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Wyświetlanie 1-15 z 36
Tytuł:
Autothermal Reforming of Diesel Oil for PdCeCrFeCu/Al2O3-Catalyzed Hydrogen Production
Autorzy:
Lin, Lin
Zhang, Kai
Sun, Chiyu
Zhang, Ying
Powiązania:
https://bibliotekanauki.pl/articles/1849270.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
diesel
reform
hydrogen
catalyst
Opis:
To make clear the feasibility and influence factors of diesel fuel autothermal reforming to hydrogen, PdCeCr-FeCu/Al2O3 catalyst was prepared by equivalent-volume impregnation method. Experimental facility based on an adiabatic tubular reactor with preheating section was designed and set up, the behaviors of diesel reforming to hydrogen with straight-run diesel as a raw material according to the analysis of the components were studied. Diesel oil reforming over a catalyst for hydrogen production was analyzed using an adiabatic tubular reactor with a preheating section that was designed and built in-house. The operating conditions were optimized. Under the suitable operating conditions, viz., catalyst bed inlet temperature of 700°C, diesel liquid space velocity of 0.24 h–1, water-carbon ratio of 20, and oxygen-carbon ratio of 0.6, the hydrogen yield reached 28.3 (mol/mol).
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 12-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Autothermal Reforming of Diesel Oil for PdCeCrFeCu/Al2O3-Catalyzed Hydrogen Production
Autorzy:
Lin, Lin
Zhang, Kai
Sun, Chiyu
Zhang, Ying
Powiązania:
https://bibliotekanauki.pl/articles/1849272.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
diesel
reform
hydrogen
catalyst
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 12-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Autothermal Reforming of Diesel Oil for PdCeCrFeCu/Al2O3-Catalyzed Hydrogen Production
Autorzy:
Lin, Lin
Zhang, Kai
Sun, Chiyu
Zhang, Ying
Powiązania:
https://bibliotekanauki.pl/articles/1849267.pdf
Data publikacji:
2021
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
diesel
reform
hydrogen
catalyst
Opis:
To make clear the feasibility and influence factors of diesel fuel autothermal reforming to hydrogen, PdCeCr-FeCu/Al2O3 catalyst was prepared by equivalent-volume impregnation method. Experimental facility based on an adiabatic tubular reactor with preheating section was designed and set up, the behaviors of diesel reforming to hydrogen with straight-run diesel as a raw material according to the analysis of the components were studied. Diesel oil reforming over a catalyst for hydrogen production was analyzed using an adiabatic tubular reactor with a preheating section that was designed and built in-house. The operating conditions were optimized. Under the suitable operating conditions, viz., catalyst bed inlet temperature of 700°C, diesel liquid space velocity of 0.24 h–1, water-carbon ratio of 20, and oxygen-carbon ratio of 0.6, the hydrogen yield reached 28.3 (mol/mol).
Źródło:
Polish Journal of Chemical Technology; 2021, 23, 2; 12-19
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characterization of FeCo based catalyst for ammonia decomposition. The effect of potassium oxide
Autorzy:
Lendzion-Bieluń, Zofia
Pelka, Rafał
Czekajło, Łukasz
Powiązania:
https://bibliotekanauki.pl/articles/778513.pdf
Data publikacji:
2014
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ammonia decomposition
hydrogen
FeCo catalyst
Opis:
FeCo fused catalyst was obtained by fusing iron and cobalt oxides with an addition of calcium, aluminium, and potassium oxides (CaO, Al2O3, K2O). An additional amount of potassium oxide was inserted by wet impregnation. Chemical composition of the prepared catalysts was determined with an aid of the XRF method. On the basis of XRD analysis it was found that cobalt was built into the structure of magnetite and solid solution of CoFe2O4 was formed. An increase in potassium content develops surface area of the reduced form of the catalyst, number of adsorption sites for hydrogen, and the ammonia decomposition rate. The nitriding process of the catalyst slows down the ammonia decomposition.
Źródło:
Polish Journal of Chemical Technology; 2014, 16, 4; 111-116
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrogen peroxide as a biodegradation stimulator in remediation processes of soils heavily contaminated with petrochemicals
Autorzy:
Rosik-Dulewska, C.
Krzyśko-Łupicka, T.
Ciesielczuk, T.
Kręcidło, Ł.
Powiązania:
https://bibliotekanauki.pl/articles/778974.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
soil
remediation
petrochemicals
hydrogen peroxide
Opis:
The soil contaminated with petroleum products must be excluded from the crops and treated to reclamation processes. Natural processes of decomposition of hydrocarbon compounds go very slow, so it is necessary to use bioaugumentation or stimulation in order to accelerate the return of the soil to high culture. In this study the effect of hydrogen peroxide on the process of cleaning soil strongly contaminated with pertochemicals was investigated. For this purpose, a pot experiment lasting 60 days was carried. The dynamics of changes in the population of filamentous fungi, yeasts and bacteria were examined and also content of aliphatic hydrocarbons (n-alkanes), monoaromatic and polycyclic aromatic hydrocarbons (PAHs). Experimental use of hydrogen peroxide in the process of biodegradation of petroleum compounds assisted in the analyzed soil led to an increase of the number of grampositive bacteria during the test. Stimulation of oil products biodegradation by hydrogen peroxide also increased by 35% decomposition efficiency of aliphatic hydrocarbons (C8-C40) and about 50% PAH’s in comparison to control samples without hydrogen peroxide. There was no influence of hydrogen peroxide on the content of monoaromatic hydrocarbons (BTEX) with respect to controls, although in the end of experiment, the total concentration decreased by about 50% compared to the initial content.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 2; 17-22
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
The oxidation of limonene at raised pressure and over the various titanium-silicate catalysts
Autorzy:
Wróblewska, A.
Makuch, E.
Miądlicki, P.
Powiązania:
https://bibliotekanauki.pl/articles/779024.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
limonene oxidation
hydrogen peroxide
TBHP
Opis:
This work presents the studies on the oxidation of limonene with hydrogen peroxide and tert-butyl hydroperoxide (TBHP) in the presence of : TS-2, Ti-Beta, Ti-MCM-41 and Ti-MWW catalysts, at the autogenic pressure and atmospheric pressure. The examination were performed at the following conditions: the temperature of 140°C (studies in the autoclave) and 80°C (studies in glass reactor), the molar ratio of limonene/oxidant (H2O2 or WNTB) = 1:1, the methanol concentration 80 wt%, the catalyst content 3 wt%, the reaction time 3 h and the intensity of stirring 500 rpm. The analysis of the results showed that in process not only 1,2-epoxylimonene was formed but also: 1,2-epoxylimonene diol, carveol, carvone and perillyl alcohol but for 1,2-epoxylimonene obtaining the better method was the method at the autogenic pressure and in the presence of TBHP.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 4; 82-87
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalytic activity of Pd-Ni in the oxidation of hydrogen for the safety of Catalytic activity of Pd-Ni in the oxidation of hydrogen for the safety of nuclear power plan
Autorzy:
Łomot, D.
Karpiński, Z.
Powiązania:
https://bibliotekanauki.pl/articles/779451.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
palladium
palladium-nickel
catalyst
hydrogen oxidation
Opis:
Pd-Ni/Al2O3 systems were investigated in the reaction of hydrogen oxidation in terms of their possible application as catalysts used in passive autocatalytic recombiners (PARs) used in nuclear power plants. Testing experiments were carried out in a flowing system at different temperatures and humidity of the reaction mixture. The bimetallic catalysts exhibited higher response to the increase of temperature and higher resistance to inhibit water than the monometallic palladium catalyst. They showed excellent stability during a few tens of hours, similarly, like their monometallic counterpart. Our bimetallic catalysts of hydrogen oxidation can be used as cheaper alternatives to catalysts based on the precious metals in the hydrogen oxidation without loss of their activity over time.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 1; 15-18
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Technological parameters of epoxidation of sesame oil with performic acid
Autorzy:
Musik, M.
Milchert, E.
Malarczyk-Matusiak, K.
Powiązania:
https://bibliotekanauki.pl/articles/778421.pdf
Data publikacji:
2018
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
sesame oil
epoxidation
performic acid
hydrogen peroxide
Opis:
The course of epoxidation of sesame oil (SO) with performic acid formed „in situ” by the reaction of 30 wt% hydrogen peroxide and formic acid in the presence of sulfuric acid(VI) as a catalyst was studied. The most advantageous of the technological independent parameters of epoxidation are as follows: temperature 80°C, H2O2  C=C 3.5:1, HCOOH/C=C 0.8:1, amount of catalyst as H2SO4 /(H2O2 +HCOOH) 1 wt%, stirring speed at least 700 rpm, reaction time 6 h. The iodine number (IN), epoxy number (EN), a relative conversion to oxirane (RCO) and oxirane oxygen content (EOe) were determined every hour during the reaction. Under optimal conditions the sesame oil conversion amounted to 90.7%, the selectivity of transformation to epoxidized sesame oil was equal to 93.2%, EN = 0.34 mol/100 g, IN = 0.04 mol/100 g oil (10.2 g/100 g oil), a relative conversion to oxirane RCO = 84.6%, and oxirane oxygen content of EOe = 5.5%.
Źródło:
Polish Journal of Chemical Technology; 2018, 20, 3; 53-59
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
PANI/NaTaO3 composite photocatalyst for enhanced hydrogen generation under UV light irradiation
Autorzy:
Zielińska, B.
Schmidt, B.
Mijowska, E.
Kaleńczuk, R.
Powiązania:
https://bibliotekanauki.pl/articles/778752.pdf
Data publikacji:
2017
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
polyaniline
NaTaO3
composite photocatalysts
hydrogen generation
Opis:
A PANI/NaTaO3  composite was successfully synthesized by an oxidative polymerization of aniline monomer in hydrochloric acid solution containing sodium tantalate. NaTaO3  at a monoclinic structure was produced via hydrothermal method. The photocatalytic activities of the unmodified NaTaO3  and PANI/NaTaO3  were evaluated for hydrogen generation from an aqueous HCOOH solution and under UV light irradiation. The results showed that the evolution rate of H2  increased significantly when NaTaO3  was modified with PANI. The enhancement of the photocatalytic activity of PANI/NaTaO3  composite was ascribed to the effective charge transfer and separation between NaTaO3  and PANI, which reduced their recombination. This indicates that PANI modification of tantalate photocatalysts may open up a new way to prepare highly efficient catalytic materials for H2  generation.
Źródło:
Polish Journal of Chemical Technology; 2017, 19, 3; 115-119
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Catalytic activity of cobalt and cerium catalysts supported on calcium hydroxyapatite in ethanol steam reforming
Autorzy:
Dobosz, J.
Hull, S.
Zawadzki, M.
Powiązania:
https://bibliotekanauki.pl/articles/779330.pdf
Data publikacji:
2016
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
hydroxyapatite
cobalt
cerium
ethanol steam reforming
hydrogen production
Opis:
In this paper, Co,Ce/Ca10(PO4)6(OH)2 catalysts with various cobalt loadings for steam reforming of ethanol (SRE) were prepared by microwave-assisted hydrothermal and sol-gel methods, and characterized by XRD, TEM, TPR-H2, N2 adsorption-desorption measurements and cyclohexanol (CHOL) decomposition tests. High ethanol conversion (close to 100%) was obtained for the catalysts prepared by both methods but these ones prepared under hydrothermal conditions (HAp-H) ensured higher hydrogen yield (3.49 mol H2/mol C2H5OH) as well as higher amount of hydrogen formed (up to 70%) under reaction conditions. The superior performance of 5Co,10Ce/HAp-H catalyst is thought to be due to a combination of factors, including increased reducibility and oxygen mobility, higher density of basic sites on its surface, and improved textural properties. The results also show a significant effect of cobalt loading on catalysts efficiency in hydrogen production: the higher H2 yield exhibit catalysts with lower cobalt content, regardless of the used synthesis method.
Źródło:
Polish Journal of Chemical Technology; 2016, 18, 3; 59-67
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Characteristics and applications of iron oxide reduction processes
Autorzy:
Halim, K.S. Abdel
El-Geassy, A .A.
Nasr, M. I.
Ramadan, Mohamed
Fathy, Naglaa
Al-Ghamdi, Abdulaziz S.
Powiązania:
https://bibliotekanauki.pl/articles/27315666.pdf
Data publikacji:
2023
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
ironmaking
iron oxides
reduction
extractive metallurgy
green hydrogen
Opis:
The present review handles the main characteristics of iron oxide reduction and its industrial applications. The reduction of iron oxide is the basis of all ironmaking processes, whether in a blast furnace or by direct reduction and/or direct smelting processes. The reduction characteristics of iron ores control the efficiency of any ironmaking process and the quality of the produced iron as well. Many controlling parameters should be considered when discussing the reducibility of iron ores such as equilibrium phase diagrams, reduction temperature, pressure, gas composition, and the nature of both iron ores and reducing agent. The different factors affecting the main routes of ironmaking will be highlighted in the present review to give a clear picture of each technology. Moreover, further innovations regarding the reduction of iron oxides such as the reduction by green hydrogen will be discussed.
Źródło:
Polish Journal of Chemical Technology; 2023, 25, 4; 81--92
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Study on synthesis and photoelectric properties of AgInS2 quantum dots
Autorzy:
Yuan, Binxia
Luo, Zige
Sun, Yongjun
Cao, Sheng
Cao, Lan
Li, Min
Powiązania:
https://bibliotekanauki.pl/articles/2106479.pdf
Data publikacji:
2022
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
AgInS
Quantum dots
Optical properties
Photocatalytic hydrogen production
Opis:
AgInS2 Quantum dots (AIS QDs) have high quantum yield and catalytic performance, which is promising materials in photo-catalytic and optoelectronic fields. In the paper, it adopted a simple and non-toxic method to synthesize AIS QDs. The effect of reaction temperature on the growth mechanism, optical and physical properties of AIS had been extensively investigated by using L-cysteine as the sulfur source, and their application in catalytic hydrogen production was also studied. The results demonstrated that the fluorescence properties will be quenched with the increase of temperature, indicating that the separation speed of electron hole pairs of samples obtained at higher temperature was faster. Meantime, the electron transport capacity and the photocurrent had also improved with the increase of reaction temperature. Finally, the sample obtained at 100 oC had higher hydrogen production rate.
Źródło:
Polish Journal of Chemical Technology; 2022, 24, 2; 21--26
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Construction of a reduced mechanism for diesel-natural gas -hydrogen using HCCI model with Direct Relation Graph and Sensitivity Analysis
Autorzy:
Rui, Zhao
Leping, Xu
Shiquan, Feng
Powiązania:
https://bibliotekanauki.pl/articles/779831.pdf
Data publikacji:
2020
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
diesel
natural gas
hydrogen
reduced mechanism
DRG
SA
Opis:
Based on the theory of direct relation graph (DRG) and sensitivity analysis (SA), a reduced mechanism for diesel CH4-H2 tri-fuel is constructed. The detailed mechanism of Lawrence Livermore National Laboratory, which has 654 elements and 2827 elementary reactions, is used for mechanism reduction with DRG. Some small thresholds are used in the process of simplifying the detailed mechanism via DRG, and a skeletal mechanism of 266 elements is obtained. Based on the framework of the skeletal mechanism, the time-consuming approach of sensitivity analysis is used for further simplification, and the skeletal mechanism is reduced to 262 elements. Validation of the reduced mechanism is done via a comparison of ignition delay time and laminar flame speed from the calculation using the reduced mechanism and the detailed mechanism or experiment. The reduced mechanism shows good agreement with the detailed mechanism and with related experimental data.
Źródło:
Polish Journal of Chemical Technology; 2020, 22, 4; 55-60
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Hydrogen evolution reaction at Ru-modified nickel-coated carbon fibre in 0.1 M NaOH
Autorzy:
Pierożyński, B.
Mikołajczyk, T.
Powiązania:
https://bibliotekanauki.pl/articles/778010.pdf
Data publikacji:
2015
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
NiCCF
Ru-modification
hydrogen evolution reaction
HER
impedance spectroscopy
Opis:
The electrochemical activity towards hydrogen evolution reaction (HER) was studied on commercially available (Toho-Tenax) and Ru-modified nickel-coated carbon fibre (NiCCF) materials. Quality and extent of Ru electrodeposition on NiCCF tows were examined by means of scanning electron microscopy (SEM). Kinetics of the hydrogen evolution reaction were investigated at room temperature, as well as over the temperature range: 20-50°C in 0.1 M NaOH solution for the cathodic overpotential range: -100 to -300 mV vs. RHE. Corresponding values of charge-transfer resistance, exchange current-density for the HER and other electrochemical parameters for the examined fibre tow composites were recorded.
Źródło:
Polish Journal of Chemical Technology; 2015, 17, 1; 18-22
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Tytuł:
Immobilization of permeabilized cells of baker’s yeast for decomposition of H2O2 by catalase
Autorzy:
Trawczyńska, Ilona
Powiązania:
https://bibliotekanauki.pl/articles/778357.pdf
Data publikacji:
2019
Wydawca:
Zachodniopomorski Uniwersytet Technologiczny w Szczecinie. Wydawnictwo Uczelniane ZUT w Szczecinie
Tematy:
cell permeabilization
baker’s yeast
hydrogen peroxide
immobilization
biocatalyst
Opis:
Permeabilization is one of the effective tools, used to increase the accessibility of intracellular enzymes. Immobilization is one of the best approaches to reuse the enzyme. Present investigation use both techniques to obtain a biocatalyst with high catalase activity. At the beginning the isopropyl alcohol was used to permeabilize cells of baker’s yeast in order to maximize the catalase activity within the treated cells. Afterwards the permeabilized cells were immobilized in calcium alginate beads and this biocatalyst was used for the degradation of hydrogen peroxide to oxygen and water. The optimal sodium alginate concentration and cell mass concentration for immobilization process were determined. The temperature and pH for maximum decomposition of hydrogen peroxide were assigned and are 20°C and 7 respectively. Prepared biocatalyst allowed 3.35-times faster decomposition as compared to alginate beads with non permeabilized cells. The immobilized biocatalyst lost ca. 30% activity after ten cycles of repeated use in batch operations. Each cycles duration was 10 minutes. Permeabilization and subsequent immobilization of the yeast cells allowed them to be transformed into biocatalysts with an enhanced catalase activity, which can be successfully used to decompose hydrogen peroxide.
Źródło:
Polish Journal of Chemical Technology; 2019, 21, 2; 59-63
1509-8117
1899-4741
Pojawia się w:
Polish Journal of Chemical Technology
Dostawca treści:
Biblioteka Nauki
Artykuł
Wyświetlanie 1-15 z 36

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