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Wyświetlanie 1-3 z 3
Tytuł:
Thermally induced damage in hexanitrohexaazaisowurtzitane
Autorzy:
Tian, Q.
Yan, G.
Sun, G.
Huang, C.
Xie, L.
Chen, B.
Huang, M.
Li, H.
Liu, X.
Wang, J.
Powiązania:
https://bibliotekanauki.pl/articles/358735.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
CL-20
SAXS
AFM
thermal effects
voids
Opis:
The evolution of the microstructure of hexanitrohexaazaisowurtzitane (CL-20) after a thermal stimulus plays a key role in the performance of CL-20. In the current work, microstructural variations of CL-20 caused by thermal treatment were investigated by X-ray diffraction, in situ variable-temperature optical microscopy, atom force microscopy, and small-angle X-ray scattering. A wave-like process, an abrupt volume expansion, movement, and fragmentation of CL-20 particles during phase transition were observed. After the phase transition (160 °C) the CL-20 sample acquired a very rough surface with numerous dimple depressions, and during the thermal decomposition stage (200 °C) a large number of voids were produced in both the bulk and the surface of the CL-20.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 3; 359-369
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Quantum Chemical Study of Aminonitrocyclopentanes as Possible High Energy Density Materials (HEDMs)
Autorzy:
Bai, J.
Chi, W. J.
Li, L. L.
Yan, T.
Wen, X. E.
Li, B. T.
Wu, H. S.
Ma, F. L.
Powiązania:
https://bibliotekanauki.pl/articles/358101.pdf
Data publikacji:
2013
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
cyclopentane derivatives
high energy density materials
impact sensitivity
quantum chemistry
DFT
available free space
Opis:
Nitro and amine groups were introduced into the cyclopentane skeleton, and the heats of formation, detonation performance, bond dissociation energies, and impact sensitivity for these aminonitrocyclopentanes were calculated in detail at the B3LYP/6-311G** level. The results show that all of the derivatives have negative heats of formation, which are influenced by the position of the substituent groups. Their stabilities were estimated and analyzed according to their bond dissociation energies and calculated characteristic H50 values. Most of the compounds were found to have a lower impact sensitivity than HMX. Furthermore, the detonation velocities and detonation pressures were predicted via the Kamlet-Jacobs equation. Of all these aminonitrocyclopentanes, E has the best detonation properties (ρ = 2.05 g/cm3, D = 9.11 m/s, P = 39.62 GPa) and can be considered as a candidate high energy density material.
Źródło:
Central European Journal of Energetic Materials; 2013, 10, 4; 467-480
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Microstructural Evolution in HMX Based Plastic-bonded Explosive During Heating and Cooling Process: an in situ Small-angle Scattering Study
Autorzy:
Yan, G.
Tian, Q.
Liu, J.
Fan, Z.
Sun, G.
Zhang, C.
Wang, Y.
Chen, B.
Gong, J.
Zhou, X.
Yang, Z.
Nie, F.
Li, J.
Li, X.
Powiązania:
https://bibliotekanauki.pl/articles/358618.pdf
Data publikacji:
2016
Wydawca:
Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
Tematy:
SANS
SAXS
HMX-PBX
thermal damages
phase transition
Opis:
The thermal damage in octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine (HMX) based plastic-bonded explosive (PBX) was investigated using in situ small-angle neutron and X-ray scattering techniques. The microstructural evolution was quantitatively characterized by the model fitting parameters of total interfacial surface area (Sv) and void volume distribution. The Sv of HMX-PBX decreased markedly above 100 °C, indicating the movement of binder into the voids. After subsequent cooling to room temperature, the scattering intensity increased significantly with increasing storage time, and a new population of voids with average diameter of 20 nm was observed, accompanied by the gradual phase transition of HMX from δ- to β-phase. The experimental results implied that serious damage within the HMX-PBX was developed during storage after heating.
Źródło:
Central European Journal of Energetic Materials; 2016, 13, 4; 916-926
1733-7178
Pojawia się w:
Central European Journal of Energetic Materials
Dostawca treści:
Biblioteka Nauki
Artykuł
    Wyświetlanie 1-3 z 3

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