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Wyszukujesz frazę "catalysts" wg kryterium: Temat


Tytuł:
Examination of steam gasification of coal with physically mixed catalysts
Autorzy:
Śpiewak, Katarzyna
Czerski, Grzegorz
Sopata, Agnieszka
Powiązania:
https://bibliotekanauki.pl/articles/779131.pdf
Data publikacji:
2019
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
coal gasification
kinetics
catalysts
Opis:
The aim of this study was to analyse the steam gasification process of ‘Janina’ coal with and without Na-, K- and Ca-catalysts. The catalysts were physically mixed with the coal due to the simplicity of this method, short time of execution and certainty that the amount of catalyst is exactly as the adopted one. The isothermal measurements were performed at 800, 900 and 950°C and a pressure of 1 MPa using thermovolumetric method. The obtained results enabled assessment of the effect of analysed catalysts on the process at various temperatures by determination of: i) carbon conversion degree; ii) yield and composition of the resulting gas; and iii) kinetics of formation reactions of main gas components – CO and H2. The addition of catalysts, as well as an increase in operating temperature, had a positive effect on the coal gasification process – reactions rates increased, and the process time was reduced.
Źródło:
Polish Journal of Chemical Technology; 2019, 21, 4; 51-57
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Impact of heating rate and solvent on Ni-based catalysts prepared by solution combustion method for syngas methanation
Autorzy:
Zeng, Yan
Ma, Hongfang
Zhang, Haitao
Ying, Weiyong
Fang, Dingye
Powiązania:
https://bibliotekanauki.pl/articles/779390.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
nickel catalysts
syngas methanation
solution combustion method
Opis:
Ni-Al2O3 catalysts prepared by solution combustion method for syngas methanation were enhanced by employing various heating rate and different solvent. The catalytic properties were tested in syngas methanation. The result indicates that both of heating rate and solvent remarkably affect Ni particle size, which is a key factor to the catalytic activity of Ni-Al2O3 catalysts for syngas methanation. Moreover, the relationship between Ni particle size and the production rate of methane per unit mass was correlated. The optimal Ni-Al2O3 catalyst prepared in ethanol at 2°C/min, achieves a maximum production rate of methane at the mean size of 20.8 nm.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 4; 95-100
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Synthesis and characteristics of titanium silicalite TS-1, Ti-Beta and Ti-MWW catalysts
Autorzy:
Wróblewska, A.
Fajdek, A.
Milchert, E.
Powiązania:
https://bibliotekanauki.pl/articles/779396.pdf
Data publikacji:
2009
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
TS-1
Ti-Beta
Ti-MWW
titanium-silicalite catalysts
Opis:
The synthesis methods of the following titanium-silicalite catalysts: TS-1, Ti-Beta and Ti-MWW were presented. The results of the analyses of the catalysts by XRD, SEM and IR, UV-vis methods were also shown. A brief description of the catalytic performances of these catalysts in the oxidation process of olefins, alkenes, alcohols and aromatic compounds was presented.
Źródło:
Polish Journal of Chemical Technology; 2009, 11, 1; 64-71
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Removal of vanadium, potassium and iron from spent vanadium catalyst by leaching with citric acid at atmospheric pressure
Autorzy:
Mazurek, K.
Powiązania:
https://bibliotekanauki.pl/articles/778659.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
citric acid
sulphur oxide
spent vanadium catalysts
leaching
recovery
Opis:
The effect of time, temperature, the catalyst particle size and the ratio of the catalyst weight to the leaching solution volume (S:L) on the treatment of spent vanadium catalyst components was determined using citric acid solutions at atmospheric pressure. The optimal parameters of catalyst leaching in 10% acid solutions at atmospheric pressure are: T = 323 K, t = 4 h, the particle size of less than 0.160 mm, the S:L ratio below 0.1. Under these conditions it was possible to dissolve about 90% of vanadium and potassium compounds and more than 60% of iron compounds contained in the catalyst. These results fall within the scope of research on a comprehensive method for recovering spent vanadium catalyst components.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 1; 59-62
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Influence of the exchanged metal ions (Cu, Co, Ni and Mn) on the selective catalytic reduction of NO with hydrocarbons over modified ferrierite
Autorzy:
Ćwikła-Bundyra, W.
Powiązania:
https://bibliotekanauki.pl/articles/778840.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
catalytic reduction
nitrogen oxides
ferrierite
selective catalysts
ion exchanged
Opis:
This article presents the research results concerning the possibilities of natural zeolite-ferrierite application for the reduction of nitrogen oxide. H-FER forms were modified by Cu+2, Co+2, Mn+2, Ni+2 using an ion exchange procedure. The effect of metal contents was shown for the ferrierite matrices and related to their catalytic properties. The catalytic properties of Cu-, Co-Ni-, and Mn- were compared for NO reduction with methane. High NO conversion was observed for copper and cobalt-ferrierite catalysts, especially in the temperature range 400 and 500oC. It was found that copper- and cobalt-ferrierite catalysts have higher activity and N2 selectivity than the catalysts composed of nickel and manganese doped on ferrierite. Moreover, the nickel and manganese containing catalysts produced more nitrous oxide than nitrogen. The presence of both copper and cobalt species seems to be an indispensable condition for a large activity and selectivity in the NO reduction.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 2; 10-15
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Preparation and characterization of multi-walled carbon nanotubes grown on transition metal catalysts
Autorzy:
Pełech, I.
Narkiewicz, U.
Kaczmarek, A.
Jędrzejewska, A.
Powiązania:
https://bibliotekanauki.pl/articles/779825.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
catalysts
carbon nanotubes
chemical vapor deposition
X-ray diffraction
thermogravimetry
Opis:
Transition metal catalysts (mainly: iron, cobalt and nickel) on various supports are successfully used in a largescale production of carbon nanotubes (CNTs), but after the synthesis it is necessary to perform very aggressive purification treatments that cause damages of CNTs and are not always effective. In this work a preparation of unsupported catalysts and their application to the multi-walled carbon nanotubes synthesis is presented. Iron, cobalt and bimetallic iron-cobalt catalysts were obtained by co-precipitation of iron and cobalt ions followed by solid state reactions. Although metal particles were not supported on the hard-to-reduce oxides, these catalysts showed nanometric dimensions. The catalysts were used for the growth of multi-walled carbon nanotubes by the chemical vapor deposition method. The syntheses were conducted under ethylene - argon atmosphere at 700°C. The obtained catalysts and carbon materials after the synthesis were characterized using transmission electron microscopy (TEM), X-ray diffraction method (XRD), Raman spectroscopy and thermogravimetric analysis (TG). The effect of the kind of catalyst on the properties of the obtained carbon material has been described.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 1; 117-122
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Fe-modified activated carbon obtained from biomass as a catalyst for α-pinene autoxidation
Autorzy:
Kamińska, Adrianna
Maciejewska, Nikola
Miądlicki, Piotr
Kiełbasa, Karolina
Sreńscek-Nazzal, Joanna
Michalkiewicz, Beata
Powiązania:
https://bibliotekanauki.pl/articles/1849280.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
activated carbon
carbonaceous catalysts
autoxidation
alpha-pinene
iron particles
biomass
Opis:
The presented work describes the autoxidation of alpha-pinene for the first time using a catalyst based on activated carbon from biomass with introduced Fe. The raw material for the preparation of the carbon material was waste orange peel, which was activated with a KOH solution. The following instrumental methods characterized the obtained catalyst (Fe/O_AC):N2 adsorption at 77 K, XRD, UV, SEM, TEM, X-ray microanalysis, and catalytic studies. It was shown that the Fe/O_AC catalyst was very active in the autoxidation of alpha-pinene. The main reaction products were: alpha-pinene oxide, verbenone, verbenol, and campholenic aldehyde.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 73-80
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Commercial Kevlar derived activated carbons for CO2 and C2H4 sorption
Autorzy:
Kaliszewski, M.
Zgrzebnicki, M.
Kałamaga, A.
Pinjara, S.
Wróbel, R. J.
Powiązania:
https://bibliotekanauki.pl/articles/1849281.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
activated carbon
carbonaceous catalysts
autoxidation
alpha-pinene
iron particles
biomass
Opis:
The carbonaceous precursor was obtained via pyrolysis of commercial aramid polymer (Kevlar). Additionally the precursor was activated at 1000°C in CO2 atmosphere for different times. Obtained materials were characterised by BET; XPS; SEM and optical microscopy. The sorption capacities were determined by temperature swing adsorption performed in TGA apparatus for CO2 and C2H4 gases. The obtained materials exhibit high difference in sorption of these gases i.e. 1.5 and 2.8 mmol/g @30°C respectively and high SSA ~1600 m2/g what can be applied in separation applications. The highest uptakes were 1.8 and 3.1 mmol/g @30°C respectively. It was found that the presence of oxygen and nitrogen functional groups enhances C2H4/CO2 uptake ratio.
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 81-87
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The effect of preparation method on the performance of PtSn/Al2O3 &enspcatalysts for acetic acid hydrogenation
Autorzy:
Zhang, K.
Zhang, H.
Ma, H.
Ying, W.
Fang, D.
Powiązania:
https://bibliotekanauki.pl/articles/779525.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
Pt-Sn catalysts
preparation method
acetic acid hydrogenation
XPS
CO-FTIR
Opis:
PtSn/Al2O3 &enspcatalysts with a given loading of 1 wt% Pt and 1 wt% Sn were prepared by co-impregnation or successive impregnation with aqueous solutions of Pt, Sn precursors and a commercial alumina. The catalysts were characterized by N2 &enspadsorption, H2-TPR (H2&ensp temperature-programmed reduction), H2-pulse chemisorption, XPS (X-ray photoelectron spectroscopy) and CO-FTIR (Fourier transform infrared spectroscopy), and tested in the hydrogenation of acetic acid. The results showed that the preparation method affected both the chemical properties and their performance in the hydrogenation of acetic acid. Sn enrichment on the catalysts surface was observed on the co-impregnated catalyst and catalyst in which the Pt precursor had been loaded first. It was found that the modification of Pt was a function of the sequence of Sn addition as revealed by CO-FTIR. Co-impregnated catalyst showed the highest activity and ethanol selectivity.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 11-17
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Magnetic recykling of complex catalysts immobilized on thiol-functionalized polymer supports
Autorzy:
Bączek, N
Strzelec, K.
Wąsikowska, K.
Powiązania:
https://bibliotekanauki.pl/articles/779554.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
encapsulation
magnetic recycling
epoxy resin
supported catalysts
Heck reaction
hydrogenation reaction
Opis:
In this work, the application of the thiol-functionalized epoxy resin encapsulated on magnetic core as supports for palladium catalysts is reported. The study focuses on obtaining of heterogeneous catalysts which can be separated by magnetic field. Palladium complex catalyst [PdCl2(PhCN)2] has been heterogenized by anchoring to these supports via ligand exchange reaction. The characterization of polymeric supports and heterogenized palladium catalysts has involved research methods like time-of-flight secondary ion mass spectrometry (TOF-SIMS), scanning electron microscopy (SEM) and nitrogen BET surface area measurements. The activity and stability during long-term use of the investigated catalytic systems were tested in a Heck and hydrogenation reaction. The influence of the type of thiols used as epoxy hardeners and the morphology of the supports on the catalytic properties of epoxy-supported palladium catalysts was discussed.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 3; 65-68
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The dependance of an activity of vanadium catalysts on a carrier regeneration method and an active phase composition
Autorzy:
Grzesiak, P.
Grobela, M.
Hłyń, T.
Łukaszyk, J.
Powiązania:
https://bibliotekanauki.pl/articles/780011.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
carrier properties
composition of active phase
SO2 oxidation
vanadium catalysts
Opis:
The results of the research studies concerning the reaction rate of SO2 oxidation on the vanadium catalysts have been described. A carrier of the active phase - silica has been regenerated from spent vanadium mass by leaching with H2SO4 solution. The dependence of the oxidation reaction rate on the method of treating a catalyst carrier as well as the composition of an active phase of the new catalyst systems has been also presented.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 4; 107-110
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Esterification of fatty acids with C8-C9 alcohols over selected sulfonic heterogeneous catalysts
Autorzy:
Nowicki, J.
Mosio-Mosiewski, J.
Powiązania:
https://bibliotekanauki.pl/articles/779516.pdf
Data publikacji:
2013
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
esterification of fatty acids
C8-C9 alcohols
sulfonic acid catalysts
Opis:
A study on the synthesis of esters of fatty acids of natural origin (oleic acid from rapeseed oil) and branched synthetic isostearic acid with commercially available alcohols C8-C9 i.e. 2-ethylhexanol (2-EH) and 3,5,5-trimethylhexanol (TMH) in the presence of selected heterogeneous catalysts containing active sulfonic groups has been made. The catalysts were obtained using ready available amorphous silicas with different textural characteristics. The influence of catalyst porosity on the catalytic properties in the esterification of fatty acids has been investigated. The effect of the synthesis temperature has also been studied. The results were compared with the results of esterification with the use of acidic ion exchange resins. It was shown that catalysts obtained on the basis of amorphous silicas are good and reusable catalysts for the esterification of fatty acids with higher alcohols.
Źródło:
Polish Journal of Chemical Technology; 2013, 15, 3; 42-47
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalysts for the utilization of methane from the coal mine ventilation air
Autorzy:
Stasińska, B.
Machocki, A.
Powiązania:
https://bibliotekanauki.pl/articles/777952.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
powietrze wentylacyjne
kopalnia węgla
metan
utylizacja metanu
katalityczne utlenianie metanu
katalizator tlenkowy
katalizator palladowy
coal mine ventilation air
utilization of methane
catalytic oxidation of methane
oxide catalysts
palladium catalysts
Opis:
The paper indicates coal mines as the source of permanent emission of low-concentrated gases, which have increased the greenhouse effect. This paper proposes the catalytic oxidation of methane as the solution to the problem of methane utilization when its concentration in the air is insufficient for flame combustion. The studies which have been conducted for many years enabled finding the active oxide and metallic catalytic systems for the reaction of methane oxidation. For the utilization of gases with low-concentrated methane, using the low-temperature catalysts, especially palladium catalysts, seems to he economically well-justified. Depending on technological solutions it can be considered as the method for methane utilization or as an environmentally friendly way for the generation of electric and thermal energy.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 3; 29-32
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Application of recycled natural aluminasilicate doped with vanadium for the decontamination of the air
Autorzy:
Marcewicz-Kuba, A.
Olszewska, D.
Powiązania:
https://bibliotekanauki.pl/articles/779849.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
katalizatory DESONOX
usuwanie SO2
montmorylonit
wanad
DESONOX catalysts
SO2 removal
montmorillonite
vanadium
Opis:
This paper reports studies on the influence of vanadium concentration on the catalytic activity of DESONOX catalysts (in DESOX reaction) based on modified montmorillonite from Jelsovy Potok. The investigation of the influence on the physicochemical properties of the catalysts on their behaviour has also been studied.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 2; 65-67
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Structural and textural characterisation of NiMo catalysts supported on various zeolites
Autorzy:
Sarbak, Z.
Fabiś, G.
Binkowski, S.
Powiązania:
https://bibliotekanauki.pl/articles/778497.pdf
Data publikacji:
2007
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
zeolity
katalizatory NiMo
właściwości strukturalne
porowatość
zeolites
NiMo catalysts
structural properties
surface area
porosity
Opis:
Structural and textural properties of nickel-molybdenum catalysts supported on four various type of zeolites of different chemical composition and porous structure have been studied by the methods of IR, XRD and the low-temperature sorption of nitrogen. The catalysts have been obtained by the two-stage impregnation of the supports with the solutions of nickel and molybdenum salts by the method of incipient wetness. The catalysts have been shown to preserve the structure characteristic of the appropriate zeolite supports.
Źródło:
Polish Journal of Chemical Technology; 2007, 9, 1; 27-32
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł

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