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    Wyświetlanie 1-6 z 6
    Tytuł:
    Activating flotation of chalcopyrite using CuSO4 and H2O2 from the cyanide tailings
    Autorzy:
    Ai, G.
    Yan, H.
    Qiu, T.
    Liu, C.
    Powiązania:
    https://bibliotekanauki.pl/articles/109562.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cyanide tailings
    chalcopyrite
    CuSO4
    H2O2
    activation mechanism
    Opis:
    The effects of CuSO4 and H2O2 on the flotation behavior of cyanide chalcopyrite were investigated by flotation tests, microcalorimetry and X-ray photoelectron spectroscopy (XPS). The underlying activation mechanism was studied in the perspective of micro-thermodynamics and surface properties. The flotation results indicated that cyanide chalcopyrite was strongly inhibited by sodium cyanide, with the maximum flotation recovery of 22.5% only. CuSO4 and H2O2 significantly improved the flotation of cyanide chalcopyrite, and the flotation recovery was increased to 92.28% and 84.35%, respectively. The micro-thermodynamics results indicated that the adsorption heat of butyl xanthate on cyanide chalcopyrite surface increased after the addition of CuSO4 and H2O2, as well as the reaction order. CuSO4 and H2O2 can significantly improve the adsorption of butyl xanthate on the surface of cyanide chalcopyrite by decreasing the apparent activation energy by 80.11% and 66.54%, respectively. XPS analysis indicated that the CuCN was generated on the surface of cyanide chalcopyrite, leading to the loss of sulfur and inhibiting the adsorption of collectors. As a result, the flotation of cyanide chalcopyrite was depressed. It is considered that, CuSO4 and H2O2 can improve the flotation of cyanide chalcopyrite by eleminating CuCN from its surface and increasing the concentration of S by 57.02% and 37.48%, respectively.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 2; 578-589
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Flotation kinetics and thermodynamic behavior of chalcopyrite and pyrite in high alkaline systems
    Autorzy:
    Yan, H.
    Yuan, Q.
    Zhou, L.
    Qiu, T.
    Ai, G.
    Powiązania:
    https://bibliotekanauki.pl/articles/110078.pdf
    Data publikacji:
    2018
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    flotation kinetics
    pyrite
    chalcopyrite
    flotation separation
    high alkaline
    microcalorimetry
    Opis:
    The monomineral flotation test and microcalorimetry were used to study the flotation kinetics and thermodynamic behavior of chalcopyrite and pyrite in high alkaline systems of lime and NaOH. The results showed that in these systems there were less hydrophilic substances on the chalcopyrite surface, so that the apparent activation energy of sodium butyl xanthate (SBX) adsorption on chalcopyrite surface was low. This promoted the adsorption of SBX and increased the flotation rate and recovery of chalcopyrite. In contrast, the hydrophilic Fe(OH)3 and SO42- formed by oxidation on the pyrite surface increased the adsorption activation energy of SBX. Thus, the flotation rate and recovery of pyrite were lower. Moreover, in the lime high alkaline system, the hydrophilic calcium film generated on the pyrite surface further hindered the adsorption of SBX, thereby further inhibiting pyrite in this environment. In other words, the lime high alkaline environment increased the apparent activation energy difference of SBX adsorption between chalcopyrite and pyrite compared to the NaOH system, facilitating the flotation separation of chalcopyrite and pyrite. The results can help with the theoretical research of flotation separation of other minerals, and provide guidance for developing low alkaline and lime-free pyrite depressants.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2018, 54, 3; 901-910
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Colloidal crystal cladded microfiber for refractive index sensing
    Autorzy:
    Yan, H. T.
    Zhao, X Y
    Zhang, Ch.
    Zhen, Z Q
    Li, Q Z
    Cao, J X
    Xia, L X
    Powiązania:
    https://bibliotekanauki.pl/articles/174902.pdf
    Data publikacji:
    2014
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    microfibers
    colloidal crystals
    refractive index sensing
    Opis:
    We investigate the evanescent field of a microfiber wrapped by colloidal crystals. The microfiber has the diameter of about 1 μm that is drawn from a single-mode fiber with an alcohol lamp. The colloidal spheres are further attached to the microfiber through thermal evaporation, then they self-assemble to crystal-like structures. The 400 nm, 590 nm, and 710 nm-diameter SiO2 colloidal spheres are used, respectively. The spectral responses are studied theoretically and experimentally, and the results agree with each other. It is revealed that the evanescent field of a microfiber could be modulated by the photonic band-gap of colloidal crystals. This characteristic is very useful in refractive index sensing for liquids.
    Źródło:
    Optica Applicata; 2014, 44, 2; 309-315
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    Mitigation scratch on fused silica optics using CO2 laser
    Autorzy:
    Liu, C.-M.
    Yan, Z.-H.
    Yang, L.
    Jiang, Y.
    Zu, X.-T.
    Wang, H.-J.
    Liao, W.
    Yuan, X.-D.
    Zheng, W.-G.
    Powiązania:
    https://bibliotekanauki.pl/articles/174978.pdf
    Data publikacji:
    2016
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    mitigation
    scratch
    fused silica
    CO2 laser
    Opis:
    The scratch on a fused silica surface was treated as a chain of connected damage sites and mitigated one after another using CO2 laser irradiation. The optical microscopy image shows that a scratch with the width of about 30 μm and length of several millimeters can be completely mitigated without the formation of debris and bubbles. The mitigated scratch can survive under raster scan laser irradiation with the fluency increased up to 11.0J/cm2 at 3ns and 351nm. On the contrary, the substrate without CO2 laser mitigation is seriously damaged under this irradiation. The light modulation induced by mitigation is much smaller when the scratch is mitigated before being damaged. The light modulation is about 2 when the distance to the mitigated sample is larger than 20cm. The birefringence induced by residual stress in the mitigated scratch is measured. The retardance of the mitigated scratch before being damaged is not visible. Therefore, residual stress in this mitigated scratch before being damaged should be not a critical potential risk in laser damage.
    Źródło:
    Optica Applicata; 2016, 46, 3; 387-397
    0078-5466
    1899-7015
    Pojawia się w:
    Optica Applicata
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A cyclonic-static micro bubble flotation column for enhancing coalescence of oil droplets from emulsion
    Autorzy:
    Li, X.
    Yan, X.
    Zhang, H.
    Powiązania:
    https://bibliotekanauki.pl/articles/109842.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    cyclonic-static micro-bubble flotation column
    coalescence
    multi-flow pattern
    oily wastewater
    Opis:
    In this work a novel cyclonic-static micro bubble flotation column, using hydraulic separator with a conventional flotation column, was developed to separate oil droplets from emulsions. The system integrated the cyclonic and laminar flow coalescence with the pipe flow coalescence. The effect of process parameters such as circulation pressure, aeration rate, feed volumetric flow rate and viscosity of fluid on the efficiency of multi-flow pattern coalescence was investigated. The obtained results indicated that the coalescence efficiency increased with the circulation pressure, feed volumetric flow rate and aeration rate, whereas an increase in viscosity of fluid reduced the extent of coalescence. Besides, the size distribution of oil droplets in the cyclonic separator, pipe flow section and column flotation section were simulated in the flotation column using a special software. The simulation was compared with experimental data on the mean size of oil droplets.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 1; 307-320
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
    Tytuł:
    A study of bubble-particle interactions in a column flotation process
    Autorzy:
    Cheng, G.
    Shi, C.
    Yan, X.
    Zhang, Z.
    Xu, H.
    Lu, Y.
    Powiązania:
    https://bibliotekanauki.pl/articles/109635.pdf
    Data publikacji:
    2017
    Wydawca:
    Politechnika Wrocławska. Oficyna Wydawnicza Politechniki Wrocławskiej
    Tematy:
    particle
    bubble
    column flotation
    collision
    attachment
    detachment
    Opis:
    Bubble-particle interactions play an important role in flotation. This study examines the behaviour of bubble clusters in a turbulent flotation cell. Particularly, the bubble-particle interaction characteristics in flotation are investigated. The bubble size in a flotation column was measured using an Olympus i-SPEED 3 high-speed camera. Relationships between the circulating volume, bubble size and bubble terminal velocity were discussed. Probabilities of collision, attachment, detachment and acquisition between bubbles and particles in different circulating volumes were calculated based on the flotation kinetic theory. Using the extended Derjaguin–Landau–Verwey–Overbeek (EDLVO) theory, the relationship between the potential energy and distance in bubble-particle interaction was analysed. The results demonstrated that as the circulating volume increased, the bubble size and velocity decreased. When the circulating volume increased from 0.253 to 0.495 m3/h, the bubble diameter decreased from 511 to 462 μm, and the corresponding bubble velocity decreased from 43.1 to 37.5 mm/s. When the circulating volume remained constant as the particle size increased, probabilities of collision, attachment, detachment and acquisition increased. When the particle size remained constant as the circulating volume increased, these probabilities also increased. At a constant circulating volume as the particle size increased, the absolute value of the total potential energy between the particle and bubble increased. When the distance between the bubble and particle was 30 nm, the energy barrier appeared.
    Źródło:
    Physicochemical Problems of Mineral Processing; 2017, 53, 1; 17-33
    1643-1049
    2084-4735
    Pojawia się w:
    Physicochemical Problems of Mineral Processing
    Dostawca treści:
    Biblioteka Nauki
    Artykuł
      Wyświetlanie 1-6 z 6

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