- Tytuł:
- Complete Diagonalization Calculation of the Optical and EPR Data for the Tetragonal $Cu^{2+}$ Center in $Cu^{2+}$-Doped ZnSe Nanocrystals
- Autorzy:
-
Wu, Xiao-Xuan
Zheng, Wen-Chen - Powiązania:
- https://bibliotekanauki.pl/articles/1399131.pdf
- Data publikacji:
- 2015-03
- Wydawca:
- Polska Akademia Nauk. Instytut Fizyki PAN
- Tematy:
-
76.30.Fc
71.70.Ch
78.40.Fy
75.10.Dg - Opis:
- By using the complete diagonalization (of energy matrix) method based on the cluster approach (where the admixture between the d orbitals of $d^{n}$ ion and p orbitals of ligands due to covalence effect is considered), the optical and electron paramagnetic resonance data (three optical band positions and four EPR parameters $g_{∥}$, $g_{⊥}$, $A_{∥}$, $A_{⊥}$) are calculated for the tetragonal $Cu^{2+}$ center in $Cu^{2+}$-doped poly vinyl alcohol (PVA) passivated ZnSe nanocrystals with the defect model of $Cu^{2+}$ in the interstitial octahedral site in ZnSe. The calculated results are near the experimental values. The tetragonal elongation of the $Cu^{2+}$ octahedral cluster in ZnSe nanocrystals is obtained. The results are discussed.
- Źródło:
-
Acta Physica Polonica A; 2015, 127, 3; 795-798
0587-4246
1898-794X - Pojawia się w:
- Acta Physica Polonica A
- Dostawca treści:
- Biblioteka Nauki
Artykuł