Temat: solvent-free synthesis - Katalog OPAC zbiorów

Skocz do pozycji: 1.

Tytuł:: Solid acidic Bentonite/FeCl3 catalysed solvent-free cyclization of some aryl enones: Synthesis and assessment of antimicrobial potentials of some aryl pyrazolines
Autorzy:: Thirunarayanan, G.
Dineshkumar, N.
Rajarajan, M.
Powiązania:: https://bibliotekanauki.pl/articles/1076026.pdf
Data publikacji:: 2019
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: 1
3
5-Substituted pyrazolines
Antimicrobial activities
Bentonite/FeCl3
IR and NMR Spectra
Solvent-free synthesis
Opis:: Some aryl pyrazolines including 3-(substituted phenyl)-5-(naphthalen-1-yl)-1-phenyl-4,5-dihydro-1H-pyrazoles were prepared by microwave irradiation promoted cyclization of aryl enones and phenylhydrazine in the presence of solid acidic bentonite/FeCl3 catalyst under solvent-free conditions. In this cyclization the obtained yields are more than 75%. The structural analysis of these pyrazoline derivatives were confirmed through analytical and spectral techniques. The effect of catalyst and solvent on this cyclization also investigated through the obtained yields. The antimicrobial activities of these pyrazoline derivatives were assessed through measurement of mm of zone of inhibition against their micro stains using well known Bauer-Kirby disc diffusion method.
Źródło:: World Scientific News; 2019, 117; 14-28
2392-2192
Pojawia się w:: World Scientific News
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 2.

Tytuł:: QSAR study of infrared and nuclear magnetic resonance spectra of 1-(3-chloro-4-nitrophenyl)-2-(substituted benzylidene) hydrazines
Autorzy:: Ananthi, V.
Rajalakshmi, K.
Thiruarayanan, G.
Powiązania:: https://bibliotekanauki.pl/articles/1178520.pdf
Data publikacji:: 2017
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: 1-(3-chloro-4-nitrophenyl)-2-(substituted benzylidene) hydrazines
FeCl3/Bentonite
Hammett equation
IR and NMR spectra
QSAR study
Solvent-free synthesis
Opis:: Ten 1-(3-chloro-4-nitrophenyl)-2-(substituted benzylidene) hydrazines have been synthesized by FeCl3/Bentonite catalyzed solvent-free condensation of substituted phenyl hydrazine and aldehydes under microwave irradiation. The synthesized hydrazides are characterized by the physical constants, micro analysis and spectroscopic data. The assigned characteristic spectroscopic data of these 1-(3-chloro-4-nitrophenyl)-2-(substituted benzylidene) hydrazines were correlated with Hammett substituent constants, F and R parameters using Hammett equation through single and multi-regression analysis. With the results of statistical analysis results, the quantitative structure activity relationships were studied and finding the effect of substituents on the spectral data.
Źródło:: World Scientific News; 2017, 70, 2; 122-139
2392-2192
Pojawia się w:: World Scientific News
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 3.

Tytuł:: Synthesis and effects of substituent on (E)-styryl-3-methyl-2-thienyl chalcones
Autorzy:: Christuraj, P.
Geetha, C.
Vanangamudi, G.
Arulkumaran, R.
Manikandan, V.
Rajakumar, P. R.
Thirunarayanan, G.
Powiązania:: https://bibliotekanauki.pl/articles/1161056.pdf
Data publikacji:: 2018
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones
FT-IR & NMR spectra
Fly-ash:H3PO4 nanocatalyst
Hammett correlation analysis
Substituent effects
UV
solvent-free synthesis
Opis:: Series of eleven substituted of (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-ones compounds by cross-aldol condensation reaction of 3-methylthiophene-2-carbaldehyde with various substituted acetaldehyde in the occurrence of Fly-Ash: H3PO4 catalyst. The effect of catalytic activity of this fly-ash:H3PO4 nanocatalyst was studied with the obtained yield of products under solvent-free conditions. The synthesized substituted (E)-3-(3-methylthiophen-2-yl)-1-phenylprop-2-en-1-one compounds was characterized by physical constants, UV, FT-IR, 1H & 13C-NMR spectral data. The infrared group frequencies of ʋ(cm-1) of COs-cis & s-trans, CHip and CHop, CH=CHop, >C=C
Źródło:: World Scientific News; 2018, 112; 55-73
2392-2192
Pojawia się w:: World Scientific News
Dostawca treści:: Biblioteka Nauki

Artykuł

Skocz do pozycji: 4.

Tytuł:: Solvent-free synthesis, antimicrobial and insect antifeedant potentials of some 4(4-chloro-1-naphthyl)-5,6-dihydro-6-(substituted phenyl)-4H-1,3-oxazine-2-amines
Autorzy:: Thirunarayanan, G.
Powiązania:: https://bibliotekanauki.pl/articles/1075725.pdf
Data publikacji:: 2019
Wydawca:: Przedsiębiorstwo Wydawnictw Naukowych Darwin / Scientific Publishing House DARWIN
Tematy:: 3-oxazine-2-amines
4-(4-chloro-1-naphthyl)-5
6-dihydro-6-(substituted phenyl)-4H-1
SiO2-H3PO4
antimicrobial potentials
insect antifeedant activity
solvent-free synthesis
Opis:: More than 85% yields of thirteen 4-(4-chloro-1-naphthyl)-5,6-dihydro-6-(substituted phenyl)-4H-1,3-oxazine-2-amines weer synthesised by SiO2-H3PO4 catalyzed solvent-free cyclization of substituted styryl4-chloro-1-naphthyl ketones and urea under microwave irradiation. The synthesized oxazine amines have been characterized by analytical and spectroscopic techniques. The antimicrobial activities of these 4-(4-chloro-1-naphthyl)-5,6-dihydro-6-(substituted phenyl)-4H-1,3-oxazine-2-amines have been appraised by means of Bauer-Kirby technique. The insect antifeedant activities of these oxazine-2-amines were assessed by Dethler’s technique using 4th instar larvae Achoea janata L.
Źródło:: World Scientific News; 2019, 118; 1-16
2392-2192
Pojawia się w:: World Scientific News
Dostawca treści:: Biblioteka Nauki

Artykuł

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