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    Wyświetlanie 1-6 z 6
    Tytuł:
    Controlled Synthesis and Application of Nano-energetic Materials Based on the Copper Oxide/Al System
    Autorzy:
    He, S.
    Chen, J.
    Yang, G.
    Qiao, Z.
    Li, J.
    Powiązania:
    https://bibliotekanauki.pl/articles/358254.pdf
    Data publikacji:
    2015
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    nanoenergetic material
    CuO/Al
    laser ignition
    plate-like
    hollow sphere
    Opis:
    Nanothermite composites containing metal oxide and metal fuel are attracting attention due to their outstanding combustion characteristics. The morphology of metal oxide is important for the performance of nanothermite composites. In this paper, branch-, plate-, sphere-, and hollow sphere-like CuO nano/microstructures were synthesized via a facile hydrothermal process. The CuO/Al based nanothermites were prepared via ultrasonic mixing of the asobtained CuO products and nano-Al. The combustion behaviour of CuO/Al based nanothermites was analyzed by DSC and laser ignition. This study shows that this nanoscale mixing resulted in a large interfacial contact area and low diffusional resistance between the fuel and the oxidizer, and the reaction reflects large energy and laser ignition sensitivity.
    Źródło:
    Central European Journal of Energetic Materials; 2015, 12, 1; 129-144
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Different Ignition Responses of Powdery and Bulky 1,3,5-Triamino-2,4,6-trinitrobenzene (TATB) Based Polymer-bonded Explosives under Ultra-high Voltage Electrostatic Discharge
    Autorzy:
    Lyu, Z.
    Long, X.
    Li, Z.
    Dai, X.
    Deng, C.
    He, S.
    Li, M.
    Yao, K.
    Wen, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/358240.pdf
    Data publikacji:
    2018
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    electrostatic spark sensitivity
    ultra-high voltage electrostatic discharge
    thermal effect
    electric field effect
    Opis:
    The electric spark induced ignition mechanism for explosives needs further study. The ignition of powdery and bulky TATB by electrostatic discharge (ESD) was investigated. Up to 200 kV ultra-high voltage ESD was applied to powdery and bulky explosives of two TATB-based polymer-bonded explosives (named PBX-1 and PBX-2). The results showed that the spark sensitivities of powdery and bulky explosives are extremely different for the same formulation. The 50% ignition voltages of powdery PBX-1 and PBX-2 were 10.8 kV and 8.5 kV, respectively, while the values for the bulky samples (tablets) were not less than 200 kV. Both heat and the electric field can be transmitted into the powdery samples, on the other hand only the electric field can be transmitted into the bulk samples. The electric field has a smaller contribution while the heat has a larger contribution to the ignition during an ESD, i.e., the thermal effect plays a main role in the ignition process. Our experimental results are in good agreement with recent results calculated by density functional theory.
    Źródło:
    Central European Journal of Energetic Materials; 2018, 15, 2; 283-298
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Modelling and Calculation of the Initial Ignition Gas Pressure Flow through a Rigid Porous Medium in a 100 mm Ignition Simulator
    Autorzy:
    Xiao, Z.
    Ying, S.
    He, W.
    Xu, F.
    Powiązania:
    https://bibliotekanauki.pl/articles/358563.pdf
    Data publikacji:
    2014
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    ignition
    ignition simulator
    porous media
    propellant
    modelling
    simulation
    Opis:
    To acquire a better understanding of the early ignition phenomena in a 100 mm ignition simulator loaded with a packed propellant bed, a theoretical model of the ignition gas flow through the rigid porous medium was developed. Three pressure gauges were installed in the lateral side of the ignition simulator for post ignition measurement of the chamber pressure. The pseudo-propellant loaded into the chamber was similar in size to the standard 13/19 single-base cylindrical propellant. It was composed of a rigid ceramic composite with low thermal conductivity. It was assumed that the pseudo-propellant bed was rigid in contrast to the assumption of an elastic porous medium. The calculated pressure values were well verified by the experimental data at a low loading density of the pseudo-propellant bed of 0.18 g•cm-3. However, there was still error between the experimental and the calculated results in the early pressure peak position closest to the ignition primer when the loading density of the pseudo-propellant bed was increased to 0.73 and 1.06 g•cm-3. This error is attributed to the change in local permeability of the pseudo-propellant bed at high loading densities, which is assumed, for ease of modelling, to be constant in the model. These calculations may enable a better understanding of the physical processes of ignition gas flow in an ignition simulator loaded with a pseudo-propellant bed.
    Źródło:
    Central European Journal of Energetic Materials; 2014, 11, 4; 475-489
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Enhanced Non-linear Viscoelastic Properties of Polymer Bonded Explosives Based on Graphene and a Neutral Polymeric Bonding Agent
    Autorzy:
    Lin, C.
    He, G.
    Liu, J.
    Pan, L.
    Liu, S.
    Powiązania:
    https://bibliotekanauki.pl/articles/358748.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    polymer bonded explosives
    graphene
    neutral polymeric bonding agent
    creep behaviour
    Opis:
    During their long-term storage and transport, polymer bonded explosives (PBXs) will be subjected to complex thermal physical environments with combined thermal and mechanical loads. The creep behaviour results in a change of physical and mechanical properties, which consequently influences the explosive performance. In this work, graphene and a neutral polymeric bonding agent (NPBA) were selected to improve the non-linear creep properties of 1,3,5-triamino-2,4,6-trinitrobenzene (TATB)-based PBXs. The results were compared with the creep response of the corresponding PBXs without additives and with graphene alone. It was observed that graphene and an NPBA exhibited a positive effect, improving the creep resistance of TATB-based PBXs. The compressive and tensile strength of 0.5 wt.% graphene-filled PBXs were improved by 5.1% and 29.2%, respectively, compared to raw TATB-based PBXs without additives. The performance of the PBXs was further enhanced by the addition of 0.1 wt.% NPBA. For a given stress and temperature, the TATB-based PBXs with graphene and NPBA deformed significantly less than the PBXs filled with graphene alone.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 4; 788-805
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Ignition and Combustion Performance of the Primary Condensed-phase Combustion Products from Boron-based Fuel-rich Propellants
    Autorzy:
    Liu, L.-L.
    He, G.-G.
    Wang, Y.-H.
    Hu, S.-G.
    Powiązania:
    https://bibliotekanauki.pl/articles/358859.pdf
    Data publikacji:
    2017
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    boron-based fuel-rich propellant
    primary combustion products
    ignition
    combustion performance
    Opis:
    The primary condensed-phase combustion products of a boron-based fuel-rich propellant were ignited using a high-power CO2 laser in a pressurized and windowed combustion chamber under variable pressure. The ignition and combustion performances were characterized using an ultraviolet-visible spectrometer and a high-speed camera. The experimental results showed that the combustion of the condensed-phase combustion products originate from the combustion of carbon, and boron may not take any part in the combustion process because of the formation of a thick boron oxide coating and agglomeration after the primary combustion process. Both particle size and the ingredients play an important role in the combustion reaction of the condensed-phase products. It was observed that a lower particle size and a higher boron carbide content are beneficial for the combustion reaction of the products; higher primary and secondary combustion pressures clearly improved the secondary combustion efficiency of the propellant in the combustion reaction.
    Źródło:
    Central European Journal of Energetic Materials; 2017, 14, 2; 448-460
    1733-7178
    Pojawia się w:
    Central European Journal of Energetic Materials
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Twenty five years of azadirachtins (1986-2011)
    Autorzy:
    Hummel, H.E.
    Hein, D.F.
    Ley, S.V.
    Morgan, E.D.
    Kraus, W.
    Schmutterer, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/54974.pdf
    Data publikacji:
    2011
    Wydawca:
    Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
    Tematy:
    azadirachtin
    biopesticide
    natural product
    seed
    neem tree
    Azadirachta indica
    marrango tree
    Azadirachta excelsa
    Tetranychus urticae
    Epilachna varivestis
    Opis:
    Azadirachtins are known as phagorepellent natural products from seeds of the neem tree Azadirachta indica A. Juss (Meliaceae), which impede the development of larval insects and sterilize adults. The labors of the past three decades ultimatively lead to a chemical structure, which has been unanimously but independently elaborated by German, British and American authors. This structure is in force ever since 1985/87 and was ultimately confirmed by Veitch & al. in Ley’s group in Cambridge, England, through total synthesis. Its 25th birthday is presently being celebrated. Marrangin (=Azadirachtin L) was discovered in Gießen and chemically identified by Kalinowski and colleagues. It occurs in seeds of the marrango tree, Azadirachta excelsa (Jack) Jacobs. In some insect species but also in mites like Tetranychus urticae, its biological activity is significantly superior to azadirachtin A. The value of these biorational compounds, with their very low vertebrate toxicity, and their low toxicity today is globally recognized. Quite recently, azadirachtin and analogues gain acceptance in veterinary and human medicine.
    Źródło:
    Pestycydy; 2011, 1-4
    0208-8703
    Pojawia się w:
    Pestycydy
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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