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    Wyświetlanie 1-5 z 5
    Tytuł:
    Thermodynamic analysis of the influence of potassium on the thermal behavior of kaolin raw material
    Autorzy:
    Hernández-Chávez, Macaria
    Vargas-Ramírez, Marissa
    Herrera-González, Ana Maria
    García-Serrano, Jesús
    Cruz-Ramírez, Alejandro
    Romero-Serrano, José Antonio
    Sánchez-Alvarado, Ricardo Gerardo
    Powiązania:
    https://bibliotekanauki.pl/articles/1448343.pdf
    Data publikacji:
    2021
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    kaolin
    thermal treatment
    thermodynamic analysis
    viscosity
    Opis:
    The mineralogy and thermal properties of two kaolin clay samples from Agua Blanca (Hidalgo-México) were determined by XRD, SEM-EDS, TGA-DSC techniques. Kaolin clay A contains a higher $Al_2O_3$ and lower impurities $(K_2O, TiO_2, Fe_2O_3)$ amount than kaolin clay B, while the SiO2 amount is similar for both kaolin clays. A theoretical approach was carried out by a thermodynamic analysis considering the chemical composition of both kaolin clay samples with the FactSage 7.3 software. Stability phase diagrams were obtained to different K2O content from 0.1 to 3 wt % and temperatures in the range from 600 to 1600°C based on the chemical composition of the kaolin clay samples. The main mineralogical compounds predicted are andalusite $(Al_2O_3•SiO_2)$, K-Potash feldspar $(K_2O•Al_2O_3•6SiO_2)$, and the $SiO_2$ polymorphs (quartz, tridymite, and cristobalite) with small amounts of ferric-pseudobrookite $(Fe_2O_5Ti)$, and rutile $(TiO_2)$. As $K_2O$ content is increased, the amounts of mullite and tridymite decrease meanwhile the potash feld spar is increased at high temperatures. A liquid phase is formed at around 1350 and 1400°C for the kaolin clay samples A and B, respectively. The viscosity of the melt is increased for the evaluated $K_2O$ additions to 1400, 1500, and 1600°C.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2021, 57, 1; 39-52
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Processing of phosphorites with extraction of phosphorus, obtaining calcium carbide and ferroalloy
    Autorzy:
    Shevko, Victor M.
    Uteyeva, Raisa A.
    Badikova, Alexandra D.
    Tleuova, Saltanat T.
    Powiązania:
    https://bibliotekanauki.pl/articles/27323638.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    phosphorite
    thermodynamic modeling
    electrical melting
    phosphorus
    calcium carbide
    ferroalloy
    Opis:
    The article considers the results of studying the thermodynamic computer modeling of the interaction of phosphorite (Karatau basin, Kazakhstan) with carbon and coke performed using the HSC-10 software package and electric smelting of the phosphorite with coke and steel shavings in an arc furnace. The modeling allowed us to determine the equilibrium extraction degrees of phosphorus into gas (Р2, Р4), silicon into ferroalloy in the form of iron silicides (FeSi2, FeSi, Fe3Si, Fe5Si3, Si) and calcium into CaС2. At temperatures above 1500 °C, regardless of the amount of iron, the extraction degree of phosphorus into gas is more 99%. The resulting ferroalloy contains 21.2-23.8% of Si, 1.6-2.8% of Al; the calcium carbide has a capacity of 288-325 dm3/kg. The extraction degree of silicon into the alloy was 89.8%, calcium in CaC2 – 72.5%, phosphorus into gas – 99.4%. The ferroalloy, formed at the electric smelting of the Chulaktau phosphorite together with coke and steel shavings and containing 24.9-29.8% of Si, is FS25 grade ferrosilicon, and the formed calcium carbide has a capacity of 278-290 dm3/kg and belongs to the third and second grades. The developed technology makes it possible to increase the degree of phosphorites’ comprehensive use two times (up to 87.5%).
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 6; art. no. 174463
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Characteristics of natural and synthetic molecular sieves and study of their interactions with fragrance compounds
    Autorzy:
    Kasperkowiak, M.
    Strzemiecka, B.
    Voelkel, A.
    Powiązania:
    https://bibliotekanauki.pl/articles/110548.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    molecular sieves
    fragrance compounds
    adsorption properties
    thermodynamic parameters
    thermal stability
    Opis:
    Structural, physicochemical and adsorption properties of two natural and one synthetic molecular sieves were investigated by various techniques: X-ray diffraction, X-ray photoelectron spectroscopy, transmission electron microscopy, low-temperature nitrogen adsorption and inverse gas chromatography. The influence of these properties on the ability to adsorb two model fragrances: p-cymene and menthol was studied. The free enthalpy, entropy and Gibbs free energy of adsorption of fragrance molecules on the surface of zeolite and zeolite-like materials were estimated by using inverse gas chromatography. Also, the influence of temperature on the stability of solid-fragrance compound systems as well as the release of the adsorbed fragrance compounds was studied. The obtained results exhibit that both porosity and chemical composition of molecular sieves influence the size and strength of adsorption of fragrance compounds. The study indicated different release characteristics for p-cymene and menthol.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2016, 52, 2; 789-802
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Temperature influence on the electrode process in the presence of 6-thioguanine and surfactants
    Autorzy:
    Nosal-Wiercińska, Agnieszka
    Kaliszczak, Waldemar
    Martyna, Marlena
    Szabelska, Anna
    Gołębiowska, Beata
    Wiśniewska, Małgorzata
    Powiązania:
    https://bibliotekanauki.pl/articles/1845199.pdf
    Data publikacji:
    2020
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    catalytic effect
    Bi(III) electroreduction
    6-thioguanine
    surfactants
    thermodynamic parameters
    kinetic parameters
    Opis:
    The measurements concerning the process of the electroreduction of Bi(III) ions in the presence of 6–thioguanine (6TG) and Triton X-100 as well as Tween 80 in the 2 $mol·dm^{-3}$ chlorates(VII) demonstrate a dependence of the process rate on temperature. The applied electrochemical techniques (DC polarography, cyclic and SWV voltammetry) allowed to determine the kinetic and thermodynamic parameters as well as their correlation with changes in kinetics of the electrode process. The catalytic activity of 6TG was confirmed by the decrease of overall enthalpies of activation. Different values of $\DeltaH^{\ne}$ and $\DeltaS^0$ for Bi(III) electroreduction in the presence of 6–thioguanine as well as Triton X-100 and Tween 80 suggest changes in kinetics of the electrode process towards inhibition.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2020, 56, 6; 14-21
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Theoretical and experimental substantiation of obtaining an alloy from flotation tailings of lead-zinc sulfide ore
    Autorzy:
    Shevko, Victor M.
    Makhanbetova, Baktygul A.
    Aitkulov, Dosmurat K.
    Powiązania:
    https://bibliotekanauki.pl/articles/2200342.pdf
    Data publikacji:
    2023
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    lead-zinc ore
    cinder
    enrichment tailings
    thermodynamic modeling
    electric melting
    ferrosilicon
    lead-zinc sublimates
    Opis:
    The article presents the results of thermodynamic and experimental research on the processing of cinders from the firing of Shalkiya deposit lead-zinc ore tailings with the production of siliceous ferroalloys. Thermodynamic modeling carried out using the HSC-6.0 complex based on the Gibbs energy minimization principle showed that the interaction occur with the formation of CaSiO3, FeSiO3, MgSiO3, K2OˑSiO2, FeSi, Fe5Si3, SiC, Fe3Si, Si, SiOg, FeSi2.33, FeSi2, CaSi, Zn, Zng, Pb, Pbg; an increase in the iron amount in the system allows increasing the silicon extraction degree into the alloy at 1800°C to 76%, to reduce the silicon concentration in the alloy from 41 to 24%; FS25 grade ferrosilicon formed at 1752-1867°C in the presence of 88-100% iron, and FS45 grade ferrosilicon – at 1863-1900°C and 20-22.4% iron. Electric melting of a charge containing 63.83% calcined cinder of tailings, 19.15% coke, and 17.02% steel chips allows to obtain FS45 grade ferrosilicon (44.1-43.9% Si) with the extraction of 69.7% silicon and sublimates with the content of 32-38% zinc and lead. The results obtained allow complex processing of lead-zinc sulfide ore tailings with the extraction of not only non-ferrous metals, but also silicon in the ferroalloy.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2023, 59, 1; art. no. 161853
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-5 z 5

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