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Wyszukujesz frazę "Photocatalysis" wg kryterium: Temat


Tytuł:
NOx photocatalytic degradation on gypsum plates modified by TiO2-N,C photocatalysts
Autorzy:
Janus, M.
Bubacz, K.
Zatorska, J.
Kusiak-Nejman, E.
Czyżewski, A.
Morawski, A. W.
Powiązania:
https://bibliotekanauki.pl/articles/779427.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
photocatalysis
modified gypsum
NOx
Opis:
In presented studies the photocatalytic decomposition of NOx on gypsum plates modified by TiO2-N,Cphotocatalysts were presented. The gypsum plates were obtained by addition of 10 or 20 wt.% of different types of titanium dioxide, such as: pure TiO2 and carbon and nitrogen co-modified TiO2 (TiO2-N,C) to gypsum. TiO2-N,C photocatalysts were obtained by heating up the starting TiO2 (Grupa Azoty Zakłady Chemiczne Police S.A) in the atmosphere of ammonia and carbon at the temperature: 100, 300 i 600ºC. Photocatalyst were characterized by FTIR/DRS, UVVis/DR, BET and XRD methods. Moreover the compressive strength tests of modified gypsum were also done. Photocatalytic activity of gypsum plates was done during NOx decomposition. The highest photocatalytic activity has gypsum with 20 wt.% addition of TiO2-N,C obtained at 300ºC.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 3; 8-12
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Simultaneous photooxidation and photoreduction of phenol and Cr(VI) ions using titania modified with nanosilica
Autorzy:
Kądziołka, Daria
Grzechulska-Damszel, Joanna
Schmidt, Beata
Powiązania:
https://bibliotekanauki.pl/articles/2174823.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
photocatalysis
titanium dioxide
nanosilica
water purification
Opis:
The photocatalytic process of phenol oxidation and Cr(VI) reduction in the presence of nano-silica modified titania was carried out. The activity of composites was tested using two different light sources. The photocatalysts with 10% of nanosilica showed the highest activity. The calcination temperature (200–800 °C) significantly determined the sensitivity of the obtained materials to the light source used. Photocatalysts alternately adsorbed and desorbed Cr(VI) ions from the reaction mixture during irradiation. In the one-component mixture, complete oxidation of phenol was observed using material calcined at 650 °C, after 3 h of UV-VIS irradiation. In the reaction mixture of Cr(VI) and phenol, the highest activity was demonstrated by photocatalyst calcined at 300 °C. The concentration of phenol decreased in proportion to the decrease of chromium ions. The obtained titania-silica composites showed oxidizing properties towards phenol and reductive properties toward Cr(VI) ions.
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 4; 23--29
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Degradation of sertraline in water by suspended and supported TiO2
Autorzy:
Rejek, M.
Grzechulska-Damszel, J.
Powiązania:
https://bibliotekanauki.pl/articles/780043.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
photocatalysis
titanium dioxide
pharmaceuticals
sertraline
water treatment
Opis:
Pharmaceutical pollutants have been detected in many countries in surface and ground water after treatment in wastewater treatment plants. The presented studies concern the photocatalytic removal of one of SSRI antidepressants - sertraline from water using TiO2  photocatalyst. The process was conducted using two laboratory installations with periodic and flow reactors. Two forms of TiO2  was used in the photocatalytic reactions: suspended and supported onto a glass fabric. The studies shown that with increasing initial concentration of pharmaceutical, photoactivity decreases. For the initial concentration of 0.025 g/dm3 , the best results – 94% removal – was achieved for the process conducted in the periodic reactor with TiO2  supported onto a glass fabric.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 2; 107-112
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photocatalytic properties of transparent TiO2 coatings doped with neodymium
Autorzy:
Wojcieszak, D.
Kaczmarek, D.
Domaradzki, J.
Mazur, M.
Morawski, A. W.
Janus, M.
Prociów, E.
Gemmellaro, P.
Powiązania:
https://bibliotekanauki.pl/articles/779161.pdf
Data publikacji:
2012
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
TiO2
neodymium
photocatalysis
wettability
surface properties
Opis:
In this work photocatalytic properties of TiO2 thin fi lms doped with 8.51 at. % of Nd were described. The self-cleaning phenomenon of thin fi lms was discussed together with the structural, optical and surface properties of prepared thin fi lms. Transparent coatings based on titanium dioxide were manufactured by high-energy reactive magnetron sputtering process. Incorporation of Nd during sputtering process results in amorphous behavior, without a signifi cant infl uence on transparency and colour as compared to the undoped TiO2-rutile matrix. Nevertheless, doping with neodymium doubles the photocatalytic activity of the matrix due to higher quantity of photo-generated charge carriers and more effi cient mechanism of energy transfer.
Źródło:
Polish Journal of Chemical Technology; 2012, 14, 3; 1-7
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Modyfication of photocatalytic properties of titanium dioxide by mechanochemical method
Autorzy:
Dulian, P.
Buras, M.
Żukowski, W.
Powiązania:
https://bibliotekanauki.pl/articles/778307.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
mechanochemistry
high-energy ball milling
titanium dioxide
photocatalysis
Opis:
The paper presents a simple way to improve the photocatalytic properties of titanium dioxide using mechanochemical method. The TiO2 (Anatase) powders was subjected to high-energy ball milling in dry environment and in methanol. It has been shown that it is possible to induce the phase transformation from Anatase to Rutile and produce a material with a higher photocatalytic activity in the UV light. Physicochemical characteristics of the products were based on the following methods and techniques: X-ray powder diffraction (XRD), IR and UV-Vis (DR) spectroscopy, measurements of specific surface area (BET). The photocatalytic activity of the powders was measured in the decomposition reaction of methyl orange in water.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 3; 68-71
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Titania/mesoporous silica nanotubes with efficient photocatalytic properties
Autorzy:
Cendrowski, K.
Powiązania:
https://bibliotekanauki.pl/articles/778607.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
mesoporous silica nanotubes
silica-titania nanocomposite
photocatalysis
phenol decomposition
Opis:
Ordered nanocrystalline titania-mesoporous silica nanotube structures are synthesized by hydrolysis of the titania precursor inside pours silica shell. Silica coating surrounding carbon nanotubes was further removed by thermal reduction. The proposed method of functionalization silica channels with the titania nanoparticles preclude aggregation of TiO2  nanoparticles. The nanocrystalline silica/titania (mt-SiO2 /TiO2 ) nanotubes were prepared according to the describe method has high specific surface area and possesses excellent photocatalytic properties capable of decomposing phenol and methylene blue in a short time. Since the nanocrystalline TiO2  is produced in the wall of the mesoporous silica tube, phenol or dye molecules can react with TiO2  nanoparticles from both the inside and outside.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 1; 103-108
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Photocatalytic hydrogen generation over alkali niobates in the presence of organic compounds
Autorzy:
Zielińska, B.
Sreńscek-Nazzal, J.
Kaleńczuk, R.J.
Powiązania:
https://bibliotekanauki.pl/articles/779439.pdf
Data publikacji:
2008
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
otrzymywanie wodoru
niobiany alkaliczne
fotokataliza
hydrogen generation
alkali niobates
photocatalysis
Opis:
The photocatalytic efficiency of alkali niobate-based compounds (Li, Na, K) for hydrogen generation has been investigated. The systematic study showed that the highest photocatalytic activity was observed in the case of Na/Nb2O5 catalyst which contained sodium niobate (NaNbO3) phase and that the most efficient electron donor for hydrogen generation was formic acid. In addition, the effect of organic donor (HCOOH) concentration on the amount of the evolved hydrogen was studied.
Źródło:
Polish Journal of Chemical Technology; 2008, 10, 4; 1-3
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Comparison of NaNbO3 and NaTaO3 as the photocatalysts in the reaction of hydrogen generation
Autorzy:
Zielińska, B.
Kaleńczuk R., J.
Powiązania:
https://bibliotekanauki.pl/articles/779228.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
NaNbO3
NaTaO3
fotokataliza
wytwarzanie wodoru
photocatalysis
hydrogen generation
Opis:
The photocatalytic production of hydrogen over several chemical compounds based on sodium niobates and tantalates has been investigated. The photocatalysts have been prepared by an impregnation method of Nb2O5and Ta2O5 in the aqueous solution of sodium hydroxide and then the calcination at the temperature range of 450 – 800°C. In this report, we present the study showing that of the catalysts explored, the highest photocatalytic activity was shown in a sample obtained at the temperature of 450°C and containing NaTaO3 as a main phase.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 3; 33-35
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the structural and surface properties on photocatalytic activity of TiO2:Nd thin films
Autorzy:
Wojcieszak, D.
Mazur, M.
Kaczmarek, D.
Morgiel, J.
Poniedziałek, A.
Domaradzki, J.
Czeczot, A.
Powiązania:
https://bibliotekanauki.pl/articles/779688.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
TiO2
neodymium
thin films
magnetron sputtering
photocatalysis
phenol decomposition
Opis:
Titanium dioxide thin films doped with the same amount of neodymium were prepared using two different magnetron sputtering methods. Thin films of anatase structure were deposited with the aid of Low Pressure Hot Target Magnetron Sputtering, while rutile coatings were manufactured using High Energy Reactive Magnetron Sputtering process. The thin films composition was determined by energy dispersive spectroscopy and the amount of the dopant was equal to 1 at. %. Structural properties were evaluated using transmission electron microscopy and revealed that anatase films had fibrous structure, while rutile had densely packed columnar structure. Atomic force microscopy investigations showed that the surface of both films was homogenous and consisted of nanocrystalline grains. Photocatalytic activity was assessed based on the phenol decomposition. Results showed that both thin films were photocatalytically active, however coating with anatase phase decomposed higher amount of phenol. The transparency of both thin films was high and equal to ca. 80% in the visible wavelength range. The photoluminescence intensity was much higher in case of the coating with rutile structure.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 2; 103-111
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Time-dependent growth of the dendritic silver prepared using square wave voltammetry technique for methylene blue photodegradation
Autorzy:
Budi, Setia
Dhanasmoro, Lintang
Purwanto, Agung
Muhab, Sukro
Powiązania:
https://bibliotekanauki.pl/articles/1849284.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Square-wave voltammetry
dendritic Ag
photocatalysis
photodegradation of methylene blue
Opis:
Silver (Ag) particle is a promising photocatalyst material with relatively high catalytic activity and good absorption in the visible light region. A dendritic structure of Ag has been studied in the purpose to enhance photocatalytic activity due to a large surface area and active site number of the metallic Ag particles. In this work, the Ag dendritic structure was synthesized from a surfactant-free electrolyte using the square wave voltammetry technique. The time-dependent growth of the Ag dendrites and their photocatalytic activity on methylene blue (MB) photodegradation are reported. Morphological analysis exhibits the fractal dendritic structure of Ag was found to continuously grow by increasing the deposition time. The Ag dendrites showed a low charge transfer resistance (366.21 Ω) and high specific capacitance (2.09 F/g). A high rate of MB degradation (45.57%) under ultraviolet irradiation indicated that the Ag dendrites produced using this technique are effective for the photocatalytic degradation of MB dye.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 60-65
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Phenol and methylene blue photodegradation over Ti/SBA-15 materials under uv light
Autorzy:
Olejnik, T.
Pasieczna-Patkowska, S.
Lesiuk, A.
Ryczkowski, J.
Powiązania:
https://bibliotekanauki.pl/articles/778785.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
TiO2
SBA-15
photocatalysis
phenol
methylene blue
FT-IR/PAS
Opis:
Ordered SBA-15 mesoporous silica supports have been synthesized and used for incorporation of titanium with different Ti/Si weight ratio via incipient wetness impregnation. Titanium tetraisopropoxide (TTIP) was used as a source of Ti. Obtained catalysts were characterized to investigate the chemical framework and morphology by nitrogen sorption measurements, powder X-ray diffraction (XRD), X-ray fluorescence elemental analysis (XRF), transmission electron microscopy (TEM), UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS) and Fourier transform infrared photoacoustic spectroscopy (FT-IR/PAS). The photocatalytic degradation of phenol and methylene blue water solutions were selected as a probe reactions to the photoactivity test of prepared samples and to verify the potential application of these materials for water purification. Experimental results indicate that the photocatalytic activity of Ti/Si mixed materials depends on the adsorption ability of composites and the photocatalytic activity of the titanium oxide.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 3; 30-38
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
TiO2 modified by ammonia as a long lifetime photocatalyst for dyes decomposition
Autorzy:
Choina, J.
Dolat, D.
Kusiak, E.
Janus, M.
Morawski, A.W.
Powiązania:
https://bibliotekanauki.pl/articles/778832.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
fotokataliza
TiO2 modyfikowany azotem
żywotność
photocatalysis
nitrogen-modified TiO2
lifetime
Opis:
Ammonia-modified TiO2 (TiO2/N), prepared in a pressure reactor was used as the well- active and longlife photocatalyst for the azo dye (Reactive Red 198) decomposition. The effect of aeration and the different value of the pH of the reaction medium on the photocatalytic degradation of Reactive Red 198 in water has been investigated. It has been reported that the degradation is greatly influenced by the reaction pH and the faster decomposition of azo dye took place at pH 3.5. When the solution was acidic, a larger amount of azo dye on the positively charged surface of TiO2 photocatalysts was adsorbed. From the obtained results it can be seen that the effectiveness of the decolourisation of the solution was faster by using the nitrogen-modified TiO2.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 4; 1-6
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of Performance of Hybrid Photolysis-DCMD and Photocatalysis-DCMD Systems Utilizing UV-C Radiation for Removal of Diclofenac Sodium Salt From Water
Autorzy:
Mozia, S.
Darowna, D.
Przepiórski, J.
Morawski, A.W.
Powiązania:
https://bibliotekanauki.pl/articles/779272.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
photocatalytic membrane reactor,
direct contact membrane distillation
photolysis
photocatalysis
diclofenac sodium salt
Opis:
The removal of a non-steroidal anti-inflammatory drug (NSAID) diclofenac sodium salt (DCF, C14H10Cl2NNaO2) from water in two hybrid systems coupling photolysis or photocatalysis with direct contact membrane distillation (DCMD) is presented. A UV-C germicidal lamp was used as a source of irradiation. The initial concentration of DCF was in the range of 0.005-0.15 mmol/dm3 and the TiO2 AeroxideŽ P25 loading (hybrid photocatalysis-DCMD) ranged from 0.05 to 0.4 g/dm3. Regardless of the applied hybrid system and the initial concentration of DCF, the model drug was completely decomposed within 4h of irradiation or less. Mineralization was less efficient than photodecomposition. In case of the hybrid photolysis-DCMD process the efficiency of TOC degradation after 5h of irradiation ranged from 27.3-48.7% depending on the DCF initial concentration. The addition of TiO2 allowed to improve the efficiency of TOC removal. The highest degradation rate was obtained at 0.3 gTiO2/dm3. During the process conducted with the lowest DCF initial concentrations (0.005-0.025 mmol/dm3) a complete mineralization was obtained. However, when higher initial amounts of DCF were used (0.05-0.15 mmol/dm3), the efficiency of TOC degradation was in the range of 82.5-85%. The quality of distillate was high regardless of the system: DCF was not detected, TOC concentration did not exceeded 0.7 mg/dm3 (1.9 mg/dm3 in permeate) and conductivity was lower than 1.6 žS/cm.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 1; 51-60
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Water purification using a novel reactor with the photoactive refill
Autorzy:
Grzechulska-Damszel, J.
Morawski, A.W.
Powiązania:
https://bibliotekanauki.pl/articles/779398.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
dwutlenek tytanu
fotokataliza
reaktor przepływowy
barwniki organiczne
titanium dioxide
photocatalysis
flow reactor
photoactive coating
organic dyes
Opis:
The aim of the presented work was the removal of organic dye, Acid Red 18, from water using a novel reactor with the photoactive refill. Titanium dioxide was immobilized on the base material as a thin layer from the alcoholic suspension followed by thermal stabilization. The prepared coating exhibits high stability in repeated cycles of water treatment. The complete removal of colour was achieved in a relatively short time of 14 hours. The proposed reactor with the photoactive refill solves the problem of the necessity of the replacement of the reactor or parts of the reactor when the photocatalysts activity decreases. In the case of activity drop of the photocatalyst, only the photoactivve refill can be easily replaced.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 1; 61-63
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
A preliminary study on antifungal effect of TiO2-based paints in natural indoor light
Autorzy:
Markowska-Szczupak, A.
Ulfig, K.
Grzmil, B.
Morawski, A. W.
Powiązania:
https://bibliotekanauki.pl/articles/778079.pdf
Data publikacji:
2010
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
działanie przeciwgrzybicze
dwutlenek tytanu
naturalne światło w pomieszczeniach
fotokatalizy
antifungal activity
titanium dioxide
natural indoor light
photocatalysis
Opis:
The antifungal activity of four commercial photocatalytic paints (KEIM Ecosil ME, Titanium FA, Photo Silicate and Silicate D) in natural indoor light was investigated. The paints contained TiO2 in rutile and anatase crystalline forms as evidenced by means of the X-ray diffraction analysis. In most cases the paints inhibited growth of fungi viz. Trichoderma viride, Aspergillus niger, Coonemeria crustacea, Eurotium herbariorum, and Dactylomyces sp . The KEIM Ecosil ME paint displayed the highest antifungal effect in the light, which could be explained with the highest anatase content. The paint antifungal activity and the fungal sensitivity to the TiO2- mediated photocatalytic reaction both decreased in the following orders: KEIM Ecosil ME > Titanium FA > Photo Silicate > Silicate D and T. viride > Dactylomyces sp. > A. niger > E. herbariorum.
Źródło:
Polish Journal of Chemical Technology; 2010, 12, 4; 53-57
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł

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