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Wyszukujesz frazę "Heavy metals" wg kryterium: Temat


Tytuł:
Analysis of the Possibility of Heavy Metal Ions Removal from Aqueous Solutions on Fruit Pomace
Autorzy:
Krasowska, Małgorzata
Kowczyk-Sadowy, Małgorzata
Szatyłowicz, Ewa
Obidziński, Sławomir
Powiązania:
https://bibliotekanauki.pl/articles/24201639.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
fruit pomace
adsorption
heavy metals
Opis:
Pomace from apples, grapes, blackcurrants, and oranges is a waste product of fruit processing, which is formed during the production of juices. Pomace is a rich source of biologically active compounds such as polyphenols, carotenoids, or vitamins. They also contain pectin, cellulose, lignin, proteins, and minerals. All these components, apart from having many beneficial properties for human health, also show sorption properties towards heavy metal ions. Therefore, this study aimed to evaluate the possibility of removing lead (II) and cadmium (II) ions from aqueous solutions by adding apple, grape, black currant, and orange pomace as well as to determine the adsorption efficiency of selected heavy metals. The studies were carried out in model systems. The results of the research showed that lead (II) and cadmium (II) ions are adsorbed on fruit pomace. The highest removal of cadmium (II) ions was observed in orange pomace and of lead (II) ions in apple pomace. The maximum tested cadmium ions absorption capacity was: 0.117235 mg/g in the case of freeze-dried apple pomace; 0.08618 mg/g in the case of freeze-dried currant pomace; 0.21915 m/g in the case of freeze-dried grape pomace and 0.29549 mg/g in the case of freeze-dried orange pomace. On the other hand, the maximum absorption of lead ions was: 0.457 mg/g in the case of freeze-dried apple pomace; 0.442 mg/g in the case of freeze-dried currant pomace; 0.3445 mg/g in the case of freeze-dried grape pomace and 0.421 mg/g in the case of freeze-dried orange pomace. On the basis of the performed measurements, it can be concluded that the tested waste can potentially be used as a cheap biosorbent for removing heavy metal ions from dilute aqueous solutions.
Źródło:
Journal of Ecological Engineering; 2023, 24, 3; 169--177
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Determination of Heavy Metals in Bee Honey as a Bioindicator in the Istog, Drenas and Kastriot Regions
Autorzy:
Demaku, Skender
Aliu, Arbnorë
Sylejmani, Donika
Ahmetaj, Blerina
Halili, Jeton
Powiązania:
https://bibliotekanauki.pl/articles/24201705.pdf
Data publikacji:
2023
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
pollution
environment
honey
heavy metals
Opis:
The major goal of this research was to employ honey as a bio-indicator to identify the heavy metal levels in bee honey in the Istog, Drenas, and Kastriot regions. As a result, honey was purposely tested in these locations, and two industrial specific areas were chosen for examination and analysis: Kastriot (Graboc) and Drenas (Vrboc), as these are considered to be among the most industrial polluted areas. A honey sample was also taken in the Istog (Vrell, as a clean area) region in order to compare not just honey, but also the area where the bee obtains nectar, as well as the sources of pollution discharge into the environment. Concentrations of heavy metals in honey, (min. and max.) amounted to: Zn (8.705–9.804 mg/kg), Mn (5.620–5.718 mg/kg), Fe (3.635–3.745 mg/kg) and Cu (2.295–2.299 mg/kg). In contrast, lower concentrations of metals, have been observed for: Ni (0.640–1.126 mg/kg), Pb (0.235–0.268 mg/kg), As (0.107–0.199 mg/kg), Cd (0.040–0.058 mg/kg) and Cr (0.025–0.036 mg/kg) while elements such as; Hg, and Co, are almost undetected. The study of hierarchical clusters revealed several groupings of elements with geogenic and anthropogenic origins. The concentrations of heavy metals selected for honey were compared to standards of other countries, such as Poland and other European Union countries. Samples were taken in October 2020 and September 2021. The concentration of heavy metals was determined using inductively coupled plasma optical emission spectrometry, ICP OES.
Źródło:
Journal of Ecological Engineering; 2023, 24, 5; 191--200
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Content of Heavy Metals in Bottom Sediments of Selected City Rivers of the Podlasie Province
Autorzy:
Skorbiłowicz, M.
Skorbiłowicz, E.
Górska, M.
Powiązania:
https://bibliotekanauki.pl/articles/124842.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metals
river
bottom sediments
Opis:
The purpose of the work was to determine the relationship between the state of the water environment quality of selected rivers (Zn, Cr, Pb, Cd and Cu tests in bottom sediments), and the sources of pollution resulting from the close proximity to the cities, through which they flow. The following rivers were selected for the study: the Biała river flowing through the city of Białystok, the Narew river flowing through the city of Tykocin and the village of Złotoria, the Supraśl river flowing through the village of Michałowo and Gródek as well as the Biała river flowing through the city of Bielsk Podlaski. The sediments were collected four times from the same points in 2016 in the period from July to October. The sediment samples were collected from the points located on rivers before and beyond towns and villages. The contents of the following metals were tested in the bottom sediment samples: Zn, Cr, Pb, Cd and Cu. The analyses were carried out applying the flame absorption spectrometry method. The statistical multivariate CA and FA analyzes were used. The highest contents of Zn, Pb and Cr were recorded in the bottom sediments from the following rivers: Biała (Białystok) and Biała inflow of Orlanka (Bielsk Podlaski), which resulted from the anthropogenic activity. The research also showed the impact of the agricultural activity due to the slightly elevated Cd level.
Źródło:
Journal of Ecological Engineering; 2018, 19, 4; 197-206
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Soil Pollution in the Azov Territories of Rostov-on-Don and Taganrog
Autorzy:
Zabaikin, Yuri V.
Lyutyagin, Dmitry V.
Yashin, Vladimir P.
Yashina, Valentina I.
Powiązania:
https://bibliotekanauki.pl/articles/1955493.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
soil
pollution
heavy metals
Azov
Opis:
The research on the topic of the dissertation was carried out within the coastal (southern) part of the Azov oblique dissected accumulative-denudated plain and the coastal strip of the coast of the Sea of Azov, as well as the valleys of the lower reaches of the Don and Kalmius rivers. The research area covered the modern territory of Taganrog and Rostov-on-Don cities and a suburban area up to 15-20 km away from the borders of these cities. According to the materials of the USSR soil map, as well as modern schemes of soil zoning in Russia, the study area covers the distribution area of ordinary chernozems and partially southern low-humus chernozems on loess rocks. The main zonal soil studied was ordinary chernozem. Ordinary warm chernozems with a short freezing period, belonging to the Azov-Ciscaucasian province of powerful and super-powerful chernozems, predominate in the soil cover of the Azov inclined plain, extending from the Donets Ridge to the shores of the Sea of Azov and the lower Don River.
Źródło:
Journal of Ecological Engineering; 2021, 22, 8; 165-171
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Vermicomposting on the Concentration of Heavy Metals in Soil with Drill Cuttings
Autorzy:
Kujawska, Justyna
Wójcik-Oliveira, Katarzyna
Powiązania:
https://bibliotekanauki.pl/articles/123685.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
drill cuttings
vermicomposting
heavy metals
Opis:
Organic and non-organic pollution present in the drilling waste may negatively impact flora and fauna. The tests conducted on earthworms may serve as indicators for the assessment of pollution bioavailability, i.a. heavy metals, polycyclic aromatic hydrocarbons, due to the relatively stable ratios between the concentration of certain pollutants in earthworms and soil. Moreover, earthworms are capable of metal bioaccumulation in tissues; therefore, they can be utilized as an ecological indicator of soil pollution. The studies on bioaccumulation of heavy metals from soils with the addition of drilling wastes in tissues of earthworms were conducted. The reduction percentage (R) of each scenario was calculated for the total concentration of all heavy metals. As data showed, all heavy metal content was reduced from its initial concentration.
Źródło:
Journal of Ecological Engineering; 2019, 20, 1; 152-157
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Evaluation of the Content of Selected Heavy Metals in Samples of Polish Honeys
Autorzy:
Sitarz-Palczak, E.
Kalembkiewicz, J.
Galas, D.
Powiązania:
https://bibliotekanauki.pl/articles/123800.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
bee products
heavy metals
FAAS
Opis:
This paper presents the result of the determination of the total content of Cu, Pb and Zn by the method of atomic absorption spectrometry with atomization in an air-acetylene flame in Polish honeys samples. The research material was a honeydew, monofloral honey and buckwheat honey. For the mineralization of samples, the following solutions were applied: 1) HNO3(conc), 2) HNO3(conc) and H2O2(conc) in the volume ratio equal to 4:1 and 3:1. On the basis of the results and recommended food standards the percentage of the recommended dietary allowances (RDA) in connection with the consumption of 100 g of product were estimated. To verify the results validation of analytical method used was carried out. It was included defining the following validation parameters values: the limit of detection and quantification; linearity and measurement range; repeatability and accuracy of the results. The contamination of the analyzed honeys by Pb is higher than the acceptable level of contamination of this element. The highest contents of Cu and Zn were characterized by monofloral honeys.
Źródło:
Journal of Ecological Engineering; 2015, 16, 3; 130-138
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Bees as Bioindicators of Environmental Pollution with Metals in an Urban Area
Autorzy:
Skorbiłowicz, E.
Skorbiłowicz, M.
Cieśluk, I.
Powiązania:
https://bibliotekanauki.pl/articles/124666.pdf
Data publikacji:
2018
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
bees
bioindicators
pollution
heavy metals
Opis:
The commonness of metal contamination, even at considerable distances from industrial centers and intensively used economic areas, has become the interest of many researchers. The issue of evaluating the state of the environment with the help of living organisms has become a very important part in the control of the natural environment. Honey bee (Apis mellifera L) is a good bioindicator as it is inextricably linked to the natural environment in which it lives. The aim of the research, and at the same time the main assumption of the study, was to evaluate the effectiveness of honeybees (Apis mellifera L) as bioindicators for the presence of Cu, Cr, Zn, Mn, Fe in the urban area (example of Bialystok city). The study includes pilot studies covering three sampling periods (March, June and September 2015). Analyses of metals were made by ASA method. The results showed the presence of Cu, Cr Zn, Mn and Fe in all bees samples. An increased content of Cr in bees was also found, which may be the result of the presence of this element in the environment (air, soil, water, plants, pollen) and in the impregnation agent applied to protect wooden elements of the bee hive. The research showed seasonal variation of metals in bees bodies. The main sources of studied metals in bee samples seem to be motorization, industry, and municipal economy within the urban area. Statistical calculations showed a common origin of majority of studied metals. Bee studies for metals contents can be an important element of a bio-monitoring of changing natural environment as a consequence of anthropogenic activity.
Źródło:
Journal of Ecological Engineering; 2018, 19, 3; 229-234
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Analysis of Heavy Metal Fraction Content in Sewage Sludge from Selected Wastewater Treatment Plants
Autorzy:
Wojciula, Ada
Boruszko, Dariusz
Pajewska, Gabriela
Powiązania:
https://bibliotekanauki.pl/articles/1839655.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
sewage sludge
heavy metals
heavy metal fraction
Opis:
Assessment of the assimilability of elements contained in sewage sludge can only be carried out if their fractions, by means of which the chemical form of the element can be identified, are determined. The total content of heavy metals only makes it possible to determine whether the sludge meets the legal requirements and can be used, inter alia, for reclamation, in agriculture or for the adaptation of land to specific needs that result from waste management plans. Therefore, when planning the agricultural use of sewage sludge, attention should be paid above all to the heavy metal fractions contained in it. This is due to the fact that plants do not assimilate every form of element to the same extent. The research and analysis carried out indicate that the metals were most closely related to fractions IV and III, for example they formed connections with silicates, as well as sulphides and organic matter. The metal forms available to plants occupied a small percentage of the total heavy metal content. It was noted that with the metastable fraction of lead increased along with population equivalent. Furthermore, the population equivalent value did not affect the distribution of individual heavy metal fractions in the sludge.
Źródło:
Journal of Ecological Engineering; 2021, 22, 4; 98-105
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Effect of Mining Activity in Accumulation of Heavy Metals in Soil and Plant (Urtica dioica L)
Autorzy:
Bislimi, Kemajl
Sahiti, Hazbije
Halili, Jeton
Bici, Mentor
Mazreku, Ilir
Powiązania:
https://bibliotekanauki.pl/articles/1839574.pdf
Data publikacji:
2021
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metals
soil
translocation factor
bioaccumulation
Opis:
Contamination of soil and water by various heavy metals such as Cd, Pb, Ni, Cu, and Fe is increasing day by day as a result of different activities, such as industrialization and urbanization. Lead (Pb), Cadmium (Cd), and Nickel (Ni) are examples of potential heavy metals that are neither essential elements nor have any role in the process of cell metabolism, but are easily absorbed and accumulated in different parts of a plant and living beings. This study was to investigate the translocation and bioaccumulation of heavy metals such as Pb, Ni, Cd, Cu, and Fe in Urtica dionica L and soil samples from 2 sites (uncontaminated – Koliq and contaminated – Kishnica in the Republic of Kosovo). The results revealed that in the contaminated site, the mean level of all the metals in soil and different parts (root, stalk, and leaf) of the plant were found to be significantly (p < 0.01) higher than the uncontaminated site. Multivariate analysis was used to determine the distribution of metals within the study area. The trace metal contents from different parts of these plants were determined by the use of AAS. The results revealed that Urtica dionica L. translocated high amounts of metals to its organs, especially to leaves, so that translocation factors were much higher than one (> 1). However, these concentrations of heavy metals in the soil and Urtica dionica L were higher than levels specified according to the standards in UK and Germany.
Źródło:
Journal of Ecological Engineering; 2021, 22, 1; 1-7
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Heavy Metal Contamination in Agricultural Soils: A Case Study in Mohammedia Benslimane Region (Morocco)
Autorzy:
Zaakour, Fatna
Kholaiq, Mariame
Khouchlaa, Aya
El Mjiri, Ikram
Rahimi, Abdelmejid
Saber, Najib
Powiązania:
https://bibliotekanauki.pl/articles/2086417.pdf
Data publikacji:
2022
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
pollution
soil
wheat
heavy metals
vine
Opis:
This research aimed to determine the physicochemical characteristics and heavy metal concentrations of agricultural soils used for grape and wheat production in Morocco in the Mohammedia Benslimane area. The organic matter (OM) content ranged from 0.6% to 2.93%. The degree of total nitrogen was higher in the wheat plots than in the vine plots in the Mohammedia and Benslimane regions. Total nitrogen average rates ranged from 0.04 to 0.5% and from 0.07 to 0.8% in the vine and wheat plots. These results imply that the soil was silty clay and clay texture, neutral to slightly acidic at all stations. The P2O5 concentrations were 11.15 ppm and 68.14 ppm under the vine and the wheat plots, respectively, while the potassium concentration ranged from 33.1 to 287.9 ppm and from 26.9 to 184.75 ppm under the vine and the wheat plots, respectively. Furthermore, the concentrations of Cd at a few stations exceeded the standard value (2 ppm), reaching 10.375 ppm. The Pb and Zn concentrations were higher in vineyard plots than in wheat plots. The Pb and Zn concentrations were 20.22 ppm and 148.60 ppm, respectively. This study reports updated information on the states of eight stations in Mohammedia and Benslimane. However, further research is necessary to determine the pollution factors in local practice crops and naturally growing plants at these stations to assess their impact on livestock and humans.
Źródło:
Journal of Ecological Engineering; 2022, 23, 5; 1--15
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The Impact of Sewage Treatment Plant on the Amount of Heavy Metals in Water of the Supraśl River Catchment Area
Autorzy:
Skorbiłowicz, M.
Skorbiłowicz, E.
Wójtowicz, P.
Ofman, P.
Zamojska, E.
Powiązania:
https://bibliotekanauki.pl/articles/123581.pdf
Data publikacji:
2016
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
sewage treatment plant
heavy metals
water
Opis:
The main purpose of this study was to evaluate the effect of treated sewage flowing from sewage treatment plants located in the basin of the Supraśl river on the concentration and load of metals in river waters and its main tributaries. Three measuring- control points were chosen, on the river and its tributaries, located near Gródek, Sokółka and Dobrzyniewo. Selected points were located behind the discharge of treated wastewater from sewage treatment plants respectively – Gródek, Sokółka and Bialystok. The samples of treated sewage and water were collected in a period from May to November, once a month in 2014. Each individual sample was examined for the content of dissolved form of the following metals: Pb2+, Cu2+, Cd2+, Ni2+, Zn2+, Fe2+/3+. After taking into account water flow of the Biała, Sokołda and Supraśl in every month, metals loads expressed in mg·h-1., transported by the Supraśl and its tributaries waters were calculated. In the study monthly metals loads discharged into the Biała, Sokołda and Supraśl by sewage treatment plants in Białystok, Sokółka and Gródek were also calculated. The studies have shown the impact of metals load in treated wastewater on metals loads in waters of studied rivers based on the obtained correlation. Most of the searched relations between loafs of Pb2+ – r = 0,88; Cd2+ – r = 0,98; Fe2+/3+ – r = 0,45; Ni2+ – r = 0,55; Zn2+ – r = 0,86 were obtained in case of wastewater treatment plant in Gródek and Supraśl waters. In the study period we observed a diversity in concentration of Cd2+, Fe2+/3+, Ni2+ and Zn2+ in treated sewage and in river waters, which affected loads of this metals.
Źródło:
Journal of Ecological Engineering; 2016, 17, 1; 136-142
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Efficiency of leaching tests in the context of the influence of the fly ash on the environment
Autorzy:
Kalembkiewicz, J.
Sitarz-Palczak, E.
Powiązania:
https://bibliotekanauki.pl/articles/125254.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metals
fly ash
leaching test
Opis:
The leachability of heavy metals (Cu, Pb and Zn) from the coal fly ash samples was studied. The investigations executed using three leachability tests (USEPA, TCLP, ASTM). The effect of different parameters was determined (the diameter of ash grains, the kind of leaching solutions, pH of leaching solutions, the volume ratio of leaching solutions to the mass of ash samples, and the leaching time) on the leachability of the heavy metals from fly ash samples. Moreover, the influence of pH and changes in the redox potential of the leaching solutions as well as the presence of organic compounds that could potentially form complexes with metals and solubility changes of metals. The concentration of the metals studied (Cu, Pb and Zn) in all obtained solutions was determined by FAAS method. On the basis of the research investigations, optimal leachability conditions for Cu, Pb and Zn from fly ash in this study have been determined. We have also found that pH of the leaching solution, and the presence of organic compounds which have a potential capacity of complexion the metals are the important factors in determining the solubility of Cu, Pb and Zn.
Źródło:
Journal of Ecological Engineering; 2015, 16, 1; 67-80
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Distribution and Seasonal Variation of Heavy Metals in Sediments of Muthupet Lagoon, Southeast Coast of India
Autorzy:
Balakrishnan, T.
Sundaramanickam, A.
Shekhar, S.
Balasubramanian, T.
Powiązania:
https://bibliotekanauki.pl/articles/125289.pdf
Data publikacji:
2015
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
seasonal variation
heavy metals
Muthupet lagoon
Opis:
This study deals with seasonal variation of heavy metals in sediments of Muthupet lagoon, Southeast coast of India from September 2011 to August 2012. The bulk sediments were association with sand, silt and clay. Geoaccumulation index (lgeo) was used to quantitatively assess the influences of heavy metal pollution. Heavy metals were determined by using Inductively Coupled Plasma Optical Emission Spectrometer (ICP-OES) and the results were compared to permissible limits of WHO/USEPA. The minimum concentration of heavy metals in all the stations were found during the post monsoon and summer seasons and the maximum concentration of heavy metals in all the stations were found during the premonsoon and monsoon seasons. The reason for the pollution was land drainage, irrigation through channels and municipal wastes and also the peak agricultural activities due to the release of fresh water from reservoirs. Among all the metals iron was found to be maximum in all the stations in postmonsoon and summer season followed by magnesium and manganese. Apart from these three metal, all other six metals are recorded in moderate range. The reason for the high concentration of these metals are anthropogenic activity, agriculture, aquaculture and the rivers regular in and out flow throughout the study duration in the lagoon area.
Źródło:
Journal of Ecological Engineering; 2015, 16, 3; 49-60
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Trace Elements in Consumer Plants
Autorzy:
Wiater, Józefa
Wojciula, Ada
Powiązania:
https://bibliotekanauki.pl/articles/125474.pdf
Data publikacji:
2019
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
heavy metals
vegetables
fruits
bioaccumulation
soils
Opis:
The aim of this study was to estimate the content of trace elements (Zn, Cu, Cr, Cd, Pb) in soils and consumer plants grown under and without the influence of traffic. The species such as lettuce, raspberry, beetroot, apple, carrot, chives and onion were selected for the study. The samples were mineralized and the heavy metal content in plants and soils was determined by means of atomic absorption spectrometry. The content of heavy metals in the soil from municipal allotments was higher than in the soil from the Saniki Colony. For both samples, the permissible soil content was not exceeded. The amount of trace elements in plants varied depending on species, but the place of vegetables and fruits origin was also important. Most of trace elements occurred in larger amounts in the plants from allotments, and in smaller amounts in the plants from Saniki Colony.
Źródło:
Journal of Ecological Engineering; 2019, 20, 10; 252-256
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Combined Adsorption of the Copper and Chromium Cations by Clinoptilolite of the Sokyrnytsya Deposit
Autorzy:
Sabadash, Vira
Gumnitsky, Jaroslaw
Lyuta, Oksana
Powiązania:
https://bibliotekanauki.pl/articles/123357.pdf
Data publikacji:
2020
Wydawca:
Polskie Towarzystwo Inżynierii Ekologicznej
Tematy:
copper
chromium
heavy metals
adsorption
zeolite
Opis:
In the paper, the assessment of the impact of heavy metals on water objects, namely copper and chromium was performed, and the methods for their neutralization were defined. A scientifically grounded method for the selection of natural zeolite for the purification of wastewater from heavy metals has been developed, provided that they are jointly present. The physicochemical characteristics of two metals related to heavy metals are presented: copper and chromium. The methods for determining the sorption capacity of natural zeolite for copper and chromium compounds, as well as the methods of analytical control of the wastewater components were presented. The results of the experimental studies on the combined adsorption of copper and chromium cations by natural zeolite under static conditions were presented. The changes in the chemical composition of the zeolite surface as a result of heavy metal sorption have been investigated. The influence of the nature of the ions and the pH of the adsorption medium on the selectivity of the heavy metal ions extraction by zeolite was analyzed. A diagram of the composition of the solution, depending on the pH values, was constructed. The pH of the beginning of deposition of the corresponding heavy metal hydroxides on the zeolite surface was calculated. While analyzing the results of experimental studies on the combined adsorption of copper and chromium ions, it was found that the copper ions are significantly better adsorbed by the sorbent than the chromium ions. Despite the same concentration of the chromium and copper ions in solution, Cu2+ is extracted selectively. As can be seen from the results of experimental studies, the concentration of copper on the surface of the sorbent increases from 0.628% mass at a concentration of 0.01 g/dm3 to 47.380% mass at a concentration of 1 g/dm3. The studies on the static activity of clinoptilolite for the copper and chromium ions indicate a simultaneous mechanism of the process, which involves ion exchange and physical adsorption. The concentration of the chromium ions on the surface of the sorbent after adsorption depends on the increase of the concentration of Cr3+ in the original solution to a lesser extent. The results of the studies on the combined adsorption of the Cu2+ and Cr3+ ions indicate the possibility of their chromatographic separation, which makes their further use possible.
Źródło:
Journal of Ecological Engineering; 2020, 21, 5; 42-46
2299-8993
Pojawia się w:
Journal of Ecological Engineering
Dostawca treści:
Biblioteka Nauki
Artykuł

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