spherical and ranged in size from 5 to 35 nm. The XRD pattern values of 2θ: 38.2° , 46.3° , and 64.58° are used to determine the planes (111), (200), and (220). The silver nanoparticle’s existence was verified by the face-centered cubic (FCC). Silver nanoparticles were found to have antibacterial efficacy against gram-positive Staphylococcus and gram-negative bacteria such as Pseudomonas aeruginosa, Klebsiella Aerogenes, Salmonella, Staphylococcus and Escherichia coli. The antibacterial activity of silver nanoparticles was observed using the agar well diffusion (AWD) method at three different concentrations (100 μg/ ml, 75 μg/ml, and 50 μg/ml). The zone of inhibition measured against the bacterial strains pseudomonas Aeruginosa, Klebsiella aerogenes, Escherichia coli, Salmonella and Staphylococcus which were (18.4±1.25 mm, 16.9±0.74 mm, 14.8±1.25 mm), (16.8±0.96 mm, 14.6±0.76 mm, 14.0±1.15 mm), (19.7±0.76 mm, 18.2±0.66 mm, 15.4±1.15 mm), (16.6±0.67 mm, 14.2±0.23 mm, 12.8±0.78 mm) and (12±0.68 mm, 10±0.20 mm, 08±0.15 mm). These nanoparticles’ potent antibacterial properties may enable them to be employed as nanomedicines for a variety of gramnegative bacterial illness treatments.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 3; 23--30
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Direct synthesis of dimethyl carbonate and propylene glycol using potassium bicarbonate as catalyst in supercritical CO2
Autorzy:
Wen, Y.
Zhang, R.
Cang, Y.
Zhang, J.
Liu, L.
Guo, X.
Fan, B.
Powiązania:
https://bibliotekanauki.pl/articles/778066.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
direct synthesis
dimethyl carbonate
carbon dioxide
potassium bicarbonate
supercritical fluids
Opis:
The improved one-pot synthesis of dimethyl carbonate and propylene glycol from propylene oxide, supercritical carbon dioxide, and methanol with potassium bicarbonate as the catalyst has been reported in this paper. As far as we know, it is the first time to use potassium bicarbonate only as the catalyst in the production process which is simple and cheap. Satisfactory conversion rate of propylene oxide and yield of the products could be achieved at the optimized conditions with quite a small amount of by-products. Our new method offers an attractive choice for the production of dimethyl carbonate in large-scale industry efficiently and environmental friendly.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 62-65
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
One-dimensional isothermal multicomponent diffusion-reaction model and its application to methanol synthesis over commercial Cu-based catalyst
Autorzy:
Lei, K.
Ma, H.
Zhang, H.
Ying, W.
Fang, D.
Powiązania:
https://bibliotekanauki.pl/articles/778972.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
global kinetics
internal effectiveness factor
diffusion-reaction model
methanol synthesis
Opis:
The present work was a study on global reaction rate of methanol synthesis. We measured experimentally the global reaction rate in the internal recycle gradientless reactor over catalyst SC309. The diffusion-reaction model of methanol synthesis was suggested. For model we chose the hydrogenation of CO and CO2 &enspas key reaction. CO and CO2 &enspwere key components in our model. The internal diffusion effectiveness factors of CO and CO2&enspin the catalyst were calculated by the numerical integration. A comparison with the experiment showed that all the absolute values of the relative error were less than 10%. The simulation results showed that decreasing reaction temperature and catalyst diameter were conducive to reduce the influence of the internal diffusion on the methanol synthesis.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 103-109
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Innovative renovation of the Church of the Revival of New Martyrs in Goretowo
Nowatorska renowacja Kościoła Odrodzenia Nowych Męczenników w Goretowo
Autorzy:
Bembel, Irina
Powiązania:
https://bibliotekanauki.pl/articles/369837.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
church architecture
reconstruction
monumental painting
synthesis of arts
traditions
canon
Opis:
The article describes the unique experience of the reconstruction of the Trinity Church (with the New Martyrs side-altar) in the Goretovo village, based in Mozhaisk area (nearby of the Moscow region). The author demonstrates a non-standard, innovative approach of the abandoned Church revitalization, which manifested in the method of the lost volume reconstruction and the new system organization of painting and decorating. The experience of the reconstruction of the Goretovo Church is useful in terms of understanding the complex relationship of creative freedom, the canonical framework and conservation standards.
Źródło:
Przestrzeń i Forma; 2020, 42; 55-66
1895-3247
2391-7725
Pojawia się w:
Przestrzeń i Forma
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Economically viable synthesis of Fe3O4 nanoparticles and their characterization
Autorzy:
Srivastava, V.
Singh, P. K.
Weng, C. H.
Sharma, Y. C.
Powiązania:
https://bibliotekanauki.pl/articles/778707.pdf
Data publikacji:
2011
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
nanożelazo
żelazo
synteza
współstrącanie
charakterystyka
pH zpc
nano iron
synthesis
coprecipitation
characterization
Opis:
Nano iron oxide particles (Fe3O4) were synthesized by coprecipitation of Fe2+ and Fe3+ by ammonia solution in the aqueous phase. Various instrumentation methods such as X ray Diffractometry (XRD), Transmission Electron Microscopy (TEM), Fourier Transform Infrared (FTIR) spectroscopy, Brunauer-Emmett-Teller (BET) and Vibrating Sample Magnetometery (VSM) were used to characterize the properties of nanoparticles. The size of the nanoparticles was measured and was found to be between 10 to 15 nm. The value of saturation magnetization of the nanoparticles was found to be 55.26 emu/g. The BET surface area of nano iron oxide particles measured to be 86.55 m2/g.
Źródło:
Polish Journal of Chemical Technology; 2011, 13, 2; 1-5
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Leaching of vanadium(V) from the mixture after potassium metavanadate synthesis based on KCl and spent vanadium catalyst
Autorzy:
Kiełkowska, U.
Białowicz, K.
Drużyński, S.
Powiązania:
https://bibliotekanauki.pl/articles/780081.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
KVO3 synthesis
spent vanadium catalyst
leaching
recovery
iron
vanadium(V)
Opis:
The results of the leaching of vanadium(V) from the mixture after potassium metavanadate synthesis from KCl and spent vanadium catalyst in the presence of steam were presented. Spent vanadium catalyst was obtained from the waste storage of a chemical plant producing sulfuric acid(VI) by the contact method. The reaction mixture was leached using different solutions: 1 M Na2CO3, 20% CO(NH2)2, 15% NaOH, 15% KOH, 2 M H2SO4. The effect of time and temperature was studied. The results showed that for reaction mixture leached for 4 h at 303 K in the presence of 15% sodium hydroxide solution at a liquid:solid ratio of 10:1, the extent of leaching of vanadium(V) was 95.43%.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 4; 33-35
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Graphene oxide-assisted synthesis of LiMn2O4 nanopowder
Autorzy:
Majchrzycki, Ł
Michalska, M.
Walkowiak, M.
Wiliński, Z.
Lipińska, L.
Powiązania:
https://bibliotekanauki.pl/articles/778629.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
LiMn2O4 spinel
graphene oxide
sol-gel synthesis
li-ion battery
Opis:
The article reports sol-gel synthesis of nanosized spinel-type lithium manganese oxide LiMn2O4 (LMO) carried out in the presence of graphene oxide (GO) and its electrochemical lithium insertion ability. The synthesis was performed in an aqueous environment with lithium acetate and manganese acetate used as precursors and citric acid as a chelating agent. The material was characterized by X-ray diffraction, SEM microscopy, Raman spectroscopy and cyclic voltammetry. The calcination step totally eliminated graphene from the final product, nevertheless its presence during the synthesis was found to affect the resulting LiMn2O4 morphology by markedly reducing the size of grains. Moreover, potentials of electrochemical lithium insertion/deinsertion reactions have been shifted, as observed in the cyclic voltammetry measurements. Along with the diminished grain size the voltammetric curves of the graphene oxide-modified material exhibit higher oxidation and lower reduction peak currents. The study demonstrates that GO mediation/assistance during the sol-gel synthesis fosters more nanostructured powder and changes the electrochemical characteristics of the product.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 3; 15-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effects of preparation methods of mixed calcium and zinc thermal stabilizers derived from dimer fatty acid and tung-oil based C22 triacid on properties of PVC
Autorzy:
Li, M.
Wang, M.
Li, S.
Huang, K.
Mao, W.
Xia, J.
Powiązania:
https://bibliotekanauki.pl/articles/778123.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
poly(vinyl chloride)
mixed calcium and zinc thermal stabilizer
synthesis technology
thermal stabilization
Opis:
Calcium and zinc salts of dimer fatty acids (DFA-Ca and DFA-Zn) were synthesized using direct neutralization and metathesis technologies, respectively. The adduct of maleic anhydride and methyl eleostearate (MAME) was also converted to the corresponding zinc soap (C22TA-Zn) and calcium soap (C22TA-Ca) by the two different synthetic routes. Mixed Ca/Zn salts between DFA-Ca and DFA-Zn, and between C22TA-Zn and C22TA-Ca were used as thermal stabilizers for poly(vinyl chloride) (PVC). The PVC thermal stability was determined using Congo red test, discoloration test, torque rheological analysis and TGA. Dynamic mechanical properties were also tested. Results indicated that the DFA-Ca/DFA-Zn thermal stabilizer from direct neutralization technology was found to be superior to that of the metathesis product. The C22TA-Ca/C22TA-Zn thermal stabilizer from direct neutralization method had overall superior thermal stability, and displayed modulus and glass transition comparable to that of metathesis product. Direct neutralization method was more excellent and convenient than metathesis technology.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 2; 78-87
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł

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